KR20040050225A - sinterd alloy of tungsten carbide having tensile strength and wear resistance character & cutting tools using the same - Google Patents

Abstract

PURPOSE: A sintering alloy for cutting tool that is suitable for obtaining high toughness and wear resistance at the same time as a tungsten carbide based alloy containing carbide and nitride is provided, and a cutting tool using the same is provided. CONSTITUTION: The tungsten carbide (WC) based sintering alloy with high toughness and wear resistance comprises 20 to 65 wt.% of tungsten carbide (WC); 20 to 60 wt.% of at least one or more of carbides or carbonitrides comprising one or more of elements selected from elements of groups 4a, 5a and 6a on the periodic table; and 10 to 30 wt.% of metal binder phase formed of transition metals, wherein the elements composing the carbonitrides or carbides are at least one or more elements selected from Ti, Ta, Mo, Nb and Zr, and wherein the tungsten carbide based sintering alloy comprises 20 to 50 wt.% of TiCN in which a ratio of TiN(TiC/TiN) is 0.25 to 0.95, 10 wt.% or less of carbide, and a balance of transition metals formed in a Co-Ni binder phase.

Description

Sinterd alloy of tungsten carbide having tensile strength and wear resistance character & cutting tools using the same}

The present invention relates to a tungsten carbide (WC) -based small alloy sintered body, and more particularly, to a tungsten carbide-based alloy containing carbon and nitride, which is suitable for simultaneously having high toughness and wear resistance, and a small alloy for cutting tools and cutting using the same. It is about a tool.

In many industries that use tools and structural materials such as high speed cutting and precision cutting in the cutting field, cermet tool alloys and carbide tool alloys are used to provide high temperature characteristics, wear resistance, plastic deformation and high toughness characteristics. It is known.

The cermet tool has a rugged wear resistance and plastic deformation resistance, but the toughness of the cermet tool is not as widely used for severe interrupted machining such as cemented carbide tools.

In addition, carbide tools have superior toughness compared to cermet tools, so they have excellent chipping and fracture resistance. However, high speed machining has low wear resistance and easy cutting edge plastic deformation.

Conventional cermet tool alloys consist mainly of titanium (Ti), titanium carbide (TiC) or titanium carbon-nitride (TiCN), and carbides of group 4a, 5a, and 6a elements (Mo ₂ C, TaC, NbC) on the periodic table. Etc. are added, and the bonding phase is mainly composed of iron group transition metals (Co, Ni).

The development of these cermet tools increases the constituent content of titanium carbide (TiC) or titanium carbon-nitride (TiCN), which is mainly hard, to improve the toughness and wear resistance. Research has been proposed to increase the nitrogen content while reducing the amount of nitrogen.

In addition, a method of improving the strength and toughness of the alloy by controlling the carbon and nitrogen content of the cermet tool alloy by controlling the thickness of the carbon-nitride core structure surrounding the hard phase of the structure has been proposed. Although the abrasion resistance and toughness of the cermet tool originally intended according to the above method were improved to some extent, it was still insufficient to obtain excellent toughness such as cemented carbide.

The carbide tool alloy is mainly composed of tungsten carbide (WC), cobalt (Co) as a binding phase, and a small amount of TiC or TaC is added to improve high temperature characteristics. Most studies on the wear resistance of such carbide tool alloys include adding grain growth inhibitors such as vanadium carbide (VC) to obtain fine grains and improving the wear resistance by reducing the cobalt (Co) concentration on the surface of the sintered body. Has been.

The improvement of cutting characteristics by ideally and at the same time significantly improving the opposing characteristics of wear resistance and toughness can be said to be limited in cermet tools and carbide tools.

SUMMARY OF THE INVENTION The present invention has been made to solve the conventional problems, and an object thereof is to obtain a suitable small-alloy alloy capable of simultaneously satisfying the excellent wear resistance and heat resistance of the cermet tool alloy and toughness comparable to that of the cemented carbide tool alloy.

