KR20020019984A - 폴리옥시프로필렌/폴리옥시에틸렌 테르펜 화합물의 경성표면용 탈지제로서의 용도 - Google Patents
폴리옥시프로필렌/폴리옥시에틸렌 테르펜 화합물의 경성표면용 탈지제로서의 용도 Download PDFInfo
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- KR20020019984A KR20020019984A KR1020027002017A KR20027002017A KR20020019984A KR 20020019984 A KR20020019984 A KR 20020019984A KR 1020027002017 A KR1020027002017 A KR 1020027002017A KR 20027002017 A KR20027002017 A KR 20027002017A KR 20020019984 A KR20020019984 A KR 20020019984A
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- degreasing
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- -1 polyoxypropylene Polymers 0.000 title claims abstract description 49
- 235000007586 terpenes Nutrition 0.000 title abstract description 6
- 238000005237 degreasing agent Methods 0.000 title description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 title 1
- 229920001451 polypropylene glycol Polymers 0.000 title 1
- 150000001875 compounds Chemical class 0.000 claims abstract description 83
- 238000005238 degreasing Methods 0.000 claims abstract description 39
- 229910052751 metal Inorganic materials 0.000 claims abstract description 15
- 239000002184 metal Substances 0.000 claims abstract description 15
- 238000004140 cleaning Methods 0.000 claims abstract description 12
- 239000001257 hydrogen Substances 0.000 claims description 29
- 229910052739 hydrogen Inorganic materials 0.000 claims description 29
- 150000003254 radicals Chemical class 0.000 claims description 29
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 20
- 239000004215 Carbon black (E152) Substances 0.000 claims description 15
- 229930195733 hydrocarbon Natural products 0.000 claims description 15
- 125000004122 cyclic group Chemical group 0.000 claims description 12
- 229920006395 saturated elastomer Polymers 0.000 claims description 12
- 150000001340 alkali metals Chemical class 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 150000002431 hydrogen Chemical group 0.000 claims description 7
- 229910052783 alkali metal Inorganic materials 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 235000012054 meals Nutrition 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical compound [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 claims description 3
- AQMHNCQZLQUNJI-UHFFFAOYSA-N [CH2]CCCCCC Chemical compound [CH2]CCCCCC AQMHNCQZLQUNJI-UHFFFAOYSA-N 0.000 claims description 2
- 125000002619 bicyclic group Chemical group 0.000 claims 1
- 125000006353 oxyethylene group Chemical group 0.000 abstract description 12
- 150000003505 terpenes Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 12
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 10
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 9
- 239000002609 medium Substances 0.000 description 8
- 239000003921 oil Substances 0.000 description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000000376 reactant Substances 0.000 description 6
- 239000003513 alkali Substances 0.000 description 5
- 239000006260 foam Substances 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 4
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 4
- 229940077388 benzenesulfonate Drugs 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 4
- ROKSAUSPJGWCSM-UWVGGRQHSA-N (-)-Nopol Chemical compound C1[C@@H]2C(C)(C)[C@H]1CC=C2CCO ROKSAUSPJGWCSM-UWVGGRQHSA-N 0.000 description 3
- ROKSAUSPJGWCSM-UHFFFAOYSA-N 2-(7,7-dimethyl-4-bicyclo[3.1.1]hept-3-enyl)ethanol Chemical compound C1C2C(C)(C)C1CC=C2CCO ROKSAUSPJGWCSM-UHFFFAOYSA-N 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000003002 pH adjusting agent Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 3
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 2
- 150000008041 alkali metal carbonates Chemical class 0.000 description 2
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 2
