JP2014139921A - 電解質組成物、作製方法、およびこれから形成される電池デバイス - Google Patents
電解質組成物、作製方法、およびこれから形成される電池デバイス Download PDFInfo
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- JP2014139921A JP2014139921A JP2013217129A JP2013217129A JP2014139921A JP 2014139921 A JP2014139921 A JP 2014139921A JP 2013217129 A JP2013217129 A JP 2013217129A JP 2013217129 A JP2013217129 A JP 2013217129A JP 2014139921 A JP2014139921 A JP 2014139921A
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- Prior art keywords
- phosphonium
- battery
- lithium
- salt
- ococoo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003792 electrolyte Substances 0.000 title claims abstract description 198
- 239000000203 mixture Substances 0.000 title claims abstract description 185
- 238000004519 manufacturing process Methods 0.000 title description 5
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 claims abstract description 291
- 239000002608 ionic liquid Substances 0.000 claims abstract description 173
- 150000001450 anions Chemical class 0.000 claims abstract description 114
- 150000001768 cations Chemical class 0.000 claims abstract description 113
- 150000004714 phosphonium salts Chemical class 0.000 claims abstract description 90
- 239000002904 solvent Substances 0.000 claims abstract description 75
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 37
- 150000003839 salts Chemical class 0.000 claims description 173
- -1 lithium hexafluorophosphate Chemical compound 0.000 claims description 109
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 105
- 239000000654 additive Substances 0.000 claims description 94
- 230000000996 additive effect Effects 0.000 claims description 81
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims description 62
- 229910013870 LiPF 6 Inorganic materials 0.000 claims description 42
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 41
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims description 41
- 229910052744 lithium Inorganic materials 0.000 claims description 41
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 37
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 35
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 claims description 33
- SBLRHMKNNHXPHG-UHFFFAOYSA-N 4-fluoro-1,3-dioxolan-2-one Chemical compound FC1COC(=O)O1 SBLRHMKNNHXPHG-UHFFFAOYSA-N 0.000 claims description 30
- 239000007787 solid Substances 0.000 claims description 29
- 239000003990 capacitor Substances 0.000 claims description 26
- 229910052799 carbon Inorganic materials 0.000 claims description 25
- 239000007788 liquid Substances 0.000 claims description 23
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 22
- 125000004432 carbon atom Chemical group C* 0.000 claims description 22
- DHKHKXVYLBGOIT-UHFFFAOYSA-N 1,1-Diethoxyethane Chemical compound CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 20
- 229910002804 graphite Inorganic materials 0.000 claims description 17
- 239000010439 graphite Substances 0.000 claims description 17
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 16
- 229910001317 nickel manganese cobalt oxide (NMC) Inorganic materials 0.000 claims description 15
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 13
- 239000011572 manganese Substances 0.000 claims description 13
- 229910052717 sulfur Inorganic materials 0.000 claims description 12
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 11
- 229910000625 lithium cobalt oxide Inorganic materials 0.000 claims description 11
- 229910052760 oxygen Inorganic materials 0.000 claims description 11
- 229910052698 phosphorus Inorganic materials 0.000 claims description 11
- 239000011593 sulfur Substances 0.000 claims description 11
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 11
