KR830004160A - 안정된 황산티타늄 용액의 제조방법 - Google Patents
안정된 황산티타늄 용액의 제조방법 Download PDFInfo
- Publication number
- KR830004160A KR830004160A KR1019800004640A KR800004640A KR830004160A KR 830004160 A KR830004160 A KR 830004160A KR 1019800004640 A KR1019800004640 A KR 1019800004640A KR 800004640 A KR800004640 A KR 800004640A KR 830004160 A KR830004160 A KR 830004160A
- Authority
- KR
- South Korea
- Prior art keywords
- titanium
- solution
- sulfate
- titanium dioxide
- reaction mixture
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/04—Oxides; Hydroxides
- C01G23/047—Titanium dioxide
- C01G23/053—Producing by wet processes, e.g. hydrolysing titanium salts
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/12—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08
- C22B34/1236—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining titanium or titanium compounds from ores or scrap by wet processes, e.g. by leaching
- C22B34/124—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining titanium or titanium compounds from ores or scrap by wet processes, e.g. by leaching using acidic solutions or liquors
- C22B34/125—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining titanium or titanium compounds from ores or scrap by wet processes, e.g. by leaching using acidic solutions or liquors containing a sulfur ion as active agent
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/008—Titanium- and titanyl sulfate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
도면은 황산제1철1수화물의 침전을 방지하며, 티타늄 함유물질을 숙성시켜 이산화티타늄을 제조하는 본 발명제법의 흐름설명도(Flow Diagram)이다.
Claims (2)
- (1) 반응에 필요한 물질의 화학당량보다 약 10%내지 약 400%과잉량의 티타늄 함유물질을 황산과 반응시켜, 약 140℃이하의 온도에서 용액의 총중량기준으로 약 25%내지 약 60중량%농도를 갖는 희석 황산용액의 황산티타늄을 제조하고(2) 수득한 반응혼합물을 황산티타늄침전이 발생하지 않도록 약 110℃이하 온도로 냉각하여 용해 황산티타늄을 함유하는 반응혼합물을 제조하며(3) 황산티타늄을 함유하는 반응혼합물을 물, 황산티타늄 용액 및 이의 혼합물로 구성되는 군으로부터 선정한 충분한 양의 희석제로 희석시켜, 불용성 고형물을 제거하면, 철/이산화티타늄 중량비율 약 0.5내지 1.2 : 1,0; 이산화티타늄함량 약 120내지 약 180g/l; 비중 약 1.4내지 1.8과 활성황산/이산화티타늄 몰비율 약 1.4내지 1.9 : 1의 특성을 갖는 반응혼합물을 제조하고(4) 미용해 고형물을 분리하는 것을 특징으로 하는 안정된 황산티타늄용액을 제조하는 방법.
