KR20220010566A - Imprint apparatus, and method of manufacturing article - Google Patents

Abstract

The present invention provides an imprint device advantageous for reducing a use amount of air and gas to be substituted between a substrate and a die. Provided is the imprint device for forming a pattern on a substrate by making an imprint material on the substrate in contact with a pattern unit of the die. The imprint device includes an arrangement unit for arranging the imprint material in a shot region of the substrate; a moving mechanism for moving the substrate; and a supply unit for supplying gas to a space between the die and the substrate from a supply port provided between the arrangement unit and the pattern unit of the die. The imprint device supplies gas to the space by the supply port and makes, compared to a gap between the die and the substrate at the supply unit, a gap therebetween at the opposite side narrower with respect to at least one of the die and the substrate, in a predetermined timing when the shot region moves from an arrangement position where the arrangement of the imprint material is performed by the arrangement unit to an imprint position where the contact is performed, according to the movement of the substrate by the moving mechanism.

Description

IMPRINT APPARATUS, AND METHOD OF MANUFACTURING ARTICLE

The present invention relates to an imprint apparatus and a method of manufacturing an article.

As one of the lithography techniques for manufacturing articles, such as a semiconductor device, the imprint technique is put to practical use. In an imprint apparatus, in order to form a pattern by bringing a mold into contact with an imprint material on a substrate, in principle, pattern defects are more likely to occur than in conventional exposure apparatuses, and reduction of this defect is a problem. Specifically, when the mold and the imprint material on the substrate are brought into contact, the curing reaction of the imprint material becomes difficult to proceed under the influence of oxygen in the atmosphere therebetween, which may cause defects in the transferred pattern. As this solution, a method of waiting until the residual gas dissolves, diffuses, or permeates through the imprint material or the mold and disappears can be considered.

In order to solve this problem, the air between the substrate and the mold is replaced with a gas with high permeability or solubility to the mold or imprint material, such as helium or carbon dioxide, and the bubble is permeated through the mold or imprint material to rapidly increase the volume of the bubble. A method of reducing it has been proposed. However, the gas used here is generally expensive, and there is a problem that the warming coefficient is also high, and there is a demand to reduce the amount of such gas used.

Japanese Patent Laid-Open No. 2013-229448

In the method of Patent Document 1, gas is injected into the shot region while the substrate is moved so that the shot region of the substrate supplied with the imprint material is positioned under the mold, and the space between the pattern portion of the mold and the substrate is accompanied by the movement of the substrate. Gas is introduced into the (imprint space). However, the gas that has once flown into the space continues to move together with the substrate while maintaining the flow width, and flows out from the imprint space. Therefore, in order to fill the imprint space with gas, it is necessary to enclose the gas so that the flow width of the gas flowing into the imprint space is equal to or greater than the width of the pattern portion, so that the amount of gas cannot be reduced.

An object of the present invention is to provide an imprint apparatus which is advantageous in reducing the amount of gas to be substituted and air between, for example, a substrate and a mold.

According to one aspect of the present invention, there is provided an imprint apparatus for forming a pattern on the substrate by contacting an imprint material on a substrate with a pattern portion of a mold, an arrangement unit for arranging the imprint material in a shot region of the substrate; a moving mechanism for moving; and a supply unit for supplying a gas to a space between the mold and the substrate from a supply port provided between the arranging unit and the pattern portion of the die; Accordingly, gas is supplied to the space by the supply unit at a predetermined timing while the shot area moves from the arrangement position where the imprint material is arranged by the arrangement unit to the imprint position where the contact is made, and and at least one of the substrates is inclined so that the distance between the mold on the supply side and the substrate on the opposite side is narrowed.

Advantageous Effects of Invention According to the present invention, it is possible to provide an imprint apparatus advantageous for reducing, for example, the amount of air between the substrate and the mold and the amount of gas to be substituted.

BRIEF DESCRIPTION OF THE DRAWINGS It is a schematic sectional drawing which shows the structure of the imprint apparatus in embodiment.
Fig. 2 is a schematic plan view showing the configuration of an imprint apparatus in the embodiment;
It is a figure which shows the flow distribution of gas in the plane of a die|mold.
Fig. 4 is a schematic cross-sectional view showing the configuration of an imprint apparatus in the embodiment;
Fig. 5 is a schematic cross-sectional view showing the configuration of an imprint apparatus in the embodiment;
Fig. 6 is a schematic cross-sectional view showing the configuration of an imprint apparatus in the embodiment;
It is a figure explaining the manufacturing method of the article in embodiment.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings. In addition, the following embodiment only shows the specific example of implementation of this invention, and this invention is not limited to the following embodiment. In addition, it cannot be said that all combinations of features described in the following embodiments are essential for solving the problems of the present invention.

