KR20080059468A - 착색된 산화알루미늄 층의 내식성 및 광견뢰도를개선시키는 방법 - Google Patents
착색된 산화알루미늄 층의 내식성 및 광견뢰도를개선시키는 방법 Download PDFInfo
- Publication number
- KR20080059468A KR20080059468A KR1020087012512A KR20087012512A KR20080059468A KR 20080059468 A KR20080059468 A KR 20080059468A KR 1020087012512 A KR1020087012512 A KR 1020087012512A KR 20087012512 A KR20087012512 A KR 20087012512A KR 20080059468 A KR20080059468 A KR 20080059468A
- Authority
- KR
- South Korea
- Prior art keywords
- polysilazane
- aluminum
- light fastness
- oxide layer
- colored
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 230000007797 corrosion Effects 0.000 title claims abstract description 17
- 238000005260 corrosion Methods 0.000 title claims abstract description 17
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 title description 9
- 238000000034 method Methods 0.000 claims abstract description 46
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 38
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 34
- 229920001709 polysilazane Polymers 0.000 claims abstract description 30
- 239000003086 colorant Substances 0.000 claims abstract description 29
- 229910000838 Al alloy Inorganic materials 0.000 claims abstract description 11
- 125000000129 anionic group Chemical group 0.000 claims abstract description 4
- 238000002048 anodisation reaction Methods 0.000 claims description 15
- 238000000576 coating method Methods 0.000 claims description 13
- 239000011248 coating agent Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 9
- 239000000654 additive Substances 0.000 claims description 7
- 239000000758 substrate Substances 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 239000012963 UV stabilizer Substances 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 claims description 2
- 238000009472 formulation Methods 0.000 claims description 2
- 239000002105 nanoparticle Substances 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 2
- 125000005369 trialkoxysilyl group Chemical group 0.000 claims description 2
- 239000002699 waste material Substances 0.000 claims description 2
- 238000009736 wetting Methods 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 24
- 238000000280 densification Methods 0.000 description 22
- 238000004040 coloring Methods 0.000 description 21
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 16
- 239000000243 solution Substances 0.000 description 12
- 238000001035 drying Methods 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 235000006408 oxalic acid Nutrition 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- 239000011777 magnesium Substances 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 5
- 229910052749 magnesium Inorganic materials 0.000 description 5
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 4
- -1 alkali metal salts Chemical class 0.000 description 4
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 4
- 238000007789 sealing Methods 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 230000000274 adsorptive effect Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- MPVDXIMFBOLMNW-ISLYRVAYSA-N 7-hydroxy-8-[(E)-phenyldiazenyl]naphthalene-1,3-disulfonic acid Chemical compound OC1=CC=C2C=C(S(O)(=O)=O)C=C(S(O)(=O)=O)C2=C1\N=N\C1=CC=CC=C1 MPVDXIMFBOLMNW-ISLYRVAYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- MQRWBMAEBQOWAF-UHFFFAOYSA-N acetic acid;nickel Chemical compound [Ni].CC(O)=O.CC(O)=O MQRWBMAEBQOWAF-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000005238 degreasing Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229940078494 nickel acetate Drugs 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229910052724 xenon Inorganic materials 0.000 description 2
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- LGCMKPRGGJRYGM-UHFFFAOYSA-N Osalmid Chemical compound C1=CC(O)=CC=C1NC(=O)C1=CC=CC=C1O LGCMKPRGGJRYGM-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- GEIAQOFPUVMAGM-UHFFFAOYSA-N ZrO Inorganic materials [Zr]=O GEIAQOFPUVMAGM-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910001515 alkali metal fluoride Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 150000001869 cobalt compounds Chemical class 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- QYFMQRSFRCFZNM-UHFFFAOYSA-K copper;sodium;trichloride Chemical compound [Na+].[Cl-].[Cl-].[Cl-].[Cu+2] QYFMQRSFRCFZNM-UHFFFAOYSA-K 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000010335 hydrothermal treatment Methods 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- DBJLJFTWODWSOF-UHFFFAOYSA-L nickel(ii) fluoride Chemical compound F[Ni]F DBJLJFTWODWSOF-UHFFFAOYSA-L 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 208000014451 palmoplantar keratoderma and congenital alopecia 2 Diseases 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- 150000003754 zirconium Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
- C25D11/18—After-treatment, e.g. pore-sealing
- C25D11/24—Chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/16—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers in which all the silicon atoms are connected by linkages other than oxygen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Metallurgy (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
- Paints Or Removers (AREA)
- Chemical Treatment Of Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102005051755.2 | 2005-10-27 | ||
| DE102005051755A DE102005051755A1 (de) | 2005-10-27 | 2005-10-27 | Verfahren zur Verbesserung der Korrosionsbeständigkeit und Lichtechtheit von gefärbten Aluminiumoxidschichten |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20080059468A true KR20080059468A (ko) | 2008-06-27 |
Family
ID=37895876
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020087012512A Withdrawn KR20080059468A (ko) | 2005-10-27 | 2006-10-13 | 착색된 산화알루미늄 층의 내식성 및 광견뢰도를개선시키는 방법 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US8057858B2 (https=) |
| EP (1) | EP1943375A2 (https=) |
| JP (1) | JP2009513824A (https=) |
| KR (1) | KR20080059468A (https=) |
| AR (1) | AR057561A1 (https=) |
| CA (1) | CA2627399A1 (https=) |
| DE (1) | DE102005051755A1 (https=) |
| TW (1) | TW200728508A (https=) |
| WO (1) | WO2007048513A2 (https=) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8309237B2 (en) | 2007-08-28 | 2012-11-13 | Alcoa Inc. | Corrosion resistant aluminum alloy substrates and methods of producing the same |
| US7732068B2 (en) * | 2007-08-28 | 2010-06-08 | Alcoa Inc. | Corrosion resistant aluminum alloy substrates and methods of producing the same |
| US20090162544A1 (en) * | 2007-12-20 | 2009-06-25 | Garesche Carl E | Method of surface coating to enhance durability of aesthetics and substrate component fatigue |
| DE102008023079A1 (de) * | 2008-05-09 | 2010-01-07 | WKW Erbslöh Automotive GmbH | Verfahren zum Verdichten eines Bauteils aus Aluminium und/oder einer Aluminiumlegierung |
| JP5633429B2 (ja) | 2011-02-25 | 2014-12-03 | スズキ株式会社 | 被処理物の塗装方法 |
| US20140262790A1 (en) * | 2013-03-12 | 2014-09-18 | Thomas Levendusky | Colored, corrosion-resistant aluminum alloy substrates and methods for producing same |
| US9725819B2 (en) | 2013-09-30 | 2017-08-08 | Apple Inc. | Methods for incorporating ultraviolet light absorbing compounds into anodic oxides |
