KR840002011A - 경화성 폴리(옥사졸리돈 및 우레탄) 조성물 및 그 제법 - Google Patents

경화성 폴리(옥사졸리돈 및 우레탄) 조성물 및 그 제법 Download PDF

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KR840002011A
KR840002011A KR1019820004517A KR820004517A KR840002011A KR 840002011 A KR840002011 A KR 840002011A KR 1019820004517 A KR1019820004517 A KR 1019820004517A KR 820004517 A KR820004517 A KR 820004517A KR 840002011 A KR840002011 A KR 840002011A
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urethane
oxazolidone
composition
curable poly
same
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KR1019820004517A
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KR890003128B1 (ko
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레너드 디설보 앤터니 (외1)
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로버트 씨·술리반
스타우퍼 케미칼 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/58—Epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/58—Epoxy resins
    • C08G18/581—Reaction products of epoxy resins with less than equivalent amounts of compounds containing active hydrogen added before or during the reaction with the isocyanate component
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2120/00—Compositions for reaction injection moulding processes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Epoxy Resins (AREA)

Abstract

내용 없음

Description

경화성 폴리(옥사졸리돈 및 우레탄) 조성물 그 제법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (17)

  1. 폴리올, 무수산 및 디에폭시드를 단일단계(step)로 반응시킴으로써 2개의 말단에폭시드 그루우프 및 2개의 비-말단, 제2히드록시 그루우프를 함유하는 프리폴리머를 형성하는 경화성 폴리(옥사졸리돈 및 우레탄) 조성물 및 그 제법.
  2. 폴리올은 폴리에틸렌 글리코올, 폴리프로필렌 글리코올, 에틸렌 글리코올, 프로필렌 글리코올 및 폴리테트라메틸렌 글리코올로 구성된 그루우프에서 선택되는 특허청구의 범위 1기재의 경화성 폴리(옥사졸리돈 및 우레탄) 조성물 및 그 제법.
  3. 무수산은 방향족 및 지방족 무수산으로 구성된 그루우프에서 선택되는 특허청구의 범위 1기재의 경화성 폴리(옥사졸리돈 및 우레탄)조성물 및 그 제법.
  4. 디에폭시드는 디히드릭 단핵 및 융해환 페놀의 디글리시딜 에에테르, 노볼락수지의 디글리시딜 에에테르, 디시클로펜타디엔디옥사이드, 비닐시클로헥산디옥사이드, 디시클로헥실옥사이드 카르복실레이트 및 방향족 제1아민의 디글리시딜 유도체로 구성된 그루우프에서 선택되는 특허청구의 범위 1기재의 경화성 폴리(옥사졸리돈 및 우레탄)조성물 및 그 제법.