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 229940071118 cumenesulfonate Drugs 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 238000007306 functionalization reaction Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 150000004676 glycans Chemical class 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 239000003129 oil well Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 235000019795 sodium metasilicate Nutrition 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 125000003944 tolyl group Chemical group 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- VNDYJBBGRKZCSX-UHFFFAOYSA-L zinc bromide Chemical compound Br[Zn]Br VNDYJBBGRKZCSX-UHFFFAOYSA-L 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 101100065878 Caenorhabditis elegans sec-10 gene Proteins 0.000 description 1
- 101100172892 Caenorhabditis elegans sec-8 gene Proteins 0.000 description 1
- 241000282472 Canis lupus familiaris Species 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 229910001508 alkali metal halide Inorganic materials 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- 229910001615 alkaline earth metal halide Inorganic materials 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000003254 anti-foaming effect Effects 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- HJMZMZRCABDKKV-UHFFFAOYSA-N carbonocyanidic acid Chemical compound OC(=O)C#N HJMZMZRCABDKKV-UHFFFAOYSA-N 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 238000006266 etherification reaction Methods 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 150000002171 ethylene diamines Chemical class 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical group 0.000 description 1
- 229940005740 hexametaphosphate Drugs 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- BDAWXSQJJCIFIK-UHFFFAOYSA-N potassium methoxide Chemical compound [K+].[O-]C BDAWXSQJJCIFIK-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- FBWNMEQMRUMQSO-UHFFFAOYSA-N tergitol NP-9 Chemical compound CCCCCCCCCC1=CC=C(OCCOCCOCCOCCOCCOCCOCCOCCOCCO)C=C1 FBWNMEQMRUMQSO-UHFFFAOYSA-N 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical class [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940102001 zinc bromide Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2037—Terpenes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/263—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
- C11D7/3227—Ethers thereof
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/16—Metals
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Materials For Medical Uses (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Lubricants (AREA)
- External Artificial Organs (AREA)
- Polyethers (AREA)
Abstract
Description
화합물 | OP 수 (x) | OE 수 (y) |
본 발명의 예 | ||
1 | 3 | 6.3 |
2 | 3 | 7 |
3 | 3 | 7.5 |
4 | 4 | 7 |
5 | 4 | 8 |
6 | 5 | 7 |
7 | 5 | 8 |
비교예 | ||
8 | 3 | 6 |
9 | 3 | 10 |
10 | 2 | 5 |
화합물 | 탈지 시간 (*) |
1 | 30 초 |
3 | 30 초 |
8 (비교) | 45 초 |
9 (비교) | 55 초 |
10 (비교) | > 2 분 |
소포된 Igepal (**) | 45 초 |
화합물 | 제거된 오일의 % |
4 | 58 |
5 | 62 |
6 | 54 |
7 | 72 |
Igepal (*) | 51 |
화합물 | 포말 수준 |
1 | 20 ㎖ |
3 | 70 ㎖ |
4 | 20 ㎖ |
5 | 50 ㎖ |
6 | 20 ㎖ |
7 | 30 ㎖ |
소포된 Igepal (*) | 70 ㎖ |
Igepal 단독 (**) | 950 ㎖ |
Claims (13)
- 하기 화학식 I 을 갖는, 화합물의 사용 중에, 0.01 내지 10 g/l 범위의 농도로 사용되는 한 개 이상의 화합물의, 경성 표면, 예컨대 금속 표면의 탈지/세정에서의 용도:[화학식 I]Z-X-[CH(R3)-CH(R4)-O]n-[CH2CH2-O]p-R5(식 중,Z 는 비시클로[a,b,c]헵테닐 또는 비시클로[a,b,c]헵틸 라디칼을 나타내며(여기서,a+b+c = 5 이며,a = 2, 3 또는 4 이고;b = 2 또는 1 이고;c = 0 또는 1 이고;상기 라디칼은 한 개 이상의 C1-C6알킬 라디칼로 임의 치환되고, 하기에 나타내는 것들로부터 선택되는 주쇄 Z 또는 해당 주쇄에서 이중 결합을 뺀 것을 포함한다;);X 는 -CH2-C(R1)(R2)-O- 또는 -O-CH(R'1)-CH(R'2)-O- 를 나타내고(여기서,동일하거나 상이할 수 있는 R1, R2, R'1및 R'2는 수소, 또는 선형, 분지형 또는 고리형, 포화 또는 불포화 C1-C22탄화수소 라디칼, 바람직하게는 C1-C6을 나타낸다);동일하거나 상이할 수 있는 R3및 R4는 수소, 또는 선형, 분지형 또는 고리형, 포화 또는 불포화 C1-C22탄화수소 라디칼을 나타내고, 단 R3또는 R4중 한 개 이상이 수소 이외의 것이고;R5는 수소, 또는 치환될 수 있는 선형, 분지형 또는 고리형, 포화 또는 불포화,방향족 또는 비방향족 C1-C22탄화수소 라디칼, 또는 하기로부터 선택되는 기를 나타낸다:-SO3M-OPO3(M)2-(CH2)r-COOM-(CH2)z-SO3M(식 중:M 은 수소, 알칼리 금속 또는 암모늄 관능기 N(R)4 +를 나타내며 (식 중, 동일하거나 상이할 수 있는 R 은 수소, 또는 히드록실화될 수 있는 선형, 분지형 또는 고리형, 포화 또는 불포화 C1-C22탄화수소 라디칼을 나타낸다);r 은 1 내지 6 의 범위이고;z 는 1 내지 6 의 범위이다);n 은 3 내지 5 (한계치 포함) 범위의 정수 또는 분수이고;p 는 6 내지 10 (한계치 제외) 범위의 정수 또는 분수이다).
- 제 1 항에 있어서, 화합물이 화학식 I 에서, n 이 3 인 것을 특징으로 하는 용도.
- 제 1 항 또는 제 2 항에 있어서, 화합물이 화학식 I 에서, p 가 6.2 내지 7 (한계치 포함) 의 범위, 바람직하게는 6.3 내지 7 (한계치 포함) 의 범위인 것을 특징으로 하는 용도.
- 제 1 항에 있어서, 화합물이 화학식 I 에서, n 이 4 내지 5 의 범위인 것을 특징으로 하는 용도.
- 제 4 항에 있어서, 화합물이 화학식 I 에서, p 가 7 (한계치 포함) 내지 10 (한계치 제외) 의 범위, 바람직하게는 8 (한계치 포함) 내지 10 (한계치 제외) 의 범위인 것을 특징으로 하는 용도.
- 제 1 항 내지 제 5 항 중 어느 한 항에 있어서, 화합물이 화학식 I 에서, 라디칼 Z 가 한 개 이상의 그 탄소 원자상에서 두 개의 C1-C6알킬 라디칼로 치환되는 것을 특징으로 하는 용도.
- 제 1 항 내지 제 6 항 중 어느 한 항에 있어서, 화합물이 화학식 I 에서, X 가 -CH2-C(R1)(R2)-O- 를 나타내고, 주쇄 Z 가 화학식 c) 내지 g) 로부터 선택되는 것을 특징으로 하는 용도.
- 제 1 항 내지 제 7 항 중 어느 한 항에 있어서, 화합물이 화학식 I 에서, 주쇄 Z 가 화학식 d) 및 e) 로부터 선택되는 것을 특징으로 하는 용도.
- 제 1 항 내지 제 5 항 중 어느 한 항에 있어서, 화합물이 화학식 I 에서, X 가 -O-CH(R'1)-CH(R'2)-O- 를 나타내고, 라디칼 Z 가 이중 결합이 없는 비시클릭 주쇄인 주쇄 c) 에 해당하는 것을 특징으로 하는 용도.
- 제 1 항 내지 제 9 항 중 어느 한 항에 있어서, 화합물이 화학식 I 에서, 라디칼 Z 가 비시클의 탄소 2 또는 탄소 5 상에서 C1-C6알킬 라디칼, 바람직하게는 메틸 라디칼로 치환되는 것을 특징으로 하는 용도.
- 제 1 항 내지 제 10 항 중 어느 한 항에 있어서, 화합물이 금속 플레이트의 탈지/세정을 위해 사용되고; 화합물의 농도가 사용 중에 0.01 내지 5 g/l 의 범위인 것을 특징으로 하는 용도.
- 제 1 항 내지 제 10 항 중 어느 한 항에 있어서, 화합물이 플랫폼의 탈지/세정을 위해 사용되고; 화합물의 농도가 사용 중에 0.01 내지 10 g/l 의 범위인 것을 특징으로 하는 용도.
