KR20150092271A - 전해질 조성물, 이의 제조 방법 및 이로부터 형성된 전지 장치 - Google Patents
전해질 조성물, 이의 제조 방법 및 이로부터 형성된 전지 장치 Download PDFInfo
- Publication number
- KR20150092271A KR20150092271A KR1020157017818A KR20157017818A KR20150092271A KR 20150092271 A KR20150092271 A KR 20150092271A KR 1020157017818 A KR1020157017818 A KR 1020157017818A KR 20157017818 A KR20157017818 A KR 20157017818A KR 20150092271 A KR20150092271 A KR 20150092271A
- Authority
- KR
- South Korea
- Prior art keywords
- phosphonium
- salt
- lithium
- ococoo
- cathode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- 239000003792 electrolyte Substances 0.000 title claims abstract description 231
- 239000000203 mixture Substances 0.000 title claims abstract description 182
- 238000000034 method Methods 0.000 title claims abstract description 59
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 claims abstract description 279
- 150000003839 salts Chemical class 0.000 claims abstract description 187
- 239000002608 ionic liquid Substances 0.000 claims abstract description 176
- 239000003990 capacitor Substances 0.000 claims abstract description 28
- 239000007788 liquid Substances 0.000 claims abstract description 25
- 150000001450 anions Chemical class 0.000 claims description 117
- -1 phosphonium salt Cation Chemical class 0.000 claims description 114
- 150000001768 cations Chemical class 0.000 claims description 91
- 239000000654 additive Substances 0.000 claims description 89
- 150000004714 phosphonium salts Chemical class 0.000 claims description 80
- 230000000996 additive effect Effects 0.000 claims description 79
- 239000002904 solvent Substances 0.000 claims description 76
- 229910052744 lithium Inorganic materials 0.000 claims description 47
- 229910013870 LiPF 6 Inorganic materials 0.000 claims description 42
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 40
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 38
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 36
- 125000000217 alkyl group Chemical group 0.000 claims description 35
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims description 34
- 239000007787 solid Substances 0.000 claims description 30
- SBLRHMKNNHXPHG-UHFFFAOYSA-N 4-fluoro-1,3-dioxolan-2-one Chemical compound FC1COC(=O)O1 SBLRHMKNNHXPHG-UHFFFAOYSA-N 0.000 claims description 27
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 claims description 23
- 229910052799 carbon Inorganic materials 0.000 claims description 22
- 125000004432 carbon atom Chemical group C* 0.000 claims description 22
- DHKHKXVYLBGOIT-UHFFFAOYSA-N 1,1-Diethoxyethane Chemical compound CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 18
- GAEKPEKOJKCEMS-UHFFFAOYSA-N gamma-valerolactone Chemical compound CC1CCC(=O)O1 GAEKPEKOJKCEMS-UHFFFAOYSA-N 0.000 claims description 18
- 229910002804 graphite Inorganic materials 0.000 claims description 17
- 239000010439 graphite Substances 0.000 claims description 17
- ZXMGHDIOOHOAAE-UHFFFAOYSA-N 1,1,1-trifluoro-n-(trifluoromethylsulfonyl)methanesulfonamide Chemical compound FC(F)(F)S(=O)(=O)NS(=O)(=O)C(F)(F)F ZXMGHDIOOHOAAE-UHFFFAOYSA-N 0.000 claims description 15
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 15
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 15
- 150000003949 imides Chemical class 0.000 claims description 14
- 229910001317 nickel manganese cobalt oxide (NMC) Inorganic materials 0.000 claims description 14
- 239000011572 manganese Substances 0.000 claims description 12
- 229910052760 oxygen Inorganic materials 0.000 claims description 11