1 is a microscope enlarged alloy structure photograph according to the present invention

The present invention for achieving the above object is 20 to 65% by weight of tungsten carbide (WC), 30 to 60% by weight of at least one of the carbides or carbonitrides of the 4a, 5a, 6a group elements of the periodic table, the combination of transition metals The tungsten carbide sub-alloy is characterized in that the phase metal is composed of 10 to 30% by weight.

According to the present invention, various insert-type cutting tools can be obtained using the above-described small alloy, and hard ceramic material is coated on the surface by physical vapor deposition (PVD) or chemical vapor deposition (CVD) using the insert-type cutting tool as a base material. Of course, a coated cutting tool can be obtained.

Titanium (Ti), tantalum (Ta), molybdenum (Mo), niobium (Nb), zirconium (Zr) and the like are preferable as the 4a, 5a and 6a group elements on the periodic table in the above composition. Titanium carbonitride (TiCN).

The TiCN powder, which is a carbonitride, has a TiCN of 20 to 50% by weight using a TiN (TiC / TiN) = 0.25 to 0.95 powder having a TiN ratio of 25 to 95%, and other carbides are Mo ₂ C, TaC Most preferably, at least one of NbC and ZrC is 10% by weight or less. On the other hand, as the transition metal, the metal forming the bonding phase is preferably a Co-Ni bonding phase.

Figure 1 shows a micrograph according to the alloy of the present invention, such a composite structure is a micronized structure due to the nitrogen containing, high concentration of WC reacts with TiCN and the second carbide (W, Ti, Ta) CN, etc. It shows the structure where carbonitride is formed and WC particles are dispersed around.

Carbon nitride particles, which are the major hard phases of the composite structure, improve the wear resistance and heat resistance of the tool, and the WC particles having a high modulus of elasticity dispersed around them serve to improve the toughness by absorbing the impact and thus have excellent cutting characteristics. Indicates.

In addition, alloys containing carbonitrides (TiCN), such as cermet tools, require a high sintering temperature of 1450 ° C. or higher due to a particularly poor sinterability in the sintering process, which is a major manufacturing process. It is possible to obtain characteristics that can be easily sintered even at temperature.

The following is described according to the embodiment.

Example 1

In designing the alloy of the present invention, each carbide, cobalt (Co) and nickel (Ni) used an industrial raw material powder having an average particle size of 1.0 to 1.5 µm and a purity of 99.9%. The carbonitride (TiCN) powder was made of TiN (TiC / TiN) = 0.25-0.95 having a TiN ratio of 25-95% to form a nitrogen-containing alloy. Table 1 shows the composition of the alloy of the present invention, conventional cermet alloys, and cemented carbides of the ISO P-series of similar grades.

Alloy composition sample Composition (% by weight) TiCN (TiC / TiN) WC (Mo, Ta, Zr) C o-Ni Invention One 52 (38/14) 26 10 16 2 42 (29/13) 35 9 14 3 31 (26/5) 50 6 13 4 20 (10/10) 65 4 11 Cermet alloy 5 59 (47/12) 8 20 13 6 58 (29/29) 14 12 16 Cemented carbide 7 8 (TiC) 73 9 10 (Co) 8 6 (TiC) 77 8 9 (Co)

As shown in Table 1, it can be seen that the alloy of the present invention is significantly different from the composition of the conventional cermet and cemented carbide. In the sintering method using the alloy of the present invention described above was prepared by the powder metallurgy method, which is a manufacturing method of a conventional cemented carbide or cermet tool.

First, each raw powder was pulverized and mixed for 50 to 80 hours by wet ball milling, followed by drying. The test pieces and cutting tools of each specification were molded at a molding pressure of 150 to 200 MPa. Sintered under vacuum (or nitrogen) atmosphere for 30 to 60 minutes in the section. The sintering temperature of the conventional cermet cutting tool is more than 1450 ℃, in the case of the present invention is sufficiently dense sintering at 1400 ℃ or less.

Example 2

The alloy of the present invention sintered as described above was ground using a diamond grinding wheel to prepare a test piece of physical properties and a cutting tool of the standard. Grindability was better than cermet alloy and showed similar grinding characteristics as cemented carbide.

