JPH10298698A - Cemented carbide - Google Patents
Cemented carbideInfo
- Publication number
- JPH10298698A JPH10298698A JP9123322A JP12332297A JPH10298698A JP H10298698 A JPH10298698 A JP H10298698A JP 9123322 A JP9123322 A JP 9123322A JP 12332297 A JP12332297 A JP 12332297A JP H10298698 A JPH10298698 A JP H10298698A
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- Prior art keywords
- carbide
- weight
- tungsten carbide
- amount
- cemented carbide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は超硬合金に関するもので
あり、特に硬度と耐蝕性に優れた切削加工工具をはじめ
として硬度と耐蝕性が求められる任意の部品、例えば構
造部品、機械部品、装飾品等に好適に使用できる新規な
超硬合金に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cemented carbide, and more particularly to a cutting tool having excellent hardness and corrosion resistance, and any part requiring hardness and corrosion resistance, such as a structural part, a machine part, and the like. The present invention relates to a novel cemented carbide that can be suitably used for decorative articles and the like.
【０００２】[0002]
【従来の技術】被削材の難削化、加工の高速化に伴い、
切削加工用工具の材料として用いられる超硬合金には高
強度、高硬度への不断の要求がある。例えば、切削工具
の用途ではフランク摩耗に対する耐摩耗性の向上に加え
て、被削材の表面（いわゆる黒皮）が接触して進行する
境界摩耗に対して強いことが特に求められる。また、す
くい面に発生し易いクレータ摩耗に対する耐性も求めら
れる。更に、最近では、Ni合金、Ti合金、高硬度鋼など
の難削材の切削でしばしば発生する被削材の工具への溶
着に対する耐性も求められる。この溶着は構成刃先とな
って工具のチッピング等の原因となり、工具寿命を著し
く短くする。2. Description of the Related Art With difficult-to-cut materials and high-speed machining,
There is a constant demand for high-strength, high-hardness cemented carbide used as a material for cutting tools. For example, in the application of a cutting tool, in addition to the improvement of abrasion resistance against flank wear, it is particularly required that the surface of a work material (so-called black scale) is strong against boundary wear which progresses by contact. Further, resistance to crater wear, which easily occurs on the rake face, is also required. Further, recently, resistance to welding of a work material to a tool, which often occurs in cutting of a difficult-to-cut material such as a Ni alloy, a Ti alloy, and high-hardness steel, is also required. This welding becomes a component edge and causes chipping of the tool, etc., and significantly shortens the tool life.
【０００３】特開昭61-12847号公報には、上記の一連の
要求に対して、Ｖ（ヴァナジウム）およびCr（クロム）
の複合添加によってＷＣ（タングステンカーバイド）の
粒成長を抑制し、それによって耐蝕性を向上させられる
ことが記載されている。また特公昭４-31012号公報と
「粉体および粉末冶金」31（1984）56には、 Cr3Ｃ
2（炭化クロム）を添加することによって耐食性を向上
させ得ることが記載されている。[0003] Japanese Patent Application Laid-Open No. 61-12847 discloses that V (vanadium) and Cr (chromium) meet the above series of requirements.
It is described that grain growth of WC (tungsten carbide) can be suppressed by composite addition of WC, thereby improving corrosion resistance. Japanese Patent Publication No. 4-31012 and “Powder and Powder Metallurgy” 31 (1984) 56 describe Cr 3 C
It is described that corrosion resistance can be improved by adding 2 (chromium carbide).
【０００４】このように、切削工具等の材料として用い
られる超硬合金では、主として硬度を上げるために微粒
のＷＣ原料を使用し、粒成長抑制と境界摩耗およびクレ
ータ摩耗の抑制のために Cr3Ｃ2 を添加して耐食性を向
上させている。As described above, in a cemented carbide used as a material for a cutting tool or the like, a fine WC raw material is mainly used for increasing hardness, and Cr 3 is used for suppressing grain growth and boundary wear and crater wear. It was added to C 2 thereby improving the corrosion resistance.
