KR20110003471A - 강화 충전제로서 실리카를 포함하는 타이어용 디엔 고무 조성물 - Google Patents
강화 충전제로서 실리카를 포함하는 타이어용 디엔 고무 조성물 Download PDFInfo
- Publication number
- KR20110003471A KR20110003471A KR1020107020197A KR20107020197A KR20110003471A KR 20110003471 A KR20110003471 A KR 20110003471A KR 1020107020197 A KR1020107020197 A KR 1020107020197A KR 20107020197 A KR20107020197 A KR 20107020197A KR 20110003471 A KR20110003471 A KR 20110003471A
- Authority
- KR
- South Korea
- Prior art keywords
- silica
- less
- rubber composition
- diene rubber
- diene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 446
- 239000000377 silicon dioxide Substances 0.000 title claims abstract description 219
- 239000000203 mixture Substances 0.000 title claims abstract description 173
- 229920003244 diene elastomer Polymers 0.000 title claims abstract description 81
- 239000012763 reinforcing filler Substances 0.000 title claims description 28
- 229920001971 elastomer Polymers 0.000 claims abstract description 104
- 238000000034 method Methods 0.000 claims abstract description 81
- 239000011256 inorganic filler Substances 0.000 claims abstract description 55
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 54
- 239000000806 elastomer Substances 0.000 claims abstract description 51
- 239000007822 coupling agent Substances 0.000 claims abstract description 34
- 239000000945 filler Substances 0.000 claims abstract description 27
- 230000001747 exhibiting effect Effects 0.000 claims abstract description 14
- 239000011164 primary particle Substances 0.000 claims description 83
- 239000002245 particle Substances 0.000 claims description 59
- 239000005060 rubber Substances 0.000 claims description 54
- 238000004519 manufacturing process Methods 0.000 claims description 49
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 45
- 238000005259 measurement Methods 0.000 claims description 36
- 238000009826 distribution Methods 0.000 claims description 32
- 239000011148 porous material Substances 0.000 claims description 27
- 230000003014 reinforcing effect Effects 0.000 claims description 23
- 238000000235 small-angle X-ray scattering Methods 0.000 claims description 21
- 238000004073 vulcanization Methods 0.000 claims description 21
- 150000001993 dienes Chemical class 0.000 claims description 17
- 238000004898 kneading Methods 0.000 claims description 13
- 239000011265 semifinished product Substances 0.000 claims description 11
- 239000012766 organic filler Substances 0.000 claims description 9
- 238000004132 cross linking Methods 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 239000012429 reaction media Substances 0.000 abstract description 66
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract description 44
- 239000002535 acidifier Substances 0.000 abstract description 38
- 239000000725 suspension Substances 0.000 abstract description 34
- 230000008569 process Effects 0.000 abstract description 31
- 238000006243 chemical reaction Methods 0.000 abstract description 28
- 239000007900 aqueous suspension Substances 0.000 abstract description 20
- 238000002156 mixing Methods 0.000 abstract description 12
- 238000001035 drying Methods 0.000 abstract description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 48
- 239000000523 sample Substances 0.000 description 43
- 239000000243 solution Substances 0.000 description 42
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 34
- 229920001577 copolymer Polymers 0.000 description 29
- 238000004448 titration Methods 0.000 description 29
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 28
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 28
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 24
- 229910004298 SiO 2 Inorganic materials 0.000 description 22
- 238000003756 stirring Methods 0.000 description 22
- 238000012360 testing method Methods 0.000 description 22
- 239000004115 Sodium Silicate Substances 0.000 description 20
- 239000006229 carbon black Substances 0.000 description 20
- 235000019241 carbon black Nutrition 0.000 description 20
- 238000002360 preparation method Methods 0.000 description 20
- 229910052911 sodium silicate Inorganic materials 0.000 description 20
- 239000005062 Polybutadiene Substances 0.000 description 19
