KR20120043254A - Cosmetic pack composition containing jeju scoria powder - Google Patents

Abstract

PURPOSE: A composition containing Jeju scoria for a cosmetic pack is provided to remove various inflammation sources and to prevent and relieve skin trouble and acne. CONSTITUTION: A composition for skin cosmetic contains 5-40 weight parts of Jeju scoria, 0.1-5 weight parts of tangerine extract, and 0.1-5 weight parts of Ecklonia cava extract as an active ingredient. The composition is manufactured in the form of a sheet type mask pack, topical cosmetic patch, cream type cosmetic pack, or gel type cosmetic. The extract is prepared using water, low alcohol(methanol, ethanol), mixture thereof, acetone, ethyl acetate, or 1,3-butylene glycol solution.

Description

Cosmetic pack composition containing Jeju scoria powder

The present invention relates to a composition for skin care packs containing Jeju volcanic stone cluster, more specifically, Jeju volcanic stone cluster, citrus extract and Ecklonia cava extract to remove various inflammatory sources of skin and adsorb skin toxin to acne or skin trouble The present invention relates to a Jeju volcanic stone cluster beauty pack composition having an excellent effect of alleviating or preventing the skin, preventing whitening, aging, skin moisturizing and skin elasticity.

The skin, which consists of the epidermis, the dermis, and the subcutaneous fat, is the largest organ that makes up the human body, and is an important organ that performs various functions such as protective function, barrier function, temperature control function, excretory function, and respiratory function. As the skin ages, the skin suddenly deteriorates its function, and in particular, external factors such as increased ultraviolet rays due to the destruction of the ozone layer, air pollution, pollution, excessive use of synthetic detergents, and inflammation, cell destruction, fatigue, and psychological stress. Due to internal factors, skin wastes increase, acne, atopic dermatitis, blotch, and spots are generated.

In particular, free radicals or free radicals generated by ultraviolet rays or external environmental factors attack cell membranes and destroy cells, resulting in inflammation of the skin. Wrinkles are formed by wrinkling, and the skin ages. The physiological changes of the skin according to aging include the thinning of the epidermis, dermis, and subcutaneous tissue, which are components of the skin, and the lipid barrier that functions as a skin barrier. As the lipid composition and content of the lipid barrier change, its function is drastically deteriorated, so that the moisture content of the skin decreases, the skin dries, and the phenomenon of causing blemishes, freckles, pigmentation, or various skin lesions.

Wrinkle formation, skin elasticity reduction, pigmentation, blemishes, acne, atopic dermatitis, etc. due to skin aging are one of the most researched areas for skin protection and beauty in the cosmetic field.

Various cosmetics have been researched to solve the skin aging phenomenon and various skin problems, and among them, the beauty pack is easy to use and can bring a certain skin improvement effect even with a single use.

However, conventional cosmetic packs have a problem that various chemicals are added to the resulting side effects. For example, inhibiting free radicals is an important factor in cosmetics for preventing skin aging, and there are known free radical oxidizing and antioxidant substances used as raw materials for cosmetics, medicines, and foods. When applied to skin, safety is a problem and its use is limited.

In addition, various cosmetic packs including chemical ingredients for removing waste products such as sebum and treating skin problems such as acne and rashes have been developed and used, but various skin side effects have been reported due to repeated use. Therefore, in terms of effects, it is required to develop a beauty pack using natural materials that are guaranteed to be safe for human skin without falling behind cosmetic packs containing chemical substances. In addition, the skin types of modern people are much more diversified, and it is common to show different types by region, and many people have sensitive or inflammatory skin such as allergy, atopy, and acne, so that they have no irritation and almost no toxicity and can remove waste products. There is a need for a study on a cosmetic pack composition that can exhibit the desired effect especially while having various effects such as inflammatory skin improvement effect, anti-aging, whitening, elasticity, and moisturizing evenly.

