KR20150047643A - 유체 접촉 분해 방법을 위한 휘발유 황 감소 촉매 - Google Patents
유체 접촉 분해 방법을 위한 휘발유 황 감소 촉매 Download PDFInfo
- Publication number
- KR20150047643A KR20150047643A KR1020157009918A KR20157009918A KR20150047643A KR 20150047643 A KR20150047643 A KR 20150047643A KR 1020157009918 A KR1020157009918 A KR 1020157009918A KR 20157009918 A KR20157009918 A KR 20157009918A KR 20150047643 A KR20150047643 A KR 20150047643A
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- KR
- South Korea
- Prior art keywords
- catalyst
- present
- catalytic cracking
- sulfur
- rare earth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003054 catalyst Substances 0.000 title claims abstract description 147
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title abstract description 71
- 229910052717 sulfur Inorganic materials 0.000 title abstract description 71
- 239000011593 sulfur Substances 0.000 title abstract description 71
- 238000000034 method Methods 0.000 title abstract description 61
- 230000008569 process Effects 0.000 title abstract description 46
- 230000009467 reduction Effects 0.000 title description 18
- 238000004231 fluid catalytic cracking Methods 0.000 title description 5
- 239000010457 zeolite Substances 0.000 claims abstract description 59
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 55
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 49
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 47
- 238000004523 catalytic cracking Methods 0.000 claims abstract description 40
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 39
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 39
- 239000011701 zinc Substances 0.000 claims abstract description 39
- 238000005336 cracking Methods 0.000 claims description 27
- 230000003197 catalytic effect Effects 0.000 claims description 4
- 239000003208 petroleum Substances 0.000 claims description 4
- 150000002898 organic sulfur compounds Chemical class 0.000 claims description 3
- 239000000203 mixture Substances 0.000 abstract description 66
- 239000000047 product Substances 0.000 abstract description 36
- 239000012263 liquid product Substances 0.000 abstract description 7
- 150000001768 cations Chemical class 0.000 abstract description 6
- 239000002245 particle Substances 0.000 description 29
- 239000002002 slurry Substances 0.000 description 22
- 229930195733 hydrocarbon Natural products 0.000 description 21
- 150000002430 hydrocarbons Chemical class 0.000 description 21
- 239000000654 additive Substances 0.000 description 16
- 239000004215 Carbon black (E152) Substances 0.000 description 15
- -1 rare earth cations Chemical class 0.000 description 15
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 14
- 239000004927 clay Substances 0.000 description 14
- 150000002910 rare earth metals Chemical class 0.000 description 14
- 239000007921 spray Substances 0.000 description 14
- 238000000354 decomposition reaction Methods 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 10
- 239000011159 matrix material Substances 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 239000012266 salt solution Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 229930192474 thiophene Natural products 0.000 description 8
- FCEHBMOGCRZNNI-UHFFFAOYSA-N 1-benzothiophene Chemical class C1=CC=C2SC=CC2=C1 FCEHBMOGCRZNNI-UHFFFAOYSA-N 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 239000003209 petroleum derivative Substances 0.000 description 7
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
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- 230000000694 effects Effects 0.000 description 6
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- 150000002500 ions Chemical class 0.000 description 5
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- 229910052691 Erbium Inorganic materials 0.000 description 4
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- 230000002779 inactivation Effects 0.000 description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
- 150000007517 lewis acids Chemical class 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 150000003464 sulfur compounds Chemical class 0.000 description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 230000009849 deactivation Effects 0.000 description 3
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
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- 238000012545 processing Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000001694 spray drying Methods 0.000 description 3