- 229920003048 styrene butadiene rubber Polymers 0.000 description 19
- 238000004627 transmission electron microscopy Methods 0.000 description 16
- 239000008367 deionised water Substances 0.000 description 14
- 229910021641 deionized water Inorganic materials 0.000 description 14
- 125000000524 functional group Chemical group 0.000 description 14
- 150000004760 silicates Chemical class 0.000 description 14
- 239000011734 sodium Substances 0.000 description 14
- -1 protectors Substances 0.000 description 13
- 238000005096 rolling process Methods 0.000 description 13
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 239000003792 electrolyte Substances 0.000 description 12
- 239000000843 powder Substances 0.000 description 12
- 239000007787 solid Substances 0.000 description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 11
- 244000043261 Hevea brasiliensis Species 0.000 description 11
- 229920003052 natural elastomer Polymers 0.000 description 11
- 229920001194 natural rubber Polymers 0.000 description 11
- 239000000047 product Substances 0.000 description 11
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 10
- 239000011324 bead Substances 0.000 description 10
- 239000006185 dispersion Substances 0.000 description 10
- 239000011159 matrix material Substances 0.000 description 10
- 238000001914 filtration Methods 0.000 description 9
- 239000005077 polysulfide Substances 0.000 description 9
- 229920001021 polysulfide Polymers 0.000 description 9
- 150000008117 polysulfides Polymers 0.000 description 9
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 9
- 230000001186 cumulative effect Effects 0.000 description 8
- 239000002609 medium Substances 0.000 description 8
- 230000002787 reinforcement Effects 0.000 description 8
- 239000002002 slurry Substances 0.000 description 8
- 238000004458 analytical method Methods 0.000 description 7
- 239000003153 chemical reaction reagent Substances 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- 230000008878 coupling Effects 0.000 description 7
- 238000010168 coupling process Methods 0.000 description 7
- 238000005859 coupling reaction Methods 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 229910052717 sulfur Inorganic materials 0.000 description 7
- 229910020175 SiOH Inorganic materials 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- 230000005540 biological transmission Effects 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 239000010410 layer Substances 0.000 description 6
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- 239000000178 monomer Substances 0.000 description 6
- 238000001228 spectrum Methods 0.000 description 6
- 239000011593 sulfur Substances 0.000 description 6
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 5
- 238000004364 calculation method Methods 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 238000002425 crystallisation Methods 0.000 description 5
- 230000008025 crystallization Effects 0.000 description 5
- 239000012065 filter cake Substances 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- 229920003049 isoprene rubber Polymers 0.000 description 5
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 5
- 239000000347 magnesium hydroxide Substances 0.000 description 5
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229910001388 sodium aluminate Inorganic materials 0.000 description 5
- 229920003051 synthetic elastomer Polymers 0.000 description 5
- 230000000930 thermomechanical effect Effects 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 241001441571 Hiodontidae Species 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 4
- 229920006978 SSBR Polymers 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 229920005549 butyl rubber Polymers 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 238000010981 drying operation Methods 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000012528 membrane Substances 0.000 description 4
- DEQZTKGFXNUBJL-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)cyclohexanamine Chemical compound C1CCCCC1NSC1=NC2=CC=CC=C2S1 DEQZTKGFXNUBJL-UHFFFAOYSA-N 0.000 description 4
- 238000003921 particle size analysis Methods 0.000 description 4
- 239000004014 plasticizer Substances 0.000 description 4