The present invention is to provide a skin cosmetic composition for removing the various inflammatory sources of the skin by using Jeju volcanic stone clusters, citrus extracts and Ecklonia cava extract in the beauty pack to absorb or to reduce the acne or skin troubles. have. In addition, the present invention is to provide a skin care pack that prevents the skin trouble occurs while the effect appears for each skin type while having various functions such as whitening, anti-aging, skin elasticity, moisturizing function evenly.

The cosmetic composition mainly comprising the Jeju volcanic stone cluster of the present invention for achieving the above object is 5 to 40 parts by weight of Jeju volcanic stone cluster, 0.1 to 5 parts by weight of citrus extract, and 5 to 10 parts by weight of Ecklonia cava extract as main active ingredients.

Cosmetic composition composed mainly of Jeju volcanic stone clusters of the present invention for achieving the above object is characterized in that it is produced in the form of one type selected from sheet mask pack, topical cosmetic patch, cream type cosmetic pack, gel type cosmetic pack.

By using the present invention volcanic stone clusters, citrus extracts and Ecklonia cava extract is provided a composition for skin care packs that can remove various inflammatory sources of the skin and adsorb skin toxins to alleviate or prevent acne or skin problems. In addition, the present invention provides a cosmetic pack that is excellent in the ability of whitening, anti-aging, skin elasticity, skin moisturizing, and does not cause skin problems.

Hereinafter, the cosmetic composition mainly containing the volcanic stone cluster of the present invention will be described in more detail.

The cosmetic composition mainly comprising Jeju volcanic stone clusters of the present invention contains 5 to 40 parts by weight of Jeju volcanic stone clusters, 0.1 to 5 parts by weight of citrus extracts, and 0.1 to 5 parts by weight of persimmon extracts.

The first pulverized volcanic stone clusters collected from Oreum in Jeju Island were roughly about 200 mesh, and heavy metal foreign substances such as arsenic (less than 2 ppm) and lead (less than 20 ppm) were removed and microorganisms (100 cfu / g) were sterilized. Thereafter, to prepare a powder suitable for use in skin care packs, either one of the ball mill or the jet mill was used for the second milling, and a high purity fine powder of 400 to 1340 mesh was obtained through a cyclone filter and a dust collector. The above-mentioned Jeju volcanic stone cluster fine powder has a characteristic that the surface area increases and the diffusion distance to the adsorption site becomes shorter as the particle size increases, so that the adsorption amount and adsorption rate of heavy metal ions increase.

The volcanic stone clusters of Jeju are sterilized at a temperature of 850 ~ 1250 ℃, so they must be disinfected at 850 ℃. Will have In addition, when the citrus extract and the Ecklonia cava extract are mixed with the activated pores act as a uniform carrier can be expected to play a role in improving the function of these extracts.

The Jeju volcanic stone cluster of the present invention comprises aluminum (228 ppm), calcium (235 ppm), iron oxide (237 ppm), and magnesium (324 ppm) as main components, and as a trace inorganic component, potassium (30 ppm) and sodium ( 58 ppm), manganese (20 ppm), nickel (3 ppm), zinc (3 ppm), especially sulfur (8 ppm) or tritium (2.5 ppm) and valnium (4 ppm), with slightly alkaline pH 8.45 to be. In addition, the Jeju volcanic stone cluster exhibits an excellent adsorption rate capable of adsorbing 90% or more of arsenic and lead components harmful to the human body in one pass when filtered through water.

Jeju volcanic stone clusters according to the present invention is preferably 5 to 40% by weight based on the total weight of the composition. This is because the effect can not be expected at less than 5% by weight, there is a difficulty in the safety or formulation formulation above 40% by weight.

