KR20090029437A - 난연성 카치온 염료 가염성 코폴리에스터 중합물, 이의제조방법 및 그 섬유 - Google Patents
난연성 카치온 염료 가염성 코폴리에스터 중합물, 이의제조방법 및 그 섬유 Download PDFInfo
- Publication number
- KR20090029437A KR20090029437A KR1020070094660A KR20070094660A KR20090029437A KR 20090029437 A KR20090029437 A KR 20090029437A KR 1020070094660 A KR1020070094660 A KR 1020070094660A KR 20070094660 A KR20070094660 A KR 20070094660A KR 20090029437 A KR20090029437 A KR 20090029437A
- Authority
- KR
- South Korea
- Prior art keywords
- flame retardant
- polymer
- cationic dye
- formula
- copolyester
- Prior art date
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/183—Terephthalic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
- C08G63/688—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
- C08G63/692—Polyesters containing atoms other than carbon, hydrogen and oxygen containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
- C08K5/42—Sulfonic acids; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
- C08G63/688—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur
- C08G63/6884—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/6886—Dicarboxylic acids and dihydroxy compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Polyesters Or Polycarbonates (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Artificial Filaments (AREA)
- Woven Fabrics (AREA)
Abstract
Description
실시예 1 | 비교예 1 | 비교예 2 | 비교예 3 | |
중합물 IV(dl/g) | 0.58 | 0.64 | 0.28 | 0.59 |
DEG(wt%) | 5.0 | 1.6 | 7.3 | 3.2 |
용융온도(℃) | 220.8 | 253.2 | - | 214.5 |
인 함량(ppm) | 7200 | 200 | 7200 | 7200 |
금속 설포네이트 함량 (몰%) | 1.3 | 1.3 | 10.0 | 1.3 |
Claims (10)
- 제 1항에 있어서, 상기 중합물의 극한점도는 0.5 ~ 0.7dl/g 이고, 용융온도가 215 ~ 240℃인 것을 특징으로 하는 난연성 카치온 염료 가염성 코폴리에스터 중합물.
- 제 1항에 있어서, 상기 중합물 내에 미반응 TPA(테레프탈산)의 함량이 20ppm 이하인 것으로 특징으로 하는 난연성 카치온 염료 가염성 코폴리에스터 중합물.
- 제 1항에 있어서, 상기 중합물 내에 말단 카르복실기의 함량이 30 내지 60 당량/톤인 것을 특징으로 하는 난연성 카치온 염료 가염성 코폴리에스터 중합물.
- 제 1항에 있어서, 상기 중합물 내에 DEG 의 함량이 전체 중합물 대비 1.5 내지 4.5 중량 % 인 것을 특징으로 하는 난연성 카치온 염료 가염성 코폴리에스터 중합물.
- TPA(테레프탈산)중합공법을 적용하는 난연성 카치온 염료 가염성 코폴리에스 터 중합물의 제조 방법에 있어서,하기 화학식 (1)로 표시되는 금속 설포네이트 함유 화합물을 전제 중합물의 카르복실산 잔기 대비 0.5 ~ 3몰% 포함하고,하기 화학식 (2)로 대표되는 인계 난연제를 인 원자 기준으로 하여 전체 중합물 대비 500 ~ 50000ppm 포함하는 것을 특징으로 하는 난연성 카치온 염료 가염성 코폴리에스터 중합물 제조 방법.[화학식 1]단, M은 알칼리 금속을 나타낸다.[화학식 2]단, R1, R2, R3 는 수소 잔기, 페닐기, C1 ~ C7의 알킬기를 나타낸다.
- 제 6항에 있어서, 상기 제조 방법은 상기 화학식 (1)의 금속 설포네이트염 함유 화합물과 상기 화학식 (2)의 인계 난연제를 제 2 에스터화 반응조(DE-2)에 투입하는 것을 특징으로 하는 난연성 카치온 염료 가염성 코폴리에스터 중합물의 제조 방법.
- 제 7항에 있어서, 상기 화학식(2)의 인계 난연제가 상기 화학식 (1)의 금속 설포네이트 함유 화합물 보다 먼저 투입되는 것을 특징으로 하는 난연성 카치온 염료 가염성 코폴리에스터 중합물의 제조 방법.
- 제 1항 내지 제 5항에 따른 상기 중합물을 이용하여 제조되는 난연성 카치온 염료 가염성 코폴리에스터 섬유.