- 239000012808 vapor phase Substances 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 2
- 229910052688 Gadolinium Inorganic materials 0.000 description 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910021193 La 2 O 3 Inorganic materials 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 description 2
- 229910052733 gallium Inorganic materials 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 2
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 2
- JCCCMAAJYSNBPR-UHFFFAOYSA-N 2-ethylthiophene Chemical compound CCC1=CC=CS1 JCCCMAAJYSNBPR-UHFFFAOYSA-N 0.000 description 1
- XQQBUAPQHNYYRS-UHFFFAOYSA-N 2-methylthiophene Chemical compound CC1=CC=CS1 XQQBUAPQHNYYRS-UHFFFAOYSA-N 0.000 description 1
- BTXIJTYYMLCUHI-UHFFFAOYSA-N 2-propylthiophene Chemical compound CCCC1=CC=CS1 BTXIJTYYMLCUHI-UHFFFAOYSA-N 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910052692 Dysprosium Inorganic materials 0.000 description 1
- 229910052693 Europium Inorganic materials 0.000 description 1
- 229910052689 Holmium Inorganic materials 0.000 description 1
- 229910052765 Lutetium Inorganic materials 0.000 description 1
- QENGPZGAWFQWCZ-UHFFFAOYSA-N Methylthiophene Natural products CC=1C=CSC=1 QENGPZGAWFQWCZ-UHFFFAOYSA-N 0.000 description 1
- 229910017493 Nd 2 O 3 Inorganic materials 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 229910052771 Terbium Inorganic materials 0.000 description 1
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
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- 238000002485 combustion reaction Methods 0.000 description 1
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- IYYZUPMFVPLQIF-UHFFFAOYSA-N dibenzothiophene Chemical class C1=CC=C2C3=CC=CC=C3SC2=C1 IYYZUPMFVPLQIF-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 1
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- 150000004820 halides Chemical class 0.000 description 1
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
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- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 230000003278 mimic effect Effects 0.000 description 1
- 229910052680 mordenite Inorganic materials 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
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- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
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- 229910052707 ruthenium Inorganic materials 0.000 description 1
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- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 210000004215 spore Anatomy 0.000 description 1
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- 229910052815 sulfur oxide Inorganic materials 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- RAOIDOHSFRTOEL-UHFFFAOYSA-N tetrahydrothiophene Chemical compound C1CCSC1 RAOIDOHSFRTOEL-UHFFFAOYSA-N 0.000 description 1
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- 238000009736 wetting Methods 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
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- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/085—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
- B01J29/088—Y-type faujasite
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- B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
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- B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
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- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
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- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
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- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1037—Hydrocarbon fractions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/202—Heteroatoms content, i.e. S, N, O, P
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US90245607P | 2007-02-21 | 2007-02-21 | |
| US60/902,456 | 2007-02-21 | ||
| PCT/US2008/001094 WO2008103224A1 (en) | 2007-02-21 | 2008-01-28 | Gasoline sulfur reduction catalyst for fluid catalytic cracking process |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020097019485A Division KR101544619B1 (ko) | 2007-02-21 | 2008-01-28 | 유체 접촉 분해 방법을 위한 휘발유 황 감소 촉매 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20150047643A true KR20150047643A (ko) | 2015-05-04 |
Family
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Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020157009918A Ceased KR20150047643A (ko) | 2007-02-21 | 2008-01-28 | 유체 접촉 분해 방법을 위한 휘발유 황 감소 촉매 |