- ZZXUZKXVROWEIF-UHFFFAOYSA-N 1,2-butylene carbonate Chemical compound CCC1COC(=O)O1 ZZXUZKXVROWEIF-UHFFFAOYSA-N 0.000 claims description 10
- VAYTZRYEBVHVLE-UHFFFAOYSA-N 1,3-dioxol-2-one Chemical compound O=C1OC=CO1 VAYTZRYEBVHVLE-UHFFFAOYSA-N 0.000 claims description 10
- BJWMSGRKJIOCNR-UHFFFAOYSA-N 4-ethenyl-1,3-dioxolan-2-one Chemical compound C=CC1COC(=O)O1 BJWMSGRKJIOCNR-UHFFFAOYSA-N 0.000 claims description 10
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 claims description 10
- RJUFJBKOKNCXHH-UHFFFAOYSA-N Methyl propionate Chemical compound CCC(=O)OC RJUFJBKOKNCXHH-UHFFFAOYSA-N 0.000 claims description 10
- GAEKPEKOJKCEMS-UHFFFAOYSA-N gamma-valerolactone Chemical compound CC1CCC(=O)O1 GAEKPEKOJKCEMS-UHFFFAOYSA-N 0.000 claims description 10
- BFZPBUKRYWOWDV-UHFFFAOYSA-N lithium;oxido(oxo)cobalt Chemical compound [Li+].[O-][Co]=O BFZPBUKRYWOWDV-UHFFFAOYSA-N 0.000 claims description 10
- 229940017219 methyl propionate Drugs 0.000 claims description 10
- PYLWMHQQBFSUBP-UHFFFAOYSA-N monofluorobenzene Chemical compound FC1=CC=CC=C1 PYLWMHQQBFSUBP-UHFFFAOYSA-N 0.000 claims description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 150000003949 imides Chemical class 0.000 claims description 9
- MCVFFRWZNYZUIJ-UHFFFAOYSA-M lithium;trifluoromethanesulfonate Chemical compound [Li+].[O-]S(=O)(=O)C(F)(F)F MCVFFRWZNYZUIJ-UHFFFAOYSA-M 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 9
- LRESCJAINPKJTO-UHFFFAOYSA-N bis(trifluoromethylsulfonyl)azanide;1-ethyl-3-methylimidazol-3-ium Chemical compound CCN1C=C[N+](C)=C1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F LRESCJAINPKJTO-UHFFFAOYSA-N 0.000 claims description 8
- 229910052731 fluorine Inorganic materials 0.000 claims description 8
- 229910052748 manganese Inorganic materials 0.000 claims description 8
- 229910052759 nickel Inorganic materials 0.000 claims description 8
- 239000010936 titanium Substances 0.000 claims description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000011651 chromium Substances 0.000 claims description 7
- 239000010949 copper Substances 0.000 claims description 7
- 229910003002 lithium salt Inorganic materials 0.000 claims description 7
- 159000000002 lithium salts Chemical class 0.000 claims description 7
- 229910052796 boron Inorganic materials 0.000 claims description 6
- 238000004146 energy storage Methods 0.000 claims description 6
- 229910002102 lithium manganese oxide Inorganic materials 0.000 claims description 6
- VGYDTVNNDKLMHX-UHFFFAOYSA-N lithium;manganese;nickel;oxocobalt Chemical compound [Li].[Mn].[Ni].[Co]=O VGYDTVNNDKLMHX-UHFFFAOYSA-N 0.000 claims description 6
- VLXXBCXTUVRROQ-UHFFFAOYSA-N lithium;oxido-oxo-(oxomanganiooxy)manganese Chemical compound [Li+].[O-][Mn](=O)O[Mn]=O VLXXBCXTUVRROQ-UHFFFAOYSA-N 0.000 claims description 6
- 239000010703 silicon Substances 0.000 claims description 6
- GEWWCWZGHNIUBW-UHFFFAOYSA-N 1-(4-nitrophenyl)propan-2-one Chemical compound CC(=O)CC1=CC=C([N+]([O-])=O)C=C1 GEWWCWZGHNIUBW-UHFFFAOYSA-N 0.000 claims description 5
- 229910015015 LiAsF 6 Inorganic materials 0.000 claims description 5
- 229910013063 LiBF 4 Inorganic materials 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 5
- 239000011737 fluorine Substances 0.000 claims description 5
- 125000001153 fluoro group Chemical group F* 0.000 claims description 5
- FRMOHNDAXZZWQI-UHFFFAOYSA-N lithium manganese(2+) nickel(2+) oxygen(2-) Chemical compound [O-2].[Mn+2].[Ni+2].[Li+] FRMOHNDAXZZWQI-UHFFFAOYSA-N 0.000 claims description 5
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 claims description 5
- 229910001496 lithium tetrafluoroborate Inorganic materials 0.000 claims description 5