Citrus fruits, citrus fruits, are widely used in ornamental, edible, medicinal and spice, etc., and the fruit peels are called tangerine peel, dermis, blueberry peel, green skin and stirrup, and seeds have been widely used for medicinal use since ancient times. It is known to be effective mainly in circulating diseases and various congestion. The herbaceous tree is described as citrus peel digests food and improves the inside, and the medicinal dictionary shows that it is effective in digesting and detoxifying food poisoning. Citrus fruits are rich in vitamins B1, B2, C and various organic acids, as well as limonoids and blood vessels that are known to be excellent anticancer effects and detoxification of liver, anticancer, anti-inflammatory, and antibacterial properties. Hesperidine, which is known to be potent, is known to be rich (Journal of Cardiovascular Pharmacology 1993 Aug; 22 (2): 225-30).

Citrus extract used in the present invention is not only a leaching liquid obtained by leaching and transferring from citrus fruits, but also a concentrate obtained by partially or fully concentrating the leaching liquid, or a stagnation, whole, regular, flow extract and tangerine prepared by drying the above concentrate again. It contains all the chemicals in the plant, as well as the main effect of the plant itself.

Citrus extracts according to the present invention typically include polar solvents such as lower alcohols such as methanol, ethanol, isopropanol, butanol, acetone or ethyl methyl ketone to produce warm jujube persimmon, true fragrance, and palm extract. Can be used, but is not limited thereto. In addition, these organic solvents may be used alone or in combination with water. The extraction method may be used by appropriately selecting and applying a method commonly known in the art.

On the other hand, when the tangerine extract according to the present invention is used in the skin care pack is preferably 0.1 to 5% by weight relative to the total weight of the composition. This is because the effect can not be expected at less than 0.1% by weight, there is a difficulty in the safety or formulation formulation above 5% by weight. However, the amount of the citrus extract is not particularly limited.

Ecklonia cava used in the present invention is a perennial seaweed belonging to the kelp family of brown seaweed. Distributed on the south east coast, south coast and Jeju island, it is the most mature in spring. The stem is a thick cylinder, and the upper part is the flat leaf part. In the spring, between the stem and the fronds, a new frond grows for 3-4 years. The color is brown, but when it is dry, it becomes black and the quality is leather. Dried Ecklonia has been used as a raw material for alginic acid or as a fertilizer for bulb crops, but it has not been developed as a cosmetic ingredient for high value-added foods, medicines and cosmetics (Kang, JW Bull. Pusan Fish. Coll., 7, 1-125, 12; (1966).

The present invention provides a solvent extract of Ecklonia cava which can be usefully used as a material for skin beauty pack, Ecklonia cava extract suitable for the purpose of the present invention can be prepared according to conventional extraction methods of drying, grinding, extraction, filtration and concentration. .

Ecklonia cava, which is the material for extraction, can be used by drying it or as it is. It is preferable to use it by drying, At this time, natural drying or hot air drying can be used as a drying method. In the embodiment of the present invention was used to wash the Ecklonia cava in purified water and naturally dried in the shade. Purified water is water sterilized by illuminating ion-exchanged water with an ultraviolet lamp to remove bacteria and metal ions. The dried Ecklonia cava is used by pulverizing with a pulverizer to facilitate solvent extraction and can be used without distinction of size, but preferably pulverized to a size of 2 to 3 cm.

Finely chopped or dried dried Ecklonia cava extract is used as a solvent. Ecklonia cava extract solvents include water, lower alcohol (methanol, ethanol), a mixture of water and lower alcohol, acetone, ethyl acetate and 1,3- Butylene glycol aqueous solution can be used. The above-mentioned extracts are particularly suitable but not necessarily limited to the extraction solvents, and the Ecklonia cava extract can be prepared using other solvents similar in physical and chemical properties to the above-mentioned solvents. The addition amount of the extraction solvent is suitably added to 1 to 20 times the weight of the Ecklonia cava. Extraction temperature and extraction time is preferably deposited for 1 to 15 days at 10 ~ 30 ℃.