<First embodiment>

First, an outline of the imprint apparatus according to the embodiment will be described. The imprint apparatus is an apparatus for forming a pattern of a cured product onto which the concavo-convex pattern of the die is transferred by bringing an imprint material supplied on a substrate into contact with a die to provide hardening energy to the imprint material.

As the imprint material, a curable composition (which may be referred to as an uncured resin) that is cured by applying curing energy is used. As the curing energy, electromagnetic waves, heat, or the like can be used. The electromagnetic wave may be, for example, light whose wavelength is selected from the range of 10 nm or more and 1 mm or less, such as infrared rays, visible rays, and ultraviolet rays. The curable composition may be a composition that is cured by irradiation with light or by heating. Among these, the photocurable composition hardened|cured by irradiation of light contains a polymeric compound and a photoinitiator at least, and may contain a nonpolymerizable compound or a solvent further as needed. The nonpolymerizable compound is at least one selected from the group consisting of a sensitizer, a hydrogen donor, an internal addition type mold release agent, a surfactant, an antioxidant, and a polymer component. The imprint material may be disposed on the substrate in a droplet shape or an island shape or a film shape formed by a plurality of droplets by an imprint material supply device (corresponding to a dispenser 80 to be described later). The viscosity (viscosity at 25°C) of the imprint material may be, for example, 1 mPa·s or more and 100 mPa·s or less. As the material of the substrate, for example, glass, ceramics, metal, semiconductor, resin and the like can be used. If necessary, a member made of a material different from that of the substrate may be provided on the surface of the substrate. The substrate is, for example, a silicon wafer, a compound semiconductor wafer, or quartz glass.

1 and 2 are schematic cross-sectional views and schematic plan views, respectively, showing the configuration of the imprint apparatus 200 in the present embodiment. In the present embodiment, the imprint apparatus 200 employs a photocuring method of curing the imprint material by irradiation of light (ultraviolet rays), but is not limited thereto, and for example, curing the imprint material by heat input. A thermosetting method can also be employ|adopted. In each figure below, the Z axis in the XYZ coordinate system is taken in a direction parallel to the light irradiation axis to the mold, and the X and Y axes are taken in directions orthogonal to each other in a plane perpendicular to the Z axis.

The illumination optical system 120 irradiates the mold 50 with ultraviolet rays from the light source 130 in the imprint process. As the light source 130 , for example, a halogen lamp that generates ultraviolet light is used. The illumination optical system 120 may include an optical element such as a lens, an aperture, a shutter for switching between irradiation and light blocking, and the like.

As shown in Fig. 2, the mold 50 has, for example, a substantially rectangular shape and a pattern portion 40 (mesa portion) in which a predetermined pattern (for example, a circuit pattern) is formed in a three-dimensional shape. have The material of the mold 50 is a material that can transmit ultraviolet rays, such as quartz glass.

The imprint head 100 functions as a mold holding part that holds and moves the mold 50 . The imprint head 100 may include a mold chuck 60 that attracts and holds the mold 50 by vacuum suction or electrostatic suction. In addition, the imprint head 100 may have a mold driving mechanism 101 that drives the mold chuck 60 in the Z-axis direction to bring the mold 50 into contact with the imprint material 30 on the substrate 20 . . The die drive mechanism 101 also has a function to adjust the position of the die 50 in the XY direction or the θ direction (rotational direction around the Z axis), and a tilt function to adjust the inclination of the die 50. have. A linear motor, an air cylinder, etc. can be employ|adopted for the actuator of this mold|type drive mechanism 101. As shown in FIG.

The dispenser 80 (placement unit) arranges (applies or supplies) the imprint material 30 on the substrate 20 . The illumination optical system 120 , the imprint head 100 , and the dispenser 80 are supported by the support 110 .

The substrate stage 10 and the substrate chuck 15 function as a substrate holding portion that holds and moves the substrate. The substrate chuck 15 is fixed on the substrate stage 10 . A number of holes are provided in the upper surface of the substrate chuck 15 , and the gas on the upper surface of the substrate chuck 15 is discharged by a vacuum pump (not shown) through these holes. The substrate 20 is disposed so that its rear surface is in contact with the upper surface of the substrate chuck 15 , and gas between the rear surface of the substrate 20 and the upper surface of the substrate chuck 15 is discharged by a vacuum pump, whereby the substrate 20 is ) is adsorbed and held by the substrate chuck 15 .