【０００５】しかし、粒子を微細化した微粒の超硬合金
ではクラックの伝播抵抗が低下する場合がある。事実、
クラックの進行に対しては粗粒の方がエネルギーを多く
要するので、粗粒の方がクラック進行阻止には寄与す
る。[0005] However, in the case of a fine-grained cemented carbide having fine particles, crack propagation resistance may decrease. fact,
Since coarse grains require more energy for the progress of cracks, coarse grains contribute to the prevention of crack progress.
【０００６】また、切削工具として使用した場合には、
加工時の高温によって結合相の硬質粒子のグリップ力が
低下する傾向がある。そして、この場合、粗粒よりも微
粒の方が粒子脱落が起こり易く、擦過摩耗の進行が早く
なる。When used as a cutting tool,
The gripping force of the hard particles of the binder phase tends to decrease due to the high temperature during processing. In this case, fine particles are more likely to fall off than coarse particles, and the progress of abrasion wear is faster.
【０００７】また、この種の超硬合金では不可避的不純
物の含有量が多いと、 Cr3Ｃ2 の添加で合金中に脆化相
が形成され、その結果、超硬合金のクラック伝播抵抗が
著しく低下し、強度の劣化を招く。In addition, if the content of unavoidable impurities is large in this type of cemented carbide, the addition of Cr 3 C 2 forms an embrittlement phase in the alloy, and as a result, the crack propagation resistance of the cemented carbide decreases. It decreases remarkably and causes deterioration of strength.
【０００８】[0008]
【発明が解決しようとする課題】本発明の目的は、上記
従来法の問題点を解決して、切削工具等に好適な特性を
有し、しかも耐食性に優れた新規な超硬合金を提供する
ことにある。SUMMARY OF THE INVENTION An object of the present invention is to solve the above-mentioned problems of the conventional method and to provide a new cemented carbide having characteristics suitable for a cutting tool and the like and excellent in corrosion resistance. It is in.
【０００９】[0009]
【課題を解決するための手段】本発明は２〜６重量％の
CoおよびNiと、CoおよびNiに対して 0.1〜30 重量％の
炭化クロムとを含み、残部が炭化タングステンおよび不
可避不純物からなる超硬合金を提供する。SUMMARY OF THE INVENTION The present invention relates to a method for preparing 2-6% by weight.
Provided is a cemented carbide containing Co and Ni and 0.1 to 30% by weight of chromium carbide with respect to Co and Ni, with the balance being tungsten carbide and unavoidable impurities.
【００１０】[0010]
【実施の態様】本発明の好ましい実施例では、Niの比率
はCoおよびNiの総量に対して 0.4〜80重量％である。本
発明の別の好まし実施例では、炭化タングステンの平均
粒度は 0.3〜５μｍである。本発明のさらに別の実施例
では、炭化タングステンは平均粒度が 0.3〜1.1 μｍの
微粒子群と、1.2 〜５μｍの粗粒子群とからなり、炭化
タングステン全体量に対する粗粒子群炭化タングステン
量の比が 0.1〜 0.9である。In a preferred embodiment of the invention, the proportion of Ni is between 0.4 and 80% by weight, based on the total amount of Co and Ni. In another preferred embodiment of the present invention, the average particle size of the tungsten carbide is 0.3-5 μm. In still another embodiment of the present invention, the tungsten carbide is composed of a fine particle group having an average particle size of 0.3 to 1.1 μm and a coarse particle group having a mean particle size of 1.2 to 5 μm. 0.1 to 0.9.