The whitening cosmetic of the present invention contains the Ecklonia cava extract 0.1 to 5% by weight, preferably 0.5 to 2% by weight, less than 0.1% by weight, the effect is insignificant, when it exceeds 5% by weight economically inefficient to be. However, the amount of the Ecklonia cava extract is not particularly limited.

The present invention will be described in more detail with reference to the following Examples. However, these examples are intended to illustrate the invention, it is apparent to those skilled in the art that the scope of the present invention is not limited to these examples.

Example 1 Preparation of Jeju Volcanic Stone Cluster

1 kg of volcanic stone clusters collected from Oreum in Jeju Island were first roughly pulverized to about 200 mesh and heated at 800 ° C. for 12 hours to remove harmful heavy metals and sterilizing microorganisms. The first coarsely pulverized Jeju volcanic stone cluster was cooled to room temperature and placed in a ball mill for 2 hours, and then pulverized for 24 hours. A high purity fine powder of 160 g of 1340 mesh was obtained through a cyclone filter and a dust collector.

Example 2 Preparation of Citrus Fruit Extract

After washing the citrus fruits with purified water and put the dried and dried dried 100 g in 1 L of 70% ethanol and extracted by cooling at room temperature for 48 hours. The extract was filtered with 0.45 μm filter paper and dried at 50 ° C. using a rotary evaporator to obtain a dry weight of 30 g.

Example 3 Preparation of Ecklonia cava Extract

After washing with purified water and drying, 1 kg of Ecklonia cava was pulverized into particles of 2-3 cm in 9 L of water and extracted for 12 to 24 hours at 15 to 25 ℃, and filtered through a filter paper Whatman 5. The extract was concentrated under reduced pressure at 30 ~ 40 ℃ using a distillation apparatus (Buich, Switzerland) with a cooling condenser to obtain 387 g (dry weight) of dried Ecklonia cava extract.

Example 4 Preparation of Skin Beauty Pack Containing Jeju Volcanic Stone Cluster, Citrus Extract and Ecklonia cava Extract

As described in Table 1, the weight of each component was emulsified at high speed to homogenize the Jeju volcanic stone cluster to act as a carrier of the citrus extract and the Ecklonia cava extract in the cosmetic pack, and a stable formulation could be prepared for a long time.

ingredient Content (% by weight) Jeju volcanic stone cluster (Example 1) 30 Citrus Extract (Example 2) 4 Ecklonia cava extract (Example 3) 4 Polyvinyl alcohol 14 glycerin 10 Cellulose sword 0.3 PEG 4000 One Propylene glycol 5 pH regulator Quantity Incense, pigment, preservative a very small amount Purified water to 100

Comparative Example 1 Preparation of Skin Care Pack Containing Jeju Volcanic Stone Cluster

As described in Table 2, the weight of each component was weighted and emulsified at high speed to uniformly distribute Jeju volcanic stone clusters in the cosmetic pack, and a stable formulation could be prepared for a long time.

ingredient Content (% by weight) Jeju volcanic stone cluster (Example 1) 30 Polyvinyl alcohol 14 glycerin 10 Cellulose gum 0.3 PEG 4000 One Propylene glycol 5 pH regulator Quantity Incense, pigment, preservative a very small amount Purified water to 100

Experimental Example 1 Anion Release Measurement

Prepared by preparing a cosmetic pack mixed with the composition of Example 4 of the present invention. The control group prepared a cosmetic pack containing Jeju volcanic stone clusters according to the composition of Comparative Example 1. It was tested at room temperature 27 ℃, humidity 49% and atmospheric anion water 108 / cc by using the charged particle measuring device, and the result of displaying the number of ions per unit volume by measuring the anion released from the measurement object is shown in Table 3 below. Shown in

division Anion (ION / cc) Example 4 950 Comparative Example 1 370

As shown in Table 3, it was found that the amount of negative ions released from the beauty pack of the present invention was much higher than that of the beauty pack containing only the Jeju volcanic stone cluster of Comparative Example 1.

