KR20150091388A - 섬유 보강 복합 재료의 제조 방법 - Google Patents
섬유 보강 복합 재료의 제조 방법 Download PDFInfo
- Publication number
- KR20150091388A KR20150091388A KR1020157017619A KR20157017619A KR20150091388A KR 20150091388 A KR20150091388 A KR 20150091388A KR 1020157017619 A KR1020157017619 A KR 1020157017619A KR 20157017619 A KR20157017619 A KR 20157017619A KR 20150091388 A KR20150091388 A KR 20150091388A
- Authority
- KR
- South Korea
- Prior art keywords
- weight
- lactam
- polymerizable composition
- fiber
- mixture
- Prior art date
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- 239000003733 fiber-reinforced composite Substances 0.000 title claims abstract description 42
- 239000000463 material Substances 0.000 title claims abstract description 39
- 238000000034 method Methods 0.000 title claims description 85
- 230000008569 process Effects 0.000 title claims description 72
- 239000004952 Polyamide Substances 0.000 claims abstract description 30
- 229920002647 polyamide Polymers 0.000 claims abstract description 30
- 239000011159 matrix material Substances 0.000 claims abstract description 20
- 239000000203 mixture Substances 0.000 claims description 188
- 150000003951 lactams Chemical class 0.000 claims description 70
- 239000000835 fiber Substances 0.000 claims description 60
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims description 50
- 239000002657 fibrous material Substances 0.000 claims description 50
- 239000000047 product Substances 0.000 claims description 38
- 239000007787 solid Substances 0.000 claims description 37
- 239000003054 catalyst Substances 0.000 claims description 34
- 239000012190 activator Substances 0.000 claims description 27
- 239000007788 liquid Substances 0.000 claims description 25
- 238000002844 melting Methods 0.000 claims description 24
- 230000008018 melting Effects 0.000 claims description 24
- 238000001816 cooling Methods 0.000 claims description 23
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- 239000000945 filler Substances 0.000 claims description 18
- 239000004744 fabric Substances 0.000 claims description 14
- -1 laid scrim Substances 0.000 claims description 14
- 150000001875 compounds Chemical class 0.000 claims description 10
- 239000013543 active substance Substances 0.000 claims description 9
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 8
- 230000015572 biosynthetic process Effects 0.000 claims description 8
- 239000012948 isocyanate Substances 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 230000009969 flowable effect Effects 0.000 claims description 7
- MOMGDEWWZBKDDR-UHFFFAOYSA-M sodium;3,4,5,6-tetrahydro-2h-azepin-7-olate Chemical compound [Na+].O=C1CCCCC[N-]1 MOMGDEWWZBKDDR-UHFFFAOYSA-M 0.000 claims description 7
- 150000008064 anhydrides Chemical class 0.000 claims description 6
- 150000002513 isocyanates Chemical class 0.000 claims description 6
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 claims description 5
- 238000000465 moulding Methods 0.000 claims description 5
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 4
- 239000004615 ingredient Substances 0.000 claims description 4
- 239000004745 nonwoven fabric Substances 0.000 claims description 4
- 239000005058 Isophorone diisocyanate Substances 0.000 claims description 3
- 150000001266 acyl halides Chemical class 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 3
- OTCKOJUMXQWKQG-UHFFFAOYSA-L magnesium bromide Chemical compound [Mg+2].[Br-].[Br-] OTCKOJUMXQWKQG-UHFFFAOYSA-L 0.000 claims description 3
- 229910001623 magnesium bromide Inorganic materials 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 claims description 2
- CJYXCQLOZNIMFP-UHFFFAOYSA-N azocan-2-one Chemical compound O=C1CCCCCCN1 CJYXCQLOZNIMFP-UHFFFAOYSA-N 0.000 claims description 2
- YDLSUFFXJYEVHW-UHFFFAOYSA-N azonan-2-one Chemical compound O=C1CCCCCCCN1 YDLSUFFXJYEVHW-UHFFFAOYSA-N 0.000 claims description 2
- 125000005442 diisocyanate group Chemical group 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- RPDAUEIUDPHABB-UHFFFAOYSA-N potassium ethoxide Chemical compound [K+].CC[O-] RPDAUEIUDPHABB-UHFFFAOYSA-N 0.000 claims description 2
- BDAWXSQJJCIFIK-UHFFFAOYSA-N potassium methoxide Chemical compound [K+].[O-]C BDAWXSQJJCIFIK-UHFFFAOYSA-N 0.000 claims description 2
- AWDMDDKZURRKFG-UHFFFAOYSA-N potassium;propan-1-olate Chemical compound [K+].CCC[O-] AWDMDDKZURRKFG-UHFFFAOYSA-N 0.000 claims description 2
- QDRKDTQENPPHOJ-UHFFFAOYSA-N sodium ethoxide Chemical compound [Na+].CC[O-] QDRKDTQENPPHOJ-UHFFFAOYSA-N 0.000 claims description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims 9
