KR830004366A - 열-경화성 중합체 - Google Patents

열-경화성 중합체 Download PDF

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Publication number
KR830004366A
KR830004366A KR1019800004904A KR800004904A KR830004366A KR 830004366 A KR830004366 A KR 830004366A KR 1019800004904 A KR1019800004904 A KR 1019800004904A KR 800004904 A KR800004904 A KR 800004904A KR 830004366 A KR830004366 A KR 830004366A
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KR
South Korea
Prior art keywords
weight
parts
copolymer
structural formula
alkylene
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Application number
KR1019800004904A
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KR840001677B1 (ko
Inventor
죤 케오프 마이클
Original Assignee
에드워드 지. 그라이어
유니온 카바이드 코포레이션
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Application filed by 에드워드 지. 그라이어, 유니온 카바이드 코포레이션 filed Critical 에드워드 지. 그라이어
Publication of KR830004366A publication Critical patent/KR830004366A/ko
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Publication of KR840001677B1 publication Critical patent/KR840001677B1/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08—Homopolymers or copolymers of acrylic acid esters
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/447—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from acrylic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0025—Crosslinking or vulcanising agents; including accelerators

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

내용 없음

Description

열-경화성 중합체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (1)

  1. (1) 알킬렌-알킬 아크릴레이트 공중합체, 상기 공중합체 100중량부 기준으로 구조식 R1-R2-R3인 0.1내지 10중량부의 이 작용성 화합물, 상기 공중합체 100중량부 기준으로 0.1 내지 10중량부의 오가노 티타네이트를 혼합하고 이 혼합물을 공중합체의 용융온도의 약 200℃ 사이의 온도에서 가열시킴을 특징으로 하는 열-경화성 중합체의 제조방법.
    상기 구조식에서
    R1및 R3는 각기 -OH, -SH 또는에서 선택되고(여기에서 R4는 탄소수 1 내지 20의 탄화수소임),
    R2는 아릴이 아닌 기로 말단화된 2가유기기이다.
    (2) 구조식 R1-R2-R3의 이작용성 화합물을 상기 이작용성 화합물 100중량부 기준으로 5 내지 1000중량부의 오가노티타네이트와 25 내지 250℃의 온도에서 반응시키고 상기 단계의 반응생성물에서 얻어진 휘발물질을 제거한 후 이 휘발물질이 제거된 반응생성물을 알킬렌-알킬 아크릴레이트 공중합체와 혼합시킴을 특징으로 하는 열-경화성 중합체의 제조방법.
    상기 구조식에서
    R1및 R3는 각기 -OH, -SH 또는에서 선택되고(여기에서 R4는 탄소수 1 내지 20의 탄화수소임)
    R2는 아릴이 아닌기로 말단화된 2가유기기이다.
    (3) 알킬렌-알킬 아크릴레이트 공중합체, 상기 공중합체 100중량부 기준으로 구조식 R1-R2-R3인 0 내지 10중량부의 이작용성 화합물, 상기 공중합체 100중량부 기준으로 0.1 내지 10중량부의 티탄킬레이트를 혼합시킴을 특징으로 하는 열-경화성 중합체의 제조방법.
    상기 구조식에서
    R1및 R3는 각기 -OH, -SH 또는에서 선택되고(여기에서 R4는 탄소수 1 내지 20의 탄화수소임)
    R2는 아릴이 아닌기로 말단화된 2가 유기기이다.
    (4) 구조식 R1-R2-R3인 이작용성 화합물을 상기 작용성 화합물 100중량부 기준으로 5 내지 1000중량부의 오가노티타네이트와 25 내지 250℃의 온도에서 반응시키고 상기 단계의 반응생성물에서 얻어진 휘발물질을 제거한 후 휘발물질이 제거된 생성물을 불활성 중합체와 혼합시킴을 특징으로 하여 알킬렌-알킬 알크릴레이트 공중합체 가교결합에 사용되는 가교결합제의 제조방법.
    상기 구조식에서
    R1및 R3는 각기 -OH, -SH 또는에서 선택되고(여기에서 R4는 탄소수 1 내지 20의 탄화수소임)
    R2는 아릴이 아닌기로 말단화된 2가 유기기이다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019800004904A 1979-12-26 1980-12-23 열-경화성 중합체의 제조방법 Expired KR840001677B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/106,502 US4351926A (en) 1979-12-26 1979-12-26 Heat curable polymer
US106,502 1993-08-13