【００１１】本発明の超硬合金は Cr3Ｃ2(炭化クロム）
を特定の条件で含有させた点にその主要な特徴がある。
すなわち、２〜６重量％のCoおよびNiと、このCoおよび
Niに対して 0.1〜30重量％の炭化クロムとを含み、残部
が炭化タングステンと不可避不純物とからなる本発明の
超硬合金は、従来のＷＣ−Co系超硬合金、ＷＣ−微量 C
r3Ｃ2-Co系超硬合金、ＷＣ−微量 Cr3Ｃ2-Co−微量Ni系
超硬合金に比べて、切削用途、特にインコネル、ナイモ
ニックなどのNi合金の切削で格段の寿命延長が可能にな
る。Niの比率がCoおよびNiに対して 0.4〜80重量％であ
る超硬合金はこの特性が一層向上する。The cemented carbide of the present invention is Cr 3 C 2 (chromium carbide).
The main feature is that is contained under specific conditions.
That is, 2 to 6% by weight of Co and Ni,
The cemented carbide of the present invention containing 0.1 to 30% by weight of chromium carbide with respect to Ni and the balance consisting of tungsten carbide and unavoidable impurities is a conventional WC-Co-based cemented carbide, WC-trace C
Compared to r 3 C 2 -Co based cemented carbide and WC-trace Cr 3 C 2 -Co-trace Ni based cemented carbide, the service life is significantly extended in cutting applications, especially when cutting Ni alloys such as Inconel and Nimonic. Will be possible. A cemented carbide in which the ratio of Ni is 0.4 to 80% by weight with respect to Co and Ni further improves this property.
【００１２】1) CoおよびNi量 CoおよびNiの含有量が２重量％未満になると靭性が著し
く低下するので好ましくない。一方、CoおよびNiの含有
量が６重量％以上になると耐塑性変形性および耐摩耗性
が低下するので好ましくない。従って、CoおよびNiの含
有量は２重量％以上で６重量％を超えないようにする。 2) Cr3 Ｃ2 量 Cr3 Ｃ 2 量がCoおよびNiに対して 0.1重量％を超えると
耐酸化性および耐境界摩耗性が不十分になる。一方、30
重量％を超えると脆化相が析出し、靭性が激減する。Co
およびNiに対する炭化クロム(Cr3Ｃ2)の重量比は10重量
％を越えるのが好ましい。 3) Ni量 Niの量がCoおよびNiに対して 0.4重量％未満では所望の
耐摩耗性および耐境界摩耗性が発揮されない。一方、80
重量％を超えると焼結不足で靭性が低下するか高温で焼
結せざるを得ず、耐摩耗性が劣化する。 4) 炭化タングステンの平均粒度 炭化タングステンの平均粒度が 0.3μｍ未満では十分焼
結できず、強度不足になる。一方、５μｍを超えると耐
摩耗性が不足する。 5) 炭化タングステン全体量に対する粗粒子群炭化タン
グステン量の比 炭化タングステン全体量に対する粗粒子群炭化タングス
テン量の比が 0.1未満では強度が不足し、 0.9を超える
と耐摩性が不足する。1) Co and Ni content If the content of Co and Ni is less than 2% by weight, the toughness is remarkably reduced, which is not preferable. On the other hand, if the content of Co and Ni is 6% by weight or more, the plastic deformation resistance and the wear resistance decrease, which is not preferable. Therefore, the content of Co and Ni should be not less than 6% by weight and not less than 2% by weight. 2) Cr 3 C 2 amount When the Cr 3 C 2 amount exceeds 0.1% by weight with respect to Co and Ni, the oxidation resistance and the boundary wear resistance become insufficient. On the other hand, 30
If the content exceeds the weight percentage, an embrittlement phase is precipitated, and the toughness is drastically reduced. Co
Preferably, the weight ratio of chromium carbide (Cr 3 C 2 ) to Ni and Ni exceeds 10% by weight. 3) Ni amount If the amount of Ni is less than 0.4% by weight with respect to Co and Ni, desired wear resistance and boundary wear resistance are not exhibited. On the other hand, 80
If the content exceeds 10% by weight, the toughness is reduced due to insufficient sintering or sintering must be performed at a high temperature, and the wear resistance deteriorates. 4) Average particle size of tungsten carbide If the average particle size of tungsten carbide is less than 0.3 μm, sintering cannot be performed sufficiently, resulting in insufficient strength. On the other hand, if it exceeds 5 μm, wear resistance will be insufficient. 5) Coarse-particle tan carbide with respect to the total amount of tungsten carbide
If the ratio of the amount of gustene to the total amount of tungsten carbide relative to the total amount of tungsten carbide is less than 0.1, the strength is insufficient, and if it exceeds 0.9, the wear resistance is insufficient.
【００１３】切削の耐摩耗性を向上させるために、本発
明の超硬合金上にＣＶＤ、ＰＶＤ等を用いてTiＣＮ、Ti
Ｃ、TiＮ等のTi化合物やアルミナ等の酸化物を被覆して
もよい。以下、本発明の実施例を説明するが、以下の開
示は本発明の特殊な実施例に過ぎず、本発明の技術的範
囲を何等限定するものではない。[0013] In order to improve the wear resistance of cutting, TiCN, TiN is formed on the cemented carbide of the present invention by using CVD, PVD or the like.
It may be coated with a Ti compound such as C or TiN or an oxide such as alumina. Hereinafter, embodiments of the present invention will be described. However, the following disclosure is merely a special embodiment of the present invention, and does not limit the technical scope of the present invention.
【００１４】[0014]
【実施例】実施例１ 下記成分を湿式混合して原料粉末１を調製した： 平均粒径が２μｍのＷＣ粉末 ： 38 重量％ 平均粒径が0.7 μｍのＷＣ粉末 ： 55.7 重量％ 平均粒径が２μｍの Cr3Ｃ2 粉末： 0.7 重量％ 平均粒径が 1.5μｍの Ni 粉末 ： 0.4 重量％ 平均粒径が 1.5μｍの Co 粉末 ： 5 重量％ この原料粉末１を型押し成形した後、10-2Torrの真空中
で1,400 ℃で真空焼結して試料１とした。この試料１で
のCoおよびNiに対する Cr3Ｃ2 の比率は13.0重量％であ
り、CoおよびNiに対するNiの比率は 7.4重量％である。
また、ＷＣ全体の平均粒径は 1.2μｍであり、全ＷＣ量
に対する平均粒径２μｍのＷＣの粗粒子群の比は 0.4で
ある。 EXAMPLE 1 Raw material powder 1 was prepared by wet mixing the following components: WC powder having an average particle size of 2 μm: 38% by weight WC powder having an average particle size of 0.7 μm: 55.7% by weight 2μm Cr 3 C 2 powder: 0.7 wt% average particle diameter of 1.5μm of Ni powder: 0.4 wt% average particle diameter of 1.5μm of Co powder: 5 wt% after the raw powder 1 and embossing molding, 10 - Sample 1 was obtained by vacuum sintering at 1,400 ° C. in a vacuum of 2 Torr. In this sample 1, the ratio of Cr 3 C 2 to Co and Ni was 13.0% by weight, and the ratio of Ni to Co and Ni was 7.4% by weight.
The average particle size of the whole WC is 1.2 μm, and the ratio of the coarse particles of WC having an average particle size of 2 μm to the total WC amount is 0.4.
【００１５】次に、下記成分を湿式混合して原料粉末２
を調製した： 平均粒径が１μｍのＷＣ粉末 ： 96.5 重量％ 平均粒径が２μｍの Cr3Ｃ2 粉末： 0.2 重量％ 平均粒径が 1.5μｍのNi粉末 ： 0.5 重量％ 平均粒径が 1.5μｍのCo粉末 ： 2.8 重量％ この原料粉末２を型押し成形した後、10-2Torrの真空中
で1400℃で真空焼結して試料２とした。この試料２での
CoおよびNiに対する Cr3Ｃ2 の量は 6.1重量％であり、
CoおよびNiに対するNiの量は15.2重量％である。Next, the following components are wet-mixed to obtain raw material powder 2
Was prepared: WC powder having an average particle diameter of 1 μm: 96.5% by weight Cr 3 C 2 powder having an average particle diameter of 2 μm: 0.2% by weight Ni powder having an average particle diameter of 1.5 μm: 0.5% by weight Average particle diameter of 1.5 μm Co powder: 2.8% by weight This raw material powder 2 was stamped and then vacuum-sintered at 1400 ° C. in a vacuum of 10 −2 Torr to obtain a sample 2. In this sample 2,
The amount of Cr 3 C 2 with respect to Co and Ni is 6.1% by weight,
The amount of Ni with respect to Co and Ni is 15.2% by weight.
【００１６】比較のために、本発明の範囲外の組成を有
する原料粉末３を調製した。すなわち、Cr3 Ｃ2 粉末を
0.3重量％とし、Co粉末を 5.8重量％としたこと以外は
試料１と同じ配合比で原料粉末３を調製し、試料１と同
じ条件で成形および焼結して試料３を作製した。この試
料３でのCoおよびNiに対する Cr3Ｃ2 の量は 4.8重量％
であり、CoおよびNiに対するNiの量は 6.5重量％であ
る。For comparison, a raw material powder 3 having a composition outside the range of the present invention was prepared. That is, Cr 3 C 2 powder
A raw material powder 3 was prepared at the same compounding ratio as that of Sample 1 except that the amount of Co powder was changed to 0.3% by weight and the amount of Co powder was changed to 5.8% by weight, and molded and sintered under the same conditions as Sample 1 to prepare Sample 3. The amount of Cr 3 C 2 with respect to Co and Ni in Sample 3 was 4.8% by weight.
And the amount of Ni with respect to Co and Ni is 6.5% by weight.
【００１７】各試料１〜３の機械特性および耐食性を評
価した結果は〔表１〕にまとめて示してある。〔表１〕
において腐蝕減量は36％ＨCl中で50℃で８時間放置した
時の条件で評価した。また、酸化増量は大気中、1000℃
×30分の条件で評価した。The results of evaluating the mechanical properties and corrosion resistance of each of the samples 1 to 3 are summarized in [Table 1]. [Table 1]
In the test, the weight loss of corrosion was evaluated under the condition of standing at 50 ° C. for 8 hours in 36% HCl. In addition, oxidation increase is 1000 ℃ in air.
Evaluation was performed under the condition of × 30 minutes.
【００１８】[0018]
【表１】 (* ：本発明範囲外）[Table 1] (*: Outside the scope of the present invention)
【００１９】〔表１〕の結果から分かるように、本発明
の試料１、２は、比較例の試料３よりCoが少ないため抗
折力がやや低いが、腐食減量、酸化増量という耐食性の
面では比較例の試料３に比べて格段に向上している。本
発明の試料の中でも Cr3Ｃ2の成分が多い試料１の方が
耐食性の観点ではやや優れている。As can be seen from the results in Table 1, Samples 1 and 2 of the present invention have slightly lower transverse rupture strength because of less Co than Sample 3 of Comparative Example. In Example 3, the value is remarkably improved as compared with Sample 3 of the comparative example. Among the samples of the present invention, Sample 1 having a large content of Cr 3 C 2 is slightly better in terms of corrosion resistance.
【００２０】実施例２ 実施例１で作製した試料１〜３を用いて切削工具を作
り、〔表２〕に示す条件で実際に切削加工を行ってその
性能を評価した。 Example 2 A cutting tool was prepared using the samples 1 to 3 prepared in Example 1, and actual cutting was performed under the conditions shown in Table 2 to evaluate its performance.