- 239000012066 reaction slurry Substances 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- 238000004062 sedimentation Methods 0.000 description 4
- 150000004819 silanols Chemical class 0.000 description 4
- 238000000527 sonication Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000002834 transmittance Methods 0.000 description 4
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- 229940095602 acidifiers Drugs 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 238000013459 approach Methods 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 230000001588 bifunctional effect Effects 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
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- 150000002019 disulfides Chemical class 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
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- 230000020477 pH reduction Effects 0.000 description 3
- 229920002857 polybutadiene Polymers 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Inorganic materials [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
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- 239000000376 reactant Substances 0.000 description 3
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- 238000000926 separation method Methods 0.000 description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 description 3
- 235000011152 sodium sulphate Nutrition 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 238000005728 strengthening Methods 0.000 description 3
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical compound [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 description 3
- 150000003568 thioethers Chemical class 0.000 description 3
- GRWFGVWFFZKLTI-IUCAKERBSA-N (-)-α-pinene Chemical compound CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 2
- CBXRMKZFYQISIV-UHFFFAOYSA-N 1-n,1-n,1-n',1-n',2-n,2-n,2-n',2-n'-octamethylethene-1,1,2,2-tetramine Chemical compound CN(C)C(N(C)C)=C(N(C)C)N(C)C CBXRMKZFYQISIV-UHFFFAOYSA-N 0.000 description 2
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 2
- ZZMVLMVFYMGSMY-UHFFFAOYSA-N 4-n-(4-methylpentan-2-yl)-1-n-phenylbenzene-1,4-diamine Chemical compound C1=CC(NC(C)CC(C)C)=CC=C1NC1=CC=CC=C1 ZZMVLMVFYMGSMY-UHFFFAOYSA-N 0.000 description 2
- KZTCAXCBXSIQSS-UHFFFAOYSA-N 4-n-(4-methylpentan-2-yl)-4-n-phenylbenzene-1,4-diamine Chemical compound C=1C=C(N)C=CC=1N(C(C)CC(C)C)C1=CC=CC=C1 KZTCAXCBXSIQSS-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 2
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- MSRJTTSHWYDFIU-UHFFFAOYSA-N octyltriethoxysilane Chemical compound CCCCCCCC[Si](OCC)(OCC)OCC MSRJTTSHWYDFIU-UHFFFAOYSA-N 0.000 description 2
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- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
- CTHJQRHPNQEPAB-UHFFFAOYSA-N 2-methoxyethenylbenzene Chemical compound COC=CC1=CC=CC=C1 CTHJQRHPNQEPAB-UHFFFAOYSA-N 0.000 description 1
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/548—Silicon-containing compounds containing sulfur
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/02—Ingredients treated with inorganic substances
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0851524 | 2008-03-10 | ||
| FR0851524A FR2928374B1 (fr) | 2008-03-10 | 2008-03-10 | Composition de caoutchouc dienique pour pneumatique comprenant une silice en tant que charge renforcante |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20110003471A true KR20110003471A (ko) | 2011-01-12 |
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| KR1020107020197A Abandoned KR20110003471A (ko) | 2008-03-10 | 2009-03-09 | 강화 충전제로서 실리카를 포함하는 타이어용 디엔 고무 조성물 |
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|---|---|
| US (1) | US9333802B2 (enExample) |
| EP (1) | EP2268491B1 (enExample) |
| JP (1) | JP5547097B2 (enExample) |
| KR (1) | KR20110003471A (enExample) |
| CN (1) | CN101959700B (enExample) |
| BR (1) | BRPI0908397A8 (enExample) |
| EA (1) | EA026303B1 (enExample) |
| FR (1) | FR2928374B1 (enExample) |
| WO (1) | WO2009112463A1 (enExample) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2928363B1 (fr) † | 2008-03-10 | 2012-08-31 | Rhodia Operations | Nouveau procede de preparation de silices precipitees, silices precipitees a morphologie, granulometrie et porosite particulieres et leurs utilisations, notamment pour le renforcement de polymeres |