The substrate stage 10 includes a moving mechanism 10a that moves the substrate stage 10 (that is, the substrate 20 ) in the XY direction on the stage surface plate 11 . The moving mechanism 10a may further have an adjustment function for adjusting the position in the Z-axis direction or the position in the θ direction, and a tilt function for adjusting the inclination of the substrate 20 . The moving mechanism 10a is configured such that the mold 50 and the imprint material 30 on the substrate 20 are in contact with the shot region of the substrate 20 at the placement position where the imprint material is placed by the dispenser 80 . The substrate 20 may be moved to move to the imprint position. Further, a purge plate 25 is provided so as to surround the outer periphery of the substrate 20 , and is held by the substrate stage 10 . The purge plate 25 has a surface substantially flush with the substrate 20 disposed on the substrate chuck 15 . The purge plate 25 may be driven in the in-plane direction of the substrate.

The control unit 1 controls each unit in the imprint apparatus 200 . The control unit 1 may be realized by a computer device including a CPU 1a or a memory 1b.

The control unit 1 controls the imprint process as follows, for example. First, the control unit 1 controls the moving mechanism 10a, and conveys the substrate 20 so that the shot region of the substrate 20 comes to a position where the imprint material is placed by the dispenser 80 . Next, the control unit 1 controls the dispenser 80 to place the imprint material 30 in the shot area located at the arrangement position. Then, the control unit 1 controls the moving mechanism 10a, and conveys the substrate 20 so that the shot region of the substrate 20 comes to the imprint position. Then, the control unit 1 controls the imprint head 100 to lower the mold 50 to contact the imprint material 30 on the shot area. By this contact, the imprint material 30 flows in (fills) into the grooves carved into the pattern portion 40 . In this state, the control unit 1 generates ultraviolet light to the light source 130 . Ultraviolet light from the light source 130 passes through the illumination optical system 120 , passes through the mold 50 , and is incident on the imprint material 30 . In this way, the imprint material 30 irradiated with ultraviolet rays is cured. A reversed pattern of the pattern of the mold 50 is formed on the cured imprint material. After the imprint material 30 is cured, the control unit 1 controls the imprint head 100 to raise the mold 50 to widen the distance between the mold 50 and the substrate 20 . Thereby, the mold 50 is separated from the cured imprint material 30 .

Further, in the above description, the imprint head 100 is lowered with respect to the imprint material 30 on the fixed substrate 20 to bring the mold 50 into contact with each other, but the reverse operation may also be applied. That is, it is good also as a structure in which the imprint material 30 on the board|substrate 20 is brought into contact by driving the board|substrate stage 10 with respect to the fixed die 50. Alternatively, the imprint head 100 and the substrate stage 10 may be respectively driven. That is, what is necessary is just a structure which changes the space|interval of the mold 50 and the board|substrate 20 relatively.

The outline of the imprint process is substantially as described above. In the imprint process, when the mold 50 and the imprint material 30 on the substrate 20 are brought into contact, the filling of the imprint material 30 may be prevented by the influence of oxygen in the atmosphere in the space therebetween. , this tends to cause pattern defects. Accordingly, the imprint apparatus 200 supplies a purge gas (fill-promoting gas) to the space between the mold 50 at the imprint position and the imprint material 30 disposed in the shot region (hereinafter also referred to as “imprint space”). A supply unit is provided. The supply unit may include gas nozzles 71 , 72 , 73 , 74 provided as a plurality of supply ports, and gas flow control units 141 , 142 , 143 , and 144 (see FIG. 2 ). As shown in FIG. 2 , the gas nozzles 71 to 74 are arranged to surround the mold 50 . In addition, the gas nozzles 71 to 74 are connected to the gas flow control units 141 to 144, respectively. Among them, the gas nozzle 71 is disposed between the mold 50 and the dispenser 80 . In the example of FIG. 1 , gas nozzles 71 to 74 serving as a plurality of supply ports are arranged in the imprint head 100 .

In addition, in FIG. 2, although the width|variety (slit width) of the gas nozzles 71-74 is drawn larger than each side of the pattern part 40 for convenience, it is not limited to this. The narrower the slit width, the greater the gas flow velocity in the vicinity of the jet port, so that the amount of air mixed is reduced. Therefore, in order to prevent ambient air from mixing with the gas ejected from the gas nozzles 71 to 74 and mixing in the imprint space, the width of the gas nozzles 71 to 74 is the width of the pattern portion 40 . make it narrower.