- 제 1 항 내지 제 10 항 중 어느 한 항에 있어서, 화합물이 오일 생산 웰의 탈지/세정을 위해 사용되고; 화합물의 농도가 0.01 내지 5 g/l 의 범위인 것을 특징으로 하는 용도.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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FR99/10559 | 1999-08-17 | ||
FR9910559A FR2797643B1 (fr) | 1999-08-17 | 1999-08-17 | Utilisation composes terpeniques polyoxypropylenes/ polyoxyethylenes comme agent de degraissage de surfaces dures |
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KR20020019984A true KR20020019984A (ko) | 2002-03-13 |
KR100588273B1 KR100588273B1 (ko) | 2006-06-09 |
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KR1020027002017A KR100588273B1 (ko) | 1999-08-17 | 2000-08-16 | 폴리옥시프로필렌/폴리옥시에틸렌 테르펜 화합물의 경성 표면용 탈지제로서의 용도 |
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EP (1) | EP1206512B1 (ko) |
JP (1) | JP3983543B2 (ko) |
KR (1) | KR100588273B1 (ko) |
CN (1) | CN1185328C (ko) |
AT (1) | ATE263826T1 (ko) |
AU (1) | AU759508B2 (ko) |
BR (1) | BR0013362B1 (ko) |
CA (1) | CA2382093C (ko) |
DE (1) | DE60009721T2 (ko) |
DK (1) | DK1206512T3 (ko) |
ES (1) | ES2214310T3 (ko) |
FR (1) | FR2797643B1 (ko) |
MX (1) | MXPA02001589A (ko) |
WO (1) | WO2001012765A1 (ko) |
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FR2918994B1 (fr) * | 2007-07-20 | 2012-10-19 | Rhodia Operations | Formulations de diesters d'acide carboxylique et leur utilisation pour le traitement de materiaux. |
FR2929954B1 (fr) * | 2008-04-09 | 2010-04-30 | Rhodia Operations | Composition aqueuse de traitement inhibitrice de la corrosion et de l'attaque acide sur des surfaces metalliques |
FR2949116B1 (fr) | 2009-08-13 | 2012-08-31 | Rhodia Operations | Composition de nettoyage de graffiti |
CN101993790B (zh) * | 2009-08-17 | 2012-06-06 | 中国石油化工股份有限公司 | 炼油装置的清洗剂及其制备方法 |
FR2950627B1 (fr) | 2009-09-28 | 2011-12-09 | Rhodia Operations | Dispersion d'un polymere hydrosoluble dans un milieu liquide |
KR101673589B1 (ko) * | 2009-10-30 | 2016-11-07 | 동우 화인켐 주식회사 | 평판표시장치의 유리기판용 세정제 조성물 |
CA2968977A1 (en) | 2014-12-02 | 2016-06-09 | Minerva Neurosciences, Inc. | Compositions comprising 2-((1-(2(4-fluorophenyl)-2-oxoethyl)piperidin-4-yl)methyl)isoindolin-1-one for treating schizophrenia |
WO2019173172A1 (en) * | 2018-03-06 | 2019-09-12 | Shrieve Chemical Products, Inc. | Lubricant and refrigerant compositions comprising polyalkylene glycols and uses thereof |
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FR2721921B1 (fr) * | 1994-07-01 | 1996-10-31 | Rhone Poulenc Chimie | Derives d'origine terpenique, composition tensioactive et/ou parfumante en contenant et formulation detergente a base de cette composition |
FR2757508B1 (fr) * | 1996-12-20 | 1999-02-26 | Rhodia Chimie Sa | Composes terpeniques polyalcoxyles, leur procede de preparation et leur utilisation comme agents demoussants |
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- 2000-08-16 WO PCT/FR2000/002325 patent/WO2001012765A1/fr active IP Right Grant
- 2000-08-16 CN CNB008132046A patent/CN1185328C/zh not_active Expired - Lifetime
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Publication number | Publication date |
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AU7013500A (en) | 2001-03-13 |
EP1206512B1 (fr) | 2004-04-07 |
CA2382093A1 (fr) | 2001-02-22 |
FR2797643B1 (fr) | 2003-06-06 |
ATE263826T1 (de) | 2004-04-15 |
DE60009721D1 (de) | 2004-05-13 |
BR0013362B1 (pt) | 2010-11-03 |
EP1206512A1 (fr) | 2002-05-22 |
JP2003507531A (ja) | 2003-02-25 |
FR2797643A1 (fr) | 2001-02-23 |
CN1376193A (zh) | 2002-10-23 |
CN1185328C (zh) | 2005-01-19 |
MXPA02001589A (es) | 2002-07-02 |
KR100588273B1 (ko) | 2006-06-09 |
JP3983543B2 (ja) | 2007-09-26 |
CA2382093C (fr) | 2005-10-25 |
DE60009721T2 (de) | 2005-03-31 |
WO2001012765A1 (fr) | 2001-02-22 |
AU759508B2 (en) | 2003-04-17 |
DK1206512T3 (da) | 2004-06-07 |
ES2214310T3 (es) | 2004-09-16 |
BR0013362A (pt) | 2002-04-30 |
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