- XUWHAWMETYGRKB-UHFFFAOYSA-N piperidin-2-one Chemical compound O=C1CCCCN1 XUWHAWMETYGRKB-UHFFFAOYSA-N 0.000 claims 2
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 claims 1
- 239000011208 reinforced composite material Substances 0.000 claims 1
- SYXYWTXQFUUWLP-UHFFFAOYSA-N sodium;butan-1-olate Chemical compound [Na+].CCCC[O-] SYXYWTXQFUUWLP-UHFFFAOYSA-N 0.000 claims 1
- RCOSUMRTSQULBK-UHFFFAOYSA-N sodium;propan-1-olate Chemical compound [Na+].CCC[O-] RCOSUMRTSQULBK-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 28
- 229920000642 polymer Polymers 0.000 description 35
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- 239000011261 inert gas Substances 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
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- 238000005470 impregnation Methods 0.000 description 7
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- 239000004753 textile Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
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- 230000014509 gene expression Effects 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 6
- 238000003856 thermoforming Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- DVPHDWQFZRBFND-DMHDVGBCSA-N 1-o-[2-[(3ar,5r,6s,6ar)-2,2-dimethyl-6-prop-2-enoyloxy-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl]-2-[4-[(2s,3r)-1-butan-2-ylsulfanyl-2-(2-chlorophenyl)-4-oxoazetidin-3-yl]oxy-4-oxobutanoyl]oxyethyl] 4-o-[(2s,3r)-1-butan-2-ylsulfanyl-2-(2-chloropheny Chemical group C1([C@H]2[C@H](C(N2SC(C)CC)=O)OC(=O)CCC(=O)OC(COC(=O)CCC(=O)O[C@@H]2[C@@H](N(C2=O)SC(C)CC)C=2C(=CC=CC=2)Cl)[C@@H]2[C@@H]([C@H]3OC(C)(C)O[C@H]3O2)OC(=O)C=C)=CC=CC=C1Cl DVPHDWQFZRBFND-DMHDVGBCSA-N 0.000 description 5
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 4
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- 239000004760 aramid Substances 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
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- BOWUOGIPSRVRSJ-UHFFFAOYSA-N 2-aminohexano-6-lactam Chemical compound NC1CCCCNC1=O BOWUOGIPSRVRSJ-UHFFFAOYSA-N 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
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- AWIAZXPQRSJZCF-UHFFFAOYSA-N 1-chlorocyclohexane-1-carbonyl chloride Chemical compound ClC(=O)C1(Cl)CCCCC1 AWIAZXPQRSJZCF-UHFFFAOYSA-N 0.000 description 2
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 2
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
- C08J5/043—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with glass fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/40—Shaping or impregnating by compression not applied
- B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
- B29C70/46—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B15/00—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
- B29B15/08—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
- B29B15/10—Coating or impregnating independently of the moulding or shaping step
- B29B15/105—Coating or impregnating independently of the moulding or shaping step of reinforcement of definite length with a matrix in solid form, e.g. powder, fibre or sheet form
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
- C08J5/243—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using carbon fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
- C08J5/244—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using glass fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2077/00—Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as moulding material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
- C08J2377/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Polyamides (AREA)
- Reinforced Plastic Materials (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Composite Materials (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12195514 | 2012-12-04 | ||
| EP12195514.0 | 2012-12-04 | ||
| PCT/EP2013/075333 WO2014086757A2 (de) | 2012-12-04 | 2013-12-03 | Verfahren zur herstellung eines faserverstärkten verbundwerkstoffs |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20150091388A true KR20150091388A (ko) | 2015-08-10 |
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|---|---|---|---|
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Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP2928653B1 (enExample) |
| JP (1) | JP2016505664A (enExample) |
| KR (1) | KR20150091388A (enExample) |
| CN (1) | CN105283286B (enExample) |
| BR (1) | BR112015013093A2 (enExample) |
