KR20070004940A - 은 촉매의 제조방법, 그 촉매 및 이 촉매의 올레핀산화에서의 용도 - Google Patents

은 촉매의 제조방법, 그 촉매 및 이 촉매의 올레핀산화에서의 용도 Download PDF

Info

Publication number
KR20070004940A
KR20070004940A KR1020067022865A KR20067022865A KR20070004940A KR 20070004940 A KR20070004940 A KR 20070004940A KR 1020067022865 A KR1020067022865 A KR 1020067022865A KR 20067022865 A KR20067022865 A KR 20067022865A KR 20070004940 A KR20070004940 A KR 20070004940A
Authority
KR
South Korea
Prior art keywords
catalyst
support
silver
olefin
rhenium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
KR1020067022865A
Other languages
English (en)
Korean (ko)
Inventor
존 로버트 로케미어
Original Assignee
셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 filed Critical 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이
Publication of KR20070004940A publication Critical patent/KR20070004940A/ko
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48Silver or gold
    • B01J23/50Silver
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
    • B01J23/68Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
    • B01J23/68Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/683Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
    • B01J23/68Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/688Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0207Pretreatment of the support
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C213/00Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C213/04Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reaction of ammonia or amines with olefin oxides or halohydrins
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/10Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes
    • C07C29/103Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers
    • C07C29/106Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers of oxiranes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01Preparation of ethers
    • C07C41/02Preparation of ethers from oxiranes
    • C07C41/03Preparation of ethers from oxiranes by reaction of oxirane rings with hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04Alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0203Impregnation the impregnation liquid containing organic compounds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020067022865A 2004-04-01 2005-03-31 은 촉매의 제조방법, 그 촉매 및 이 촉매의 올레핀산화에서의 용도 Withdrawn KR20070004940A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US55844004P 2004-04-01 2004-04-01
US60/558,440 2004-04-01

Publications (1)

Publication Number Publication Date
KR20070004940A true KR20070004940A (ko) 2007-01-09

Family

ID=34964800

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020067022865A Withdrawn KR20070004940A (ko) 2004-04-01 2005-03-31 은 촉매의 제조방법, 그 촉매 및 이 촉매의 올레핀산화에서의 용도

Country Status (9)

Country Link
US (1) US7538235B2 (enExample)
EP (1) EP1735091A1 (enExample)
JP (1) JP2007531622A (enExample)
KR (1) KR20070004940A (enExample)
CN (1) CN1956783A (enExample)
CA (1) CA2561673A1 (enExample)
IN (1) IN2006DE05676A (enExample)
TW (1) TW200600190A (enExample)
WO (1) WO2005097316A1 (enExample)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8716175B2 (en) * 2006-04-10 2014-05-06 Mitsubishi Chemical Corporation Catalyst for producing ethylene oxide, process for producing the catalyst and process for producing ethylene oxide
CN101360562B (zh) * 2006-04-10 2013-02-06 三菱化学株式会社 环氧乙烷制造用催化剂及其制造方法、以及环氧乙烷的制造方法
JP4978277B2 (ja) * 2006-04-10 2012-07-18 三菱化学株式会社 酸化エチレン製造用触媒およびその製造方法ならびに酸化エチレンの製造方法
JP2007301554A (ja) * 2006-04-10 2007-11-22 Mitsubishi Chemicals Corp 酸化エチレン製造用触媒およびその製造方法ならびに酸化エチレンの製造方法
US7977274B2 (en) * 2006-09-29 2011-07-12 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Catalyst with bimodal pore size distribution and the use thereof
US7932408B2 (en) 2006-09-29 2011-04-26 Scientific Design Company, Inc. Catalyst with bimodal pore size distribution and the use thereof
KR20090083937A (ko) 2006-11-20 2009-08-04 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 담체 처리방법, 촉매 제조방법, 촉매, 및 이 촉매의 용도
CN103599798B (zh) * 2007-05-09 2015-11-18 国际壳牌研究有限公司 环氧化催化剂及其制备方法和生产环氧烷、1,2-二醇、1,2-二醇醚、1,2-碳酸酯或烷醇胺的方法
PL2297125T3 (pl) * 2008-05-07 2013-12-31 Shell Int Research Sposób wytwarzania tlenku olefiny, 1,2-diolu, eteru 1,2-diolu, 1,2-węglanu albo alkanoloaminy
EP2297124B1 (en) * 2008-05-07 2013-08-21 Shell Internationale Research Maatschappij B.V. A process for the start-up of an epoxidation process, a process for the production of ethylene oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine
ES2391809T3 (es) * 2008-10-08 2012-11-30 Basf Se Método para producir óxidos de alquileno
GB201118228D0 (en) 2011-10-21 2011-12-07 Ingen Gtl Ltd Methods of preparation and forming supported active metal catalysts and precursors
WO2013057319A2 (en) * 2011-10-21 2013-04-25 Ingen Gtl Limited Methods of preparation and forming supported active metal catalysts and precursors
EP3083040B1 (en) 2013-12-19 2025-03-05 Scientific Design LLC High-concentration silver solutions for ethylene oxide catalyst preparation
CN110586170B (zh) * 2018-06-12 2021-10-01 中国石油化工股份有限公司 一乙醇胺和二乙醇胺催化剂的钝化方法
CN110605073B (zh) * 2018-06-15 2022-03-15 中国石油化工股份有限公司 用于烯烃环氧化工艺的催化剂装填方法及烯烃环氧化方法