The imprint apparatus 200 performs imprinting by supplying a purge gas to the imprint space from the gas nozzles 71 to 74 . As the purge gas, a permeable gas that is excellent in diffusibility and solubility in the imprint material from the viewpoint of filling properties and that permeates the mold when the mold and the imprint material are in contact can be employed. Alternatively, as the purge gas, a condensable gas that is liquefied by an increase in the spatial pressure between the mold and the imprint material in contact with the mold and the imprint material on the substrate may be employed. When the mold and the imprint material are in contact, the imprint material or gas remaining in the mold is dissolved or diffused in the case of a permeable gas, and in the case of a condensable gas, it is liquefied by the pressure increase due to the imprint, and its volume is several hundred minutes compared to that of gas. decreases to 1. Thereby, the influence on pattern formation of a residual gas is suppressed. Specific examples of the permeable gas include nitrogen, helium, carbon dioxide, hydrogen, xenon, pentafluoropropane and the like. In addition, as the condensable gas, one gas selected from the group consisting of hydrofluorocarbon represented by pentafluoropropane, hydrofluoroether, and the like, or a mixed gas thereof, can be employed specifically as the condensable gas.

With the above configuration, in the imprint process of the present embodiment, the purge gas (hereinafter simply referred to as "gas") as described above can be supplied from the gas nozzles 71 to 74 . Hereinafter, details of the imprint process accompanying the supply of gas in the present embodiment will be described.

First, as shown in FIG. 1A , the control unit 1 controls the moving mechanism 10a so that the shot region of the substrate 20 is the placement position at which the imprint material is placed by the dispenser 80 . The substrate 20 is transported so as to come to Next, the control unit 1 controls the dispenser 80 to place the imprint material 30 in the shot region of the substrate 20 . Thereafter, as shown in FIG. 1B , the control unit 1 controls the moving mechanism 10a in the SD direction of the substrate 20 so that the shot region of the substrate 20 comes to the imprint position. start the return of

Then, the control part 1 controls the gas flow control part 141, and starts supply of the gas G from the gas nozzle 71. For example, the control unit 1 controls the gas flow rate control unit 141 , and at a point in time before the shot region of the substrate 20 passes under the gas nozzle 71 , the gas from the gas nozzle 71 is Start supplying G. The supplied gas G is drawn into the space between the mold 50 and the substrate 20 with the movement of the substrate 20 . The control unit 1 controls the imprint head 100 after the supply of the gas G is started, and as the substrate stage 10 advances in the SD direction from the position of the dispenser 80 to the mold 50 , The mold 50 is inclined so that the gap between the mold 50 and the substrate 20 is gradually reduced. The inclination of the mold 50 suppresses the flow rate at which the gas G enters between the mold 50 and the substrate 20 with the movement of the substrate 20 , thereby increasing the flow width of the gas G .

After a predetermined period of time has elapsed since the gas G is sufficiently supplied, the control unit 1 controls the gas flow rate control unit 141 to stop the supply of the gas G from the gas nozzle 71 . Thereafter, when the shot region of the substrate 20 is located under the pattern portion 40 of the mold 50 , the control unit 1 stops driving of the substrate stage 10 , and is shown in FIG. 1( c ). As shown, the mold 50 is returned horizontally. Thereafter, the control unit 1 aligns the pattern portion 40 with the shot region, controls the imprint head 100 to lower the mold 50 to make contact with the imprint material 30 on the shot region. . In this state, the control unit 1 generates ultraviolet light from the light source 130 to cure the imprint material 30 . After the imprint material 30 is cured, the controller 1 controls the imprint head 100 to raise the mold 50 to separate the mold 50 from the cured imprint material 30 .

The above example describes the control of gas from the gas nozzle 71 corresponding to the movement direction when the substrate stage 10 is moved in the SD direction to position the substrate 20 in the imprint position. When the moving direction of the substrate stage 10 is different from the SD direction, the gas is controlled from the corresponding gas nozzle among the gas nozzles 72 , 73 , 74 .