- 제 9항에 따른 상기 코폴리에스터 섬유를 이용하여 제조되는 것을 특징으로 하는 직편물 제품.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020070094660A KR100894780B1 (ko) | 2007-09-18 | 2007-09-18 | 난연성 카치온 염료 가염성 코폴리에스터 중합물, 이의제조방법 및 그 섬유 |
TW097130887A TW200914515A (en) | 2007-09-18 | 2008-08-13 | Flame-retardant cationic dye-dyeable copolyester polymer, manufacturing method thereof and flame-retardant cationic dye-dyeable copolyester fibers |
DE102008046383A DE102008046383A1 (de) | 2007-09-18 | 2008-09-09 | Flammhemmendes, mit kationischem Farbstoff färbbares Copolyesterpolymer, Verfahren zur Herstellung desselben und flammhemmende, mit kationischem Farbstoff färbbare Copolyesterfasern |
CNA2008102118515A CN101392050A (zh) | 2007-09-18 | 2008-09-11 | 阻燃共聚酯聚合物、其制造方法以及阻燃共聚酯纤维 |
JP2008235890A JP2009074088A (ja) | 2007-09-18 | 2008-09-16 | 難燃性カチオン染料可染性コポリエステル重合物、その製造方法およびその繊維 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020070094660A KR100894780B1 (ko) | 2007-09-18 | 2007-09-18 | 난연성 카치온 염료 가염성 코폴리에스터 중합물, 이의제조방법 및 그 섬유 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20090029437A true KR20090029437A (ko) | 2009-03-23 |
KR100894780B1 KR100894780B1 (ko) | 2009-04-24 |
Family
ID=40348803
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020070094660A KR100894780B1 (ko) | 2007-09-18 | 2007-09-18 | 난연성 카치온 염료 가염성 코폴리에스터 중합물, 이의제조방법 및 그 섬유 |
Country Status (5)
Country | Link |
---|---|
JP (1) | JP2009074088A (ko) |
KR (1) | KR100894780B1 (ko) |
CN (1) | CN101392050A (ko) |
DE (1) | DE102008046383A1 (ko) |
TW (1) | TW200914515A (ko) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103122497A (zh) * | 2013-01-09 | 2013-05-29 | 江苏盛虹科技股份有限公司 | 常压易染再生基涤纶长丝及其制备方法 |
KR20160081624A (ko) * | 2014-12-31 | 2016-07-08 | 도레이케미칼 주식회사 | 염착성이 우수한 난연성 폴리에스테르 수지, 이의 제조방법 및 이를 포함하는 심색성이 우수한 난연섬유 |
KR20170112568A (ko) * | 2016-03-31 | 2017-10-12 | 도레이케미칼 주식회사 | 인테리어용 섬유, 이의 제조방법, 및 이를 포함하는 블라인드 |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5751729B2 (ja) * | 2010-08-31 | 2015-07-22 | トンファ ユニバーシティ | 側鎖を有する脂肪族ジオールとm−ベンゼンジカルボン酸ジエステル−5−スルホン酸ナトリウム又はカリウムとで改質された共重合エステルおよびその繊維の製造方法 |
KR101224692B1 (ko) * | 2010-12-17 | 2013-01-21 | 도레이첨단소재 주식회사 | 염색성 및 수축성이 우수한 난연성 폴리에스테르 수지 및 그 제조방법 |
CN103122543A (zh) * | 2011-11-18 | 2013-05-29 | 东丽纤维研究所(中国)有限公司 | 一种阻燃纺织品及其应用 |
CN105088535B (zh) * | 2015-09-07 | 2017-08-29 | 杭州奥坦斯布艺有限公司 | 一种阻燃隔热弹性聚酯材料及其制备方法和应用 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5180793A (en) * | 1991-12-31 | 1993-01-19 | Hoechst Celanese Corporation | Flame resistant, low pilling polyester fiber |
JPH06287414A (ja) * | 1993-04-07 | 1994-10-11 | Toray Ind Inc | 難燃性ポリエステルの製造方法 |
JP2001172373A (ja) * | 1999-12-17 | 2001-06-26 | Toyobo Co Ltd | ポリエステル樹脂、それからなる中空成形体、シ−ト状物及び延伸フイルム |
JP4076413B2 (ja) | 2002-09-19 | 2008-04-16 | 日本エステル株式会社 | ポリエステル樹脂及びポリエステル繊維 |
JP2004232172A (ja) * | 2003-02-03 | 2004-08-19 | Toray Ind Inc | 難燃性ポリエステル繊維 |
JP2005273043A (ja) | 2004-03-23 | 2005-10-06 | Nippon Ester Co Ltd | 難燃性カチオン可染ポリエステル繊維 |
KR100561083B1 (ko) * | 2004-05-10 | 2006-03-15 | 주식회사 효성 | 카치온 염료 가염성 난연성 폴리에스터 중합물 및 이의제조방법, 그리고 이로부터 제조되는 코폴리에스터 섬유 |
JP2006169687A (ja) | 2004-12-17 | 2006-06-29 | Toyobo Co Ltd | カチオン染料可染型難燃性ポリエステル繊維と難燃性織編物およびそれらの製造方法 |
-
2007