- 229910052717 sulfur Inorganic materials 0.000 claims description 11
- ZZXUZKXVROWEIF-UHFFFAOYSA-N 1,2-butylene carbonate Chemical compound CCC1COC(=O)O1 ZZXUZKXVROWEIF-UHFFFAOYSA-N 0.000 claims description 10
- BJWMSGRKJIOCNR-UHFFFAOYSA-N 4-ethenyl-1,3-dioxolan-2-one Chemical compound C=CC1COC(=O)O1 BJWMSGRKJIOCNR-UHFFFAOYSA-N 0.000 claims description 10
- ZKOGUIGAVNCCKH-UHFFFAOYSA-N 4-phenyl-1,3-dioxolan-2-one Chemical compound O1C(=O)OCC1C1=CC=CC=C1 ZKOGUIGAVNCCKH-UHFFFAOYSA-N 0.000 claims description 10
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 claims description 10
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 10
- 229910000625 lithium cobalt oxide Inorganic materials 0.000 claims description 10
- 239000011593 sulfur Substances 0.000 claims description 10
- 239000010936 titanium Substances 0.000 claims description 10
- VAYTZRYEBVHVLE-UHFFFAOYSA-N 1,3-dioxol-2-one Chemical compound O=C1OC=CO1 VAYTZRYEBVHVLE-UHFFFAOYSA-N 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- BFZPBUKRYWOWDV-UHFFFAOYSA-N lithium;oxido(oxo)cobalt Chemical compound [Li+].[O-][Co]=O BFZPBUKRYWOWDV-UHFFFAOYSA-N 0.000 claims description 9
- MCVFFRWZNYZUIJ-UHFFFAOYSA-M lithium;trifluoromethanesulfonate Chemical compound [Li+].[O-]S(=O)(=O)C(F)(F)F MCVFFRWZNYZUIJ-UHFFFAOYSA-M 0.000 claims description 9
- PYLWMHQQBFSUBP-UHFFFAOYSA-N monofluorobenzene Chemical compound FC1=CC=CC=C1 PYLWMHQQBFSUBP-UHFFFAOYSA-N 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 9
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 claims description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
- 229910052731 fluorine Inorganic materials 0.000 claims description 8
- 229910003002 lithium salt Inorganic materials 0.000 claims description 8
- 159000000002 lithium salts Chemical class 0.000 claims description 8
- 229910052748 manganese Inorganic materials 0.000 claims description 8
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 8
- 229910052719 titanium Inorganic materials 0.000 claims description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000011651 chromium Substances 0.000 claims description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 7
- 108010000020 Platelet Factor 3 Proteins 0.000 claims description 6
- 229910052796 boron Inorganic materials 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 6
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 6
- 238000004146 energy storage Methods 0.000 claims description 6
- FRMOHNDAXZZWQI-UHFFFAOYSA-N lithium manganese(2+) nickel(2+) oxygen(2-) Chemical compound [O-2].[Mn+2].[Ni+2].[Li+] FRMOHNDAXZZWQI-UHFFFAOYSA-N 0.000 claims description 6
- 229910044991 metal oxide Inorganic materials 0.000 claims description 6
- 150000004706 metal oxides Chemical class 0.000 claims description 6
- 239000010703 silicon Substances 0.000 claims description 6
- 229910015015 LiAsF 6 Inorganic materials 0.000 claims description 5
- 229910013063 LiBF 4 Inorganic materials 0.000 claims description 5
- 239000011149 active material Substances 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 239000011737 fluorine Substances 0.000 claims description 5
- 125000001153 fluoro group Chemical group F* 0.000 claims description 5
- GELKBWJHTRAYNV-UHFFFAOYSA-K lithium iron phosphate Chemical compound [Li+].[Fe+2].[O-]P([O-])([O-])=O GELKBWJHTRAYNV-UHFFFAOYSA-K 0.000 claims description 5
- 229910001496 lithium tetrafluoroborate Inorganic materials 0.000 claims description 5