- (1) 반응에 필요한 물질의 화학당량보다 약 10%내지 약 400%과잉량의 티타늄 함유물질을 황산과 반응시켜, 약 140℃이하의 온도에서 용액의 총중량기준으로 약 25%내지 약 60중량%농도를 갖는 희석 황산용액의 황산티타늄을 제조하고,(2) 수득한 반응혼합물을 황산티타늄침전이 발생하지 않도록 약 110℃이하 온도로 냉각하여 용해황산티타늄을 함유하는 반응혼합물을 제조하며(3) 황산티타늄을 함유하는 반응혼합물을 물, 황산티타늄용액 및 이의 혼합물로 구성되는 군으로부터 선정한 충분한 양의 희석제로 희석시켜, 불용성 고형물을 제거하면, 철/이산화티타늄 중량비율 약 0.7내지 1.1 : 1,0; 이산화티타늄함량 약 120내지 약 180g/l; 비중 약 1.4내지 1.8과 활성황산/이산화티타늄 몰비율 약 1.4내지 1.9 : 1의 특성을 갖는 반응혼합물을 제조하고,(4) 미용해고형물을 반응혼합물로부터 분리하여 황산철 및 황산티타늄용액을 제조하며,(5) 황산철 및 황산티타늄용액에서 황산철을 분리하여 황산티타늄용액을 제조하고,(6) 이 황산티타늄용액을 가수분해시켜 이산화티타늄수화물과 폐황산용액을 제조하여(7) 여기서 얻은 이산화티타늄수화물을 가소시켜 이산화티타늄으로 만들고, 또(8) 이산화티타늄을 회수하는 것을 특징으로 하는 황산티타늄용액으로부터 이산화티타늄을 제조하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/188,805 US4275041A (en) | 1980-09-19 | 1980-09-19 | Process for manufacturing a stable titanyl sulfate solution |
| US188805 | 1980-09-19 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR830004160A true KR830004160A (ko) | 1983-07-06 |
| KR830002426B1 KR830002426B1 (ko) | 1983-10-26 |
Family
ID=22694595
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019800004640A KR830002426B1 (ko) | 1980-09-19 | 1980-12-05 | 안정한 황산티타늄 용액의 제조방법 |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US4275041A (ko) |
| JP (1) | JPS5756323A (ko) |
| KR (1) | KR830002426B1 (ko) |
| AU (1) | AU540040B2 (ko) |
| BE (1) | BE886899A (ko) |
| BR (1) | BR8008525A (ko) |
| CA (1) | CA1158414A (ko) |
| DE (1) | DE3045185C2 (ko) |
| ES (1) | ES497252A0 (ko) |
| FI (1) | FI803728L (ko) |
| FR (1) | FR2490618A1 (ko) |
| GB (1) | GB2084121B (ko) |
| IN (1) | IN155017B (ko) |
| IT (1) | IT1141121B (ko) |
| NL (1) | NL8006505A (ko) |
| PL (2) | PL133082B1 (ko) |
| YU (2) | YU314980A (ko) |
| ZA (1) | ZA807481B (ko) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4505886A (en) * | 1983-07-01 | 1985-03-19 | Nl Industries, Inc. | Process for preparing high quality titanium dioxide |
| JPH02144032A (ja) * | 1988-11-25 | 1990-06-01 | Matsushita Electric Ind Co Ltd | 充電式電気掃除機 |
| ITVR20120236A1 (it) * | 2012-12-05 | 2014-06-06 | Michelangelo Manfrini | Concia eco-compatibile con titanio (iv) ossisolfato. |
| WO2019204556A1 (en) * | 2018-04-19 | 2019-10-24 | Graver Technologies Llc | Titania-based treatment solution and method of promoting precipitation and removal of heavy metals from an aqueous source |
| CN113713591A (zh) * | 2021-08-20 | 2021-11-30 | 淄博火炬能源有限责任公司 | 高含铜量高挥发性废酸处理系统及操作方法 |
| CN115536061B (zh) * | 2022-11-04 | 2024-01-26 | 攀枝花东方钛业有限公司 | 一种低品位钛矿制备硫酸氧钛的方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1338473A (en) * | 1919-02-04 | 1920-04-27 | Peter Spence & Sons Ltd | Preparation of titanium compounds |
| US1504671A (en) * | 1923-07-17 | 1924-08-12 | Blumenfeld Joseph | Titanium compound |
| US1504669A (en) * | 1924-04-28 | 1924-08-12 | Blumenfeld Joseph | Titanium compound |
| US1504670A (en) * | 1924-04-28 | 1924-08-12 | Blumenfeld Joseph | Titanium compound |
| FR623718A (fr) * | 1926-08-03 | 1927-06-29 | Titan Co A S | Procédé pour dissoudre des matières titanifères dans des acides |
