KR20010041559A - 직렬식 반응기를 이용한 중합체 블렌드의 제조방법 - Google Patents

직렬식 반응기를 이용한 중합체 블렌드의 제조방법 Download PDF

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Publication number
KR20010041559A
KR20010041559A KR1020007009743A KR20007009743A KR20010041559A KR 20010041559 A KR20010041559 A KR 20010041559A KR 1020007009743 A KR1020007009743 A KR 1020007009743A KR 20007009743 A KR20007009743 A KR 20007009743A KR 20010041559 A KR20010041559 A KR 20010041559A
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South Korea
Prior art keywords
polymer
reactor
ethylene
weight
monomers
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KR1020007009743A
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English (en)
Korean (ko)
Inventor
코즈위드챨스
해링톤브루스에이
뎃타슈드힌
폴리베르나드제이
왈저존에프쥬니어
크라우더도나제이
Original Assignee
엑손 케미칼 패턴츠 인코포레이티드
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Publication of KR20010041559A publication Critical patent/KR20010041559A/ko
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63908—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Ethene-propene or ethene-propene-diene copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00—Crosslinking
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
KR1020007009743A 1998-03-04 1999-03-02 직렬식 반응기를 이용한 중합체 블렌드의 제조방법 Withdrawn KR20010041559A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US7671298P 1998-03-04 1998-03-04
US60/076,712 1998-03-04
PCT/US1999/004553 WO1999045049A1 (en) 1998-03-04 1999-03-02 Method for making polymer blends by using series reactors

Publications (1)

Publication Number Publication Date
KR20010041559A true KR20010041559A (ko) 2001-05-25

Family

ID=22133747

Family Applications (2)

Application Number Title Priority Date Filing Date
KR1020007009743A Withdrawn KR20010041559A (ko) 1998-03-04 1999-03-02 직렬식 반응기를 이용한 중합체 블렌드의 제조방법
KR1020007009704A Ceased KR20010041531A (ko) 1998-03-04 1999-03-03 일련 반응기로부터 중합체 배합물을 동적 가황처리하는방법

Family Applications After (1)

Application Number Title Priority Date Filing Date
KR1020007009704A Ceased KR20010041531A (ko) 1998-03-04 1999-03-03 일련 반응기로부터 중합체 배합물을 동적 가황처리하는방법

Country Status (14)

Country Link
US (2) US6319998B1 (enExample)
EP (2) EP1060202B1 (enExample)
JP (2) JP4242067B2 (enExample)
KR (2) KR20010041559A (enExample)
CN (2) CN1292007A (enExample)
AU (2) AU2888499A (enExample)
BR (2) BR9909216A (enExample)
CA (2) CA2319778A1 (enExample)
DE (2) DE69912931T2 (enExample)
EA (1) EA200000904A1 (enExample)
ES (2) ES2207185T3 (enExample)
IL (1) IL138116A0 (enExample)
PL (1) PL342705A1 (enExample)
WO (2) WO1999045049A1 (enExample)

Families Citing this family (92)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7919561B2 (en) 1996-09-04 2011-04-05 Exxonmobil Chemical Patents Inc. Process of producing thermoplastic polymer blends
FR2807440A1 (fr) * 2000-04-06 2001-10-12 Centre Nat Rech Scient Materiaux micro-composites polymere/polymere et procede pour leur preparation
GB0008690D0 (en) * 2000-04-07 2000-05-31 Borealis Polymers Oy Process
US6455638B2 (en) * 2000-05-11 2002-09-24 Dupont Dow Elastomers L.L.C. Ethylene/α-olefin polymer blends comprising components with differing ethylene contents
WO2002046251A2 (en) * 2000-12-04 2002-06-13 Exxonmobil Chemical Patents Inc. Ethylene copolymer compositions suitable for viscosity index improvers and lubricant compositions
CA2430222A1 (en) 2000-12-20 2002-06-27 Exxonmobil Chemical Patents Inc. Olefin polymerization process to produce branched polymer compositions
GB0126147D0 (en) * 2001-10-31 2002-01-02 Borealis Tech Oy Process
US7022793B2 (en) 2001-11-27 2006-04-04 Basell Polyolefine Gmbh Process for the treatment of polymer compositions
AU2002347954A1 (en) 2001-12-12 2003-06-23 Exxonmobil Chemical Patents Inc. Compositions suitable for elastomeric membranes
ATE461947T1 (de) * 2002-02-08 2010-04-15 Exxonmobil Chem Patents Inc Multimodale ethylen-, alpha-olefin- und dien- polymere, verfahren zu ihrer herstellung und vorrichtungen, die derartige zusammensetzungen enthalten
US7135533B2 (en) * 2002-06-19 2006-11-14 Exxonmobil Chemical Patents Inc. Ethylene, higher alpha-olefin comonomer and dienes, especially vinyl norbornene and polymers made using such processes
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
EP2261292B1 (en) 2002-10-15 2014-07-23 ExxonMobil Chemical Patents Inc. Polyolefin adhesive compositions
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
WO2005049672A1 (en) * 2003-11-14 2005-06-02 Exxonmobil Chemical Patents Inc. Transparent and translucent crosslinked propylenebased elastomers, and their production and use
ES2370503T3 (es) * 2004-10-13 2011-12-19 Exxonmobil Chemical Patents Inc. Composiciones de mezclas de reactor elastoméricas.
WO2006044149A1 (en) * 2004-10-13 2006-04-27 Exxonmobil Chemical Patents Inc. Elastomeric reactor blend compositions
WO2006083515A1 (en) * 2005-01-31 2006-08-10 Exxonmobil Chemical Patents Inc. Polymer blends and pellets and methods of producing same
US7803876B2 (en) * 2005-01-31 2010-09-28 Exxonmobil Chemical Patent Inc. Processes for producing polymer blends and polymer blend pellets
US7585917B2 (en) * 2005-06-13 2009-09-08 Exxonmobil Chemical Patents Inc. Thermoplastic blend compositions
US7935760B2 (en) * 2005-06-22 2011-05-03 Exxonmobil Chemical Patents Inc. Process of making a heterogeneous polymer blend
US7951872B2 (en) * 2005-06-22 2011-05-31 Exxonmobil Chemical Patents Inc. Heterogeneous polymer blend with continuous elastomeric phase and process of making the same
US9745461B2 (en) 2005-06-22 2017-08-29 Exxonmobil Chemical Patents Inc. Vulcanized polymer blends
US9644092B2 (en) 2005-06-22 2017-05-09 Exxonmobil Chemical Patents Inc. Heterogeneous in-situ polymer blend
US7928164B2 (en) * 2005-06-22 2011-04-19 Exxonmobil Chemical Patents Inc. Homogeneous polymer blend and process of making the same
US20060293462A1 (en) * 2005-06-22 2006-12-28 Sunny Jacob Heterogeneous polymer blend and process of making the same
US8022142B2 (en) * 2008-12-15 2011-09-20 Exxonmobil Chemical Patents Inc. Thermoplastic olefin compositions
JP4997234B2 (ja) * 2005-06-22 2012-08-08 エクソンモービル・ケミカル・パテンツ・インク 異種ポリマーブレンド及びその製造方法
JP2009501262A (ja) * 2005-07-15 2009-01-15 エクソンモービル・ケミカル・パテンツ・インク 熱可塑性ポリマーブレンドの生成方法