Further, in the above example, the control unit 1 controls the imprint head 100 so that the gap between the mold 50 and the substrate 20 gradually decreases as the substrate stage 10 advances in the SD direction. (50) was inclined. Instead of this, the control unit 1 controls the substrate stage 10 (moving mechanism 10a), and gradually the gap between the mold 50 and the substrate 20 as the substrate stage 10 advances in the SD direction. You may incline the board|substrate 20 so that this may become small. Alternatively, both the mold 50 and the substrate 20 may be inclined. That is, at least one of the mold 50 and the substrate 20 may be inclined. In addition, the inclination of the die 50 or the substrate 20 is, for example, 0.1 mm or more and 2.0 mm or less, the difference between the distance between the nearest distance between the die 50 and the substrate 20 and the distance at the most distant place. It should be done so that

Here, the reason for inclining the mold 50 as described above will be described. By inclining the mold 50 as described above, the gap between the mold 50 and the substrate 20 is narrowed on the side opposite to the side where the gas flows into the space between the mold 50 and the substrate 20 . For this reason, the outflow of gas from the space between the mold 50 and the board|substrate 20 can be prevented. In this way, with respect to the flow of gas in the space between the mold 50 and the substrate 20, a pressure gradient in which the pressure rises on the downstream side in the SD direction is added. Thereby, compared with the case where the opposing angles of the mold 50 and the substrate 20 are parallel, the gas G that is introduced in accordance with the movement of the substrate 20 in the space between the mold 50 and the substrate 20 . the flow rate is suppressed. When the flow rate becomes small, the effect of expanding the flow width of the gas G is obtained while the flow rate of the gas G supplied from the gas nozzle 71 is maintained.

As described above, according to the present embodiment, the imprint apparatus 200 prevents the outflow of gas G from the space between the mold 50 and the substrate 20 at least between the mold 50 and the substrate 20 . Bevel one side. The inclination is performed at a predetermined timing while the shot area is moved from the arrangement position by the dispenser 80 to the imprint position by the movement of the substrate 20 by the movement mechanism 10a. The predetermined timing may be, for example, after the movement of the substrate 20 by the movement mechanism 10a is started, and before the shot region passes under the gas nozzle 71 . Alternatively, the predetermined timing is a point in time after the movement of the substrate 20 by the movement mechanism 10a is started and before the shot region passes under the gas nozzle 71 , and It may be a time point after the gas supply is started.

3 : is a top view which showed the distribution of the flow of the gas G in the surface in the direction opposite to the board|substrate 20 in the mold|die 50. As shown in FIG. The dispenser 80 is on the left side of the mold 50 , and the substrate stage 10 advances in the SD direction shown from left to right. 3(a) and 3(b) show the distribution of gas G when the same flow rate of gas G is supplied from the gas nozzle 71 while driving the substrate stage 10 in the SD direction. have. Fig. 3 (a) is a distribution when the mold 50 and the substrate 20 are opposed to each other in parallel, and Fig. 3 (b) is the distribution of the mold 50 and the substrate 20 as it proceeds in the SD direction. This is a distribution when the mold 50 is inclined so that the gap is narrowed. By the inclination of the mold 50 , the effect of expanding the flow width of the gas G is obtained while maintaining the flow rate of the gas G supplied from the gas nozzle 71 . Thereby, the gas in the imprint space can be effectively replaced with the gas G. Moreover, since the gas flow rate required in order to set it as the flow width of a desired gas is reduced by this, the usage-amount of gas can be reduced.

<Second embodiment>

4 shows the configuration of the imprint apparatus 200 in the second embodiment. In FIG. 1 related to the first embodiment, gas nozzles 71 to 74 are arranged as a plurality of supply ports in the imprint head 100 at a position between the mold 50 and the dispenser 80 . In contrast, in the example of FIG. 4 , a plurality of holes communicating the mold 50 and the chuck 60 are formed, and gas nozzles 71 to 74 serving as a plurality of supply ports are disposed therein. Other configurations are the same as those of the first embodiment.

When the gas nozzles 71 to 74 are disposed outside the mold 50 as in the first embodiment, a decrease in the flow rate of the gas G introduced in the SD direction accompanying the movement of the substrate 20 in the SD direction is avoided. can't When the flow rate of the gas G decreases, the amount of the gas G introduced into the space between the mold 50 and the substrate 20 decreases, and the possibility that the gas G leaks to the outside of the space increases. On the other hand, in this embodiment, since the gas nozzles 71 to 74 are formed by holes penetrating the mold 50 , compared to the configuration of the first embodiment, the gas G is supplied at a position close to the pattern portion 40 . can supply Thereby, the gas G can be introduced into the imprint space more reliably. With this configuration, since the amount of gas leaking from the space between the mold 50 and the substrate 20 can be reduced, the gas in the space between the mold 50 and the substrate 20 can be more effectively removed from the gas. can be substituted with G.

