KR20210023744A - 최적화된 증류를 사용하는 올레핀의 올리고머화 방법 - Google Patents

최적화된 증류를 사용하는 올레핀의 올리고머화 방법 Download PDF

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Publication number
KR20210023744A
KR20210023744A KR1020200104335A KR20200104335A KR20210023744A KR 20210023744 A KR20210023744 A KR 20210023744A KR 1020200104335 A KR1020200104335 A KR 1020200104335A KR 20200104335 A KR20200104335 A KR 20200104335A KR 20210023744 A KR20210023744 A KR 20210023744A
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South Korea
Prior art keywords
oligomerization
distillation column
reactor
olefins
reaction stage
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KR1020200104335A
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English (en)
Korean (ko)
Inventor
스테판 파이츠
구이도 스토흐니올
아르민 마티아스 릭스
니클라스 폴
타니타 발레리 식스
Original Assignee
에보니크 오퍼레이션즈 게엠베하
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Publication of KR20210023744A publication Critical patent/KR20210023744A/ko
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/10—Catalytic processes with metal oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/009—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in combination with chemical reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14—Fractional distillation or use of a fractionation or rectification column
    • B01D3/143—Fractional distillation or use of a fractionation or rectification column by two or more of a fractionation, separation or rectification step
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/005—Processes comprising at least two steps in series
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/04—Purification; Separation; Use of additives by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with alkali- or alkaline earth metals or beryllium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020200104335A 2019-08-21 2020-08-20 최적화된 증류를 사용하는 올레핀의 올리고머화 방법 Pending KR20210023744A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP19192737.5 2019-08-21
EP19192737 2019-08-21

Publications (1)

Publication Number Publication Date
KR20210023744A true KR20210023744A (ko) 2021-03-04

Family

ID=67659612

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020200104335A Pending KR20210023744A (ko) 2019-08-21 2020-08-20 최적화된 증류를 사용하는 올레핀의 올리고머화 방법

Country Status (9)

Country Link
US (1) US11332421B2 (https=)
EP (1) EP3782971B1 (https=)
JP (1) JP2021031495A (https=)
KR (1) KR20210023744A (https=)
CN (1) CN112409119A (https=)
ES (1) ES2958382T3 (https=)
MY (1) MY197577A (https=)
SG (1) SG10202007883WA (https=)
TW (1) TWI834907B (https=)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4029926A1 (de) 2021-01-15 2022-07-20 Evonik Operations GmbH Zweistufige abgaswäsche

Family Cites Families (31)