| KR1020097019485A Expired - Fee Related KR101544619B1 (ko) | 2007-02-21 | 2008-01-28 | 유체 접촉 분해 방법을 위한 휘발유 황 감소 촉매 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020097019485A Expired - Fee Related KR101544619B1 (ko) | 2007-02-21 | 2008-01-28 | 유체 접촉 분해 방법을 위한 휘발유 황 감소 촉매 |
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| Country | Link |
|---|---|
| US (1) | US8901026B2 (enExample) |
| EP (1) | EP2121182B1 (enExample) |
| JP (1) | JP5335697B2 (enExample) |
| KR (2) | KR20150047643A (enExample) |
| CN (1) | CN101678339B (enExample) |
| AR (1) | AR065396A1 (enExample) |
| AU (1) | AU2008219190B2 (enExample) |
| BR (1) | BRPI0807925B1 (enExample) |
| CA (1) | CA2678810C (enExample) |
| CL (1) | CL2008000525A1 (enExample) |
| CO (1) | CO6231010A2 (enExample) |
| IL (1) | IL200409A0 (enExample) |
| MX (1) | MX2009008844A (enExample) |
| RU (1) | RU2442649C2 (enExample) |
| TW (1) | TWI441681B (enExample) |
| WO (1) | WO2008103224A1 (enExample) |
| ZA (1) | ZA200905883B (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110297585A1 (en) * | 2010-06-02 | 2011-12-08 | Air Liquide Large Industries U.S. Lp | Process For Reducing The Quantity Of Carbon Dioxide Produced In A Fluid Catalytic Cracking Regeneration Off Gas |
| TWI598335B (zh) * | 2012-10-25 | 2017-09-11 | W R 康格雷氏公司 | 用於製造吡啶及其烷基衍生物之改良方法、觸媒 |
| JP7012450B2 (ja) * | 2017-03-30 | 2022-01-28 | 日揮触媒化成株式会社 | 流動接触分解触媒の製造方法 |
| EP3998118A4 (en) * | 2019-07-09 | 2023-08-30 | China Petroleum & Chemical Corporation | Y-type molecular sieve containing rare earth and preparation method therefor, and catalytic cracking catalyst containing molecular sieve |
| JP7595638B2 (ja) * | 2019-07-09 | 2024-12-06 | 中国石油化工股▲ふん▼有限公司 | レアアースを含むy型分子篩、その製造方法、および当該分子篩を含む接触分解触媒 |
| CN117282462A (zh) * | 2023-09-01 | 2023-12-26 | 青岛惠城环保科技集团股份有限公司 | 一种sz/m值小于1的催化裂化催化剂的制备方法和应用 |
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-
2008
- 2008-01-28 WO PCT/US2008/001094 patent/WO2008103224A1/en not_active Ceased
- 2008-01-28 BR BRPI0807925A patent/BRPI0807925B1/pt not_active IP Right Cessation
- 2008-01-28 US US12/527,232 patent/US8901026B2/en not_active Expired - Fee Related
- 2008-01-28 RU RU2009134963/04A patent/RU2442649C2/ru not_active IP Right Cessation
- 2008-01-28 CN CN2008800129689A patent/CN101678339B/zh not_active Expired - Fee Related
- 2008-01-28 EP EP08724874.6A patent/EP2121182B1/en not_active Not-in-force
- 2008-01-28 MX MX2009008844A patent/MX2009008844A/es active IP Right Grant
- 2008-01-28 CA CA2678810A patent/CA2678810C/en not_active Expired - Fee Related
- 2008-01-28 JP JP2009550870A patent/JP5335697B2/ja not_active Expired - Fee Related
- 2008-01-28 AU AU2008219190A patent/AU2008219190B2/en not_active Ceased
- 2008-01-28 KR KR1020157009918A patent/KR20150047643A/ko not_active Ceased
- 2008-01-28 KR KR1020097019485A patent/KR101544619B1/ko not_active Expired - Fee Related
- 2008-02-19 TW TW097105712A patent/TWI441681B/zh not_active IP Right Cessation
- 2008-02-20 AR ARP080100684A patent/AR065396A1/es not_active Application Discontinuation
- 2008-02-20 CL CL200800525A patent/CL2008000525A1/es unknown
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2009
- 2009-08-13 IL IL200409A patent/IL200409A0/en unknown
- 2009-08-25 ZA ZA2009/05883A patent/ZA200905883B/en unknown
- 2009-09-18 CO CO09101679A patent/CO6231010A2/es not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| RU2009134963A (ru) | 2011-03-27 |
| WO2008103224A1 (en) | 2008-08-28 |
| ZA200905883B (en) | 2010-11-24 |
| RU2442649C2 (ru) | 2012-02-20 |
| JP5335697B2 (ja) | 2013-11-06 |
| EP2121182A1 (en) | 2009-11-25 |
| TWI441681B (zh) | 2014-06-21 |
| CN101678339B (zh) | 2013-01-02 |
| AR065396A1 (es) | 2009-06-03 |
| BRPI0807925A2 (pt) | 2014-07-15 |
| CL2008000525A1 (es) | 2008-08-29 |
| CA2678810A1 (en) | 2008-08-28 |
| MX2009008844A (es) | 2009-08-28 |
| JP2010519031A (ja) | 2010-06-03 |
| BRPI0807925B1 (pt) | 2017-02-14 |
| EP2121182A4 (en) | 2014-03-12 |
| IL200409A0 (en) | 2010-04-29 |
| KR20090115756A (ko) | 2009-11-05 |
| AU2008219190B2 (en) | 2013-05-09 |
| AU2008219190A1 (en) | 2008-08-28 |
| TW200848161A (en) | 2008-12-16 |
| EP2121182B1 (en) | 2018-07-04 |
| KR101544619B1 (ko) | 2015-08-17 |
| US8901026B2 (en) | 2014-12-02 |
| CO6231010A2 (es) | 2010-12-20 |
| CN101678339A (zh) | 2010-03-24 |
| CA2678810C (en) | 2015-08-25 |
| US20100133145A1 (en) | 2010-06-03 |
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