Family Cites Families (111)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2238474A (en) 1941-04-15 Process for making olefin oxides
US2424083A (en) 1943-08-11 1947-07-15 Shell Dev Supported silver catalyst
US2901441A (en) 1953-01-28 1959-08-25 Publicker Ind Inc Preparation of an oxidation catalyst
GB1170663A (en) 1967-03-22 1969-11-12 Shell Int Research Process for preparing Silver Catalysts
US3563913A (en) 1967-10-30 1971-02-16 Shell Oil Co Silver catalyst production
BE731346A (enExample) 1968-04-10 1969-09-15
GB1257352A (enExample) 1968-04-24 1971-12-15
US3844981A (en) 1969-12-23 1974-10-29 Exxon Research Engineering Co Method for preparation of olefin oxidation catalyst
US4012425A (en) 1972-01-07 1977-03-15 Shell Oil Company Ethylene oxide process
US4356312A (en) 1972-01-07 1982-10-26 Shell Oil Company Ethylene oxide process
US3962285A (en) 1972-06-05 1976-06-08 Exxon Research And Engineering Company Olefin oxidation process
DE2304831C3 (de) 1973-02-01 1978-06-22 Kali-Chemie Ag, 3000 Hannover Verfahren zur katalytischen Entfernung von Kohlenmonoxid, unverbrannten Kohlenwasserstoffen und Stickoxiden aus Autoabgasen
US4207210A (en) 1973-10-26 1980-06-10 Shell Oil Company Process for preparing an ethylene oxide catalyst
GB1489335A (en) 1973-10-26 1977-10-19 Shell Int Research Catalyst for the production of ethylene oxide
US3972829A (en) 1974-11-07 1976-08-03 Universal Oil Products Company Method of depositing a catalytically active metallic component on a carrier material
US4005049A (en) 1975-05-23 1977-01-25 Standard Oil Company (Indiana) Silver catalysts
US3997476A (en) 1975-07-08 1976-12-14 Exxon Research And Engineering Company Alumina treatment
GB1574426A (en) 1976-03-25 1980-09-10 Shell Int Research Process for preparing modified silver catalysts
US4212772A (en) 1976-05-19 1980-07-15 Basf Aktiengesellschaft Catalyst for the manufacture of ethylene oxide
GB1575810A (en) 1976-10-21 1980-10-01 Shell Int Research Process for the performance of silver catalysts
DE2740480B2 (de) 1977-09-08 1979-07-05 Hoechst Ag, 6000 Frankfurt Verfahren zur Verbesserung der Wirksamkeit von Silber-Trägerkatalysatoren
US5387751A (en) 1978-02-10 1995-02-07 Imperial Chemical Industries Plc Production of olefine oxides
US4361503A (en) 1978-07-21 1982-11-30 Mobil Oil Corporation Catalyst for converting synthesis gas to high octane predominantly olefinic naphtha
US4916243A (en) 1979-03-20 1990-04-10 Union Carbide Chemicals And Plastics Company Inc. New catalyst composition and process for oxidation of ethylene to ethylene oxide
HU177860B (en) 1979-05-22 1982-01-28 Mta Koezponti Hivatala Method for producing carrier metal catalyzers
US4235798A (en) 1979-06-28 1980-11-25 Union Carbide Corporation Process for producing two-carbon atom oxygenated compounds from synthesis gas with minimal production of methane
US4244889A (en) 1979-12-19 1981-01-13 Union Carbide Corporation Production of acetamides with rhodium-manganese catalysts
JPS56141842A (en) 1980-04-07 1981-11-05 Kanegafuchi Chem Ind Co Ltd Catalyst formed in novel cylindrical shape
US4376724A (en) 1980-04-14 1983-03-15 Showa Denko Kabushiki Kaisha Rhodium catalyst and method for preparing the same