<Third embodiment>

In the first and second embodiments, the pressure is increased on the downstream side in the SD direction with respect to the flow of gas in the space between the mold 50 and the substrate 20 by inclining the mold 50 . A pressure gradient was added. On the other hand, in 3rd Embodiment, the supply/exhaust mechanism which prevents the outflow of gas from the space between the mold 50 and the board|substrate 20 is provided rather than making the mold 50 incline. Fig. 5 shows the configuration of the imprint apparatus 200 in the present embodiment. The imprint apparatus 200 includes a first supply unit that supplies a gas G (first gas) to a space between the mold 50 and the substrate 20 . The first supply unit may include gas nozzles 71 , 72 , 73 , 74 provided as a plurality of supply ports, and gas flow control units 141 , 142 , 143 , 144 , similar to those of the first embodiment (Fig. see 2). Among them, the gas nozzle 71 (first supply port) is disposed between the mold 50 and the dispenser 80 .

In addition, with respect to the mold 50 , the supply and exhaust devices 150 and 160 are provided on the outside of the gas nozzles 71 to 74 . Among these, the supply/exhaust device 160 is provided in the position 2nd supply port on the opposite side to the gas nozzle 71 with the pattern part 40 of the mold 50 interposed therebetween. The air supply and exhaust devices 150 and 160 are supported by, for example, the support body 110 . The supply/exhaust devices 150 and 160 may include, for example, a fan for forced air supply and forced exhaust. Here, the operation of supplying air (second gas) toward the space between the mold 50 and the substrate 20 by the supply and exhaust devices 150 and 160 is referred to as an air supply operation, and the supply and exhaust devices 150 and 160 . The operation of exhausting air from the corresponding space is called an exhaust operation. The supply/exhaust devices 150 and 160 function as a supply unit (second supply unit) for supplying air when performing an air supply operation, and function as an exhaust unit for discharging air when performing an exhaust operation.

The control unit 1 first controls the moving mechanism 10a to convey the substrate 20 so that the shot region of the substrate 20 comes to a position where the imprint material is placed by the dispenser 80 . Next, the control unit 1 controls the dispenser 80 to place the imprint material 30 in the shot region of the substrate 20 . Thereafter, the control unit 1 controls the moving mechanism 10a to start the transfer of the substrate 20 in the SD direction so that the shot region of the substrate 20 comes to the imprint position. At the time of this conveyance, the control part 1 makes the supply/exhaust device 160 downstream with respect to the pattern part 40 of the mold 50 perform an air supply operation|movement. Alternatively, the control unit 1 causes the air supply/exhaust device 150 on the upstream side in the SD direction to perform an exhaust operation with respect to the pattern portion 40 of the mold 50 . Alternatively, the control unit 1 causes the air supply/exhaust device 160 on the downstream side in the SD direction to perform an air supply operation with respect to the pattern part 40 of the mold 50, and further, the pattern part ( 40), the exhaust operation may be performed by the air supply/exhaust device 150 on the upstream side in the SD direction. By this supply/exhaust operation, a pressure gradient that prevents the outflow of gas from the space between the mold 50 and the substrate 20 is added.

However, the applied pressure gradient needs to be in a range in which the airflow of the gas G drawn between the mold 50 and the substrate 20 by the movement of the substrate 20 does not flow backward. Such a pressure gradient PG is based on the premise of the Couet-Pouschli flow, if the viscosity of the gas G is μ, the distance between the mold 50 and the substrate 20 is d, and the velocity of the substrate 20 is v. , is expressed as

PG<6μv/d^2

Then, the control part 1 controls the gas flow control part 141, and starts supply of the gas G from the gas nozzle 71. For example, the control unit 1 controls the gas flow rate control unit 141 , and at a point in time before the shot region of the substrate 20 passes under the gas nozzle 71 , the gas from the gas nozzle 71 is Start supplying G. The supplied gas G is introduced into the space between the mold 50 and the substrate 20 with the movement of the substrate 20 .

After a predetermined period of time has elapsed since the gas G is sufficiently supplied, the control unit 1 controls the gas flow rate control unit 141 to stop the supply of the gas G from the gas nozzle 71 . Then, when the shot region of the substrate 20 is located under the pattern portion 40 of the mold 50 , the control unit 1 controls the driving of the substrate stage 10 and Stop supply/exhaust operation. The subsequent operation is the same as in the first embodiment. However, the present invention is not limited thereto, and the supply/exhaust operation may be continuously continued.