| JP6046665B2 (ja) * | 2014-06-10 | 2016-12-21 | トヨタ自動車株式会社 | 断熱膜の形成方法および断熱膜 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH535835A (de) * | 1970-04-02 | 1973-04-15 | Alusuisse | Verfahren zur elektrolytischen Einfärbung von Oxidschichten auf Aluminium und seinen Legierungen |
| US3773631A (en) * | 1970-10-16 | 1973-11-20 | Blasberg Gmbh & Co Kg Friedr | Aqueous electrolytic bath for coloring anodic oxide layers on aluminum and aluminum alloy substrates and process for coloring said substrates |
| JPS62283164A (ja) * | 1986-05-30 | 1987-12-09 | Shin Etsu Chem Co Ltd | 表面被覆材 |
| EP0936288A3 (en) | 1998-01-07 | 2000-06-07 | Clariant Finance (BVI) Limited | A process for producing colour variations on electrolytically pigmented anodized aluminium |
| EP1087038A1 (de) | 1999-09-23 | 2001-03-28 | Clariant International Ltd. | Verfahren zum Färben von Aluminiumoxydschichten |
| JP2001111076A (ja) * | 1999-10-08 | 2001-04-20 | Tdk Corp | コーティング体および太陽電池モジュール |
| JP2001172715A (ja) | 1999-12-13 | 2001-06-26 | Nippon Steel Corp | 極低炭素ステンレス溶鋼の製造方法 |
| JP2001172795A (ja) * | 1999-12-14 | 2001-06-26 | Ulvac Kyushu Corp | アルミニウム複合品及びアルミニウム複合品の表面処理方法 |
| TWI259844B (en) * | 2001-04-27 | 2006-08-11 | Clariant Int Ltd | Anti-fouling coating solution containing inorganic polysilazane |
| JP2003055794A (ja) * | 2001-08-10 | 2003-02-26 | Nagoya Alumite Kk | 染色アルマイト塗装物 |
| JP2004155834A (ja) * | 2002-11-01 | 2004-06-03 | Clariant Internatl Ltd | ポリシラザン含有コーティング液 |
| DE102004011212A1 (de) | 2004-03-04 | 2005-09-29 | Clariant International Limited | Perhydropolysilazane enthaltende Beschichtungen für Metall- und Polymeroberflächen |
| DE102004011213A1 (de) | 2004-03-04 | 2005-09-22 | Clariant International Limited | Beschichtungen für Metalloberflächen, Verfahren zu deren Herstellung sowie deren Verwendung als selbstreinigende Schutzschicht, insbesondere für Autofelgen |
| DE102004054661A1 (de) * | 2004-11-12 | 2006-05-18 | Clariant International Limited | Verwendung von Polysilazanen zur Beschichtung von Metallbändern |
| TW200621918A (en) | 2004-11-23 | 2006-07-01 | Clariant Int Ltd | Polysilazane-based coating and the use thereof for coating films, especially polymer films |
| DE102005003627A1 (de) | 2005-01-26 | 2006-07-27 | Clariant International Limited | Verfahren zur Erzeugung einer permanenten Schutzschicht auf Edelmetalloberflächen durch Beschichten mit Lösungen auf Polysilazanbasis |
| DE102005042944A1 (de) | 2005-09-08 | 2007-03-22 | Clariant International Limited | Polysilazane enthaltende Beschichtungen für Metall- und Polymeroberflächen |
-
2005
- 2005-10-27 DE DE102005051755A patent/DE102005051755A1/de not_active Withdrawn
-
2006
- 2006-08-29 TW TW095131784A patent/TW200728508A/zh unknown
- 2006-10-13 CA CA002627399A patent/CA2627399A1/en not_active Abandoned
- 2006-10-13 JP JP2008536970A patent/JP2009513824A/ja active Pending
- 2006-10-13 WO PCT/EP2006/009907 patent/WO2007048513A2/de not_active Ceased
- 2006-10-13 US US12/084,191 patent/US8057858B2/en not_active Expired - Fee Related
- 2006-10-13 KR KR1020087012512A patent/KR20080059468A/ko not_active Withdrawn
- 2006-10-13 EP EP06792425A patent/EP1943375A2/de not_active Withdrawn
- 2006-10-25 AR ARP060104657A patent/AR057561A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US8057858B2 (en) | 2011-11-15 |
| WO2007048513A2 (de) | 2007-05-03 |
| JP2009513824A (ja) | 2009-04-02 |
| US20090220806A1 (en) | 2009-09-03 |
| TW200728508A (en) | 2007-08-01 |
| EP1943375A2 (de) | 2008-07-16 |
| AR057561A1 (es) | 2007-12-05 |
| DE102005051755A1 (de) | 2007-05-10 |
| CA2627399A1 (en) | 2007-05-03 |
| WO2007048513A3 (de) | 2007-10-25 |
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