JPS56164013A (en) 1980-05-23 1981-12-16 Showa Alum Ind Kk Preparation of alumina with low content of radioactive element
US4382149A (en) 1980-11-05 1983-05-03 Borden, Inc. Supported silver catalyst
US4368144A (en) 1980-12-22 1983-01-11 Nippon Shokubai Kagaku Kogyo Co., Ltd. Silver catalyst for production of ethylene oxide
US4379134A (en) 1981-02-13 1983-04-05 Union Carbide Corporation Process of preparing high purity alumina bodies
US4367167A (en) 1981-07-17 1983-01-04 The Dow Chemical Company Process for preparing supported metal catalysts
US4366092A (en) 1981-07-31 1982-12-28 The Dow Chemical Company Process for making a silver-gold alloy catalyst for oxidizing ethylene to ethylene oxide
US4361504A (en) 1981-09-04 1982-11-30 The Dow Chemical Company Process for making a silver catalyst useful in ethylene oxide production
BG37835A3 (en) 1982-06-30 1985-08-15 Hoechst Aktiengesellschaft Method for preparing silver catalyst
DE3310685A1 (de) 1982-07-24 1984-02-09 Hoechst Ag, 6230 Frankfurt Silberkatalysatoren, verfahren zu ihrer herstellung und ihre verwendung zur herstellung von ethylenoxid
JPS5946132A (ja) 1982-09-06 1984-03-15 Nippon Shokubai Kagaku Kogyo Co Ltd メタクロレイン合成用触媒
GB8304749D0 (en) 1983-02-21 1983-03-23 Ici Plc Catalysts
WO1985000365A1 (en) 1983-07-05 1985-01-31 Union Carbide Corporation Alkoxylation using calcium catalysts and products therefrom
US4845296A (en) * 1983-12-13 1989-07-04 Union Carbide Corporation Process for preparing alkanolamines
JPS60216844A (ja) 1984-04-13 1985-10-30 Nippon Shokubai Kagaku Kogyo Co Ltd エチレンオキシド製造用銀触媒
NL8501945A (nl) 1984-12-07 1986-07-01 Unilever Nv Katalysator geschikt voor het ontzwavelen en de bereiding van deze katalysator.
DE3445289A1 (de) 1984-12-12 1986-06-19 Basf Ag, 6700 Ludwigshafen Geformter katalysator fuer heterogen katalysierte reaktionen
US4628129A (en) 1985-02-04 1986-12-09 Union Carbide Corporation Process for the preparation of ethylene glycol
NL8501862A (nl) 1985-06-28 1987-01-16 Shell Int Research Werkwijze ter bereiding van een zilver-houdende katalysator.
GB8613818D0 (en) 1986-06-06 1986-07-09 Ici Plc Catalysts
EP0211521B1 (en) 1985-07-31 1990-03-21 Imperial Chemical Industries Plc Process of promoting catalysts for the production of alkylene oxides
US4994587A (en) 1985-08-12 1991-02-19 Union Carbide Chemicals And Plastics Company, Inc. Catalytic system for epoxidation of alkenes employing low sodium catalyst supports
US4994588A (en) 1985-08-13 1991-02-19 Union Carbide Chemicals And Plastics Company Inc. Fluorine-containing catalytic system for expoxidation of alkenes
US4994589A (en) 1985-08-13 1991-02-19 Union Carbide Chemicals And Plastics Company Inc. Catalytic system for epoxidation of alkenes
GB8526774D0 (en) 1985-10-30 1985-12-04 Sandoz Ltd Bacillus thuringiensis hybrids
GB8610441D0 (en) 1986-04-29 1986-06-04 Shell Int Research Preparation of silver-containing catalyst
US4761394A (en) 1986-10-31 1988-08-02 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4820675A (en) 1986-10-31 1989-04-11 Shell Oil Company Ethylene oxide catalyst & process for preparing the catalyst