Experimental Example 2 Experiment of Measuring Skin Moisturizing Effect

Prepared by preparing a cosmetic pack mixed with the composition of Example 4 of the present invention. The control group prepared a cosmetic pack containing Jeju volcanic stone clusters according to the composition of Comparative Example 1. As a control group, 10 women in their 30's and 60's were divided into three groups. After washing several times with water, water was removed and purified water, Example 4, and Comparative Example 1 were corrected after 5 minutes, respectively. After 10 minutes, it was measured using a corneometer (Courage-Khazaka Electronics, Germany; CM 825), and measured 5 times at 10 minute intervals. In the experiment, the room temperature was 23 ℃ and the relative humidity was 22%, and the water content was calculated by the following equation. The average value was used by measuring three times repeatedly, and the average value for 40 people is described in Table 4 below.

Moisture content (%) = value after sample application-value before sample application

Minutes Purified water(%) Example 4 (%) Comparative Example 1 (%) 10 8.5 70.5 23.5 20 5.4 55.5 21.2 30 0.1 47.0 14.0 40 0.0 35.2 7.1 50 0.0 23.4 3.0 60 0.0 15.5 1.4

As shown in Table 4, compared to the cosmetic pack containing only Jeju volcanic stone cluster of Comparative Example 1, the moisture content of the case of using the cosmetic pack of the present invention was significantly higher, it was found that the lasting effect was also excellent.

Experimental Example 3 Wrinkle Prevention Effect Measurement Experiment

Prepared by preparing a cosmetic pack mixed with the composition of Example 4 of the present invention. The control group prepared a cosmetic pack containing Jeju volcanic stone clusters according to the composition of Comparative Example 1. The elastase inhibitory activity was measured about the prepared composition. The measurement of elastase inhibitory activity was measured using azocasein as follows. That is, 0.005 g of azocasein was dissolved in 0.2 M Tris-CI buffer (pH 8.0) and used as a substrate. In this experiment, 1 unit / 100 μl elastase and 0.8 mM N-Suc- (Ala) 3-ρ-nitroanilide were added to 0.2 M Tris-CI buffer (pH 8.0) for 20 minutes at 25 ° C. Absorbance was measured at nm to quantify the amount of ρ-nitroanilide produced from the substrate. One unit of elastase inhibitory activity was defined as the amount of elastase enzyme that produced 1 umol of ρ-nitroanilide per minute. In addition, inhibitory activity is computed from the following formula.

[Elastase inhibitory activity (%) = (1-B / A) × 100]

* A: Elastase of untreated group

* B: Elastase of treatment group

division Elastase inhibitory activity (%) Example 4 89.9 Comparative Example 1 39.4

As shown in Table 5, the cosmetic pack composition of Example 4 of the present invention, compared to the cosmetic pack composition containing only Jeju volcanic stone cluster of Comparative Example 1 was found to be excellent in effect as 89.9% of the elastase inhibitory activity. Therefore, it can be seen that the cosmetic pack composition containing the Jeju volcanic stone cluster, citrus extract and Ecklonia cava extract of the present invention has excellent elastase inhibitory activity and excellent anti-wrinkle function.

Experimental Example 4 Whitening Effect Measurement Experiment

Prepared by preparing a cosmetic pack mixed with the composition of Example 4 of the present invention. The control group prepared a cosmetic pack containing Jeju volcanic stone clusters according to the composition of Comparative Example 1. The prepared compositions were analyzed for chromaticity (brightness, redness, yellowness) and tyrosinase inhibitory activity. The results are shown in Table 6.