- QSZMZKBZAYQGRS-UHFFFAOYSA-N lithium;bis(trifluoromethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F QSZMZKBZAYQGRS-UHFFFAOYSA-N 0.000 claims description 5
- 229910044991 metal oxide Inorganic materials 0.000 claims description 5
- 150000004706 metal oxides Chemical class 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 229910052709 silver Inorganic materials 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- 229910000733 Li alloy Inorganic materials 0.000 claims description 4
- 229910000676 Si alloy Inorganic materials 0.000 claims description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 229910017052 cobalt Inorganic materials 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- 229910021389 graphene Inorganic materials 0.000 claims description 4
- 239000001989 lithium alloy Substances 0.000 claims description 4
- 229910000686 lithium vanadium oxide Inorganic materials 0.000 claims description 4
- 239000004332 silver Substances 0.000 claims description 4
- 229910052718 tin Inorganic materials 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 3
- NDPGDHBNXZOBJS-UHFFFAOYSA-N aluminum lithium cobalt(2+) nickel(2+) oxygen(2-) Chemical compound [Li+].[O--].[O--].[O--].[O--].[Al+3].[Co++].[Ni++] NDPGDHBNXZOBJS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052738 indium Inorganic materials 0.000 claims description 3
- 239000005751 Copper oxide Substances 0.000 claims description 2
- 229910007857 Li-Al Inorganic materials 0.000 claims description 2
- 229910008365 Li-Sn Inorganic materials 0.000 claims description 2
- 229910008447 Li—Al Inorganic materials 0.000 claims description 2
- 229910006309 Li—Mg Inorganic materials 0.000 claims description 2
- 229910006759 Li—Sn Inorganic materials 0.000 claims description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 2
- RLTFLELMPUMVEH-UHFFFAOYSA-N [Li+].[O--].[O--].[O--].[V+5] Chemical compound [Li+].[O--].[O--].[O--].[V+5] RLTFLELMPUMVEH-UHFFFAOYSA-N 0.000 claims description 2
- 239000011149 active material Substances 0.000 claims description 2
- 229910052787 antimony Inorganic materials 0.000 claims description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 2
- 229910052797 bismuth Inorganic materials 0.000 claims description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 2
- 229910000431 copper oxide Inorganic materials 0.000 claims description 2
- 229910052732 germanium Inorganic materials 0.000 claims description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 2
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 2
- GELKBWJHTRAYNV-UHFFFAOYSA-K lithium iron phosphate Chemical compound [Li+].[Fe+2].[O-]P([O-])([O-])=O GELKBWJHTRAYNV-UHFFFAOYSA-K 0.000 claims description 2
- RAVDHKVWJUPFPT-UHFFFAOYSA-N silver;oxido(dioxo)vanadium Chemical compound [Ag+].[O-][V](=O)=O RAVDHKVWJUPFPT-UHFFFAOYSA-N 0.000 claims description 2
- JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 1
- GPVWCGHDIGTNCE-UHFFFAOYSA-N [Fe](=S)=S.[Li] Chemical compound [Fe](=S)=S.[Li] GPVWCGHDIGTNCE-UHFFFAOYSA-N 0.000 claims 1
- FDLZQPXZHIFURF-UHFFFAOYSA-N [O-2].[Ti+4].[Li+] Chemical compound [O-2].[Ti+4].[Li+] FDLZQPXZHIFURF-UHFFFAOYSA-N 0.000 claims 1
- 239000013543 active substance Substances 0.000 claims 1
- DFFDSQBEGQFJJU-UHFFFAOYSA-N butyl hydrogen carbonate Chemical compound CCCCOC(O)=O DFFDSQBEGQFJJU-UHFFFAOYSA-N 0.000 claims 1
- 210000004027 cell Anatomy 0.000 description 92
- 238000003860 storage Methods 0.000 description 74
- 239000008151 electrolyte solution Substances 0.000 description 64
- 229940021013 electrolyte solution Drugs 0.000 description 64
- 125000001424 substituent group Chemical group 0.000 description 62
- 238000007254 oxidation reaction Methods 0.000 description 50
- 230000003647 oxidation Effects 0.000 description 47
- 239000000463 material Substances 0.000 description 44
- 239000003446 ligand Substances 0.000 description 42
- 238000002411 thermogravimetry Methods 0.000 description 40
- 238000002474 experimental method Methods 0.000 description 35
- 150000004032 porphyrins Chemical class 0.000 description 33
- 239000010410 layer Substances 0.000 description 31
- 238000006243 chemical reaction Methods 0.000 description 28
- 150000001875 compounds Chemical class 0.000 description 26
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 25
- 125000004429 atom Chemical group 0.000 description 25
- 150000002500 ions Chemical class 0.000 description 25
- 229910052751 metal Inorganic materials 0.000 description 24
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- 125000003118 aryl group Chemical group 0.000 description 22
- 101150047356 dec-1 gene Proteins 0.000 description 21
- 239000010408 film Substances 0.000 description 21
- 229910052757 nitrogen Inorganic materials 0.000 description 19
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 18
- 229910001416 lithium ion Inorganic materials 0.000 description 18
- 239000000758 substrate Substances 0.000 description 17
- 125000002524 organometallic group Chemical group 0.000 description 16
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
- 125000005842 heteroatom Chemical group 0.000 description 14
- 150000002678 macrocyclic compounds Chemical class 0.000 description 14
- 239000004743 Polypropylene Substances 0.000 description 13
- 230000006870 function Effects 0.000 description 13
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 13
- 229920001155 polypropylene Polymers 0.000 description 13
- 238000012546 transfer Methods 0.000 description 13
- ZXMGHDIOOHOAAE-UHFFFAOYSA-N 1,1,1-trifluoro-n-(trifluoromethylsulfonyl)methanesulfonamide Chemical compound FC(F)(F)S(=O)(=O)NS(=O)(=O)C(F)(F)F ZXMGHDIOOHOAAE-UHFFFAOYSA-N 0.000 description 12
- 229910052782 aluminium Inorganic materials 0.000 description 12
- 230000008901 benefit Effects 0.000 description 12
- 229910021645 metal ion Inorganic materials 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 10
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- 150000003863 ammonium salts Chemical class 0.000 description 9
- 239000006182 cathode active material Substances 0.000 description 9
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 9
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- ZKOGUIGAVNCCKH-UHFFFAOYSA-N 4-phenyl-1,3-dioxolan-2-one Chemical compound O1C(=O)OCC1C1=CC=CC=C1 ZKOGUIGAVNCCKH-UHFFFAOYSA-N 0.000 description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 8
- 238000004502 linear sweep voltammetry Methods 0.000 description 8
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- 229920000742 Cotton Polymers 0.000 description 6
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- 125000000753 cycloalkyl group Chemical group 0.000 description 6
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- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 description 5
- 125000003545 alkoxy group Chemical group 0.000 description 5
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- 125000001889 triflyl group Chemical group FC(F)(F)S(*)(=O)=O 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 4
- DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical compound C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 description 4
- 125000002252 acyl group Chemical group 0.000 description 4
- 125000003342 alkenyl group Chemical group 0.000 description 4
- 239000006183 anode active material Substances 0.000 description 4
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- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 4
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- 229910003473 lithium bis(trifluoromethanesulfonyl)imide Inorganic materials 0.000 description 4
- ACFSQHQYDZIPRL-UHFFFAOYSA-N lithium;bis(1,1,2,2,2-pentafluoroethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)C(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)C(F)(F)F ACFSQHQYDZIPRL-UHFFFAOYSA-N 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- KKQAVHGECIBFRQ-UHFFFAOYSA-N methyl propyl carbonate Chemical compound CCCOC(=O)OC KKQAVHGECIBFRQ-UHFFFAOYSA-N 0.000 description 4
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- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 description 4
- 238000012552 review Methods 0.000 description 4
- 229910052703 rhodium Inorganic materials 0.000 description 4
- 239000010948 rhodium Substances 0.000 description 4
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- QGPWMPVOXJEOHH-UHFFFAOYSA-M triethyl(methyl)phosphanium;iodide Chemical compound [I-].CC[P+](C)(CC)CC QGPWMPVOXJEOHH-UHFFFAOYSA-M 0.000 description 1
- WUGKRSAUUCWQLX-UHFFFAOYSA-N triethyl(methyl)phosphanium;nitrate Chemical compound [O-][N+]([O-])=O.CC[P+](C)(CC)CC WUGKRSAUUCWQLX-UHFFFAOYSA-N 0.000 description 1
- VXDBZKGRGPBUOE-UHFFFAOYSA-M triethyl(propyl)phosphanium;bromide Chemical compound [Br-].CCC[P+](CC)(CC)CC VXDBZKGRGPBUOE-UHFFFAOYSA-M 0.000 description 1
- NKKDYOFUNUWUTQ-UHFFFAOYSA-M triethyl(propyl)phosphanium;iodide Chemical compound [I-].CCC[P+](CC)(CC)CC NKKDYOFUNUWUTQ-UHFFFAOYSA-M 0.000 description 1
- 230000005641 tunneling Effects 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 238000004832 voltammetry Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0567—Liquid materials characterised by the additives
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0568—Liquid materials characterised by the solutes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
- H01M2300/0045—Room temperature molten salts comprising at least one organic ion
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
- Fuel Cell (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/706,323 | 2012-12-05 | ||
| US13/706,323 US20130095392A1 (en) | 2008-07-14 | 2012-12-05 | Electrolyte Compositions, Methods Of Making And Battery Devices Formed There From |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2014139921A true JP2014139921A (ja) | 2014-07-31 |
| JP2014139921A5 JP2014139921A5 (https=) | 2016-12-08 |
Family
ID=50883859
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013217129A Withdrawn JP2014139921A (ja) | 2012-12-05 | 2013-10-18 | 電解質組成物、作製方法、およびこれから形成される電池デバイス |
| JP2015546467A Pending JP2016506033A (ja) | 2012-12-05 | 2013-10-18 | 電解質組成物、作製方法、及びこれから形成される電池デバイス |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015546467A Pending JP2016506033A (ja) | 2012-12-05 | 2013-10-18 | 電解質組成物、作製方法、及びこれから形成される電池デバイス |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP2929588A4 (https=) |
| JP (2) | JP2014139921A (https=) |
| KR (1) | KR20150092271A (https=) |
| CN (1) | CN104969405A (https=) |
| WO (1) | WO2014088711A1 (https=) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2018063897A (ja) * | 2016-10-14 | 2018-04-19 | 株式会社デンソー | 燃料電池およびその製造方法 |
| JP2022522559A (ja) * | 2018-08-30 | 2022-04-20 | ハイドロ－ケベック | コーティングされたリチウムイオン再充電可能電池活物質 |
| JP2022189403A (ja) * | 2021-06-11 | 2022-12-22 | プライムプラネットエナジー＆ソリューションズ株式会社 | 非水電解液、およびこれを備える非水電解液二次電池 |
| JP2024083235A (ja) * | 2022-12-09 | 2024-06-20 | 三星エスディアイ株式会社 | 電解液添加剤、これを含むリチウム二次電池用電解液、およびリチウム二次電池 |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016043823A2 (en) * | 2014-06-20 | 2016-03-24 | The Penn State Research Foundation | Supercapacitor |
| JP2016110075A (ja) | 2014-10-03 | 2016-06-20 | 株式会社半導体エネルギー研究所 | 発光装置、モジュール、及び電子機器 |