US4766105A (en) 1986-10-31 1988-08-23 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4808738A (en) 1986-10-31 1989-02-28 Shell Oil Company Ethylene oxide process
IL84232A (en) 1986-10-31 1992-06-21 Shell Int Research Catalyst and process for the catalytic production of ethylene oxide
GB8626687D0 (en) 1986-11-07 1986-12-10 Shell Int Research Preparing silver catalyst
US4908343A (en) 1987-02-20 1990-03-13 Union Carbide Chemicals And Plastics Company Inc. Catalyst composition for oxidation of ethylene to ethylene oxide
US5057481A (en) 1987-02-20 1991-10-15 Union Carbide Chemicals And Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
GB8716653D0 (en) 1987-07-15 1987-08-19 Shell Int Research Silver-containing catalyst
ES2004759A6 (es) 1987-07-17 1989-02-01 Espanola Alumina Sa Metodo de obtencion de alumina especial a partir del polvo producido en la calcinacion de alumina metalurgica
US4921681A (en) 1987-07-17 1990-05-01 Scientific Design Company, Inc. Ethylene oxide reactor
EP0317088A1 (en) 1987-10-22 1989-05-24 Glaxo Group Limited Ketone derivatives
JP2561678B2 (ja) 1987-11-06 1996-12-11 三菱化学株式会社 エチレンオキシド製造用銀触媒
CN1009437B (zh) 1988-02-03 1990-09-05 中国石油化工总公司 乙烯氧化制环氧乙烷高效银催化剂
EP0383636A1 (en) 1989-02-17 1990-08-22 Nippon Shokubai Co., Ltd. Carrier for catalyst and method for production thereof
US5037794A (en) 1989-09-12 1991-08-06 The B. F. Goodrich Company Attrition resistant catalyst support
US5187140A (en) 1989-10-18 1993-02-16 Union Carbide Chemicals & Plastics Technology Corporation Alkylene oxide catalysts containing high silver content
US5254786A (en) 1990-08-27 1993-10-19 Shell Oil Company Olefin disproportionation catalyst and process
US5112795A (en) 1990-10-12 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Supported silver catalyst, and processes for making and using same
ATE170425T1 (de) 1990-10-12 1998-09-15 Union Carbide Chem Plastic Alkylenoxid-katalysator mit verbesserter aktivität und/oder stabilität
US5100859A (en) 1991-01-22 1992-03-31 Norton Company Catalyst carrier
US5145824A (en) 1991-01-22 1992-09-08 Shell Oil Company Ethylene oxide catalyst
ES2098387T3 (es) 1992-03-30 1997-05-01 Union Carbide Chem Plastic Procedimiento para producir un catalizador para la produccion de alcanoatos de alquenilo.
JPH05312579A (ja) 1992-05-08 1993-11-22 Murata Mfg Co Ltd ジャイロコンパス
US5407888A (en) 1992-05-12 1995-04-18 Basf Aktiengesellschaft Silver catalyst
US6184175B1 (en) 1993-03-01 2001-02-06 Scientic Design Company, Inc. Process for preparing silver catalyst
DE4311608A1 (de) 1993-04-08 1994-12-15 Huels Chemische Werke Ag Silberkatalysator zur Oxidation von Ethylen zu Ethylenoxid und Verfahren zur Herstellung von Ethylenoxid
US5502020A (en) 1993-04-14 1996-03-26 Mitsubishi Petrochemical Co., Ltd. Catalyst for production of ethylene oxide and process for producing the catalyst
US5447897A (en) 1993-05-17 1995-09-05 Shell Oil Company Ethylene oxide catalyst and process
DE4317641C2 (de) 1993-05-27 2001-05-17 Somos Gmbh Verfahren zum Trocknen eines strömenden Gases
US5380697A (en) 1993-09-08 1995-01-10 Shell Oil Company Ethylene oxide catalyst and process
US5364826A (en) 1993-09-13 1994-11-15 Shell Oil Company Process for preparing ethylene oxide catalysts