Target Degree of coloring Tyrosinase Inhibitory Activity (IC ₅₀ ) L (brightness) a (red) b (yellow) Example 4 85.22 -3.09 16.54 0.65 mg / ml Comparative Example 1 70.02 -1.02 27.02 1.82 mg / ml

As shown in the above Table 6, it was found that the composition of Example 4 of the present invention has a high degree of coloration and tyrosinase inhibitory activity and thus has excellent whitening activity. In particular, it was confirmed that the tyrosinase inhibitory activity is about 2.8 times better than that of Comparative Example 1, the control group.

<Experiment 5> Experiment to confirm skin trouble alleviation effect

Prepared by preparing a cosmetic pack mixed with the composition of Example 4 of the present invention. The control group prepared a cosmetic pack containing Jeju volcanic stone clusters according to the composition of Comparative Example 1. In order to check the improvement of skin troubles, 40 women in their 20s and 30s who complain of skin problems such as acne and rashes were divided into two groups of 20 people, once a week for 1 month. The prepared beauty pack was used and then surveyed.

The degree of improvement is divided into 5 to 1 points, which is divided into "5 points-improvement is very large, 4 points-improvement is large, 3 points-improved, 2 points-no improvement effect, 1 points-side effects" The results are shown in Table 7 below.

Panel number Example 4 Comparative Example 1 One 5 4 2 5 4 3 5 4 4 5 3 5 5 3 6 5 3 7 5 4 8 5 4 9 5 4 10 5 3 11 5 3 12 5 3 13 5 4 14 4 4 15 5 3 16 5 3 17 4 4 18 5 4 19 5 3 20 5 3 Total score 98 70

As shown in Table 7 above, it could be confirmed that the cosmetic pack of the present invention had a much greater effect on the skin trouble than the cosmetic pack of Comparative Example 1.

Experimental Example 6 Skin Condition Change Experiment

Prepared by preparing a cosmetic pack mixed with the composition of Example 4 of the present invention. The control group prepared a cosmetic pack containing Jeju volcanic stone clusters according to the composition of Comparative Example 1. 50 women, 10 women in their 20s and 60s, were selected, and the skin condition was measured and recorded before the start of the test. The subject was asked to use the bedtime once a week for one month. The left side of the facial face was to use the cosmetic pack of the present invention, the right side was to use a control. After 1 month, it measured about moisture retention, skin elasticity, and wrinkles.

Moisturizing power was evaluated by measuring moisture content using a Corneometer (Courase-Khazaka Electronics, Germany; CM 825), skin elasticity and wrinkles were measured using a Cutometer (Courase-Khazaka Electronics, Germany SEM 474).

The results are shown in Table 8 below.

division Before use Example 4 After Use After using Comparative Example 1 Moisturizing

low 32 persons 1 person 18 people is average 10 people 12 people 20 people high 8 people 37 people 12 people Skin elasticity

bad 30 persons 1 person 15 people is average 12 people 10 people 25 persons good 8 people 39 persons 10 people wrinkle

little 13 people 29 people 15 people is average 17 people 18 people 20 people many 20 people 3 people 15 people

As shown in Table 8, the site using the cosmetic pack of the present invention for one month was found to be significantly improved moisturizing and skin elasticity and wrinkles.

However, the site using the Jeju volcanic stone cluster beauty pack of Comparative Example 1 was somewhat improved, but the effect was very small compared to the site using Example 4 of the present invention.

Claims (3)

Jeju volcanic stone clusters, citrus extracts and Ecklonia cava extract as an active ingredient, characterized in that the skin pack composition .
According to claim 1, wherein the skin care pack composition Jeju volcanic stone clusters 5 ~ 40 parts by weight, citrus extract 0.1 ~ 5 parts by weight, persimmon extract 0.1 ~ 5 parts by weight Composition.
The method of claim 1, wherein Skin cosmetic pack containing Jeju volcanic stone clusters, citrus extracts and Ecklonia cava extract, characterized in that it is manufactured in one form selected from a sheet mask pack, a topical cosmetic patch, a cream type cosmetic pack, and a gel type cosmetic pack using the composition for skin beauty pack. Composition.