KR20060090816A - 알루미늄-마그네슘 합금의 갈바닉 증착을 위한 전해질 - Google Patents
알루미늄-마그네슘 합금의 갈바닉 증착을 위한 전해질 Download PDFInfo
- Publication number
- KR20060090816A KR20060090816A KR1020067005934A KR20067005934A KR20060090816A KR 20060090816 A KR20060090816 A KR 20060090816A KR 1020067005934 A KR1020067005934 A KR 1020067005934A KR 20067005934 A KR20067005934 A KR 20067005934A KR 20060090816 A KR20060090816 A KR 20060090816A
- Authority
- KR
- South Korea
- Prior art keywords
- electrolyte
- magnesium
- aluminum
- alkyl group
- compound
- Prior art date
Links
- 239000003792 electrolyte Substances 0.000 title claims abstract description 62
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical group [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 title claims abstract description 31
- 230000008021 deposition Effects 0.000 title claims abstract description 23
- 229910000861 Mg alloy Inorganic materials 0.000 title claims abstract description 17
- 239000011777 magnesium Substances 0.000 claims abstract description 32
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 26
- 150000001875 compounds Chemical class 0.000 claims abstract description 25
- 238000000576 coating method Methods 0.000 claims abstract description 22
- 239000000203 mixture Substances 0.000 claims abstract description 17
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 10
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 10
- 229910052792 caesium Inorganic materials 0.000 claims abstract description 9
- 229910052701 rubidium Inorganic materials 0.000 claims abstract description 9
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 8
- 238000004519 manufacturing process Methods 0.000 claims abstract description 8
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims abstract description 7
- -1 magnesium alkyl compound Chemical class 0.000 claims abstract description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 26
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 22
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 21
- 239000011248 coating agent Substances 0.000 claims description 15
- 229910052782 aluminium Inorganic materials 0.000 claims description 14
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 13
- 239000011734 sodium Substances 0.000 claims description 13
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 9
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 9
- 239000011591 potassium Chemical group 0.000 claims description 9
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical group [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 8
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical group [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims description 8
- 239000004020 conductor Substances 0.000 claims description 7
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 6
- QWTDNUCVQCZILF-UHFFFAOYSA-N iso-pentane Natural products CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 claims description 6
- 239000003960 organic solvent Substances 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 150000002430 hydrocarbons Chemical class 0.000 claims description 5
- 150000002681 magnesium compounds Chemical class 0.000 claims description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 5
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 4
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 4
- 239000008096 xylene Substances 0.000 claims description 4
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- 239000003849 aromatic solvent Substances 0.000 claims description 3
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 125000005234 alkyl aluminium group Chemical group 0.000 claims description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- 229930195734 saturated hydrocarbon Natural products 0.000 claims 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims 1
- 238000000151 deposition Methods 0.000 description 19
- 239000000243 solution Substances 0.000 description 9
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
- 238000011065 in-situ storage Methods 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 125000002734 organomagnesium group Chemical group 0.000 description 5
- 229910052786 argon Inorganic materials 0.000 description 4
- 230000003750 conditioning effect Effects 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000004070 electrodeposition Methods 0.000 description 3