KR101353124B1 (ko) * 2005-10-31 2014-01-17 다우 글로벌 테크놀로지스 엘엘씨 프로필렌계 엘라스토머 조성물
JP5552232B2 (ja) * 2005-12-06 2014-07-16 エクソンモービル・ケミカル・パテンツ・インク エチレンエラストマー組成物
US7709577B2 (en) * 2005-12-07 2010-05-04 Exxonmobil Chemical Patents Inc. Process of making polymer blends
EP1847554A1 (en) * 2006-03-30 2007-10-24 Total Petrochemicals Research Feluy Slurry polymerisation process of ethylene in the presence of low amount of scavenger
US7935761B2 (en) * 2006-06-08 2011-05-03 Exxonmobil Chemical Patents Inc. Process for preparing articles
EP2029665B1 (en) 2006-06-08 2010-11-24 ExxonMobil Chemical Patents Inc. Process for preparing articles
US7915345B2 (en) 2006-06-08 2011-03-29 Exxonmobil Chemical Patents Inc. Solution blending process for preparing thermoplastic vulcanizates
US7985804B2 (en) * 2006-11-06 2011-07-26 Exxonmobil Chemical Patents Inc. Rubber toughened compositions, articles, films, and methods of making the same
US7256240B1 (en) * 2006-12-22 2007-08-14 Exxonmobil Chemical Patents Inc. Process of making polymer blends
US7482409B2 (en) 2007-01-31 2009-01-27 Sumitomo Chemical Company, Limited Process for producing ethylene-α-olefin-polyene copolymer
JP2008208351A (ja) 2007-01-31 2008-09-11 Sumitomo Chemical Co Ltd エチレン−α−オレフィン系共重合体の製造方法
US7943711B2 (en) * 2007-05-14 2011-05-17 Exxonmobil Chemical Patents Inc. Ethylene elastomer compositions
US8487033B2 (en) * 2007-05-16 2013-07-16 Exxonmobil Chemical Patents Inc. Thermoplastic elastomer compositions, methods for making the same, and articles made therefrom
US8962762B2 (en) * 2007-06-13 2015-02-24 Exxonmobil Chemical Patents Inc. Thermoplastic polymer compositions, methods for making the same, and articles made therefrom
US7939610B2 (en) * 2008-05-22 2011-05-10 Exxonmobil Research And Engineering Company Polymerization processes for broadened molecular weight distribution
US8399586B2 (en) * 2008-09-05 2013-03-19 Exxonmobil Research And Engineering Company Process for feeding ethylene to polymerization reactors
US8772414B2 (en) * 2008-09-16 2014-07-08 Dow Global Technologies Llc Polymeric compositions and foams, methods of making the same, and articles prepared from the same
US8101685B2 (en) * 2008-12-15 2012-01-24 Exxonmobil Chemical Patents Inc. Thermoplastic elastomer polyolefin in-reactor blends and molded articles therefrom
US8106127B2 (en) * 2008-12-15 2012-01-31 Exxonmobil Chemical Patents Inc. Heterogeneous in-reactor polymer blends
US8093335B2 (en) * 2008-12-15 2012-01-10 Exxonmobil Chemical Patents Inc. Thermoplastic polyolefin in-reactor blends and molded articles therefrom
US8497325B2 (en) 2008-12-15 2013-07-30 Exxonmobil Chemical Patents Inc. Thermoplastic polyolefin blends and films therefrom
US8410217B2 (en) * 2008-12-15 2013-04-02 Exxonmobil Chemical Patents Inc. Thermoplastic polyolefin blends
US8969481B2 (en) 2008-12-18 2015-03-03 Exxonmobil Chemical Patent Inc. Peroxide cured TPV
US8378042B2 (en) * 2009-04-28 2013-02-19 Exxonmobil Chemical Patents Inc. Finishing process for amorphous polymers
US20120028866A1 (en) * 2010-07-28 2012-02-02 Sudhin Datta Viscosity Modifiers Comprising Blends of Ethylene-Based Copolymers
US9127151B2 (en) 2009-04-28 2015-09-08 Exxonmobil Chemical Patents Inc. Polymer compositions having improved properties as viscosity index improvers and use thereof in lubricating oils
SG177650A1 (en) * 2009-07-15 2012-03-29 Dow Global Technologies Llc Polymer compositions, methods of making the same, and articles prepared from the same
WO2011090859A1 (en) 2010-01-22 2011-07-28 Exxonmobil Chemical Patents Inc. Ethylene copolymers, methods for their production, and use