* Cited by examiner, † Cited by third party
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DE4339713A1 (de) * 1993-11-22 1995-05-24 Basf Ag Verfahren zur Oligomerisierung von Olefinen zu hochlinearen Oligomeren und Katalysatoren dafür
TW425381B (en) * 1997-11-14 2001-03-11 Basf Ag Process for preparing essentially unbranched octenes and dodecenes by oligomerization of unbranched butenes
DE19922038A1 (de) * 1999-05-12 2000-11-16 Basf Ag Verfahren zur Oligomerisierung von C2- bis C8-Olefinen
DE10015002A1 (de) * 2000-03-25 2001-09-27 Basf Ag Verfahren zur Herstellung von Oligomeren
DE10310483A1 (de) 2003-03-11 2004-09-23 Basf Ag Verfahren zur Herstellung von Oligomeren von Alkenen mit 4 bis 8 Kohlenstoffatomen
US7145049B2 (en) * 2003-07-25 2006-12-05 Catalytic Distillation Technologies Oligomerization process
DE10335510A1 (de) 2003-07-31 2005-03-10 Stockhausen Chem Fab Gmbh Beschichteter Katalysator-Trägerkörper
DE102005018606A1 (de) * 2005-04-21 2006-11-09 Basf Ag Verfahren zur Oligomerisierung von Olefinen mit 2 bis 6 Kohlenstoffatomen
US20090068440A1 (en) 2005-06-20 2009-03-12 Gunther Bub Production of acrolein, acrylic acid and water-absorbent polymer structures made from glycerine
KR101442857B1 (ko) * 2006-06-07 2014-09-22 바스프 에스이 올레핀의 공이량체화 방법
DE102006039205A1 (de) 2006-08-22 2008-03-20 Stockhausen Gmbh Auf nachwachsenden Rohstoffen basierende Acrylsäure und wasserabsorbierende Polymergebilde sowie Verfahren zu deren Herstellung mittels Dehydratisierung
DE102006039203B4 (de) 2006-08-22 2014-06-18 Evonik Degussa Gmbh Verfahren zur Herstellung von durch Kristallisation gereinigter Acrylsäure aus Hydroxypropionsäure sowie Vorrichtung dazu
KR20100110877A (ko) 2008-01-29 2010-10-13 바스프 에스이 알켄의 올리고머화 방법
DE102008007081B4 (de) * 2008-01-31 2018-12-06 Evonik Degussa Gmbh Verfahren zur Herstellung von n-Buten-Oligomeren und 1-Buten aus technischen Mischungen I von C4-Kohlenwasserstoffen
KR100977454B1 (ko) 2008-02-26 2010-08-24 삼성전자주식회사 광대역 무선통신 시스템에서 하향링크 버스트 할당 장치 및방법
KR101669300B1 (ko) * 2008-11-19 2016-10-25 바스프 에스이 올레핀의 올리고머화
EP2582648B1 (de) * 2010-06-15 2014-04-30 Basf Se Verfahren zur co-oligomerisierung von olefinen
CN103946187B (zh) * 2011-11-21 2016-01-20 巴斯夫欧洲公司 制备丁烯低聚物的方法
DE102013212481A1 (de) * 2013-06-27 2014-12-31 Evonik Industries Ag Oligomerisierung von C4-Strömen mit geringstem Gehalt an 1-Buten
US9834495B2 (en) * 2014-06-26 2017-12-05 Uop Llc Exotherm, conversion and selectivity management for oligomerization process
JP6228246B2 (ja) 2015-03-03 2017-11-08 エボニック デグサ ゲーエムベーハーＥｖｏｎｉｋ Ｄｅｇｕｓｓａ ＧｍｂＨ エテンのオリゴマー化に使用される不均一系触媒の再生
PL3255029T3 (pl) 2016-06-10 2019-04-30 Evonik Degussa Gmbh Oligomeryzacja etenu w warunkach nadkrytycznych
EP3266757B1 (de) 2016-07-08 2019-12-25 Evonik Operations GmbH Herstellung von zumindest 1-hexen und octen aus ethen
US10227279B2 (en) 2016-09-12 2019-03-12 Evonik Degussa Gmbh Dehydrogenation of LPG or NGL and flexible utilization of the olefins thus obtained
US10882028B2 (en) 2018-03-14 2021-01-05 Evonik Operations Gmbh Ni-containing catalyst for the oligomerization of olefins
US11253844B2 (en) 2018-03-14 2022-02-22 Evonik Operations Gmbh Oligomerization catalyst and process for the production thereof
US10850261B2 (en) 2018-03-14 2020-12-01 Evonik Operations Gmbh Oligomerization catalyst and process for the production thereof
US10882027B2 (en) 2018-03-14 2021-01-05 Evonik Operations Gmbh Process for producing an oligomerization catalyst
US10633302B2 (en) 2018-07-25 2020-04-28 Evonik Operations Gmbh Process for oligomerization of butene with determination of the proportion of acidic catalysis
US11186782B2 (en) 2019-01-08 2021-11-30 Evonik Operations Gmbh Catalyst and process for removing mercaptans from hydrocarbon streams
EP3680224B1 (de) 2019-01-08 2023-05-24 Evonik Operations GmbH Verfahren zur entfernung mehrfach ungesättigter kohlenwasserstoffe aus c4-kohlenwasserstoffströmen in anwesenheit von mercaptanen, disulfiden und c5-kohlenwasserstoffen

Also Published As

Publication number Publication date
TW202112715A (zh) 2021-04-01
US20210053892A1 (en) 2021-02-25
US11332421B2 (en) 2022-05-17
CN112409119A (zh) 2021-02-26
SG10202007883WA (en) 2021-03-30
EP3782971B1 (de) 2023-07-19
EP3782971A1 (de) 2021-02-24
JP2021031495A (ja) 2021-03-01
ES2958382T3 (es) 2024-02-08
TWI834907B (zh) 2024-03-11
MY197577A (en) 2023-06-26

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