| JP2011074332A (ja) * | 2009-10-02 | 2011-04-14 | Yokohama Rubber Co Ltd:The | タイヤサイドウォール用ゴム組成物およびそれを用いた空気入りタイヤ |
| JP5256262B2 (ja) * | 2009-12-07 | 2013-08-07 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物及び空気入りタイヤ |
| JP5457165B2 (ja) * | 2009-12-22 | 2014-04-02 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物及び空気入りタイヤ |
| JP5468891B2 (ja) * | 2009-12-22 | 2014-04-09 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物及び空気入りタイヤ |
| JP5457164B2 (ja) * | 2009-12-22 | 2014-04-02 | 住友ゴム工業株式会社 | ベーストレッド用ゴム組成物及び空気入りタイヤ |
| FR2960544B1 (fr) * | 2010-05-27 | 2012-08-17 | Michelin Soc Tech | Bandage pneumatique dont la zone sommet est pourvue d'une couche interne reduisant les bruits de roulage |
| BR112014004740A2 (pt) * | 2011-08-31 | 2017-03-28 | Bridgestone Corp | composição de borracha, composição de borracha reticulada e pneu |
| FR2981076B1 (fr) * | 2011-10-11 | 2013-11-01 | Michelin Soc Tech | Methode pour preparer un melange maitre d'elastomere dienique et de silice |
| FR2981078B1 (fr) * | 2011-10-11 | 2013-11-01 | Michelin Soc Tech | Methode pour preparer un melange maitre d'elastomere dienique et de silice |
| BR112014010345A2 (pt) * | 2011-11-01 | 2017-04-18 | Sumitomo Rubber Ind | método para avaliação de módulo de elasticidade de repulsão, dureza e perda de energia de material de polímero |
| FR2984896B1 (fr) | 2011-12-21 | 2014-10-24 | Michelin Soc Tech | Pneumatique comprenant une composition essentiellement depourvue de derive guanidique et comprenant une amine primaire |
| FR2984900B1 (fr) * | 2011-12-21 | 2014-02-07 | Michelin Soc Tech | Pneumatique comprenant une composition essentiellement depourvue de derive guanidique et comprenant une hydroxyalkylpiperazine |
| FR2984898B1 (fr) | 2011-12-21 | 2014-08-15 | Michelin Soc Tech | Pneumatique comprenant une composition essentiellement depourvue de derive guanidique et comprenant un aminoetheralcool |
| FR2984895B1 (fr) | 2011-12-21 | 2016-01-01 | Michelin Soc Tech | Pneumatique comprenant une composition essentiellement depourvue de derive guanidique et comprenant un hydroxyde de metal alcalin ou alcalino-terreux |
| FR2997897B1 (fr) * | 2012-11-15 | 2014-12-26 | Michelin & Cie | Bandage pneumatique avec une bande de roulement comprenant un materiau degradable a base d'alcool polyvinylique |
| EP3201010A4 (en) * | 2012-12-31 | 2018-05-09 | Compagnie Générale des Etablissements Michelin | Tire tread with incompatible rubbers |
| JP5907308B2 (ja) | 2013-02-25 | 2016-04-26 | 横浜ゴム株式会社 | タイヤトレッド用ゴム組成物及びこれを用いる空気入りタイヤ |
| CN105209537B (zh) * | 2013-05-17 | 2017-06-16 | 横滨橡胶株式会社 | 轮胎胎面用橡胶组合物及充气轮胎 |
| PT3105178T (pt) * | 2014-02-14 | 2018-02-02 | Rhodia Operations | Processo para a preparação de sílicas precipitadas, sílicas precipitadas e suas utilizações, em particular para o reforço de polímeros |
| JP6463369B2 (ja) * | 2014-02-14 | 2019-01-30 | ローディア オペレーションズ | 沈澱シリカの製造方法、沈澱シリカおよび、特にポリマーの強化のための、それらの使用 |
| JP6064953B2 (ja) * | 2014-08-27 | 2017-01-25 | 横浜ゴム株式会社 | タイヤ用ゴム組成物および空気入りタイヤ |
| JP6064952B2 (ja) * | 2014-08-27 | 2017-01-25 | 横浜ゴム株式会社 | タイヤ用ゴム組成物および空気入りタイヤ |
| RU2689750C1 (ru) * | 2015-07-15 | 2019-05-28 | Кабот Корпорейшн | Способ получения эластомерного композита, армированного диоксидом кремния и углеродной сажей, и продукты, содержащие эластомерный композит |
| JP6702997B2 (ja) * | 2015-10-19 | 2020-06-03 | 株式会社ブリヂストン | ゴム組成物及びタイヤ |
| US10563050B2 (en) * | 2015-12-15 | 2020-02-18 | The Goodyear Tire & Rubber Company | Pneumatic tire |
| FR3047735A1 (fr) * | 2016-02-12 | 2017-08-18 | Michelin & Cie | Composition de caoutchouc comprenant une silice essentiellement spherique et peu structuree |
| FR3065960B1 (fr) * | 2017-05-05 | 2019-06-28 | Compagnie Generale Des Etablissements Michelin | Composition de caoutchouc comprenant au moins une silice en tant que charge renforcante inorganique |
| MX2020002217A (es) * | 2017-08-29 | 2020-08-20 | Evonik Operations Gmbh | Tamaño de partícula esférica de sílice para control de rda. |
| CN111278663B (zh) * | 2017-10-30 | 2022-04-26 | 米其林集团总公司 | 设有由至少异戊二烯弹性体、增强树脂和金属盐制成的内层的轮胎 |