- 2007-09-18 KR KR1020070094660A patent/KR100894780B1/ko active IP Right Grant
-
2008
- 2008-08-13 TW TW097130887A patent/TW200914515A/zh unknown
- 2008-09-09 DE DE102008046383A patent/DE102008046383A1/de not_active Ceased
- 2008-09-11 CN CNA2008102118515A patent/CN101392050A/zh active Pending
- 2008-09-16 JP JP2008235890A patent/JP2009074088A/ja active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103122497A (zh) * | 2013-01-09 | 2013-05-29 | 江苏盛虹科技股份有限公司 | 常压易染再生基涤纶长丝及其制备方法 |
KR20160081624A (ko) * | 2014-12-31 | 2016-07-08 | 도레이케미칼 주식회사 | 염착성이 우수한 난연성 폴리에스테르 수지, 이의 제조방법 및 이를 포함하는 심색성이 우수한 난연섬유 |
KR20170112568A (ko) * | 2016-03-31 | 2017-10-12 | 도레이케미칼 주식회사 | 인테리어용 섬유, 이의 제조방법, 및 이를 포함하는 블라인드 |
Also Published As
Publication number | Publication date |
---|---|
TW200914515A (en) | 2009-04-01 |
KR100894780B1 (ko) | 2009-04-24 |
JP2009074088A (ja) | 2009-04-09 |
CN101392050A (zh) | 2009-03-25 |
DE102008046383A1 (de) | 2009-03-19 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR100894780B1 (ko) | 난연성 카치온 염료 가염성 코폴리에스터 중합물, 이의제조방법 및 그 섬유 | |
JP4098787B2 (ja) | カチオン染料可染性及び難燃性のポリエステル重合体及びその製造方法 | |
US8470916B2 (en) | Halogen-free flame retardants | |
KR100841175B1 (ko) | 상압 카치온 염료 가염성 코폴리에스터 중합물, 그 제조 방법 및 이를 이용한 상압 카치온 염료 가염성 코폴리에스터 섬유 | |
KR100764378B1 (ko) | 난연성 폴리에스터 중합물의 제조방법, 이로부터 제조되는중합물 및 섬유 | |
Ge et al. | Phosphorus‐containing telechelic polyester‐based ionomer: facile synthesis and antidripping effects | |
CN102030894A (zh) | 含磷聚对苯二甲酸丙二醇酯阻燃嵌段共聚酯及其制备方法 | |
US4229552A (en) | Fire-retardant polyester compositions | |
KR100867196B1 (ko) | 난연 및 염기성 가염 폴리에스테르 섬유의 제조방법 | |
KR100525064B1 (ko) | 복합사용 알칼리 이용성 코폴리에스터 중합물과 이의제조방법 및 이를 사용한 폴리에스터 복합섬유 | |
CN114989406A (zh) | 一种非金属有机化合物在dmt法合成聚酯中的应用、dmt法功能共聚酯及其制法 | |
KR101083773B1 (ko) | 색상이 우수한 난연성 폴리에스테르 및 그의 제조방법 | |
KR100308541B1 (ko) | 난연성 폴리에스터섬유의 제조방법 | |
KR20150069483A (ko) | 난연성 폴리에스테르 수지 조성물, 이를 이용한 loi가 우수한 난연성 폴리에스테르 수지 및 폴리에스테르 섬유 | |
KR20200061866A (ko) | 카티온 가염성 폴리에스테르 수지 및 이를 이용한 염색성이 개선된 카티온 가염성 폴리에스테르 섬유 | |
JP5216971B2 (ja) | カチオン可染性ポリエステル繊維の製造方法 | |
KR950002610B1 (ko) | 난연성 폴리에스테르의 제조방법 | |
KR0170068B1 (ko) | 난연성 폴리에스테르의 제조방법 | |
KR100341940B1 (ko) | 난연성 폴리에스터의 제조방법 | |
KR100370274B1 (ko) | 난연성 폴리에스터 중합물의 제조방법 | |
KR100236755B1 (ko) | 난연성 폴리에스테르의 제조방법 | |
JP2005273043A (ja) | 難燃性カチオン可染ポリエステル繊維 | |
KR20200040519A (ko) | 카티온 가염성 폴리에스테르 수지 및 이를 이용한 카티온 가염성 폴리에스테르 섬유 | |
KR19990070137A (ko) | 난연성 폴리에스터의 제조방법 | |
KR980009312A (ko) | 난연성 폴리에스테르의 제조방법 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A201 | Request for examination | ||
E701 | Decision to grant or registration of patent right | ||
GRNT | Written decision to grant | ||
FPAY | Annual fee payment |
Payment date: 20121220 Year of fee payment: 5 |
|
FPAY | Annual fee payment |
Payment date: 20140305 Year of fee payment: 6 |
|
FPAY | Annual fee payment |
Payment date: 20150305 Year of fee payment: 7 |
|
FPAY | Annual fee payment |
Payment date: 20160316 Year of fee payment: 8 |
|
FPAY | Annual fee payment |
Payment date: 20180312 Year of fee payment: 10 |
|
FPAY | Annual fee payment |
Payment date: 20190312 Year of fee payment: 11 |
|
FPAY | Annual fee payment |
Payment date: 20200311 Year of fee payment: 12 |