KR20080023363A - 아이소사이아네이트계 화합물의 분해회수 방법 및 그의분해회수 설비 - Google Patents
아이소사이아네이트계 화합물의 분해회수 방법 및 그의분해회수 설비 Download PDFInfo
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- KR20080023363A KR20080023363A KR1020087002660A KR20087002660A KR20080023363A KR 20080023363 A KR20080023363 A KR 20080023363A KR 1020087002660 A KR1020087002660 A KR 1020087002660A KR 20087002660 A KR20087002660 A KR 20087002660A KR 20080023363 A KR20080023363 A KR 20080023363A
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- Prior art keywords
- isocyanate
- compound
- reactor
- isocyanate compound
- decomposition
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- 239000012948 isocyanate Substances 0.000 title claims abstract description 178
- -1 isocyanate compounds Chemical class 0.000 title claims abstract description 136
- 238000000354 decomposition reaction Methods 0.000 title claims abstract description 103
- 238000011084 recovery Methods 0.000 title claims abstract description 76
- 238000000034 method Methods 0.000 title claims abstract description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 134
- 150000001875 compounds Chemical class 0.000 claims abstract description 114
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000002994 raw material Substances 0.000 claims abstract description 24
- 150000002513 isocyanates Chemical class 0.000 claims description 49
- 239000007788 liquid Substances 0.000 claims description 49
- 239000007795 chemical reaction product Substances 0.000 claims description 26
- 230000018044 dehydration Effects 0.000 claims description 17
- 238000006297 dehydration reaction Methods 0.000 claims description 17
- 239000000243 solution Substances 0.000 claims description 12
- 238000004891 communication Methods 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 8
- 230000002093 peripheral effect Effects 0.000 claims description 5
- 230000002940 repellent Effects 0.000 claims description 5
- 239000005871 repellent Substances 0.000 claims description 5
- 238000000746 purification Methods 0.000 claims description 4
- 239000011259 mixed solution Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 239000012530 fluid Substances 0.000 abstract 1
- 238000004821 distillation Methods 0.000 description 17
- 239000000126 substance Substances 0.000 description 10
- 239000002699 waste material Substances 0.000 description 10
- 239000000047 product Substances 0.000 description 8
- 239000006227 byproduct Substances 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000000539 dimer Substances 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 5
- 238000005292 vacuum distillation Methods 0.000 description 5
- 239000000178 monomer Substances 0.000 description 4
- 230000010349 pulsation Effects 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 230000002194 synthesizing effect Effects 0.000 description 3
- VOZKAJLKRJDJLL-UHFFFAOYSA-N tolylenediamine group Chemical group CC1=C(C=C(C=C1)N)N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000005086 pumping Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000013638 trimer Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 150000001718 carbodiimides Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000006471 dimerization reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000013076 target substance Substances 0.000 description 1
- 238000005829 trimerization reaction Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
- B01J19/20—Stationary reactors having moving elements inside in the form of helices, e.g. screw reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0053—Details of the reactor
- B01J19/006—Baffles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J3/00—Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
- B01J3/02—Feed or outlet devices therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J3/00—Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
- B01J3/04—Pressure vessels, e.g. autoclaves
- B01J3/042—Pressure vessels, e.g. autoclaves in the form of a tube
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/62—Preparation of compounds containing amino groups bound to a carbon skeleton by cleaving carbon-to-nitrogen, sulfur-to-nitrogen, or phosphorus-to-nitrogen bonds, e.g. hydrolysis of amides, N-dealkylation of amines or quaternary ammonium compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00761—Details of the reactor
- B01J2219/00763—Baffles
- B01J2219/00765—Baffles attached to the reactor wall
- B01J2219/0077—Baffles attached to the reactor wall inclined
- B01J2219/00772—Baffles attached to the reactor wall inclined in a helix
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/18—Details relating to the spatial orientation of the reactor
- B01J2219/185—Details relating to the spatial orientation of the reactor vertical
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/19—Details relating to the geometry of the reactor
- B01J2219/194—Details relating to the geometry of the reactor round
- B01J2219/1941—Details relating to the geometry of the reactor round circular or disk-shaped
- B01J2219/1943—Details relating to the geometry of the reactor round circular or disk-shaped cylindrical
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
Description
Claims (10)
- 적어도 1개의 아이소사이아네이트기 또는 아이소사이아네이트기로부터 유도된 기를 갖는 아이소사이아네이트계 화합물을 용융상태 또는 용액상태로 고압 고온수에 연속적으로 혼입하여 분산시키는 것,아이소사이아네이트계 화합물과 고압 고온수를 포함하는 혼합액을 반응기에 연속적으로 공급하고, 아이소사이아네이트계 화합물을 반응기내에서 분해반응시키는 것, 및아이소사이아네이트계 화합물의 원료 또는 그 유도체를 회수하는 것을 포함하는 아이소사이아네이트계 화합물의 분해회수 방법.
- 제 1 항에 있어서,용융상태 또는 용액상태의 아이소사이아네이트계 화합물의 혼입 위치에 있어서의 고압 고온수가 0.5m/s 이상의 선속도를 갖는 아이소사이아네이트계 화합물의 분해회수 방법.
- 제 1 항 또는 제 2 항에 있어서,아이소사이아네이트계 화합물과 고압 고온수를 포함하는 혼합액을 반응기내에서 선회류로서 상승시키는 아이소사이아네이트계 화합물의 분해회수 방법.