【００２１】各試料１〜３を第２表の切削条件１〜３で
実施し、併記した判定による結果を第３表に示す。Each of the samples 1 to 3 was cut under the cutting conditions 1 to 3 shown in Table 2 and the results of the judgments shown in Table 3 are shown in Table 3.
【表２】 [Table 2]
【００２２】上記切削条件で、切削条件１では最大摩耗
幅で品質を評価し、切削条件２では20個の切刃で発生し
た欠損切刃数で評価し、切削条件３では平均摩耗幅で評
価した。評価結果は〔表３〕にまとめて示してある。In the above cutting conditions, the quality is evaluated by the maximum wear width under the cutting condition 1, the evaluation is made by the number of cut edges generated by 20 cutting edges under the cutting condition 2, and the average wear width is evaluated under the cutting condition 3. did. The evaluation results are summarized in [Table 3].
【００２３】[0023]
【表３】 [Table 3]
【００２４】〔表３〕から分かるように、本発明の超硬
合金を用いた切削工具は特に耐摩耗性において著しく高
い性能を示す。なお、切削特性については試料１は試料
２よりもやや優れた特性を示している。As can be seen from Table 3, the cutting tool using the cemented carbide of the present invention exhibits remarkably high performance especially in wear resistance. As for the cutting characteristics, the sample 1 shows slightly superior characteristics to the sample 2.
【００２５】実施例３ 〔表４〕に示す組成を有する試料４〜14を作製した。 Example 3 Samples 4 to 14 having the compositions shown in Table 4 were prepared.
【００２６】[0026]
【表４】 [Table 4]
【００２７】各試料について特性を測定した結果は〔表
５〕にまとめて示してある。なお、〔表５〕に示す酸化
増加量は実施例１と同じ方法で評価した。また、切削条
件３は実施例２と同じ方法で評価した。The results of measuring the characteristics of each sample are summarized in Table 5 below. The oxidation increase shown in [Table 5] was evaluated in the same manner as in Example 1. Cutting condition 3 was evaluated in the same manner as in Example 2.
【００２８】[0028]
【表５】 [Table 5]
【００２９】[0029]
【発明の効果】以上説明した通り、本発明の超硬合金は
耐食性において優れた特性を示し、従って、単なる切削
工具材料としての用途に止まらず、各種工具や耐食性の
求められる分野、特に高硬度鋼、Ni基合金、Co基合金、
Ti基合金などの難削材切削の加工分野、例えば熱間官圧
延ロール、時計枠、海水用ポンプスリーブやネカニカル
シール、強腐食性高圧バルブシートやボール、硬質装飾
品等で極めて信頼性の高い超硬合金材料として使用する
ことができる。As described above, the cemented carbide of the present invention exhibits excellent characteristics in corrosion resistance. Therefore, it is not limited to use as a mere cutting tool material, but in various tools and fields where corrosion resistance is required, especially in high hardness. Steel, Ni-based alloy, Co-based alloy,
Extremely reliable in machining areas of difficult-to-cut materials such as Ti-based alloys, such as hot rolled rolls, watch frames, seawater pump sleeves and necanical seals, highly corrosive high-pressure valve seats and balls, and hard decorative products Can be used as high cemented carbide material.
Claims (4)
Niに対して 0.1〜30重量％の炭化クロムとを含み、残部
が炭化タングステンおよび不可避不純物からなる超硬合
金。1. A method according to claim 1, wherein 2 to 6% by weight of Co and Ni,
A cemented carbide containing 0.1 to 30% by weight of chromium carbide with respect to Ni, with the balance being tungsten carbide and unavoidable impurities.
〜80重量％である請求項１に記載の超硬合金。2. The ratio of Ni is 0.4 to the total amount of Co and Ni.
The cemented carbide according to claim 1, wherein the amount is from about 80% by weight.
μｍである請求項１または２に記載の超硬合金。3. The tungsten carbide has an average particle size of 0.3-5.