  5. 폴리올내의 히드록시 그루우프의 분자량은 2이며, 무수산의 분자량은 약 2를 초과하지 않고, 디에폭시드의 분자량은 무수산의 분자량보다 적지 않은 특허청구의 범위 1기재의 경화성 폴리(옥사졸리돈 및 우레탄)조성물 및 그 제법.
  6. 비-경화 프리폴리머 조성물은 특허청구의 범위 1∼5기재의 방법에 의하여 형성되며, 상기 조성물이 하기 구조식[Ⅰ] 및 [Ⅱ]의 혼합물인 경화성 폴리(옥사졸리돈 및 우레탄)조성물 및 그 제법.
    식중, R1∼R5는 독자적으로 탄소원자가 고유결합될 수 있는 그루우프이며, R이 R1∼R5와 동일하고 수소원자로 또한 포함한다.
  7. 폴리이소시안에이트와 2개의 달단에폭시그루우프 및 2개의 비-말단, 제2히드록시 그루우프를 가진 프리폴리머를 함유하는 프리폴리머 조성물로 이루어지는 옥사졸리돈 및 우레탄 결합을 함유하는 경화성 폴리(옥사졸리돈 및 우레탄 조성물) 및 그 제법.
  8. 프리폴리머 조성물은 특허청구의 범위 6 기재의 구조식[Ⅱ]의 프리폴리머를 함유하는 특허청구의 범위 7기재의 경화성 폴리(옥사졸리돈 및 우레탄)조성물 및 그 제법.
  9. 프리폴리머 조성물내에 특허청구의 범위 6 기재의 구조식 [Ⅰ]을 또한 포함하는 특허청구의 범위 7 또는 8 기재의 경화성 폴리(옥사졸리돈 및 우레탄) 조성물 및 그 제법.
  10. 특허청구의 범위 7∼8 기재의 조성물의 반응에 의하여 형성되는 경화성 폴리(옥사졸리돈 및 우레탄)조성물 및 그 제법.
  11. 특허청구의 범위 6 기재의 구조식[Ⅰ]의 프리폴리머를 또한 함유하는 특허청구의 범위 7∼8 기재의 조성물의 반응에 의하여 형성되는 경화성 폴리(옥사졸리돈 및 우레탄)조성물 및 그 제법.
  12. 옥사졸리돈 결합은 중합체등뼈내에 존재하고, 에스테르 결합에 의하여 서로 분리되며, 우레탄 결합은 중합체등뼈에 인접된 측쇄내에 존재하는 실질적으로 이소시안에이트 결합을 갖지 않은 반복 단위 내에 옥사졸리돈 및 우레탄 결합을 함유하여 이루어지는 경화성 폴리(옥사졸리돈 및 우레탄)조성물 및 그 제법.
  13. 옥사졸리돈 대 우레탄의 분자량은 약 90:10∼약 2:98의 범위내로 이루어지는 특허청구의 범위 12기재의 경화성폴리(옥사졸리돈 및 우레탄)조성물 및 그제법.
  14. 최소한 1개의 보강제를 포함하는 특허청구의 범위 12 기재의 경화성 폴리(옥사졸리돈 및 우레탄)조성물 및 그 제법.
  15. 하기 구조식Ⅲ을 가진 반복단위를 함유하는 특허청구의 범위 12기재의 경화성 폴리(옥사졸리돈 및 우레탄)조성물 및 그 제법.
    식 중, R 및 R1∼R5는 독자적으로 탄소원자가 공유결합될 수 있는 그루우프이며, R6∼R7은 R1∼R5와 동일하고 수소를 또한 포함한다.
  16. 하기 구조식[Ⅳ]의 반복단위를 또한 포함하는 특허청구의 범위 12 기재의 경화성 폴리(옥사졸리돈 및 우레탄) 조성물 및 그 제법.
    식 중, R 및 R1∼R3은 독자적으로 탄소원자가 공유결합될 수 있는 그 루우프이며, R4∼R9는 R∼R3과 동일하고 또한 수소를 포함한다.
  17. 반응 사출성형 방법으로 형성된 특허청구의 범위 12∼16 기재의 경화성 폴리(옥사졸리돈 및 우레탄)조성물 및 그 제법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR8204517A 1981-10-08 1982-10-07 열경화성 폴리(옥사졸리돈 및 우레탄)조성물 KR890003128B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US309737 1981-10-08
US06/309,737 US4386191A (en) 1981-10-08 1981-10-08 Compositions for forming poly(oxazolidone/urethane) thermosets and products therefrom
US309,737 1981-10-08