US5418202A (en) 1993-12-30 1995-05-23 Shell Oil Company Ethylene oxide catalyst and process
US5545603A (en) 1994-11-01 1996-08-13 Shell Oil Company Ethylene oxide catalyst and process
DE69520409T3 (de) * 1994-12-15 2010-02-18 Shell Internationale Research Maatschappij B.V. Verfahren zur Herstellung von Äthylenoxid-Katalysatoren
AU690809B2 (en) 1995-02-01 1998-04-30 Shell Internationale Research Maatschappij B.V. Alkylene oxide catalyst and process
JP3802106B2 (ja) 1995-06-08 2006-07-26 日本ケッチェン株式会社 炭化水素油の水素化処理触媒とその製造方法およびその活性化方法
US5705661A (en) 1995-09-25 1998-01-06 Mitsubishi Chemical Corporation Catalyst for production of ethylene oxide
US5739075A (en) 1995-10-06 1998-04-14 Shell Oil Company Process for preparing ethylene oxide catalysts
US5801259A (en) 1996-04-30 1998-09-01 Shell Oil Company Ethylene oxide catalyst and process
US5935894A (en) 1997-07-02 1999-08-10 Laroche Industries, Inc. Alumina based adsorbent containing alkali metal compounds
WO1999019065A1 (en) 1997-10-14 1999-04-22 Japan Energy Corporation Catalyst support, catalyst, reactor for hydrogenation reaction, and catalytic reaction method
FR2770421B1 (fr) 1997-10-31 1999-12-10 Inst Francais Du Petrole Procede de preparation de catalyseurs utilisables dans les reactions de transformation de composes organiques
EP0937498B1 (en) 1998-02-20 2004-08-18 Nippon Shokubai Co., Ltd. Silver catalyst for production of ethylene Oxide, method for production thereof, and method for production of ethylene oxide
TR200100751T2 (tr) 1998-09-14 2001-09-21 Shell Internationale Research Maatschappij B.V. Geliştirilmiş katalitik özelliklere sahip bir katalizörün hazırlanması için bir işlem
ID28550A (id) * 1998-09-14 2001-05-31 Shell Int Research Proses pemindahan jenis-jenis yang dapat berionisasi dari permukaan katalis untuk meningkatkan sifat-sifat katalitik
EP1140354A1 (en) * 1998-09-14 2001-10-10 Shell Internationale Researchmaatschappij B.V. Epoxidation catalyst carrier, preparation and use thereof
DE69924453T2 (de) * 1998-11-17 2006-02-16 Nippon Shokubai Co., Ltd. Katalysatorträger zur Verwendung in der Herstellung von Ethylenoxid
JP3800488B2 (ja) 2000-05-08 2006-07-26 株式会社日本触媒 エチレングリコールの製造方法
WO2002026370A1 (en) 2000-09-26 2002-04-04 Shell Internationale Research Maatschappij B.V. Rod-shaped inserts in reactor tubes
EP1201301B1 (en) 2000-10-25 2005-03-30 Mitsubishi Chemical Corporation Process of olefins oxidation using a catalyst comprising silver and alkali metal(s)
US6855272B2 (en) 2001-07-18 2005-02-15 Kellogg Brown & Root, Inc. Low pressure drop reforming exchanger
AU2003217756B2 (en) 2002-02-25 2008-11-20 Shell Internationale Research Maatschappij B.V. Supported silver catalyst and an epoxidation process using the catalyst
US6846774B2 (en) 2003-04-23 2005-01-25 Scientific Design Co., Inc. Ethylene oxide catalyst
KR20050120814A (ko) 2003-05-07 2005-12-23 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 은-함유 촉매 및 이의 제조 방법 및 사용 방법
US20040224841A1 (en) 2003-05-07 2004-11-11 Marek Matusz Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof
US20060293180A1 (en) 2003-08-22 2006-12-28 Thorsteinson Erlind M Modified alumina carriers and silver-based catalysts for the production of alkylene oxides