| DE102016209969A1 (de) | 2016-06-07 | 2017-12-07 | Robert Bosch Gmbh | Hybridsuperkondensator mit feuerhemmendem Elektrolyt |
| JP7090228B2 (ja) * | 2016-09-30 | 2022-06-24 | パナソニックＩｐマネジメント株式会社 | 電気化学デバイス |
| CN109863633B (zh) * | 2016-10-28 | 2022-08-12 | 松下知识产权经营株式会社 | 电化学装置 |
| CA3109523A1 (en) * | 2018-08-30 | 2020-03-05 | Hydro-Quebec | Rechargeable battery with ionic liquid electrolyte and electrode pressure |
| CN110534736A (zh) * | 2019-08-28 | 2019-12-03 | 电子科技大学 | 一种高电位锂离子电池ncm三元正极材料及其制备方法 |
| KR102626832B1 (ko) * | 2021-09-14 | 2024-01-19 | 주식회사 엘지에너지솔루션 | 리튬 이차전지용 비수 전해액 및 이를 포함하는 리튬 이차전지 |
| CA3255094A1 (en) * | 2022-03-31 | 2025-04-01 | Lg Energy Solution, Ltd. | NON-AQUEOUS ELECTROLYTIC SOLUTION FOR LITHIUM SECONDARY BATTERIES AND LITHIUM SECONDARY BATTERIES INCLUDING IT |
| CN115207275A (zh) * | 2022-07-25 | 2022-10-18 | 中国科学院上海硅酸盐研究所 | 一种基于va族单质或其复合材料负极的双极性电极及双极性锂离子电池 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0963643A (ja) * | 1995-06-14 | 1997-03-07 | Furukawa Battery Co Ltd:The | リチウム二次電池 |
| CA2283670C (fr) * | 1998-02-03 | 2011-06-07 | Acep Inc. | Materiaux utiles en tant que solutes electrolytiques |
| US20020110739A1 (en) * | 2000-05-26 | 2002-08-15 | Mcewen Alan B. | Non-flammable electrolytes |
| EP1399417B1 (de) * | 2001-06-01 | 2009-08-12 | MERCK PATENT GmbH | Verfahren zur herstellung von perfluoralkansulfonsäureestern |
| DE102004018929A1 (de) * | 2004-04-20 | 2005-11-17 | Degussa Ag | Elektrolytzusammensetzung sowie deren Verwendung als Elektrolytmaterial für elektrochemische Energiespeichersysteme |
| JP2008071499A (ja) * | 2006-09-12 | 2008-03-27 | Nippon Chem Ind Co Ltd | 電解質、それを含有するリチウムイオン二次電池用電解液およびこれを用いたリチウムイオン二次電池 |
| EP2117069A4 (en) * | 2007-01-19 | 2011-03-09 | Stella Chemifa Corp | ELECTRICAL STORAGE |
| US8586798B2 (en) * | 2008-07-14 | 2013-11-19 | Esionic Es, Inc. | Heat transfer medium, phosphonium ionic liquids, and methods of making |
| CN106848377B (zh) * | 2009-08-10 | 2019-11-08 | 株式会社Lg 化学 | 锂二次电池 |
| US9093722B2 (en) * | 2010-09-30 | 2015-07-28 | Uchicago Argonne, Llc | Functionalized ionic liquid electrolytes for lithium ion batteries |
-
2013
- 2013-10-18 EP EP13860259.4A patent/EP2929588A4/en not_active Withdrawn
- 2013-10-18 KR KR1020157017818A patent/KR20150092271A/ko not_active Withdrawn
- 2013-10-18 JP JP2013217129A patent/JP2014139921A/ja not_active Withdrawn
- 2013-10-18 CN CN201380072288.7A patent/CN104969405A/zh active Pending
- 2013-10-18 WO PCT/US2013/065784 patent/WO2014088711A1/en not_active Ceased
- 2013-10-18 JP JP2015546467A patent/JP2016506033A/ja active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2018063897A (ja) * | 2016-10-14 | 2018-04-19 | 株式会社デンソー | 燃料電池およびその製造方法 |
| WO2018070161A1 (ja) * | 2016-10-14 | 2018-04-19 | 株式会社デンソー | 燃料電池およびその製造方法 |
| JP2022522559A (ja) * | 2018-08-30 | 2022-04-20 | ハイドロ－ケベック | コーティングされたリチウムイオン再充電可能電池活物質 |
| JP2023181319A (ja) * | 2018-08-30 | 2023-12-21 | ハイドロ－ケベック | コーティングされたリチウムイオン再充電可能電池活物質 |
| JP7443340B2 (ja) | 2018-08-30 | 2024-03-05 | ハイドロ－ケベック | コーティングされたリチウムイオン再充電可能電池活物質 |
| JP2022189403A (ja) * | 2021-06-11 | 2022-12-22 | プライムプラネットエナジー＆ソリューションズ株式会社 | 非水電解液、およびこれを備える非水電解液二次電池 |
| JP7349107B2 (ja) | 2021-06-11 | 2023-09-22 | プライムプラネットエナジー＆ソリューションズ株式会社 | 非水電解液、およびこれを備える非水電解液二次電池 |
| JP2024083235A (ja) * | 2022-12-09 | 2024-06-20 | 三星エスディアイ株式会社 | 電解液添加剤、これを含むリチウム二次電池用電解液、およびリチウム二次電池 |
| JP7777110B2 (ja) | 2022-12-09 | 2025-11-27 | 三星エスディアイ株式会社 | 電解液添加剤、これを含むリチウム二次電池用電解液、およびリチウム二次電池 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104969405A (zh) | 2015-10-07 |
| JP2016506033A (ja) | 2016-02-25 |
| EP2929588A4 (en) | 2016-12-07 |
| WO2014088711A1 (en) | 2014-06-12 |
| KR20150092271A (ko) | 2015-08-12 |
| EP2929588A1 (en) | 2015-10-14 |
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