The structure photograph (sample number 2) of the alloy from each of the prepared test pieces is shown in FIG. As described above, the alloy structure of the present invention is represented by a complex structure of both the conventional cermet and the cemented carbide structure.

Coercive force, hardness, and bending strength of each alloy. The mechanical properties such as failure recognition are shown in Table 2.

Mechanical properties sample Coercive force (Oe) Hardness (Hra) Bending strength (kg / mm ² ) Fracture Toughness (MPam ^1/2 ) Thermal Conductivity (W / mK) Invention One 243 92.6 224 10.8 22.2 2 226 92.4 231 12.1 25.0 3 213 91.9 228 13.0 29.7 4 202 91.7 220 13.1 35.1 Cermet alloy 5 157 92.8 208 8.8 17.6 6 172 92.6 218 9.4 19.1 Cemented carbide 7 198 91.6 242 13.8 37.6 8 206 91.8 237 13.5 39.2

As shown in Table 2, it can be seen that the alloy of the present invention has a similar hardness compared to the conventional cutting tool alloy cermet, while significantly improving fracture toughness and thermal conductivity. In addition, compared to the typical cemented carbide of the ISO P-series of the same use it can be seen that it has a high hardness value of the cermet tool alloy level while having similar strength and fracture toughness values.

Example 3

Cutting tools were fabricated using the alloys of Examples 1 and 2 to evaluate cutting performance. The cutting tool specifications were prepared with SPKN1203EDTR milling inserts and are shown in Table 3 comparing cutting performance with conventional cermet and cemented carbide tools of the same use.

In the milling test, dry up-cutting of SCM4 (HB240) and KP4 (alloyed steel, HB320), 90 × 90 × 200 mm alloy steel, was carried out and the cutting conditions (cutting speed V, feed rate f, The cutting distance d) was evaluated as the cutting distance from the cutting edge flank of each cutting tool to 0.25mm, and it would be difficult to cut any more due to the lack of tools or chipping during cutting. In this case, tool life was evaluated as being over.

Cutting conditions for the workpiece: cutting speed V = 200 m / min.

Feedrate f = 0.2mm / rev.

Depth of cut d = 2.0 mm

Milling Cutting Performance Test Workpiece Tool type sample Test result Cutting distance (m, tool life) Damage comparison SCM4 (Alloy Steel, HB240) The present invention 2 5.8 Normal wear 4 5.5 Normal wear Cermet 6 3.9 Chipping wear Carbide 8 2.1 Normal wear KP4 (Alloy Steel, HB320) The present invention 2 3.1 Normal wear 4 3.7 Normal wear Cermet 6 2.2 Chipping wear Carbide 8 1.3 Wear

As shown in Table 3, it can be seen that the cutting tool of the alloy of the present invention has excellent cutting performance compared to conventional cermet tools or cemented carbide tools.

In the alloy cutting tool of the present invention, not only the cutting distance to the tool life is superior to other tools, but also the cutting edge of the tool life progresses to normal wear, whereas the cermet and carbide tools have chipping or defects at the end of their life. . This is because the chipping wear of the cermet tool lacks toughness, and in the case of cemented carbide tools, defect wear occurs at the end of the service life due to the lack of wear resistance. On the other hand, it is judged that the cutting tool of the alloy of the present invention has excellent cutting performance because it has a balance of wear resistance and toughness.

In addition, when cutting SCM4 workpieces to investigate the toughness (break resistance) of each cutting tool, the cutting test results until each tool is missing while increasing the moving speed under the same cutting conditions to induce chipping and defects. 4 is shown.

