KR840001610A - 수용성 디스아조 화합물의 제조방법 - Google Patents

수용성 디스아조 화합물의 제조방법 Download PDF

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KR840001610A
KR840001610A KR1019820004022A KR820004022A KR840001610A KR 840001610 A KR840001610 A KR 840001610A KR 1019820004022 A KR1019820004022 A KR 1019820004022A KR 820004022 A KR820004022 A KR 820004022A KR 840001610 A KR840001610 A KR 840001610A
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formula
compound
group
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following general
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KR1019820004022A
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KR890002825B1 (ko
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후크스 헤르만
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하인리히 벡커·베르하르트 벡크
훽스트 아크티엔 게젤샤프트
베른하르트 벡크
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/02—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring
    • C09B62/04—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring to a triazine ring
    • C09B62/08—Azo dyes
    • C09B62/09—Disazo or polyazo dyes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
    • C07D251/40—Nitrogen atoms
    • C07D251/48—Two nitrogen atoms
    • C07D251/50—Two nitrogen atoms with a halogen atom attached to the third ring carbon atom
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
    • C09B62/4401—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring with two or more reactive groups at least one of them being directly attached to a heterocyclic system and at least one of them being directly attached to a non-heterocyclic system
    • C09B62/4403—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring with two or more reactive groups at least one of them being directly attached to a heterocyclic system and at least one of them being directly attached to a non-heterocyclic system the heterocyclic system being a triazine ring
    • C09B62/4411—Azo dyes
    • C09B62/4415—Disazo or polyazo dyes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
    • C09B62/503—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring the reactive group being an esterified or non-esterified hydroxyalkyl sulfonyl or mercaptoalkyl sulfonyl group, a quaternised or non-quaternised aminoalkyl sulfonyl group, a heterylmercapto alkyl sulfonyl group, a vinyl sulfonyl or a substituted vinyl sulfonyl group, or a thiophene-dioxide group
    • C09B62/507—Azo dyes
    • C09B62/513—Disazo or polyazo dyes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음

Description

수용성 디스아조 화합물의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (2)

  1. 다음 일반식(2)의 이중으로 커플링하는 화합물을 다음 일반식(3)의 방향족 아민의 디아조니움 화합물 당량과 커플링하거나, 또는 다음 일반식(4)의 아조 화합물을 20 내지 50℃ 및 pH 2.0 내지 7.0에서 다음 일반식(5)의 대칭성 디아미노 화합물 당량과 수성 매질 중에서 반응시켜 다음 일반식(1)의 디스아조 화합물을 제조함을 특징으로 하는, 일반식(Ⅰ)의 수용성 대칭 디스아조 화합물의 제조방법.
    상기 식에서 2번 반복되는 식 부분, 즉 D, R, X, Y, Z, M 및 m은 각 경우마다 서로 동일하며, 그룹 Z는 각 경우마다 에틸렌디옥시 치환기에 대해 오르토-또는 파라-위치에서 벤젠핵에 결합하고, 아미노 그룹-NH- 및 그룹 Z는 각 경우마다 서로에 대해 메타-위치에서 벤젠핵에 결합하며, D는 방향족 디아조 성분의 기이고, X는 수소원자 또는 다음에 정의하는 식 Z에 따른 그룹인 섬유-반응성 그룹이고, Y는 불소 원자 또는 염소원자이고, Z는 식 -SO2-CH=CH2또는 -SO2-CH2-CH2-R′(여기서 R′는 알칼리성 조건하에 수성 매질중에서 제거될 수 있는 치환기 또는 하이드록시그룹이다)의 그룹이며, M은 수소원자 또는 알칼리 금속 또는 알칼리성 토금속의 당량이고, R은 수소원자 또는 탄소수 1 내지 4의 알킬그룹이고, m은 1 또는 2이다.
  2. 다음 일반식(6)의 화합물을 5 내지 50℃ 및 pH 3.5 내지 7.0에서 다음 일반식(5)의 디아민 당량과 반응시키거나, 또는 다음 일반식(5)의 디아미노 화합물을 -10 내지 15℃ 및 pH 2.5 내지 5.5에서 2, 4, 6-트리플루오로-S-트리아진 또는 2, 4, 6-트리클로로-S-트리아진 2배 몰량과 수성 또는 수성-유기성 매질 중에서 반응시켜 다음 일반식(7)의 대칭성 화합물을 생성시킨 후 이 (7)의 화합물을 다음 일반식(8)의 아미노나프톨설폰산 당량과 축합시켜 다음 일반식(2)의 화합물을 제조함을 특징으로 하는, 다음 일반식(2)의 화합물의 제조방법.
    상기식에서, 2번 반복되는 식 부분, 즉 R, Y, Z, M 및 m은 각 경우마다 서로 동일하며, 그룹 Z는 각 경우마다 에틸렌디옥시 치환기에 대해 오르토-또는 파라-위치에서 벤젠 핵에 결합하고, 아미노 그룹-NH- 및 그룹 Z는 각 경우마다 서로에 대해 메타-위치에서 벤젠 핵에 결합하며, Y는 불소 원자 또는 염소원자이고, Z는 식 -SO2-CH=CH2또는 -SO2-CH2-CH2-R′(여기서 R′는 알칼리성 조건하에 수성 매질중에서 제거될 수 있는 치환기 또는 하이드록시 그룹이다)의 그룹이며, M은 수소원자 또는 알칼리 금속 또는 알칼리성 토금속의 당량이고, R은 수소원자 또는 탄소수 1 내지 4의 알킬그룹이고, m은 1 또는 2이다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR8204022A 1981-09-08 1982-09-06 수용성 디스아조 화합물의 제조방법 KR890002825B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DEP3135432.7 1981-09-08
DE19813135432 DE3135432A1 (de) 1981-09-08 1981-09-08 Wasserloesliche disazoverbindungen und wasserloesliche azokomponenten als deren vorprodukte sowie die herstellung und verwendung dieser verbindungen
DE31354327 1981-09-08