- VGYDTVNNDKLMHX-UHFFFAOYSA-N lithium;manganese;nickel;oxocobalt Chemical compound [Li].[Mn].[Ni].[Co]=O VGYDTVNNDKLMHX-UHFFFAOYSA-N 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 229910000733 Li alloy Inorganic materials 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 229910021389 graphene Inorganic materials 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 239000001989 lithium alloy Substances 0.000 claims description 4
- 229910003473 lithium bis(trifluoromethanesulfonyl)imide Inorganic materials 0.000 claims description 4
- 229910002102 lithium manganese oxide Inorganic materials 0.000 claims description 4
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 claims description 4
- QSZMZKBZAYQGRS-UHFFFAOYSA-N lithium;bis(trifluoromethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F QSZMZKBZAYQGRS-UHFFFAOYSA-N 0.000 claims description 4
- VLXXBCXTUVRROQ-UHFFFAOYSA-N lithium;oxido-oxo-(oxomanganiooxy)manganese Chemical compound [Li+].[O-][Mn](=O)O[Mn]=O VLXXBCXTUVRROQ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052709 silver Inorganic materials 0.000 claims description 4
- 229910052718 tin Inorganic materials 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 3
- 229910000676 Si alloy Inorganic materials 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- NDPGDHBNXZOBJS-UHFFFAOYSA-N aluminum lithium cobalt(2+) nickel(2+) oxygen(2-) Chemical compound [Li+].[O--].[O--].[O--].[O--].[Al+3].[Co++].[Ni++] NDPGDHBNXZOBJS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052738 indium Inorganic materials 0.000 claims description 3
- 239000005751 Copper oxide Substances 0.000 claims description 2
- 229910007857 Li-Al Inorganic materials 0.000 claims description 2
- 229910008447 Li—Al Inorganic materials 0.000 claims description 2
- 229910052787 antimony Inorganic materials 0.000 claims description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 2
- 229910052797 bismuth Inorganic materials 0.000 claims description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 2
- 229910000431 copper oxide Inorganic materials 0.000 claims description 2
- 230000026731 phosphorylation Effects 0.000 claims description 2
- 238000006366 phosphorylation reaction Methods 0.000 claims description 2
- RAVDHKVWJUPFPT-UHFFFAOYSA-N silver;oxido(dioxo)vanadium Chemical compound [Ag+].[O-][V](=O)=O RAVDHKVWJUPFPT-UHFFFAOYSA-N 0.000 claims description 2
- NJMWOUFKYKNWDW-UHFFFAOYSA-N 1-ethyl-3-methylimidazolium Chemical compound CCN1C=C[N+](C)=C1 NJMWOUFKYKNWDW-UHFFFAOYSA-N 0.000 claims 1
- MQKATURVIVFOQI-UHFFFAOYSA-N [S-][S-].[Li+].[Li+] Chemical compound [S-][S-].[Li+].[Li+] MQKATURVIVFOQI-UHFFFAOYSA-N 0.000 claims 1
- 230000015654 memory Effects 0.000 abstract description 30
- 238000012546 transfer Methods 0.000 abstract description 17
- 239000000446 fuel Substances 0.000 abstract description 6
- 230000003068 static effect Effects 0.000 abstract description 4
- 210000004027 cell Anatomy 0.000 description 117
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 93
- 238000003860 storage Methods 0.000 description 84
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 59
- 125000001424 substituent group Chemical group 0.000 description 59
- 238000007254 oxidation reaction Methods 0.000 description 49
- 230000003647 oxidation Effects 0.000 description 47
- 239000003446 ligand Substances 0.000 description 45
- 239000000463 material Substances 0.000 description 45
- 238000002411 thermogravimetry Methods 0.000 description 40
- 239000010410 layer Substances 0.000 description 32
- 238000002474 experimental method Methods 0.000 description 31
- 150000004032 porphyrins Chemical class 0.000 description 30