SG182319A1 (en) 2010-01-27 2012-08-30 Exxonmobil Chem Patents Inc Copolymers, compositions thereof, and methods for making them
JP5357825B2 (ja) * 2010-04-28 2013-12-04 三井化学株式会社 エチレン系共重合体、および組成物
EP2598572B1 (en) 2010-07-28 2020-03-18 ExxonMobil Chemical Patents Inc. Ethylene based copolymer compositions as viscosity modifiers and methods for making them
KR101530137B1 (ko) 2010-07-28 2015-06-18 엑손모빌 케미칼 패턴츠 인코포레이티드 에틸렌계 공중합체의 블렌드를 포함하는 점도 개질제
JP5753264B2 (ja) 2010-07-28 2015-07-22 エクソンモービル ケミカル パテンツ インコーポレイテッド エチレンベースコポリマーのブレンドを含む粘度調整剤
CA2724943A1 (en) 2010-12-10 2012-06-10 Nova Chemicals Corporation Catalyst activation in a dual reactor process
JP2014505155A (ja) 2011-02-15 2014-02-27 エクソンモービル ケミカル パテンツ インコーポレイテッド 熱可塑性ポリオレフィンブレンド
JP5861832B2 (ja) * 2011-06-30 2016-02-16 Jnc株式会社 微多孔膜
KR102002893B1 (ko) 2011-12-29 2019-07-23 다우 글로벌 테크놀로지스 엘엘씨 개선된 점도를 갖는 에틸렌계 폴리머 조성물
US9139794B2 (en) * 2012-02-03 2015-09-22 Exxonmobil Chemical Patents Inc. Process for the production of polymeric compositions useful as oil modifiers
JP6088548B2 (ja) 2012-02-03 2017-03-01 エクソンモービル ケミカル パテンツ インコーポレイテッド 油改質剤として有用なポリマー組成物を製造する方法
US10316176B2 (en) 2012-02-03 2019-06-11 Exxonmobil Chemical Patents Inc. Polymer compositions and methods of making them
CN102675513B (zh) * 2012-06-06 2013-08-07 吉林众鑫化工集团有限公司 溶液法生产三元乙丙橡胶聚合反应器及工艺过程控制方法
WO2014070414A1 (en) * 2012-10-31 2014-05-08 Exxonmobil Chemical Patents Inc. Propylene copolymer compositions and processes to produce them
US10654948B2 (en) 2013-03-13 2020-05-19 Chevron Phillips Chemical Company Lp Radically coupled resins and methods of making and using same
US10577440B2 (en) 2013-03-13 2020-03-03 Chevron Phillips Chemical Company Lp Radically coupled resins and methods of making and using same
EP3026080A1 (en) * 2014-11-26 2016-06-01 Lion Copolymer Geismar, LLC Low damping high strength polymer with long chain branching for use in anti-vibration applications
EP3026070A1 (en) * 2014-11-26 2016-06-01 Lion Copolymer Geismar, LLC Process for making an ethylene elastomer with long chain branching for use in anti-vibration applications
WO2017172102A1 (en) 2016-03-31 2017-10-05 Exxonmobil Chemical Patents Inc. Low crystalline polymer compositions prepared in a dual reactor
WO2017206008A1 (en) 2016-05-30 2017-12-07 Dow Global Technologies Llc Ethylene/alpha-olefin/diene interpolymer
CN107474194B (zh) * 2016-06-08 2022-03-18 中国石油化工股份有限公司 一种高分子聚合物材料的制造方法
KR102653792B1 (ko) 2016-12-26 2024-04-03 다우 글로벌 테크놀로지스 엘엘씨 에틸렌/α-올레핀/비공액 폴리엔 혼성 중합체 조성물 및 이로부터 제조된 물품
US20200362263A1 (en) 2017-11-21 2020-11-19 Exxonmobil Chemical Patents Inc. Bimodal Copolymer Compositions Useful as Oil Modifiers
CN111465677B (zh) 2017-12-13 2023-07-07 雪佛龙奥伦耐有限责任公司 用作油改性剂的双峰共聚物组合物和包含该组合物的润滑油
EP3732216B1 (en) 2017-12-26 2023-04-19 Dow Global Technologies LLC Process for the production of multimodal ethylene-based polymers
KR102663559B1 (ko) * 2017-12-26 2024-05-20 다우 글로벌 테크놀로지스 엘엘씨 다중모드 에틸렌계 중합체 처리 시스템 및 방법
CN111655744B (zh) 2017-12-26 2023-04-28 陶氏环球技术有限责任公司 韧性改善的多峰型乙烯类聚合物组合物
BR112020011475B1 (pt) 2017-12-26 2023-05-16 Dow Global Technologies Llc Método para produzir um polímero à base de etileno multimodal
BR112020016302A2 (pt) * 2018-02-14 2020-12-15 Dow Global Technologies Llc Composições de interpolímero de etileno/alfa-olefina com desempenho de envelhecimento térmico a longo prazo melhorado
JP7216184B2 (ja) 2018-07-23 2023-01-31 エクソンモービル・ケミカル・パテンツ・インク バイモーダルゴム、熱可塑性加硫物の調製およびそれから作られた物品
CN113015766A (zh) 2018-10-30 2021-06-22 陶氏环球技术有限责任公司 热塑性硫化橡胶样材料
KR102753857B1 (ko) 2018-11-15 2025-01-14 롯데케미칼 주식회사 프로필렌 중합용 담지촉매 및 이를 이용하는 폴리프로필렌 수지의 제조방법
CN114989519B (zh) * 2022-06-09 2023-08-25 重庆理工大学 一种环烯烃聚合物在长余辉材料上的应用