- 238000007689 inspection Methods 0.000 description 3
- 150000002901 organomagnesium compounds Chemical class 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- QVGLDPPIMKSVBG-UHFFFAOYSA-N 2-methylbutane Chemical compound CCC(C)C.CCC(C)C QVGLDPPIMKSVBG-UHFFFAOYSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- PWJAKLDKEZIGFV-UHFFFAOYSA-N CCC(C)[Mg] Chemical compound CCC(C)[Mg] PWJAKLDKEZIGFV-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- RYZCLUQMCYZBJQ-UHFFFAOYSA-H lead(2+);dicarbonate;dihydroxide Chemical compound [OH-].[OH-].[Pb+2].[Pb+2].[Pb+2].[O-]C([O-])=O.[O-]C([O-])=O RYZCLUQMCYZBJQ-UHFFFAOYSA-H 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000005486 organic electrolyte Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/42—Electroplating: Baths therefor from solutions of light metals
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Electroplating Methods And Accessories (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03021877A EP1518945A1 (de) | 2003-09-27 | 2003-09-27 | Elektrolyt für die galvanische Abscheidung von Aluminium-Magnesium-Legierungen |
| EP03021877.0 | 2003-09-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20060090816A true KR20060090816A (ko) | 2006-08-16 |
Family
ID=34178513
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020067005934A KR20060090816A (ko) | 2003-09-27 | 2004-09-09 | 알루미늄-마그네슘 합금의 갈바닉 증착을 위한 전해질 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20070108061A1 (de) |
| EP (2) | EP1518945A1 (de) |
| JP (1) | JP2007506862A (de) |
| KR (1) | KR20060090816A (de) |
| CN (1) | CN1860257A (de) |
| RU (1) | RU2347857C2 (de) |
| WO (1) | WO2005033374A1 (de) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1524336A1 (de) * | 2003-10-18 | 2005-04-20 | Aluminal Oberflächtentechnik GmbH & Co. KG | Mit einer Aluminium-/Magnesium-Legierung beschichtete Werkstücke |
| CN103334132B (zh) * | 2013-07-17 | 2016-05-25 | 沈阳大学 | 室温电沉积制备铝镁合金膜的方法 |
| CN103510136B (zh) * | 2013-09-22 | 2015-08-19 | 电子科技大学 | 一种在超细钨丝表面电沉积铝镁合金薄膜的方法 |
| CN106435706B (zh) * | 2015-08-04 | 2019-02-26 | 张无量 | 镁制血管支架的电化学抛光方法 |
| JP7179358B2 (ja) * | 2017-06-01 | 2022-11-29 | ルミシールド テクノロジーズ インコーポレイテッド | 水溶液中における金属リッチ層の電気化学的堆積のための方法および組成物 |
| CN113846353B (zh) * | 2021-10-13 | 2023-03-28 | 东北大学 | 一种使用极性非质子有机溶剂制备铝镁合金的方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3028319A (en) * | 1960-02-01 | 1962-04-03 | Ethyl Corp | Manufacture of magnesium organo compounds |
| CH576006A5 (de) * | 1971-05-07 | 1976-05-31 | Siemens Ag | |
| US4778575A (en) * | 1988-01-21 | 1988-10-18 | The United States Of America As Represented By The United States Department Of Energy | Electrodeposition of magnesium and magnesium/aluminum alloys |
| DE19855666A1 (de) * | 1998-12-01 | 2000-06-08 | Studiengesellschaft Kohle Mbh | Aluminiumorganische Elektrolyte und Verfahren zur elektrolytischen Beschichtung mit Aluminium oder Aluminium-Magnesium Legierungen |
| US7250102B2 (en) * | 2002-04-30 | 2007-07-31 | Alumiplate Incorporated | Aluminium electroplating formulations |
| WO2002088434A1 (en) * | 2001-04-30 | 2002-11-07 | Alumiplate Incorporated | Aluminium electroplating formulations |
-
2003
- 2003-09-27 EP EP03021877A patent/EP1518945A1/de not_active Withdrawn
-
2004
- 2004-09-09 KR KR1020067005934A patent/KR20060090816A/ko not_active Application Discontinuation
- 2004-09-09 WO PCT/EP2004/052113 patent/WO2005033374A1/de active Application Filing
- 2004-09-09 JP JP2006527396A patent/JP2007506862A/ja active Pending
- 2004-09-09 RU RU2006116263/02A patent/RU2347857C2/ru not_active IP Right Cessation
- 2004-09-09 US US10/573,519 patent/US20070108061A1/en not_active Abandoned
- 2004-09-09 CN CNA2004800280473A patent/CN1860257A/zh active Pending
- 2004-09-09 EP EP04787118A patent/EP1664389A1/de not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| EP1664389A1 (de) | 2006-06-07 |
| RU2347857C2 (ru) | 2009-02-27 |
| RU2006116263A (ru) | 2007-11-27 |
| CN1860257A (zh) | 2006-11-08 |
| US20070108061A1 (en) | 2007-05-17 |
| EP1518945A1 (de) | 2005-03-30 |
| JP2007506862A (ja) | 2007-03-22 |
| WO2005033374A1 (de) | 2005-04-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A201 | Request for examination | ||
| E902 | Notification of reason for refusal | ||
| E601 | Decision to refuse application |