| US12103334B2 (en) | 2018-05-04 | 2024-10-01 | Bridgestone Americas Tire Operations, Llc | Tire tread rubber composition |
| WO2019213229A1 (en) | 2018-05-04 | 2019-11-07 | Bridgestone Americas Tire Operations, Llc | Tire tread rubber composition |
| US12371553B2 (en) | 2018-05-04 | 2025-07-29 | Bridgestone Americas Tire Operations, Llc | Tire tread rubber composition |
| WO2019213233A1 (en) | 2018-05-04 | 2019-11-07 | Bridgestone Americas Tire Operations, Llc | Tire tread rubber composition |
| JP6811750B2 (ja) * | 2018-08-10 | 2021-01-13 | 東ソー・シリカ株式会社 | ゴム補強充填用含水ケイ酸 |
| JP6811751B2 (ja) * | 2018-08-10 | 2021-01-13 | 東ソー・シリカ株式会社 | ゴム補強充填用含水ケイ酸 |
| US10947368B2 (en) | 2019-03-04 | 2021-03-16 | The Goodyear Tire & Rubber Company | Pneumatic tire |
| WO2020243311A1 (en) | 2019-05-29 | 2020-12-03 | Bridgestone Americas Tire Operations, Llc | Tire tread rubber composition and related methods |
| US12365787B2 (en) | 2019-05-29 | 2025-07-22 | Bridgestone Americas Tire Operations, Llc | Tire tread rubber composition and related methods |
| US12325797B2 (en) | 2019-05-29 | 2025-06-10 | Bridgestone Americas Tire Operations, Llc | Tire tread rubber composition and related methods |
| JP2020196842A (ja) * | 2019-06-05 | 2020-12-10 | 住友ゴム工業株式会社 | 空気入りタイヤ |
| JP7473350B2 (ja) | 2020-02-05 | 2024-04-23 | 東ソー・シリカ株式会社 | ゴム補強充填剤用含水ケイ酸および含水ケイ酸含有ゴム組成物 |
| US11440350B2 (en) | 2020-05-13 | 2022-09-13 | The Goodyear Tire & Rubber Company | Pneumatic tire |
| CN113321217A (zh) * | 2021-06-30 | 2021-08-31 | 确成硅化学股份有限公司 | 一种高冰面抓着力轮胎专用高分散白炭黑的制备方法 |
| WO2023118285A1 (en) * | 2021-12-23 | 2023-06-29 | Rhodia Operations | Precipitated silica and process for its manufacture |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6977065B1 (en) * | 1993-10-07 | 2005-12-20 | Degussa Ag | Precipitated silicas |
| FR2763593B1 (fr) * | 1997-05-26 | 1999-07-09 | Michelin & Cie | Composition de caoutchouc a base de silice destinee a la fabrication d'enveloppes de pneumatiques routiers ayant une resistance au roulement amelioree |
| JP4413609B2 (ja) * | 2001-08-13 | 2010-02-10 | ソシエテ ド テクノロジー ミシュラン | 補強用充填剤として特定のシリカを含むタイヤ用ジエンゴム組成物 |
| CA2457769C (fr) * | 2001-08-13 | 2011-04-26 | Rhodia Chimie | Procede de preparation de silices, silices a distribution granulometrique et/ou repartition poreuse particulieres et leurs utilisations, notamment pour le renforcement de polymeres |
| US7378468B2 (en) * | 2003-11-07 | 2008-05-27 | The Goodyear Tire & Rubber Company | Tire having component of rubber composition containing a carbonaceous filler composite of disturbed crystalline phrases and amorphous carbon phases |
| FR2886303B1 (fr) * | 2005-05-26 | 2007-07-20 | Rhodia Chimie Sa | Utilisation d'une combinaison particuliere d'un agent de couplage et d'un agent de recouvrement, comme systeme de couplage(charge blanche-elastomere) dans les compositions de caoutchouc comprenant une charge inorganique |
-
2008
- 2008-03-10 FR FR0851524A patent/FR2928374B1/fr active Active
-
2009
- 2009-03-09 JP JP2010550161A patent/JP5547097B2/ja not_active Expired - Fee Related
- 2009-03-09 US US12/921,540 patent/US9333802B2/en not_active Expired - Fee Related
- 2009-03-09 EP EP09721057.9A patent/EP2268491B1/fr active Active
- 2009-03-09 WO PCT/EP2009/052736 patent/WO2009112463A1/fr not_active Ceased
- 2009-03-09 KR KR1020107020197A patent/KR20110003471A/ko not_active Abandoned
- 2009-03-09 CN CN200980107704.6A patent/CN101959700B/zh not_active Expired - Fee Related
- 2009-03-09 BR BRPI0908397A patent/BRPI0908397A8/pt not_active IP Right Cessation
- 2009-03-09 EA EA201071051A patent/EA026303B1/ru not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| EA026303B1 (ru) | 2017-03-31 |
| WO2009112463A1 (fr) | 2009-09-17 |
| EP2268491B1 (fr) | 2014-08-27 |
| BRPI0908397A2 (pt) | 2015-08-11 |
| EP2268491A1 (fr) | 2011-01-05 |
| FR2928374B1 (fr) | 2011-10-07 |
| US20110152405A1 (en) | 2011-06-23 |
| US9333802B2 (en) | 2016-05-10 |
| BRPI0908397A8 (pt) | 2016-01-12 |
| FR2928374A1 (fr) | 2009-09-11 |
| JP2011516630A (ja) | 2011-05-26 |
| CN101959700A (zh) | 2011-01-26 |
| CN101959700B (zh) | 2016-08-03 |
| EA201071051A1 (ru) | 2011-04-29 |
| JP5547097B2 (ja) | 2014-07-09 |
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