CA2678810C - Gasoline sulfur reduction catalyst for fluid catalytic cracking process - Google Patents
Gasoline sulfur reduction catalyst for fluid catalytic cracking process Download PDFInfo
- Publication number
- CA2678810C CA2678810C CA2678810A CA2678810A CA2678810C CA 2678810 C CA2678810 C CA 2678810C CA 2678810 A CA2678810 A CA 2678810A CA 2678810 A CA2678810 A CA 2678810A CA 2678810 C CA2678810 C CA 2678810C
- Authority
- CA
- Canada
- Prior art keywords
- catalyst
- zeolite
- rare earth
- zinc
- earth element
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000003054 catalyst Substances 0.000 title claims abstract description 205
- 238000000034 method Methods 0.000 title claims abstract description 85
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 83
- 229910052717 sulfur Inorganic materials 0.000 title claims abstract description 83
- 239000011593 sulfur Substances 0.000 title claims abstract description 83
- 230000008569 process Effects 0.000 title claims abstract description 58
- 238000004231 fluid catalytic cracking Methods 0.000 title claims description 9
- 230000009467 reduction Effects 0.000 title description 29
- 239000010457 zeolite Substances 0.000 claims abstract description 77
- 239000000203 mixture Substances 0.000 claims abstract description 74
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 69
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 67
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 67
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 48
- 238000005336 cracking Methods 0.000 claims abstract description 48
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 48
- 239000011701 zinc Substances 0.000 claims abstract description 48
- 238000004523 catalytic cracking Methods 0.000 claims abstract description 40
- 150000001768 cations Chemical class 0.000 claims abstract description 12
- 239000002245 particle Substances 0.000 claims description 38
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 20
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 20
- -1 gallolinium Chemical compound 0.000 claims description 17
- 239000011159 matrix material Substances 0.000 claims description 15
- 239000004927 clay Substances 0.000 claims description 14
- 239000011230 binding agent Substances 0.000 claims description 11
- 239000000377 silicon dioxide Substances 0.000 claims description 10
- 229910052691 Erbium Inorganic materials 0.000 claims description 5
- 229910052769 Ytterbium Inorganic materials 0.000 claims description 5
- 229910052765 Lutetium Inorganic materials 0.000 claims description 4
- 229910052775 Thulium Inorganic materials 0.000 claims description 4
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 claims description 4
- OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 claims description 4
- 239000003208 petroleum Substances 0.000 claims description 4
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052692 Dysprosium Inorganic materials 0.000 claims description 3
- 229910052693 Europium Inorganic materials 0.000 claims description 3
- 229910052689 Holmium Inorganic materials 0.000 claims description 3
- 229910052771 Terbium Inorganic materials 0.000 claims description 3
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 claims description 3
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 claims description 3
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 claims description 3
- 150000002898 organic sulfur compounds Chemical class 0.000 claims description 3
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 claims description 3
- 229910052723 transition metal Inorganic materials 0.000 claims description 3
- 150000003624 transition metals Chemical class 0.000 claims description 3
- 239000000047 product Substances 0.000 abstract description 38
- 239000012263 liquid product Substances 0.000 abstract description 7
- 229930195733 hydrocarbon Natural products 0.000 description 22
- 150000002430 hydrocarbons Chemical class 0.000 description 22
- 239000002002 slurry Substances 0.000 description 22
- 238000006243 chemical reaction Methods 0.000 description 18
- 150000002910 rare earth metals Chemical class 0.000 description 18
- 239000007921 spray Substances 0.000 description 18
- 239000004215 Carbon black (E152) Substances 0.000 description 17
- 239000000654 additive Substances 0.000 description 16
- 239000000243 solution Substances 0.000 description 12
- 239000000126 substance Substances 0.000 description 10
- FCEHBMOGCRZNNI-UHFFFAOYSA-N 1-benzothiophene Chemical class C1=CC=C2SC=CC2=C1 FCEHBMOGCRZNNI-UHFFFAOYSA-N 0.000 description 9
- 230000009849 deactivation Effects 0.000 description 9
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 8
- 239000012266 salt solution Substances 0.000 description 8
- 230000008901 benefit Effects 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 229930192474 thiophene Natural products 0.000 description 7
- 229910052782 aluminium Inorganic materials 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000003209 petroleum derivative Substances 0.000 description 6
- 239000011148 porous material Substances 0.000 description 6
- 239000012013 faujasite Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 230000008929 regeneration Effects 0.000 description 5
- 238000011069 regeneration method Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000002841 Lewis acid Substances 0.000 description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
- 150000007517 lewis acids Chemical class 0.000 description 4
- 230000014759 maintenance of location Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 150000003464 sulfur compounds Chemical class 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 238000013459 approach Methods 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 239000000571 coke Substances 0.000 description 3
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000001694 spray drying Methods 0.000 description 3
- 150000003577 thiophenes Chemical class 0.000 description 3
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 3
- 239000012808 vapor phase Substances 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910003120 Zn-Ce Inorganic materials 0.000 description 2
- 229910007612 Zn—La Inorganic materials 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 2
- 229910052815 sulfur oxide Inorganic materials 0.000 description 2
- RAOIDOHSFRTOEL-UHFFFAOYSA-N tetrahydrothiophene Chemical compound C1CCSC1 RAOIDOHSFRTOEL-UHFFFAOYSA-N 0.000 description 2
- LXUNZSDDXMPKLP-UHFFFAOYSA-N 2-Methylbenzenethiol Chemical compound CC1=CC=CC=C1S LXUNZSDDXMPKLP-UHFFFAOYSA-N 0.000 description 1
- JCCCMAAJYSNBPR-UHFFFAOYSA-N 2-ethylthiophene Chemical compound CCC1=CC=CS1 JCCCMAAJYSNBPR-UHFFFAOYSA-N 0.000 description 1
- XQQBUAPQHNYYRS-UHFFFAOYSA-N 2-methylthiophene Chemical compound CC1=CC=CS1 XQQBUAPQHNYYRS-UHFFFAOYSA-N 0.000 description 1
- BTXIJTYYMLCUHI-UHFFFAOYSA-N 2-propylthiophene Chemical compound CCCC1=CC=CS1 BTXIJTYYMLCUHI-UHFFFAOYSA-N 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910052688 Gadolinium Inorganic materials 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- QENGPZGAWFQWCZ-UHFFFAOYSA-N Methylthiophene Natural products CC=1C=CSC=1 QENGPZGAWFQWCZ-UHFFFAOYSA-N 0.000 description 1
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229910001423 beryllium ion Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000003421 catalytic decomposition reaction Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000005243 fluidization Methods 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- SOOARYARZPXNAL-UHFFFAOYSA-N methyl-thiophenol Natural products CSC1=CC=CC=C1O SOOARYARZPXNAL-UHFFFAOYSA-N 0.000 description 1
- 229910052680 mordenite Inorganic materials 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 125000001741 organic sulfur group Chemical group 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000011027 product recovery Methods 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 229910052566 spinel group Inorganic materials 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/085—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
- B01J29/088—Y-type faujasite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
- C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1037—Hydrocarbon fractions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/202—Heteroatoms content, i.e. S, N, O, P
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US90245607P | 2007-02-21 | 2007-02-21 | |
| US60/902,456 | 2007-02-21 | ||
| PCT/US2008/001094 WO2008103224A1 (en) | 2007-02-21 | 2008-01-28 | Gasoline sulfur reduction catalyst for fluid catalytic cracking process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2678810A1 CA2678810A1 (en) | 2008-08-28 |
| CA2678810C true CA2678810C (en) | 2015-08-25 |
Family
ID=39710349
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2678810A Expired - Fee Related CA2678810C (en) | 2007-02-21 | 2008-01-28 | Gasoline sulfur reduction catalyst for fluid catalytic cracking process |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US8901026B2 (enExample) |
| EP (1) | EP2121182B1 (enExample) |
| JP (1) | JP5335697B2 (enExample) |
| KR (2) | KR101544619B1 (enExample) |
| CN (1) | CN101678339B (enExample) |
| AR (1) | AR065396A1 (enExample) |
| AU (1) | AU2008219190B2 (enExample) |
| BR (1) | BRPI0807925B1 (enExample) |
| CA (1) | CA2678810C (enExample) |
| CL (1) | CL2008000525A1 (enExample) |
| CO (1) | CO6231010A2 (enExample) |
| IL (1) | IL200409A0 (enExample) |
| MX (1) | MX2009008844A (enExample) |
| RU (1) | RU2442649C2 (enExample) |
| TW (1) | TWI441681B (enExample) |
| WO (1) | WO2008103224A1 (enExample) |
| ZA (1) | ZA200905883B (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110297585A1 (en) * | 2010-06-02 | 2011-12-08 | Air Liquide Large Industries U.S. Lp | Process For Reducing The Quantity Of Carbon Dioxide Produced In A Fluid Catalytic Cracking Regeneration Off Gas |
| TWI598335B (zh) | 2012-10-25 | 2017-09-11 | Ｗ Ｒ 康格雷氏公司 | 用於製造吡啶及其烷基衍生物之改良方法、觸媒 |
| JP7012450B2 (ja) * | 2017-03-30 | 2022-01-28 | 日揮触媒化成株式会社 | 流動接触分解触媒の製造方法 |
| KR20220025200A (ko) * | 2019-07-09 | 2022-03-03 | 차이나 페트로리움 앤드 케미컬 코포레이션 | 희토류 함유 y형 분자체, 그의 제조 방법, 및 분자체를 함유하는 접촉 분해 촉매 |
| TWI887252B (zh) * | 2019-07-09 | 2025-06-21 | 大陸商中國石油化工科技開發有限公司 | 含稀土的y型分子篩及其製備方法、含該分子篩的催化裂解催化劑 |
| CN117282462A (zh) * | 2023-09-01 | 2023-12-26 | 青岛惠城环保科技集团股份有限公司 | 一种sz/m值小于1的催化裂化催化剂的制备方法和应用 |
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| US3804780A (en) | 1972-03-15 | 1974-04-16 | Mobil Oil Corp | Catalyst of zinc-rare earth exchanged zeolite |
| US4957892A (en) | 1980-07-29 | 1990-09-18 | Uop | Process for combusting solid sulfur containing material |
| US4340465A (en) | 1980-09-29 | 1982-07-20 | Chevron Research Company | Dual component crystalline silicate cracking catalyst |
| US4405443A (en) | 1982-03-29 | 1983-09-20 | Standard Oil Company (Indiana) | Process for removing sulfur oxides from a gas |
| US4542116A (en) | 1982-03-29 | 1985-09-17 | The Standard Oil Company | Catalyst for removing sulfur oxides from a gas |
| US4764269A (en) | 1985-07-15 | 1988-08-16 | W. R. Grace & Co. | Cracking catalyst |
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| SU1482931A1 (ru) * | 1987-06-04 | 1989-05-30 | Предприятие П/Я А-7850 | Способ получени высокооктанового бензина |
| US4957718A (en) | 1987-11-24 | 1990-09-18 | Uop | Process for reducing emissions of sulfur oxides and composition useful in same |
| US5043308A (en) * | 1989-03-29 | 1991-08-27 | Amoco Corporation | Crystalline rare earth aluminum borates |
| US5174890A (en) * | 1989-07-31 | 1992-12-29 | Union Oil Company Of California | Catalytic cracking using a metals scavenging composition |
| US5021146A (en) | 1989-12-28 | 1991-06-04 | Mobil Oil Corporation | Reducing NOx emissions with group IIIB compounds |
| US5037538A (en) | 1990-02-26 | 1991-08-06 | Mobil Oil Corporation | Catalytic cracking process with isolated catalyst for conversion of NO.sub.x |
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| JPH11300208A (ja) | 1998-04-21 | 1999-11-02 | Idemitsu Kosan Co Ltd | 接触分解触媒 |
| JP4067171B2 (ja) * | 1998-04-22 | 2008-03-26 | 触媒化成工業株式会社 | 炭化水素流動接触分解用触媒組成物 |
| US6974787B2 (en) | 1998-08-31 | 2005-12-13 | Exxonmobil Corporation | Gasoline sulfur reduction in fluid catalytic cracking |
| US6846403B2 (en) | 1998-12-28 | 2005-01-25 | Mobil Oil Corporation | Gasoline sulfur reduction in fluid catalytic cracking |
| DE19962669B4 (de) | 1998-12-28 | 2004-07-01 | Mobil Oil Corp. | Verringerung des Schwefelgehaltes in Benzin beim katalytischen Wirbelschichtcracken |
| US6528447B1 (en) | 1999-03-19 | 2003-03-04 | Indian Oil Corporation Limited | Process for the preparation of a catalyst composite |
| RU2166529C1 (ru) * | 1999-09-01 | 2001-05-10 | Левинбук Михаил Исаакович | Способ получения моторных топлив |
| US6635169B1 (en) | 1999-09-20 | 2003-10-21 | Mobil Oil Corporation | Method for reducing gasoline sulfur in fluid catalytic cracking |
| US6096194A (en) | 1999-12-02 | 2000-08-01 | Zeochem | Sulfur adsorbent for use with oil hydrogenation catalysts |
| DE10036055A1 (de) | 2000-07-25 | 2002-02-07 | Bayer Ag | Verfahren zur Herstellung von di- oder trifunktionellen Initiatorsystemen auf Lithiumbasis sowie deren Verwendung |
| US20020043154A1 (en) | 2000-08-25 | 2002-04-18 | Engelhard Corporation | Zeolite compounds for removal of sulfur compounds from gases |
| BR0100680A (pt) | 2001-02-21 | 2002-11-05 | Petroleo Brasileiro Sa | Composições catalìticas multiparticuladas para craqueamento catalìtico fluido (fcc), processo de craqueamento catalìtico fluido (fcc) e uso das mesmas |
| US6635168B2 (en) | 2001-04-13 | 2003-10-21 | W. R. Grace & Co.-Conn | Gasoline sulfur reduction catalyst for fluid catalytic cracking process |
| RU2283177C2 (ru) * | 2001-08-14 | 2006-09-10 | Петролеум Энерджи Сентер | Катализатор для каталитического крекинга тяжелых нефтепродуктов в псевдоожиженном слое и способ каталитического крекинга в псевдоожиженном слое |
| US6709572B2 (en) * | 2002-03-05 | 2004-03-23 | Exxonmobil Research And Engineering Company | Catalytic cracking process |
| JP2004066035A (ja) | 2002-08-02 | 2004-03-04 | Nippon Oil Corp | 炭化水素の脱硫方法および燃料電池システム |
| CN1261216C (zh) | 2003-05-30 | 2006-06-28 | 中国石油化工股份有限公司 | 一种含分子筛的烃类裂化催化剂及其制备方法 |
| US8084383B2 (en) * | 2004-03-16 | 2011-12-27 | W.R. Grace & Co.-Conn. | Gasoline sulfur reduction catalyst for fluid catalytic cracking process |
| US20050205466A1 (en) | 2004-03-19 | 2005-09-22 | Beswick Colin L | Zn-containing FCC catalyst and use thereof for the reduction of sulfur in gasoline |
| TWI428180B (zh) * | 2005-02-25 | 2014-03-01 | Grace W R & Co | 適用於流體化觸媒裂解程序之汽油硫減量觸媒 |
-
2008
- 2008-01-28 AU AU2008219190A patent/AU2008219190B2/en not_active Ceased
- 2008-01-28 MX MX2009008844A patent/MX2009008844A/es active IP Right Grant
- 2008-01-28 WO PCT/US2008/001094 patent/WO2008103224A1/en not_active Ceased
- 2008-01-28 CN CN2008800129689A patent/CN101678339B/zh not_active Expired - Fee Related
- 2008-01-28 BR BRPI0807925A patent/BRPI0807925B1/pt not_active IP Right Cessation
- 2008-01-28 KR KR1020097019485A patent/KR101544619B1/ko not_active Expired - Fee Related
- 2008-01-28 EP EP08724874.6A patent/EP2121182B1/en not_active Not-in-force
- 2008-01-28 CA CA2678810A patent/CA2678810C/en not_active Expired - Fee Related
- 2008-01-28 JP JP2009550870A patent/JP5335697B2/ja not_active Expired - Fee Related
- 2008-01-28 US US12/527,232 patent/US8901026B2/en not_active Expired - Fee Related
- 2008-01-28 RU RU2009134963/04A patent/RU2442649C2/ru not_active IP Right Cessation
- 2008-01-28 KR KR1020157009918A patent/KR20150047643A/ko not_active Ceased
- 2008-02-19 TW TW097105712A patent/TWI441681B/zh not_active IP Right Cessation
- 2008-02-20 AR ARP080100684A patent/AR065396A1/es not_active Application Discontinuation
- 2008-02-20 CL CL200800525A patent/CL2008000525A1/es unknown
-
2009
- 2009-08-13 IL IL200409A patent/IL200409A0/en unknown
- 2009-08-25 ZA ZA2009/05883A patent/ZA200905883B/en unknown
- 2009-09-18 CO CO09101679A patent/CO6231010A2/es not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0807925A2 (pt) | 2014-07-15 |
| EP2121182A4 (en) | 2014-03-12 |
| KR20150047643A (ko) | 2015-05-04 |
| CL2008000525A1 (es) | 2008-08-29 |
| US8901026B2 (en) | 2014-12-02 |
| EP2121182A1 (en) | 2009-11-25 |
| KR20090115756A (ko) | 2009-11-05 |
| AU2008219190B2 (en) | 2013-05-09 |
| AR065396A1 (es) | 2009-06-03 |
| CN101678339A (zh) | 2010-03-24 |
| MX2009008844A (es) | 2009-08-28 |
| RU2442649C2 (ru) | 2012-02-20 |
| US20100133145A1 (en) | 2010-06-03 |
| WO2008103224A1 (en) | 2008-08-28 |
| ZA200905883B (en) | 2010-11-24 |
| IL200409A0 (en) | 2010-04-29 |
| RU2009134963A (ru) | 2011-03-27 |
| AU2008219190A1 (en) | 2008-08-28 |
| BRPI0807925B1 (pt) | 2017-02-14 |
| CN101678339B (zh) | 2013-01-02 |
| KR101544619B1 (ko) | 2015-08-17 |
| CO6231010A2 (es) | 2010-12-20 |
| JP5335697B2 (ja) | 2013-11-06 |
| EP2121182B1 (en) | 2018-07-04 |
| CA2678810A1 (en) | 2008-08-28 |
| TW200848161A (en) | 2008-12-16 |
| JP2010519031A (ja) | 2010-06-03 |
| TWI441681B (zh) | 2014-06-21 |
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Legal Events
| Date | Code | Title | Description |
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| EEER | Examination request |
Effective date: 20130123 |
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| MKLA | Lapsed |
Effective date: 20210128 |