Toughness Comparison Test Tool type sample Feed speed (feed. Mm / rev) Remarks 0.1 0.2 0.3 0.4 0.5 0.6 0.7 Invention Tool 2 0 0 0 0 0 0 0 4 0 0 0 0 0 0 × f = 0.7 deficit Cermet 6 0 0 0 × × × × f = 0.4 deficit Carbide 8 0 0 0 0 0 × × f = 0.6 deficit

※ Workpiece: SCM4. Cutting speed: V = 100m / min. Depth of cut: d = 2.0mm

As a result of the toughness test, the cutting tool of the alloy of the present invention showed excellent toughness rather than cermet carbide tools. As shown in Table 2, the fracture toughness value is the best of the cemented carbide, but the present invention has a fracture toughness close to this, and the alloy tool of the present invention having a higher hardness value has no tool defect even at a relatively higher feed rate. This shows that the toughness and abrasion resistance of the tool material must be balanced.

On the other hand, in milling cutting, the higher the cutting speed, the more easily cracks are generated on the cutting edge of the tool, and in particular, the tool life is often determined by the occurrence and development of such cracks. In order to investigate the thermal crack resistance of each tool, the cutting speed was adjusted to 250m / min in the same milling cutting test as the workpiece KP4 cutting conditions in Table 3, and the cutting distance of 1.5m was cut and the thermal cracks of the cutting edges were examined.

The thermal cracking resistance of the alloy tool and the cemented carbide tool of the present invention was similar, but the wear phenomenon of the cemented carbide was more severe. In the cermet tool, thermal cracking was most developed, which is primarily because of low thermal conductivity as shown in Table 2.

As shown in Table 2, the alloy tool of the present invention has a relatively high thermal conductivity compared to the cermet, and thus has a high thermal cracking resistance.

As described above, the alloy tool of the present invention has excellent mechanical properties and cutting characteristics as well as excellent toughness and wear resistance as well as excellent thermal properties compared to conventional carbide tools (coating tools), cermet tools, and ceramic tools. The new versatile tool is expected to show excellent performance in the cutting of various metal workpieces in the future. In addition, it is expected to be applied to coating tools as well as uncoated tools because it shows more excellent wear resistance when used as a coating base material.

As described above, the cutting tools using the alloy of the present invention satisfy the toughness and wear resistance at the same time, so that not only the cutting area of the conventional cermet tool, but also the use area of the cemented carbide tool can be widely used as a long-life tool. A wide range of applications as a new universal cutting tool is possible in cutting applications such as stainless steel as well as steel, and cutting is used as the base material and the surface is coated by physical vapor deposition (PVD) or chemical vapor deposition (CVD). As well as being used in a tool, it can be widely used for various wear-resistant materials, such as a metal mold | die, dice | die, and a jig | tool using the said material. In addition, the cutting tool of the present invention can be used to replace both cutting processes in the cutting tool of the present invention, compared to using a coated carbide tool for interrupted or rough machining, which is a conventional cutting method for steel, and to a cermet tool for finishing or finishing. There is a big advantage to that. In addition, in the manufacture of the alloy of the present invention sinterability is better than the conventional cermet tool alloy is possible to sinter even at a temperature lower than about 50 ℃ or less, and excellent moldability and grinding properties, and easy to manufacture tool alloys and lower manufacturing costs There are also advantages.

Claims (5)

20 to 65% by weight of tungsten carbide (WC), 20 to 60% by weight of at least one carbide or carbonitride including at least one member selected from group 4a, 5a, and 6a elements of the periodic table, A tungsten carbide base binder having high toughness and abrasion resistance, which is composed of -30 wt%. The method of claim 1, A tungsten carbide base alloy having high toughness and wear resistance, characterized in that the carbonitride or carbide-forming element contains at least one of Ti, Ta, Mo, Nb, and Zr. The method of claim 2, It has high toughness and abrasion resistance, characterized by a TiCN content of 20 to 50% by weight, a carbide of 10% by weight or less, and transition metals as Co-Ni-bonded phases having a TiN (TiC / TiN) ratio of 0.25 to 0.95. Tungsten carbide base binder. Cutting tool, characterized in that consisting of a small alloy of any one of claims 1 to 3. The method of claim 4, wherein A coating cutting tool having high toughness and wear resistance by coating a hard ceramic material on a surface by physical vapor deposition (PVD) or chemical vapor deposition (CVD) using the cutting tool as a base material.