| US2617724A (en) * | 1947-10-04 | 1952-11-11 | Nat Lead Co | Process for dissolution of titaniferous materials |
| US3071439A (en) * | 1960-01-27 | 1963-01-01 | Dow Unquinesa S A | Method for the preparation of titanium hydrate |
| DE1592406B2 (de) * | 1967-09-25 | 1978-12-14 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Titandioxydpigmenten mit hohem Weißgrad |
| BE754202A (fr) * | 1969-07-31 | 1970-12-31 | Titangesellschaft Mbg | Procede pour extraire le fer de minerais titaniferes |
| CA923711A (en) * | 1969-09-12 | 1973-04-03 | Ishihara Sangyo Kaisha | Titanium dioxide concentrate and its manufacturing process |
-
1980
- 1980-09-19 US US06/188,805 patent/US4275041A/en not_active Expired - Lifetime
- 1980-11-25 CA CA000365443A patent/CA1158414A/en not_active Expired
- 1980-11-27 IN IN845/DEL/80A patent/IN155017B/en unknown
- 1980-11-28 ES ES497252A patent/ES497252A0/es active Granted
- 1980-11-28 NL NL8006505A patent/NL8006505A/nl not_active Application Discontinuation
- 1980-11-28 GB GB8038295A patent/GB2084121B/en not_active Expired
- 1980-12-01 ZA ZA00807481A patent/ZA807481B/xx unknown
- 1980-12-01 FI FI803728A patent/FI803728L/fi not_active Application Discontinuation
- 1980-12-01 JP JP55168143A patent/JPS5756323A/ja active Granted
- 1980-12-01 DE DE3045185A patent/DE3045185C2/de not_active Expired
- 1980-12-03 AU AU65027/80A patent/AU540040B2/en not_active Ceased
- 1980-12-05 IT IT26475/80A patent/IT1141121B/it active
- 1980-12-05 KR KR1019800004640A patent/KR830002426B1/ko active
- 1980-12-11 PL PL1980228394A patent/PL133082B1/pl unknown
- 1980-12-11 PL PL1980243538A patent/PL133743B1/pl unknown
- 1980-12-15 YU YU03149/80A patent/YU314980A/xx unknown
- 1980-12-22 FR FR8027258A patent/FR2490618A1/fr active Granted
- 1980-12-29 BE BE0/203352A patent/BE886899A/fr not_active IP Right Cessation
- 1980-12-29 BR BR8008525A patent/BR8008525A/pt unknown
-
1983
- 1983-01-13 YU YU00071/83A patent/YU7183A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ZA807481B (en) | 1981-11-25 |
| YU314980A (en) | 1983-04-30 |
| IN155017B (ko) | 1984-12-22 |
| PL133082B1 (en) | 1985-05-31 |
| ES8201933A1 (es) | 1982-01-01 |
| YU7183A (en) | 1986-04-30 |
| DE3045185A1 (de) | 1982-04-01 |
| BE886899A (fr) | 1981-04-16 |
| GB2084121B (en) | 1984-06-27 |
| ES497252A0 (es) | 1982-01-01 |
| CA1158414A (en) | 1983-12-13 |
| JPS6127327B2 (ko) | 1986-06-25 |
| FI803728L (fi) | 1982-03-20 |
| AU6502780A (en) | 1982-06-24 |
| BR8008525A (pt) | 1982-08-10 |
| NL8006505A (nl) | 1982-04-16 |
| GB2084121A (en) | 1982-04-07 |
| IT1141121B (it) | 1986-10-01 |
| FR2490618B1 (ko) | 1983-10-14 |
| PL133743B1 (en) | 1985-06-29 |
| JPS5756323A (en) | 1982-04-03 |
| AU540040B2 (en) | 1984-11-01 |
| IT8026475A0 (it) | 1980-12-05 |
| KR830002426B1 (ko) | 1983-10-26 |
| FR2490618A1 (fr) | 1982-03-26 |
| DE3045185C2 (de) | 1986-04-10 |
| US4275041A (en) | 1981-06-23 |
| PL228394A1 (ko) | 1982-04-26 |
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