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KR840002011A true KR840002011A (ko) 1984-06-11
KR890003128B1 KR890003128B1 (ko) 1989-08-23

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KR8204517A KR890003128B1 (ko) 1981-10-08 1982-10-07 열경화성 폴리(옥사졸리돈 및 우레탄)조성물

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US (1) US4386191A (ko)
EP (1) EP0077174B1 (ko)
JP (1) JPS5871916A (ko)
KR (1) KR890003128B1 (ko)
CA (1) CA1204548A (ko)
CS (1) CS236685B2 (ko)
DD (1) DD208625A5 (ko)
DE (1) DE3279920D1 (ko)
ES (1) ES516313A0 (ko)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4504633A (en) * 1983-06-01 1985-03-12 Stauffer Chemical Company Modified poly(oxazolidone/urethane) compositions
US4605711A (en) * 1983-06-01 1986-08-12 Stauffer Chemical Company Modified poly(oxazolidone/urethane) compositions
CA1250987A (en) * 1983-10-17 1989-03-07 Gerald Fesman Flame retardant mixture for polyurethane materials
US4613660A (en) * 1985-02-19 1986-09-23 Ashland Oil, Inc. Polyol/polyepoxide/polyurethane adhesive
US4726868A (en) * 1985-02-19 1988-02-23 Ashland Oil, Inc. Polyol/polyepoxide/polyurethane adhesive
US4612156A (en) * 1985-02-26 1986-09-16 The Dow Chemical Company Solventless process for producing resinous materials
US4614786A (en) * 1985-08-12 1986-09-30 Ashland Oil Inc. Stable isocyanate/epoxide prepolymers and thermoset polyurethanes produced therefrom
JPS6259670A (ja) * 1985-09-09 1987-03-16 Kansai Paint Co Ltd 樹脂被覆用組成物
EP0305331A3 (de) * 1987-08-25 1991-05-08 Ciba-Geigy Ag Epoxidflexibilisatoren
JPH0436307A (ja) * 1990-06-01 1992-02-06 Yuka Shell Epoxy Kk 変性エポキシ樹脂及びエポキシ樹脂塗料
US5049281A (en) * 1990-12-06 1991-09-17 Exxon Research And Engineering Company Multi-block polymer comprising a first prepolymer, made by combining epoxy with diamine, chain extended with a compatible second prepolymer, the membrane made therefrom and its use in separations
US5039418A (en) * 1990-12-06 1991-08-13 Exxon Research And Engineering Company Membrane made from a multi-block polymer comprising an oxazolidone prepolymer chain extended with a compatible second prepolymer and its use in separations
US5039417A (en) * 1990-12-06 1991-08-13 Exxon Research And Engineering Company Membrane made from a multi-block polymer comprising an imide or amide-acid prepolymer chain extended with a compatible second prepolymer and its use in separations
US5221481A (en) * 1990-12-06 1993-06-22 Exxon Research And Engineering Company Multi-block polymer comprising an ester prepolymer, made by combining epoxy with polyester, chain extended with a compatible second prepolymer, the membrane made therefrom and its use for separations
US5130017A (en) * 1990-12-06 1992-07-14 Exxon Research And Engineering Company Multi-block polymer comprising a first amide acid prepolymer, chain extended with a compatible second prepolymer, the membrane made therefrom and its use in separations
US5039422A (en) * 1990-12-06 1991-08-13 Exxon Research And Engineering Company Multi-block polymer comprising a urea prepolymer chain extended with a compatible second prepolymer, the membrane made therefrom and its use in separations
US5237076A (en) * 1992-08-28 1993-08-17 The Aerospace Corporation Preparation of liquid crystalline di(alkoxyglycidyl) compounds, and their use in curable epoxide mixtures
EP2072556A1 (de) * 2007-12-17 2009-06-24 Sika Technology AG Verfahren zur Herstellung von hydroxyfunktionellen Polymeren, die hieraus gewinnbaren Isocyanatgruppen-endständigen Polyadditionsprodukte sowie deren Verwendung
US9637586B2 (en) * 2015-02-12 2017-05-02 Uop Llc High temperature resistant epoxy resins for producing hollow fiber membrane modules for high temperature gas separation applications
CN110144035A (zh) * 2019-05-24 2019-08-20 桂林电子科技大学 一种聚乙二醇接枝环氧树脂复合材料及其制备方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2891034A (en) * 1949-08-12 1959-06-16 Ciba Ltd Composition comprising a reaction product of a polyester and a polyepoxide and process for preparation
US3142657A (en) * 1949-08-12 1964-07-28 Ciba Ltd Elastic reaction product of a polyepoxide, a glycol, and an acid anhydride
DE1096600B (de) * 1955-12-19 1961-01-05 Minnesota Mining & Mfg Verfahren zur Herstellung ausgehaerteter Kunstharze durch Umsetzung von Epoxydgruppen aufweisenden Kunstharzen
US2947717A (en) * 1956-06-11 1960-08-02 Devoe & Raynolds Co Inc Epoxide resin compositions
BE563324A (ko) * 1956-12-20
US3299008A (en) * 1958-12-23 1967-01-17 Shell Oil Co Process for preparing flexible resinified products from polyepoxides and resulting products
US3294865A (en) * 1965-12-13 1966-12-27 Celanese Coatings Company Inc Curing of epoxy resins with polycarboxylates, polyhydric phenols or polyhydric alcohols and, as an accelerator, an alkali metal salt
US3507820A (en) * 1966-10-13 1970-04-21 Dainippon Ink & Chemicals Process for preparing a polyester compound from epoxy resin material obtained from 2-methylepichlorohydrin
CH487962A (de) * 1968-02-19 1970-03-31 Ciba Geigy In kristalline Kunststoffprodukte umwandelbare Formmassen auf Basis von Diepoxiden und Polyester-dicarbonsäuren
US3576903A (en) * 1968-04-29 1971-04-27 Minnesota Mining & Mfg Epoxy-terminated adducts of carboxy terminated polyesters and polyepoxides
JPS4940863B1 (ko) * 1970-01-22 1974-11-06
US3687897A (en) * 1970-06-22 1972-08-29 Dow Chemical Co Preparation of oxazolidinones by reacting an isocyanate, or isothiocyanate with an epoxide in the presence of a phosphonium halide acid, ester, or acid ester of the element c
JPS5133905B2 (ko) * 1972-04-14 1976-09-22

Also Published As

Publication number Publication date
EP0077174A3 (en) 1983-08-24
US4386191A (en) 1983-05-31
CS236685B2 (en) 1985-05-15
KR890003128B1 (ko) 1989-08-23
DD208625A5 (de) 1984-04-04
EP0077174B1 (en) 1989-09-06
CA1204548A (en) 1986-05-13
DE3279920D1 (en) 1989-10-12
ES8403955A1 (es) 1984-04-01
EP0077174A2 (en) 1983-04-20
ES516313A0 (es) 1984-04-01
JPS5871916A (ja) 1983-04-28

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