As described above, according to the present embodiment, the imprint apparatus 200 supplies air from the air supply/exhaust apparatus 160 so as to prevent the outflow of gas G from the space between the mold 50 and the substrate 20 . . This air supply is performed at a predetermined timing while the shot area moves from the arrangement position by the dispenser 80 to the imprint position by the movement of the substrate 20 by the movement mechanism 10a. The predetermined timing may be, for example, after the movement of the substrate 20 by the movement mechanism 10a is started, and before the shot region passes under the gas nozzle 71 . Alternatively, the predetermined timing is a point in time after the movement of the substrate 20 by the movement mechanism 10a is started and before the shot region passes under the gas nozzle 71 , and It may be a time point after the gas supply is started.

As described above, the movement of the substrate 20 by the air supply operation by the supply/exhaust device 160 at the time of supplying the gas G or the exhaust operation by the supply/exhaust device 150 performed in addition to it. As a result, the flow rate of the incoming gas G is suppressed. When the flow rate is suppressed, the effect of expanding the flow width of the gas G can be obtained while maintaining the flow rate of the gas G supplied from the gas nozzle 71 . By this effect, since the gas flow rate required in order to set it as the flow width of a desired gas is reduced, the usage-amount of gas can also be reduced.

<Fourth embodiment>

In the third embodiment, for example, a mode including a supply/exhaust device 150 that performs a supply/exhaust operation by a fan is shown. This embodiment is a modification thereof. Fig. 6(a) shows the configuration of the imprint apparatus 200 in the present embodiment. Here, with respect to the mold 50 of the imprint head 100 , gas nozzles 91 to 94 are provided further outside than the gas nozzles 71 to 74 .

FIG. 6B is a diagram illustrating the arrangement of the gas nozzles 71 to 74 and the gas nozzles 91 to 94 with respect to the pattern portion 40 . The gas nozzles 91, 92, 93, and 94 are respectively connected to the gas flow control units 151, 152, 153, and 154, whereby the flow rates of the gas A supplied from the gas nozzles 91 to 94 are individually controlled. can be As gas A, at least any of clean air (clean dry air) and nitrogen other than gas G can be used.

In addition, the arrangement of the gas nozzles 91 to 94 is not limited thereto. For example, as long as the control of the gas A and the gas G is clearly separated, the function of the gas nozzles 91 to 94 for supplying the gas A may also be used as the gas nozzles 71 to 74 . Further, as in the second embodiment (FIG. 4), as the gas nozzles 71 to 74, the pattern portion 40 is formed from the center of each side of the die 50 so as to surround the pattern portion 40 of the die 50. A case in which the gas G is supplied through a hole opened at a position directed at a predetermined distance in the direction is considered. In this case, it is good also as a structure which supplies gas A through the hole opened in the die 50 so that these holes may be surrounded.

Control of the gas flow control units 151 to 154 is the same as in the third embodiment. For example, the control unit 1 controls the gas flow rate control unit 153 and supplies the gas A from the gas nozzle 93 as opposed to moving the substrate 20 in the SD direction. This corresponds to making the air supply/exhaust device 150 on the downstream side in the SD direction perform the air supply operation in the third embodiment. Thereby, the pressure gradient which prevents the outflow of gas from the space between the mold 50 and the board|substrate 20 is added, and the effect similar to 3rd Embodiment can be acquired.

<Embodiment of manufacturing method of article>

The pattern of the cured product formed by using the imprint apparatus can be used permanently on at least a part of various articles or temporarily when various articles are manufactured. An article is an electric circuit element, an optical element, MEMS, a recording element, a sensor, or a mold|type etc. Examples of the electric circuit element include volatile or nonvolatile semiconductor memories such as DRAM, SRAM, flash memory, and MRAM, and semiconductor elements such as LSI, CCD, image sensor and FPGA. As a type|mold, the mold for imprints, etc. are mentioned.

The pattern of the cured product is used as it is as a constituent member of at least a part of the article, or is temporarily used as a resist mask. After etching or ion implantation or the like is performed in the processing step of the substrate, the resist mask is removed.

Next, the manufacturing method of an article is demonstrated. In step SA of FIG. 7 , a substrate 1z such as a silicon substrate on which a material to be processed such as an insulator 2z is formed on the surface is prepared, and then, an imprint material ( 3z) is given. Here, the imprint material 3z in the form of a plurality of droplets is provided on the substrate.

