KR830004368A - 페로센 촉매화 탄성체의 제조방법 - Google Patents
페로센 촉매화 탄성체의 제조방법 Download PDFInfo
- Publication number
- KR830004368A KR830004368A KR1019800004614A KR800004614A KR830004368A KR 830004368 A KR830004368 A KR 830004368A KR 1019800004614 A KR1019800004614 A KR 1019800004614A KR 800004614 A KR800004614 A KR 800004614A KR 830004368 A KR830004368 A KR 830004368A
- Authority
- KR
- South Korea
- Prior art keywords
- units
- weight
- per
- parts
- structural formula
- Prior art date
Links
- 229920001971 elastomer Polymers 0.000 title 1
- 239000000806 elastomer Substances 0.000 title 1
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 title 1
- -1 dimethylsiloxane units Chemical group 0.000 claims 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 229910052717 sulfur Inorganic materials 0.000 claims 2
- 239000011593 sulfur Substances 0.000 claims 2
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 claims 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
- 239000000945 filler Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 150000001451 organic peroxides Chemical class 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 229920001296 polysiloxane Polymers 0.000 claims 1
- 125000003396 thiol group Chemical class [H]S* 0.000 claims 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 claims 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
- C08L83/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16H—GEARING
- F16H55/00—Elements with teeth or friction surfaces for conveying motion; Worms, pulleys or sheaves for gearing mechanisms
- F16H55/32—Friction members
- F16H55/36—Pulleys
- F16H55/48—Pulleys manufactured exclusively or in part of non-metallic material, e.g. plastics
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/18—Polysiloxanes containing silicon bound to oxygen-containing groups to alkoxy or aryloxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
- C08G77/28—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen sulfur-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/70—Siloxanes defined by use of the MDTQ nomenclature
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicon Polymers (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (1)
- 다음의 성분들을 혼합하여 제조한 산소 경화성 조성물.(A) 디메틸실옥산 단위, 하이드록시디메틸실옥산단위, 위트리메틸실옥산 단위, 구조식(1),(2),(3),(4),(5) 및 (6)의 단위들 중에서 선택된 단위들의 조합물로 주로 구성된 메르캅토 오가노폴리실록산 :상기 구조식에서;R은 탄소수 1 내지 3의 알킬기 또는 페닐기중에서 선택한 1가 그룹,R1은 탄소수 1 내지 3의 알킬기 중에서 선택한 1가그룹,n은 1 내지 4 중의 값이며메르캅토오가노폴리실옥산에는 분자 단위당 적어도 평균 2개의 황함유 실옥산이 있으며 메르캅토오가노폴리실옥산 내의 총 실옥산 단위의 수를 기준으로 하여 황-함유 단위가 10몰% 이하이며,(B) 다음 구조식(7),(8) 및 (9)중에서 선택한 단위의 조합에 의해 분자가 구성되며 분자단위당 적어도 3개의 디오가노실옥산 단위를 가지며 하이드록시 디메틸실옥산, 다음 구조식(10),(11),(12) 및 (13) 중에서 선택한 말단 보호단위가 있으며 분자당 적어도 2개의 지방족 불포화 실옥산 단위가 있는 지방족 불포화 폴리디오가노 실옥산;상기 구조식에서 R과 R1은 상기에서와 같으며,(C) 상기 (A)와 (B)의 중량을 합한 중량 100중량부당 0 내지 10중량부의 유기과산화물;(D) 상기 (A)와 (B)의 중량을 합한 중량 100중량부당 0 내지 200중량부의 충진제; 및(E) 상기 (A)와 (B)의 중량을 합한 100중량부당 0.01내지 5중량부의, 다음 구조식의 디사이클로펜타디에닐 철 화합물.여기서 R2와 R3는 서로 같거나 다른 기로서 수소, 저급(C1~C3)알킬, 아세틸, 카복실, 비닐 및 트리메틸실릴중에서 선택한 기이다.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/099,283 US4268655A (en) | 1979-12-03 | 1979-12-03 | Ferrocene catalyzed elastomer formation |
| US99,283 | 1979-12-03 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR830004368A true KR830004368A (ko) | 1983-07-09 |
| KR840000525B1 KR840000525B1 (ko) | 1984-04-17 |
Family
ID=22274190
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019800004614A KR840000525B1 (ko) | 1979-12-03 | 1980-12-03 | 페로센 촉매화 탄성체의 제조방법 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US4268655A (ko) |
| EP (1) | EP0030801B1 (ko) |
| JP (2) | JPS6030707B2 (ko) |
| KR (1) | KR840000525B1 (ko) |
| BR (1) | BR8008948A (ko) |
| CA (1) | CA1154195A (ko) |
| DD (1) | DD154998A5 (ko) |
| DE (1) | DE3066871D1 (ko) |
| ES (1) | ES497374A0 (ko) |
| WO (1) | WO1981001560A1 (ko) |