- 150000001875 compounds Chemical class 0.000 description 28
- 101150047356 dec-1 gene Proteins 0.000 description 26
- 239000008151 electrolyte solution Substances 0.000 description 26
- 230000001965 increasing effect Effects 0.000 description 25
- 150000002500 ions Chemical class 0.000 description 25
- 229910052751 metal Inorganic materials 0.000 description 24
- 239000002184 metal Substances 0.000 description 24
- 125000003118 aryl group Chemical group 0.000 description 23
- 125000004429 atom Chemical group 0.000 description 23
- 238000006243 chemical reaction Methods 0.000 description 20
- 229910001416 lithium ion Inorganic materials 0.000 description 18
- 239000000758 substrate Substances 0.000 description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 16
- 239000010408 film Substances 0.000 description 16
- 229910052757 nitrogen Inorganic materials 0.000 description 16
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
- 239000004743 Polypropylene Substances 0.000 description 15
- 229920001155 polypropylene Polymers 0.000 description 15
- 125000005842 heteroatom Chemical group 0.000 description 14
- 239000000243 solution Substances 0.000 description 14
- 229910052782 aluminium Inorganic materials 0.000 description 12
- 229910021645 metal ion Inorganic materials 0.000 description 11
- 125000002524 organometallic group Chemical group 0.000 description 11
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 11
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 10
- 125000000623 heterocyclic group Chemical group 0.000 description 10
- GWLJTAJEHRYMCA-UHFFFAOYSA-N phospholane Chemical compound C1CCPC1 GWLJTAJEHRYMCA-UHFFFAOYSA-N 0.000 description 10
- 239000004698 Polyethylene Substances 0.000 description 9
- 230000008901 benefit Effects 0.000 description 9
- 239000006182 cathode active material Substances 0.000 description 9
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 9
- 239000011888 foil Substances 0.000 description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 9
- 150000002678 macrocyclic compounds Chemical class 0.000 description 9
- 229920000573 polyethylene Polymers 0.000 description 9
- 239000002244 precipitate Substances 0.000 description 9
- 230000008569 process Effects 0.000 description 9
- 229910052723 transition metal Inorganic materials 0.000 description 9
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 8
- RJUFJBKOKNCXHH-UHFFFAOYSA-N Methyl propionate Chemical compound CCC(=O)OC RJUFJBKOKNCXHH-UHFFFAOYSA-N 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 8
- 229940017219 methyl propionate Drugs 0.000 description 8
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 8
- 150000003624 transition metals Chemical class 0.000 description 8
- 150000003863 ammonium salts Chemical class 0.000 description 7
- 239000011230 binding agent Substances 0.000 description 7
- 230000008878 coupling Effects 0.000 description 7
- 238000010168 coupling process Methods 0.000 description 7
- 238000005859 coupling reaction Methods 0.000 description 7
- 125000004122 cyclic group Chemical group 0.000 description 7
- 238000001914 filtration Methods 0.000 description 7
- 230000006870 function Effects 0.000 description 7
- 239000011245 gel electrolyte Substances 0.000 description 7
- 229910052759 nickel Inorganic materials 0.000 description 7
- 229910052698 phosphorus Inorganic materials 0.000 description 7
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 6
- 125000003545 alkoxy group Chemical group 0.000 description 6
- 125000000753 cycloalkyl group Chemical group 0.000 description 6