| WO (1) | WO2014086757A2 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20210024105A (ko) * | 2018-08-03 | 2021-03-04 | 드레슬러 그룹 게엠베하 앤드 컴퍼니 케이지 | 플라스틱을 분쇄하고 그로부터 분말상 물질을 생산하기 위한 방법 및 장치 |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9834885B2 (en) | 2012-12-04 | 2017-12-05 | Basf Se | Process for the production of a fiber-reinforced composite material |
| EP2980132A1 (de) * | 2014-08-01 | 2016-02-03 | Basf Se | Verfahren zur Herstellung getränkter Faserstrukturen |
| JP2018507953A (ja) * | 2015-02-23 | 2018-03-22 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 繊維強化部品又は半製品の製造方法 |
| JP7418946B2 (ja) | 2015-05-12 | 2024-01-22 | ビーエーエスエフ ソシエタス・ヨーロピア | カプロラクタム製剤 |
| WO2017102310A1 (de) * | 2015-12-18 | 2017-06-22 | Lanxess Deutschland Gmbh | Herstellung von faserverbundwerkstoffen |
| EP3196225A1 (de) | 2016-01-20 | 2017-07-26 | LANXESS Deutschland GmbH | Polymerisierbare zusammensetzung |
| EP3235861A1 (de) | 2016-04-18 | 2017-10-25 | LANXESS Deutschland GmbH | Polymerisierbare zusammensetzung |
| FR3053702B1 (fr) * | 2016-07-05 | 2019-09-13 | Saint-Gobain Adfors | Textile tisse hybride pour le renforcement de composite |
| JP2018104537A (ja) * | 2016-12-26 | 2018-07-05 | 東レ株式会社 | 基材 |
| JP6911440B2 (ja) * | 2017-03-24 | 2021-07-28 | 宇部興産株式会社 | ポリアミド複合材料の製造方法 |
| JP2021147522A (ja) * | 2020-03-19 | 2021-09-27 | 積水化成品工業株式会社 | プリプレグ及び繊維強化プラスチック |
| CN115873399A (zh) * | 2023-01-09 | 2023-03-31 | 欣润新材料科技(江苏)有限公司 | 一种高刚性低翘曲增强复合材料及其制备方法 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5269980A (en) | 1991-08-05 | 1993-12-14 | Northeastern University | Production of polymer particles in powder form using an atomization technique |
| DE4308842A1 (de) | 1993-03-19 | 1994-09-22 | Peter Prof Dr Walzel | Verfahren und Vorrichtung zum Zerstäuben von Flüssigkeiten |
| DE19527154C2 (de) * | 1995-07-25 | 2001-06-07 | Inventa Ag | Thermoplastisch verformbare Verbundwerkstoffe |
| DE19602638A1 (de) | 1996-01-25 | 1997-08-07 | Inventa Ag | Verfahren zur Herstellung von thermisch nachverformbaren Verbundwerkstoffen mit Polylactam-Matrix |
| KR20040071235A (ko) | 2001-12-20 | 2004-08-11 | 이엠에스-케미에 아게 | 열가소성 매트릭스를 이용한 복합 재료의 제조 방법 |
| FR2864094B1 (fr) * | 2003-12-19 | 2006-02-10 | Rhodia Industrial Yarns Ag | Materiaux composites comprenant un materiau de renfort et une matrice thermoplastique, article compose precurseur de ces materiaux et produits obtenus a partir de ces materiaux |
| CN101707929B (zh) * | 2007-06-20 | 2017-01-18 | 罗地亚管理公司 | 复合聚酰胺制品 |
| DE102007032778A1 (de) | 2007-07-13 | 2009-01-15 | Linde Ag | Vorrichtung und Verfahren zum Prillen |
| FR2953847B1 (fr) * | 2009-12-14 | 2012-12-14 | Rhodia Operations | Article composite a base de resines polyamides de faibles masses moleculaires |
| US10538624B2 (en) * | 2010-10-07 | 2020-01-21 | Basf Se | Process for producing monomer compositions and use of these for producing a polyamide molding |
| JP5857055B2 (ja) * | 2010-10-07 | 2016-02-10 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | モノマー−組成物を製造するための方法、及びこの方法をポリアミド成形物を製造するために使用する方法 |
| EP2681038B1 (de) * | 2011-03-03 | 2015-04-15 | Basf Se | Verfahren zur herstellung von faserverstärkten, flachen halbzeugen mit polyamidmatrix |
| FR2973047A1 (fr) * | 2011-03-23 | 2012-09-28 | Rhodia Operations | Procede de fabrication d'etoffes impregnees pour articles composites |
| WO2013004645A1 (de) | 2011-07-05 | 2013-01-10 | Basf Se | Feste partikel, enthaltend lactam, aktivator und katalysator, sowie verfahren zu deren herstellung und deren verwendung |
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- 2013-12-03 EP EP13814448.0A patent/EP2928653B1/de not_active Not-in-force
- 2013-12-03 KR KR1020157017619A patent/KR20150091388A/ko not_active Ceased
- 2013-12-03 BR BR112015013093A patent/BR112015013093A2/pt not_active Application Discontinuation
- 2013-12-03 CN CN201380072142.2A patent/CN105283286B/zh not_active Expired - Fee Related
- 2013-12-03 JP JP2015545778A patent/JP2016505664A/ja active Pending
- 2013-12-03 WO PCT/EP2013/075333 patent/WO2014086757A2/de not_active Ceased
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20210024105A (ko) * | 2018-08-03 | 2021-03-04 | 드레슬러 그룹 게엠베하 앤드 컴퍼니 케이지 | 플라스틱을 분쇄하고 그로부터 분말상 물질을 생산하기 위한 방법 및 장치 |
Also Published As
| Publication number | Publication date |
|---|---|
| BR112015013093A2 (pt) | 2017-07-11 |
| WO2014086757A3 (de) | 2014-07-31 |
| CN105283286B (zh) | 2018-02-02 |
| WO2014086757A2 (de) | 2014-06-12 |
| JP2016505664A (ja) | 2016-02-25 |
| EP2928653A2 (de) | 2015-10-14 |
| EP2928653B1 (de) | 2018-09-26 |
| CN105283286A (zh) | 2016-01-27 |
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