Publications (2)

Publication Number Publication Date
KR840001610A true KR840001610A (ko) 1984-05-16
KR890002825B1 KR890002825B1 (ko) 1989-08-04

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KR8204022A KR890002825B1 (ko) 1981-09-08 1982-09-06 수용성 디스아조 화합물의 제조방법

Country Status (7)

Country Link
EP (1) EP0076922B1 (ko)
JP (1) JPS5853959A (ko)
KR (1) KR890002825B1 (ko)
BR (1) BR8205228A (ko)
CS (1) CS233731B2 (ko)
DE (2) DE3135432A1 (ko)
IN (1) IN157311B (ko)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5175262A (en) * 1989-03-13 1992-12-29 Basf Aktiengesellschaft Doubled reactive dyes
DE3908073A1 (de) * 1989-03-13 1990-09-20 Basf Ag Verdoppelte reaktivfarbstoffe
DE4021727A1 (de) * 1990-07-07 1992-01-09 Basf Ag Verdoppelte reaktivfarbstoffe mit vier halogentriazinankern
IT1396202B1 (it) * 2009-10-13 2012-11-16 Everlight Usa Inc Nuova sostanza colorante reattiva con gruppo ponte dialchiletere.

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2748975A1 (de) * 1977-11-02 1979-05-03 Hoechst Ag Wasserloesliche farbstoffe, verfahren zu ihrer herstellung, deren verwendung als faserreaktive farbstoffe zum faerben und bedrucken von fasermaterialien und die mit ihnen gefaerbten fasermaterialien
DE2904124A1 (de) * 1979-02-03 1980-08-14 Hoechst Ag Wasserloesliche, faserreaktive disazofarbstoffe, verfahren zu deren herstellung und ihre verwendung zum faerben und bedrucken von hydroxygruppen- und carbonamidgruppenhaltigen fasermaterialien

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Publication number Publication date
JPH0424390B2 (ko) 1992-04-24
DE3135432A1 (de) 1983-03-24
IN157311B (ko) 1986-03-01
EP0076922B1 (de) 1985-06-19
JPS5853959A (ja) 1983-03-30
KR890002825B1 (ko) 1989-08-04
DE3264285D1 (en) 1985-07-25
EP0076922A1 (de) 1983-04-20
BR8205228A (pt) 1983-08-16
CS233731B2 (en) 1985-03-14

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