| ZA (1) | ZA807318B (ko) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4526954A (en) * | 1983-12-28 | 1985-07-02 | Union Carbide Corporation | Organosiloxane polymers and compositions containing same curable upon exposure to gaseous oxygen |
| GB8408621D0 (en) * | 1984-04-04 | 1984-05-16 | Dow Corning Ltd | Curable organopolysiloxane compositions |
| JP2713760B2 (ja) * | 1988-11-16 | 1998-02-16 | サンスター技研株式会社 | 高分子分散剤およびエポキシ樹脂組成物 |
| JP2849667B2 (ja) * | 1994-08-12 | 1999-01-20 | 法弘 中嶋 | プラスチック製滑車及びその製造方法 |
| US7582126B2 (en) | 2005-12-20 | 2009-09-01 | Arkema France | Fatty ester compositions with improved oxidative stability |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2868751A (en) * | 1956-01-18 | 1959-01-13 | Union Carbide Corp | Method of curing silicone water repellents with cyclopentadienyl transition element catalysts and aqueous compositions of same |
| FR1186850A (fr) * | 1956-03-12 | 1959-09-02 | Dow Corning | Dérivés triorganosilylferrocène |
| US2979482A (en) * | 1956-10-15 | 1961-04-11 | Dow Corning | Organopolysiloxanes stabilized with ferrocene and ferrocene derivatives |
| US3445419A (en) * | 1966-01-21 | 1969-05-20 | Dow Corning | Room temperature vulcanizable silicones |
| DE2008426A1 (ko) | 1969-02-27 | 1970-09-10 | ||
| US3655713A (en) * | 1970-07-13 | 1972-04-11 | Dow Corning | Silacyclopentane thiols and thiolates |
| US3816282A (en) * | 1971-04-15 | 1974-06-11 | Gen Electric | Radiation induced polymerization of polysiloxanes |
| US3873499A (en) * | 1973-11-29 | 1975-03-25 | Dow Corning | Fast curing mercaptoalkyl vinyl siloxane resins |
| US4039505A (en) * | 1976-03-03 | 1977-08-02 | Dow Corning Corporation | Siloxane elastomers containing sulfur and method of preparation |
| US4039504A (en) * | 1976-03-03 | 1977-08-02 | Dow Corning Corporation | Mercaptosiloxane elastomer and method of preparation |
| US4066603A (en) * | 1976-03-03 | 1978-01-03 | Dow Corning Corporation | Sulfur containing silicone elastomer and method of preparation |
| US4067027A (en) * | 1976-08-31 | 1978-01-03 | Asia American Industries Ltd. | Binocular telescope containing a camera |
| US4070328A (en) * | 1977-01-03 | 1978-01-24 | Dow Corning Corporation | Mercaptoorganopolysiloxanes cured to elastomers with peroxides and nitrogen compounds |
| US4070329A (en) * | 1977-01-03 | 1978-01-24 | Dow Corning Corporation | Siloxane elastomer prepared from mercaptoorg anopolysiloxanes |
-
1979
- 1979-12-03 US US06/099,283 patent/US4268655A/en not_active Expired - Lifetime
-
1980
- 1980-11-12 BR BR8008948A patent/BR8008948A/pt unknown
- 1980-11-12 JP JP81500317A patent/JPS6030707B2/ja not_active Expired
- 1980-11-12 WO PCT/US1980/001521 patent/WO1981001560A1/en unknown
- 1980-11-12 JP JP81500317A patent/JPS56501609A/ja active Pending
- 1980-11-13 CA CA000364584A patent/CA1154195A/en not_active Expired
- 1980-11-20 DE DE8080304155T patent/DE3066871D1/de not_active Expired
- 1980-11-20 EP EP80304155A patent/EP0030801B1/en not_active Expired
- 1980-11-24 ZA ZA00807318A patent/ZA807318B/xx unknown
- 1980-12-02 ES ES497374A patent/ES497374A0/es active Granted
- 1980-12-03 KR KR1019800004614A patent/KR840000525B1/ko active IP Right Grant
- 1980-12-03 DD DD80225685A patent/DD154998A5/de unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BR8008948A (pt) | 1981-10-20 |
| EP0030801A3 (en) | 1981-10-07 |
| ES8205247A1 (es) | 1982-06-01 |
| JPS56501609A (ko) | 1981-11-05 |
| DE3066871D1 (en) | 1984-04-12 |
| ES497374A0 (es) | 1982-06-01 |
| JPS6030707B2 (ja) | 1985-07-18 |
| EP0030801B1 (en) | 1984-03-07 |
| CA1154195A (en) | 1983-09-20 |
| EP0030801A2 (en) | 1981-06-24 |
| JPS56500069A (ko) | 1981-01-22 |
| KR840000525B1 (ko) | 1984-04-17 |
| ZA807318B (en) | 1981-09-30 |
| WO1981001560A1 (en) | 1981-06-11 |
| DD154998A5 (de) | 1982-05-05 |
| US4268655A (en) | 1981-05-19 |
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