Also Published As

Publication number Publication date
IN2006DE05676A (enExample) 2007-08-31
JP2007531622A (ja) 2007-11-08
US7538235B2 (en) 2009-05-26
EP1735091A1 (en) 2006-12-27
US20050222442A1 (en) 2005-10-06
CA2561673A1 (en) 2005-10-20
CN1956783A (zh) 2007-05-02
WO2005097316A1 (en) 2005-10-20
TW200600190A (en) 2006-01-01

Similar Documents

Publication Publication Date Title
KR101629038B1 (ko) 산화올레핀, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산방법
RU2328491C2 (ru) Способ эпоксидирования олефинов и катализатор для применения в способе
US7348444B2 (en) Process for the production of an olefin oxide
CA2570656C (en) A process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine
TWI446963B (zh) 環氧化催化劑、製備該催化劑之方法及製備烯烴氧化物、1,2-二醇、1,2-二醇醚、1,2-碳酸酯或烷醇胺之方法
TWI464154B (zh) 製備烯烴氧化物、1,2-二醇、1,2-二醇醚、1,2-碳酸酯或烷醇胺之方法
EP2617488A2 (en) Process for preparing a catalyst for use in an olefin epoxidation process and epoxidation process using the catalyst
KR20070004940A (ko) 은 촉매의 제조방법, 그 촉매 및 이 촉매의 올레핀산화에서의 용도
KR20070004941A (ko) 은 촉매의 제조방법, 그 촉매 및 이 촉매의 올레핀산화에서의 용도
CA2571179C (en) A process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine
US8603937B2 (en) Olefin epoxidation process, a catalyst for use in the process, a carrier for use in preparing the catalyst, and a process for preparing the carrier
US7713903B2 (en) Carrier, a process for preparing the carrier, an olefin epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, A 1,2-diol, A 1,2-diol ether, or an alkanolamine
KR20070015939A (ko) 은 촉매의 제조방법, 그 촉매 및 이 촉매의 올레핀산화에서의 용도

Legal Events

Date Code Title Description
PA0105 International application

Patent event date: 20061031

Patent event code: PA01051R01D

Comment text: International Patent Application

PG1501 Laying open of application
PC1203 Withdrawal of no request for examination
WITN Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid