KR20140010050A - 자가열 프로판 탈수소화를 위한 화염 분무 열분해에 의해 제조된 촉매 - Google Patents
자가열 프로판 탈수소화를 위한 화염 분무 열분해에 의해 제조된 촉매Info
- Publication number
- KR20140010050A KR20140010050A KR1020137022257A KR20137022257A KR20140010050A KR 20140010050 A KR20140010050 A KR 20140010050A KR 1020137022257 A KR1020137022257 A KR 1020137022257A KR 20137022257 A KR20137022257 A KR 20137022257A KR 20140010050 A KR20140010050 A KR 20140010050A
- Authority
- KR
- South Korea
- Prior art keywords
- precursor compound
- pyrolysis
- zirconium
- lanthanum
- acetylacetonate
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 57
- 238000006356 dehydrogenation reaction Methods 0.000 title claims abstract description 16
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- 239000001294 propane Substances 0.000 title claims description 11
- 238000005118 spray pyrolysis Methods 0.000 title description 5
- 239000002243 precursor Substances 0.000 claims abstract description 61
- 150000001875 compounds Chemical class 0.000 claims abstract description 54
- 238000000034 method Methods 0.000 claims abstract description 42
- 238000000197 pyrolysis Methods 0.000 claims abstract description 42
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- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 24
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- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 8
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims abstract description 8
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- ZOAIGCHJWKDIPJ-UHFFFAOYSA-M caesium acetate Chemical compound [Cs+].CC([O-])=O ZOAIGCHJWKDIPJ-UHFFFAOYSA-M 0.000 claims abstract description 7
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- 238000004519 manufacturing process Methods 0.000 claims description 9
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- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
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- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 150000002823 nitrates Chemical class 0.000 description 3
- 239000012454 non-polar solvent Substances 0.000 description 3
- 239000002798 polar solvent Substances 0.000 description 3
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Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
- B01J37/349—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of flames, plasmas or lasers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/58—Platinum group metals with alkali- or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
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- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
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- C—CHEMISTRY; METALLURGY
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- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
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- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
- C07C5/3335—Catalytic processes with metals
- C07C5/3337—Catalytic processes with metals of the platinum group
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- C—CHEMISTRY; METALLURGY
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- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
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- C—CHEMISTRY; METALLURGY
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- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
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- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
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- C—CHEMISTRY; METALLURGY
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- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/56—Platinum group metals
- C07C2523/63—Platinum group metals with rare earths or actinides
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
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- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Health & Medical Sciences (AREA)
- Plasma & Fusion (AREA)
- Toxicology (AREA)
- Dispersion Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
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| EP11151937 | 2011-01-25 | ||
| EP11151937.7 | 2011-01-25 | ||
| PCT/IB2012/050302 WO2012101566A1 (fr) | 2011-01-25 | 2012-01-23 | Catalyseur obtenu par pyrolyse de flamme pour la déshydrogénation autothermique du propane |
Publications (1)
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|---|---|
| KR20140010050A true KR20140010050A (ko) | 2014-01-23 |
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| KR1020137022257A KR20140010050A (ko) | 2011-01-25 | 2012-01-23 | 자가열 프로판 탈수소화를 위한 화염 분무 열분해에 의해 제조된 촉매 |
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| EP (1) | EP2667969A1 (fr) |
| JP (1) | JP2014511258A (fr) |
| KR (1) | KR20140010050A (fr) |
| CN (1) | CN103379958A (fr) |
| BR (1) | BR112013019046A2 (fr) |
| WO (1) | WO2012101566A1 (fr) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8933262B2 (en) | 2011-05-24 | 2015-01-13 | Basf Se | Process for preparing polyisocyanates from biomass |
| DE102015112612A1 (de) * | 2015-07-31 | 2017-02-02 | Leibniz-Institut Für Katalyse E.V. An Der Universität Rostock | Verfahren zur Herstellung von Olefinen sowie Katalysator |
| JP2018177750A (ja) * | 2017-04-21 | 2018-11-15 | Ｊｘｔｇエネルギー株式会社 | 不飽和炭化水素の製造方法及び脱水素触媒の再生方法 |
| JP7064896B2 (ja) * | 2018-02-15 | 2022-05-11 | Ｅｎｅｏｓ株式会社 | 不飽和炭化水素の製造方法 |
| JP7064897B2 (ja) * | 2018-02-15 | 2022-05-11 | Ｅｎｅｏｓ株式会社 | 不飽和炭化水素の製造方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19654391A1 (de) * | 1996-12-27 | 1998-07-02 | Basf Ag | Katalysator zur selektiven Herstellung von Propylen aus Propan |
| DE19937107A1 (de) * | 1999-08-06 | 2001-02-08 | Basf Ag | Katalysator mit bimodaler Porenradienverteilung |
| DE10333755A1 (de) * | 2003-07-24 | 2005-03-31 | Basf Ag | Verfahren zur Dehydrierung von Carbonylverbindungen |
| CN101164690A (zh) * | 2006-10-20 | 2008-04-23 | 中国科学院大连化学物理研究所 | 一种负载型铂基三元催化剂及制法和应用 |
| EP2432590A1 (fr) * | 2009-05-20 | 2012-03-28 | Basf Se | Catalyseur monolithique et son utilisation |
| CN101773850B (zh) * | 2010-01-28 | 2012-02-15 | 清华大学 | 一种低碳烷烃脱氢制烯烃催化剂及其应用 |
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2012
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- 2012-01-23 JP JP2013549929A patent/JP2014511258A/ja not_active Withdrawn
- 2012-01-23 CN CN2012800086590A patent/CN103379958A/zh active Pending
- 2012-01-23 EP EP12739695.0A patent/EP2667969A1/fr not_active Withdrawn
- 2012-01-23 BR BR112013019046A patent/BR112013019046A2/pt not_active IP Right Cessation
- 2012-01-23 WO PCT/IB2012/050302 patent/WO2012101566A1/fr active Application Filing
Also Published As
| Publication number | Publication date |
|---|---|
| CN103379958A (zh) | 2013-10-30 |
| WO2012101566A1 (fr) | 2012-08-02 |
| BR112013019046A2 (pt) | 2017-05-02 |
| JP2014511258A (ja) | 2014-05-15 |
| EP2667969A1 (fr) | 2013-12-04 |
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