- 적어도 1개의 아이소사이아네이트기 또는 아이소사이아네이트기로부터 유도된 기를 갖는 아이소사이아네이트계 화합물에 고압 고온수를 접촉시켜 분해반응시키는 반응기와,반응기에 연속적으로 고압 고온수를 공급하는 물 공급라인과,물 공급라인에 아이소사이아네이트계 화합물을 용융상태 또는 용액상태로 연속적으로 공급하는 화합물 공급라인과,물 공급라인의 반응기에의 연통부 부근에 화합물 공급라인을 연통하는 개폐 밸브와,반응기로부터 배출되는 분해반응 생성물의 탈수를 행하는 탈수장치와,탈수후의 분해반응 생성물의 정제를 행하는 정제장치를 포함하는 아이소사이아네이트계 화합물의 분해회수 설비.
- 제 4 항에 있어서,개폐 밸브가,물 공급라인에 장착되어, 고압 고온수가 흐르는 수류 통로를 갖는 수류 통관 부재와,수류 통로내에 개구되어, 화합물 공급라인으로부터 공급되는 용융상태 또는 액체상태의 아이소사이아네이트계 화합물이 유출하는 화합물 공급구와,수류 통로내에의 아이소사이아네이트계 화합물의 유출을 폐지하는 폐밸브 상 태에 있어서, 화합물 공급구내에의 고압 고온수의 유입을 저지하는 진퇴 자재인 밸브 막대를 포함하는 아이소사이아네이트계 화합물의 분해회수 설비.
- 제 4 항에 있어서,반응기가,상측에 분해반응 생성물의 배출구를, 하측에 물 공급라인이 연통하는 혼합액 공급구를 갖는 수직인 원통상의 용기 본체와,이 용기 본체내에 수납되어, 혼합액 공급구로부터 유입하는 혼합액을 선회류로서 상승시키는 액 선회장치를 포함하는 아이소사이아네이트계 분해대상 화합물의 분해회수 설비.
- 제 5 항에 있어서,반응기가,상측에 분해반응 생성물의 배출구를, 하측에 물 공급라인이 연통하는 혼합액 공급구를 갖는 수직인 원통상의 용기 본체와,이 용기 본체내에 수납되어, 혼합액 공급구로부터 유입하는 혼합액을 선회류로서 상승시키는 액 선회장치를 포함하는 아이소사이아네이트계 분해대상 화합물의 분해회수 설비.
- 제 6 항에 있어서,액 선회장치가,용기 본체의 직경방향의 중심에 설치되는 날개 지지부재와,날개 지지부재에 나선상으로 고착되는 동시에, 외주단면이 용기 본체의 내주면에 접촉하는 나선 날개를 포함하는 아이소사이아네이트계 분해대상 화합물의 분해회수 설비.
- 제 7 항에 있어서,액 선회장치가,용기 본체의 직경방향의 중심에 설치되는 날개 지지부재와,날개 지지부재에 나선상으로 고착되는 동시에, 외주단면이 용기 본체의 내주면에 접촉하는 나선 날개를 포함하는 아이소사이아네이트계 분해대상 화합물의 분해회수 설비.
- 제 4 항 내지 제 9 항 중 어느 한 항에 있어서,고압 고온수, 및 용융상태 또는 액체상태의 아이소사이아네이트계 화합물이, 다(多) 피스톤 펌프에 의해 압송되는 아이소사이아네이트계 분해대상 화합물의 분해회수 설비.
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JPJP-P-2005-00202419 | 2005-07-12 | ||
JP2005202419 | 2005-07-12 |
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KR20080023363A true KR20080023363A (ko) | 2008-03-13 |
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US (2) | US8038958B2 (ko) |
EP (1) | EP1903026B1 (ko) |
KR (1) | KR100986520B1 (ko) |
CN (1) | CN101223127B (ko) |
PL (1) | PL1903026T3 (ko) |
TW (1) | TW200714639A (ko) |
WO (1) | WO2007007791A1 (ko) |
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2006
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- 2006-07-12 WO PCT/JP2006/313870 patent/WO2007007791A1/ja active Application Filing
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2012070806A2 (ko) * | 2010-11-24 | 2012-05-31 | 전남대학교산학협력단 | 아임계수를 이용한 오염 토양 정화 방법 및 장치 |
WO2012070806A3 (ko) * | 2010-11-24 | 2012-08-23 | 전남대학교산학협력단 | 아임계수를 이용한 오염 토양 정화 방법 및 장치 |
Also Published As
Publication number | Publication date |
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TWI347959B (ko) | 2011-09-01 |
US8669394B2 (en) | 2014-03-11 |
US20090275776A1 (en) | 2009-11-05 |
EP1903026B1 (en) | 2012-12-26 |
CN101223127A (zh) | 2008-07-16 |
KR100986520B1 (ko) | 2010-10-07 |
TW200714639A (en) | 2007-04-16 |
EP1903026A4 (en) | 2010-09-08 |
PL1903026T3 (pl) | 2013-06-28 |
WO2007007791A1 (ja) | 2007-01-18 |
EP1903026A1 (en) | 2008-03-26 |
US8038958B2 (en) | 2011-10-18 |
US20110190534A1 (en) | 2011-08-04 |
CN101223127B (zh) | 2012-09-05 |
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