The cemented carbide according to claim 1 or 2, which has a diameter of μm.
1.1μｍの微粒子群と1.2 〜５μｍの粗粒子群とからな
り、炭化タングステンの全体量に対する粗粒子群炭化タ
ングステン量の比が 0.1〜 0.9である請求項１〜３のい
ずれか一項に記載の超硬合金。4. The tungsten carbide having an average particle size of 0.3 to
The fine particle group of 1.1 μm and the coarse particle group of 1.2 to 5 μm, wherein the ratio of the amount of tungsten carbide in the coarse particle group to the total amount of tungsten carbide is 0.1 to 0.9. Cemented carbide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9123322A JPH10298698A (en) | 1997-04-25 | 1997-04-25 | Cemented carbide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9123322A JPH10298698A (en) | 1997-04-25 | 1997-04-25 | Cemented carbide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH10298698A true JPH10298698A (en) | 1998-11-10 |
Family
ID=14857695
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9123322A Pending JPH10298698A (en) | 1997-04-25 | 1997-04-25 | Cemented carbide |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH10298698A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10298699A (en) * | 1997-04-25 | 1998-11-10 | Sumitomo Electric Ind Ltd | Cemented carbide |
| WO2002027054A1 (en) * | 2000-09-27 | 2002-04-04 | Sandvik Ab | Tool for coldforming operations |
| JP2002155336A (en) * | 2000-11-15 | 2002-05-31 | Fuji Dies Kk | Grooving roll for strip for manufacture of heat transfer tube |
| JP2010121735A (en) * | 2008-11-20 | 2010-06-03 | Motoyama Eng Works Ltd | Valve |
| CN109763053A (en) * | 2019-03-05 | 2019-05-17 | 常熟中材钨业科技有限公司 | A kind of mold high temperature toughness cemented carbide material and preparation method thereof |
| WO2020128689A1 (en) * | 2018-12-18 | 2020-06-25 | Hyperion Materials & Technologies (Sweden) Ab | Cemented carbide for high demand applications |
| CN114293083A (en) * | 2021-12-30 | 2022-04-08 | 株洲硬质合金集团有限公司 | Hard alloy for plate and preparation method thereof |
| CN115747599A (en) * | 2022-11-28 | 2023-03-07 | 株洲硬质合金集团有限公司 | high-Cr-content coarse-grain hard alloy and preparation method and application thereof |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10298699A (en) * | 1997-04-25 | 1998-11-10 | Sumitomo Electric Ind Ltd | Cemented carbide |
| WO2002027054A1 (en) * | 2000-09-27 | 2002-04-04 | Sandvik Ab | Tool for coldforming operations |
| JP2002155336A (en) * | 2000-11-15 | 2002-05-31 | Fuji Dies Kk | Grooving roll for strip for manufacture of heat transfer tube |
| JP2010121735A (en) * | 2008-11-20 | 2010-06-03 | Motoyama Eng Works Ltd | Valve |
| WO2020128689A1 (en) * | 2018-12-18 | 2020-06-25 | Hyperion Materials & Technologies (Sweden) Ab | Cemented carbide for high demand applications |
| CN109763053A (en) * | 2019-03-05 | 2019-05-17 | 常熟中材钨业科技有限公司 | A kind of mold high temperature toughness cemented carbide material and preparation method thereof |
| CN114293083A (en) * | 2021-12-30 | 2022-04-08 | 株洲硬质合金集团有限公司 | Hard alloy for plate and preparation method thereof |
| CN115747599A (en) * | 2022-11-28 | 2023-03-07 | 株洲硬质合金集团有限公司 | high-Cr-content coarse-grain hard alloy and preparation method and application thereof |
| CN115747599B (en) * | 2022-11-28 | 2024-05-17 | 株洲硬质合金集团有限公司 | Coarse-grain hard alloy with high Cr content and preparation method and application thereof |
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