- 238000000354 decomposition reaction Methods 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000012528 membrane Substances 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 6
- 239000011574 phosphorus Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 229920006395 saturated elastomer Polymers 0.000 description 6
- 239000007784 solid electrolyte Substances 0.000 description 6
- 210000000352 storage cell Anatomy 0.000 description 6
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 description 5
- 239000002033 PVDF binder Substances 0.000 description 5
- 150000001721 carbon Chemical group 0.000 description 5
- 125000004093 cyano group Chemical group *C#N 0.000 description 5
- 238000013461 design Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000000605 extraction Methods 0.000 description 5
- 229910052736 halogen Inorganic materials 0.000 description 5
- 150000002367 halogens Chemical class 0.000 description 5
- 230000000977 initiatory effect Effects 0.000 description 5
- 125000005647 linker group Chemical group 0.000 description 5
- 239000011777 magnesium Substances 0.000 description 5
- 230000014759 maintenance of location Effects 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 5
- 239000004810 polytetrafluoroethylene Substances 0.000 description 5
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- 239000004065 semiconductor Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- DJMUYABFXCIYSC-UHFFFAOYSA-N 1H-phosphole Chemical compound C=1C=CPC=1 DJMUYABFXCIYSC-UHFFFAOYSA-N 0.000 description 4
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 125000002252 acyl group Chemical group 0.000 description 4
- 125000003342 alkenyl group Chemical group 0.000 description 4
- 125000003368 amide group Chemical group 0.000 description 4
- 125000004104 aryloxy group Chemical group 0.000 description 4
- DFFDSQBEGQFJJU-UHFFFAOYSA-N butyl hydrogen carbonate Chemical compound CCCCOC(O)=O DFFDSQBEGQFJJU-UHFFFAOYSA-N 0.000 description 4
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 4
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 4
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- 125000001072 heteroaryl group Chemical group 0.000 description 4
- 238000009830 intercalation Methods 0.000 description 4
- ACFSQHQYDZIPRL-UHFFFAOYSA-N lithium;bis(1,1,2,2,2-pentafluoroethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)C(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)C(F)(F)F ACFSQHQYDZIPRL-UHFFFAOYSA-N 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
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- 125000001500 prolyl group Chemical group [H]N1C([H])(C(=O)[*])C([H])([H])C([H])([H])C1([H])[H] 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 description 4
- 241000894007 species Species 0.000 description 4
- 125000001889 triflyl group Chemical group FC(F)(F)S(*)(=O)=O 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- MDAXKAUIABOHTD-UHFFFAOYSA-N 1,4,8,11-tetraazacyclotetradecane Chemical compound C1CNCCNCCCNCCNC1 MDAXKAUIABOHTD-UHFFFAOYSA-N 0.000 description 3
- 229910017008 AsF 6 Inorganic materials 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical compound N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 description 3
- 229910020366 ClO 4 Inorganic materials 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 229910013684 LiClO 4 Inorganic materials 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- WTKZEGDFNFYCGP-UHFFFAOYSA-O Pyrazolium Chemical compound C1=CN[NH+]=C1 WTKZEGDFNFYCGP-UHFFFAOYSA-O 0.000 description 3
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical class C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 3
- 229910018286 SbF 6 Inorganic materials 0.000 description 3
- DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical compound C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 description 3
- 125000000304 alkynyl group Chemical group 0.000 description 3
- 239000006183 anode active material Substances 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 150000004696 coordination complex Chemical class 0.000 description 3
- 238000009831 deintercalation Methods 0.000 description 3
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- WUGKRSAUUCWQLX-UHFFFAOYSA-N triethyl(methyl)phosphanium;nitrate Chemical compound [O-][N+]([O-])=O.CC[P+](C)(CC)CC WUGKRSAUUCWQLX-UHFFFAOYSA-N 0.000 description 1
- VXDBZKGRGPBUOE-UHFFFAOYSA-M triethyl(propyl)phosphanium;bromide Chemical compound [Br-].CCC[P+](CC)(CC)CC VXDBZKGRGPBUOE-UHFFFAOYSA-M 0.000 description 1
- NKKDYOFUNUWUTQ-UHFFFAOYSA-M triethyl(propyl)phosphanium;iodide Chemical compound [I-].CCC[P+](CC)(CC)CC NKKDYOFUNUWUTQ-UHFFFAOYSA-M 0.000 description 1
- 125000000876 trifluoromethoxy group Chemical group FC(F)(F)O* 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 238000004832 voltammetry Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0567—Liquid materials characterised by the additives
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0568—Liquid materials characterised by the solutes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0569—Liquid materials characterised by the solvents
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
- H01M2300/0045—Room temperature molten salts comprising at least one organic ion
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y02E60/122—
-
- Y02E60/521—
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
- Fuel Cell (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/706,323 | 2012-12-05 | ||
| US13/706,323 US20130095392A1 (en) | 2008-07-14 | 2012-12-05 | Electrolyte Compositions, Methods Of Making And Battery Devices Formed There From |
| PCT/US2013/065784 WO2014088711A1 (en) | 2012-12-05 | 2013-10-18 | Electrolyte compositions, methods of making and battery devices formed there from |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20150092271A true KR20150092271A (ko) | 2015-08-12 |
Family
ID=50883859
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020157017818A Withdrawn KR20150092271A (ko) | 2012-12-05 | 2013-10-18 | 전해질 조성물, 이의 제조 방법 및 이로부터 형성된 전지 장치 |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP2929588A4 (https=) |
| JP (2) | JP2014139921A (https=) |
| KR (1) | KR20150092271A (https=) |
| CN (1) | CN104969405A (https=) |
| WO (1) | WO2014088711A1 (https=) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20230039255A (ko) * | 2021-09-14 | 2023-03-21 | 주식회사 엘지에너지솔루션 | 리튬 이차전지용 비수 전해액 및 이를 포함하는 리튬 이차전지 |
| WO2023191572A1 (ko) * | 2022-03-31 | 2023-10-05 | 주식회사 엘지에너지솔루션 | 리튬 이차전지용 비수성 전해액 및 이를 포함하는 리튬 이차전지 |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016043823A2 (en) * | 2014-06-20 | 2016-03-24 | The Penn State Research Foundation | Supercapacitor |
| JP2016110075A (ja) | 2014-10-03 | 2016-06-20 | 株式会社半導体エネルギー研究所 | 発光装置、モジュール、及び電子機器 |
| DE102016209969A1 (de) | 2016-06-07 | 2017-12-07 | Robert Bosch Gmbh | Hybridsuperkondensator mit feuerhemmendem Elektrolyt |
| JP7090228B2 (ja) * | 2016-09-30 | 2022-06-24 | パナソニックＩｐマネジメント株式会社 | 電気化学デバイス |
| JP6631462B2 (ja) * | 2016-10-14 | 2020-01-15 | 株式会社デンソー | 燃料電池およびその製造方法 |
| CN109863633B (zh) * | 2016-10-28 | 2022-08-12 | 松下知识产权经营株式会社 | 电化学装置 |
| KR20210062021A (ko) * | 2018-08-30 | 2021-05-28 | 하이드로-퀘벡 | 코팅된 리튬 이온 재충전 가능한 배터리 활물질 |
| CA3109523A1 (en) * | 2018-08-30 | 2020-03-05 | Hydro-Quebec | Rechargeable battery with ionic liquid electrolyte and electrode pressure |
| CN110534736A (zh) * | 2019-08-28 | 2019-12-03 | 电子科技大学 | 一种高电位锂离子电池ncm三元正极材料及其制备方法 |
| JP7349107B2 (ja) * | 2021-06-11 | 2023-09-22 | プライムプラネットエナジー＆ソリューションズ株式会社 | 非水電解液、およびこれを備える非水電解液二次電池 |
| CN115207275A (zh) * | 2022-07-25 | 2022-10-18 | 中国科学院上海硅酸盐研究所 | 一种基于va族单质或其复合材料负极的双极性电极及双极性锂离子电池 |
| KR20240086920A (ko) * | 2022-12-09 | 2024-06-19 | 삼성에스디아이 주식회사 | 전해액 첨가제, 이를 포함하는 리튬 이차 전지용 전해액, 및 리튬 이차 전지 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0963643A (ja) * | 1995-06-14 | 1997-03-07 | Furukawa Battery Co Ltd:The | リチウム二次電池 |
| CA2283670C (fr) * | 1998-02-03 | 2011-06-07 | Acep Inc. | Materiaux utiles en tant que solutes electrolytiques |
| US20020110739A1 (en) * | 2000-05-26 | 2002-08-15 | Mcewen Alan B. | Non-flammable electrolytes |
| EP1399417B1 (de) * | 2001-06-01 | 2009-08-12 | MERCK PATENT GmbH | Verfahren zur herstellung von perfluoralkansulfonsäureestern |
| DE102004018929A1 (de) * | 2004-04-20 | 2005-11-17 | Degussa Ag | Elektrolytzusammensetzung sowie deren Verwendung als Elektrolytmaterial für elektrochemische Energiespeichersysteme |
| JP2008071499A (ja) * | 2006-09-12 | 2008-03-27 | Nippon Chem Ind Co Ltd | 電解質、それを含有するリチウムイオン二次電池用電解液およびこれを用いたリチウムイオン二次電池 |
| EP2117069A4 (en) * | 2007-01-19 | 2011-03-09 | Stella Chemifa Corp | ELECTRICAL STORAGE |
| US8586798B2 (en) * | 2008-07-14 | 2013-11-19 | Esionic Es, Inc. | Heat transfer medium, phosphonium ionic liquids, and methods of making |
| CN106848377B (zh) * | 2009-08-10 | 2019-11-08 | 株式会社Lg 化学 | 锂二次电池 |
| US9093722B2 (en) * | 2010-09-30 | 2015-07-28 | Uchicago Argonne, Llc | Functionalized ionic liquid electrolytes for lithium ion batteries |
-
2013
- 2013-10-18 EP EP13860259.4A patent/EP2929588A4/en not_active Withdrawn
- 2013-10-18 KR KR1020157017818A patent/KR20150092271A/ko not_active Withdrawn
- 2013-10-18 JP JP2013217129A patent/JP2014139921A/ja not_active Withdrawn
- 2013-10-18 CN CN201380072288.7A patent/CN104969405A/zh active Pending
- 2013-10-18 WO PCT/US2013/065784 patent/WO2014088711A1/en not_active Ceased
- 2013-10-18 JP JP2015546467A patent/JP2016506033A/ja active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20230039255A (ko) * | 2021-09-14 | 2023-03-21 | 주식회사 엘지에너지솔루션 | 리튬 이차전지용 비수 전해액 및 이를 포함하는 리튬 이차전지 |
| WO2023043190A1 (ko) * | 2021-09-14 | 2023-03-23 | 주식회사 엘지에너지솔루션 | 리튬 이차전지용 비수 전해액 및 이를 포함하는 리튬 이차전지 |
| EP4293783A4 (en) * | 2021-09-14 | 2024-04-10 | LG Energy Solution Ltd. | NON-AQUEOUS ELECTROLYTE FOR LITHIUM SECONDARY BATTERY, AND LITHIUM SECONDARY BATTERY COMPRISING SAME |
| US12283663B2 (en) | 2021-09-14 | 2025-04-22 | Lg Energy Solution, Ltd. | Non-aqueous electrolyte solution for lithium secondary battery and lithium secondary battery including the same |
| WO2023191572A1 (ko) * | 2022-03-31 | 2023-10-05 | 주식회사 엘지에너지솔루션 | 리튬 이차전지용 비수성 전해액 및 이를 포함하는 리튬 이차전지 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104969405A (zh) | 2015-10-07 |
| JP2014139921A (ja) | 2014-07-31 |
| JP2016506033A (ja) | 2016-02-25 |
| EP2929588A4 (en) | 2016-12-07 |
| WO2014088711A1 (en) | 2014-06-12 |
| EP2929588A1 (en) | 2015-10-14 |
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Patent event date: 20150702 Patent event code: PA01051R01D Comment text: International Patent Application |
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