Publications (2)

Publication Number Publication Date
KR830004366A true KR830004366A (ko) 1983-07-09
KR840001677B1 KR840001677B1 (ko) 1984-10-13

Family

ID=22311753

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019800004904A Expired KR840001677B1 (ko) 1979-12-26 1980-12-23 열-경화성 중합체의 제조방법

Country Status (9)

Country Link
US (1) US4351926A (ko)
EP (1) EP0032587A3 (ko)
JP (1) JPS6025041B2 (ko)
KR (1) KR840001677B1 (ko)
AU (1) AU539523B2 (ko)
BR (1) BR8008418A (ko)
CA (1) CA1157032A (ko)
ES (4) ES8205822A1 (ko)
IN (1) IN155409B (ko)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4452937A (en) * 1980-12-22 1984-06-05 Union Carbide Corporation Ethylene polymer compositions stabilized against water treeing and electrical treeing by an organo titanium chelate; and the use thereof as insulation about electrical conductors
FR2571376B1 (fr) * 1984-10-10 1986-10-03 Atochem Procede de reticulation de copolymeres ethylene-ester d'hydroxyalkyle
CN114292405B (zh) * 2021-12-31 2023-02-10 清远华湾材料研究院有限公司 一种聚葡萄糖乙基丙烯酸酯及其制备方法与应用

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3491075A (en) * 1965-10-13 1970-01-20 Union Oil Co Crosslinking of polymers having dependent ester groups with polyvalent metal alkoxides
JPS5247486B2 (ko) * 1972-04-20 1977-12-02
US3779963A (en) * 1972-06-30 1973-12-18 Union Carbide Corp Process for introducing functional substituents onto a polymer backbone using mild oxidative conditions
US4020214A (en) * 1973-06-21 1977-04-26 General Electric Company Method of making an insulated electrical conductor using pressureless curing of filled ethylene containing polymeric compositions, and an insulated conductor formed thereby
US3969434A (en) * 1973-10-29 1976-07-13 E. I. Du Pont De Nemours And Company Process for preparing ionically crosslinked copolymers
US4012567A (en) * 1975-03-12 1977-03-15 Uniroyal Inc. Titanate ester cure of unsaturated elastomers
JPS5223673B2 (ko) * 1975-03-18 1977-06-25
AU1359976A (en) * 1975-05-07 1977-11-10 Union Carbide Corp Electrical conductors
US4005247A (en) * 1975-10-30 1977-01-25 Ashland Oil, Inc. Pressure sensitive adhesive compositions
US4185051A (en) * 1977-12-22 1980-01-22 Monsanto Company Pressure sensitive adhesive compositions containing a polymetaloxane
NZ190052A (en) * 1978-03-31 1980-11-14 Union Carbide Corp Water-curable silane-modified alkylene alkylacrylate copolymers
US4292231A (en) * 1980-02-26 1981-09-29 Ashland Oil, Inc. Pressure sensitive adhesion compositions

Also Published As

Publication number Publication date
ES508798A0 (es) 1983-03-16
CA1157032A (en) 1983-11-15
JPS5698253A (en) 1981-08-07
ES8304168A1 (es) 1983-03-16
ES498095A0 (es) 1982-07-01
IN155409B (ko) 1985-01-26
JPS6025041B2 (ja) 1985-06-15
KR840001677B1 (ko) 1984-10-13
US4351926A (en) 1982-09-28
EP0032587A2 (en) 1981-07-29
AU539523B2 (en) 1984-10-04
AU6560980A (en) 1981-07-02
EP0032587A3 (en) 1982-01-13
ES508797A0 (es) 1983-03-16
ES8205822A1 (es) 1982-07-01
ES508799A0 (es) 1983-06-01
BR8008418A (pt) 1981-07-14
ES8306380A1 (es) 1983-06-01
ES8304167A1 (es) 1983-03-16

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Patent event code: PA01091R01D

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Patent event date: 19801223

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Patent event date: 19841220