In step SB of FIG. 7 , the imprint die 4z is made to face the side on which the concave-convex pattern is formed toward the imprint material 3z on the substrate. In step SC of FIG. 7, the board|substrate 1z to which the imprint material 3z was provided and the mold 4z are brought into contact, and a pressure is applied. The imprint material 3z is filled in the gap between the mold 4z and the material to be processed 2z. When light is irradiated through the mold 4z as curing energy in this state, the imprint material 3z is cured.

In step SD of FIG. 7 , after the imprint material 3z is cured, the mold 4z and the substrate 1z are separated to form a pattern of the cured product of the imprint material 3z on the substrate 1z. The pattern of the cured product is such that the concave portion of the mold has a shape corresponding to the convex portion of the cured product and the convex portion of the mold corresponds to the concave portion of the cured product, that is, the concave-convex pattern of the mold 4z is transferred to the imprint material 3z. do.

In step SE of FIG. 7 , when the pattern of the cured product is etched as an etch-resistant type, a portion of the surface of the workpiece 2z without the cured product or thinly remaining is removed to form a groove 5z. In step SF of FIG. 7, if the pattern of the hardened|cured material is removed, the article in which the groove|channel 5z was formed in the surface of the to-be-processed material 2z can be obtained. Although the pattern of the cured product is removed here, it may not be removed even after processing, and may be used, for example, as a film for interlayer insulation included in a semiconductor element, ie, as a constituent member of an article.

1: Control
10: substrate stage
10a: moving mechanism
20: substrate
30: imprint material
50: brother
71: gas nozzle
80: dispenser
100: imprint head
200: imprint device

Claims (12)

An imprint apparatus for forming a pattern on the substrate by contacting an imprint material on a substrate with a pattern portion of a mold,
an arrangement unit for disposing the imprint material in a shot region of the substrate;
a moving mechanism for moving the substrate such that the shot region moves in a direction from an arrangement position at which arrangement is performed by the arrangement unit toward an imprint position at which the contact is made;
a first supply part for supplying a first gas to a space between the mold and the substrate from a first supply port provided between the arrangement part and the pattern part of the mold;
The first gas and the first gas in the space from a second supply port provided at a position on the opposite side to the first supply port and downstream in the direction with respect to the pattern portion of the die with the pattern portion of the die interposed therebetween is a second supply unit for supplying another second gas
to provide
While the shot region moves from the arrangement position where arrangement is performed by the arrangement unit to the imprint position where the contact is made in accordance with the movement of the substrate by the moving mechanism, the first gas on the downstream side of the direction The imprint apparatus according to claim 1, wherein the second supply unit supplies the second gas so as to provide a pressure gradient in which the pressure of is increased. The imprint apparatus according to claim 1, wherein the second supply unit supplies the second gas so as to prevent an outflow of the first gas from the space. The imprint apparatus of claim 1 , wherein the second supply unit supplies the second gas to expand a width through which the first gas flows. The method according to claim 1, wherein the first supply unit supplies the first gas while the shot region moves from the arrangement position to the imprint position and after supply of the second gas is started. imprint device. The method according to claim 1, further comprising: an exhaust part provided between the arrangement part and the first supply port to exhaust the space;
and evacuating by the exhaust unit to impart the pressure gradient while the shot region moves from the arrangement position to the imprint position. The method according to claim 1, wherein the second supply unit supplies the second gas after the movement of the substrate by the moving mechanism is started and before the shot region passes under the first supply port. an imprint device. The second supply unit according to claim 1, wherein after the movement of the substrate by the moving mechanism is started, before the shot region passes under the first supply port, the second supply unit comprises: The imprint apparatus according to claim 1 , wherein the second gas is supplied after the supply of the first gas is started. The imprint apparatus according to claim 1, wherein the first supply port and the second supply port are each formed by a hole passing through the mold. The imprint apparatus according to claim 1, wherein a width of the first supply port is narrower than a width of the pattern portion of the mold. The imprint apparatus according to claim 1, wherein the first gas includes at least any one of a permeable gas that permeates through the mold by the contact and a condensable gas that liquefies by the contact. The apparatus of claim 1 , wherein the second gas is clean dry air or nitrogen. A step of forming a pattern on a substrate using the imprint apparatus according to any one of claims 1 to 11;
processing the substrate on which the pattern is formed;
A method of making an article, characterized in that the article is produced from the treated substrate.

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