Family Cites Families (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL270258A (enExample) 1960-10-17
NL296509A (enExample) 1962-09-10
US3629212A (en) 1965-05-08 1971-12-21 Huels Chemische Werke Ag Reactivation of ziegler-type catalysts
GB1200362A (en) 1967-07-28 1970-07-29 Ici Ltd Polymer composition
US4016342A (en) 1975-03-07 1977-04-05 Exxon Research And Engineering Company Process and product
US3969470A (en) 1975-04-21 1976-07-13 E. I. Du Pont De Nemours And Company Process for recycling hydrogen when making blends of olefin copolymers
US4306041A (en) 1980-03-14 1981-12-15 Exxon Research & Engineering Co. Process for the preparation of ethylene-higher alpha olefin polymers (P-891)
FR2493855B1 (fr) 1980-11-13 1986-01-10 Naphtachimie Sa Compositions de polypropylene de resistance au choc ameliorees
US4491652A (en) 1981-05-13 1985-01-01 Uniroyal, Inc. Sequentially prepared thermoplastic elastomer and method of preparing same
JPS587402A (ja) 1981-07-07 1983-01-17 Mitsui Petrochem Ind Ltd 重合方法
JPH064733B2 (ja) 1986-02-03 1994-01-19 日本石油化学株式会社 高剛性かつ耐衝撃性ポリオレフイン樹脂組成物
US4966944A (en) 1986-12-10 1990-10-30 Quantum Chemical Corporation Impact propylene copolymers with improved bruise resistance
US5391629A (en) 1987-01-30 1995-02-21 Exxon Chemical Patents Inc. Block copolymers from ionic catalysts
US5700896A (en) 1988-07-30 1997-12-23 Hoechst Aktiengesellschaft Polymer having long isotactic sequences and randomly-distributed ethylene content obtained by polymerizing propylene in presence of specific catalysts
ATE154060T1 (de) 1988-09-30 1997-06-15 Exxon Chemical Patents Inc Lineare ethylen-copolymermischungen von copolymeren mit engen molekulargewichts- und kompositionsverteilungen
EP0366411A3 (en) 1988-10-28 1991-04-24 Exxon Chemical Patents Inc. Graft polymers of ethylene-propylene-diene monomer polymers with propylene, means of preparation, and use of polypropylene compositions
DE69031022T2 (de) * 1989-04-24 1998-01-02 Mitsui Petrochemical Ind Höheres alpha-olefincopolymerisat, verfahren zu seiner herstellung, daraus hergestelltes vulkanisiertes produkt und vulkanisierbare gummizusammensetzung
US5157081A (en) * 1989-05-26 1992-10-20 Advanced Elastomer Systems, L.P. Dynamically vulcanized alloys having two copolymers in the crosslinked phase and a crystalline matrix
IL95097A0 (en) 1989-08-23 1991-06-10 Himont Inc Thermoplastic olefin polymer and its preparation
US5026798A (en) 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
DE3942363A1 (de) 1989-12-21 1991-06-27 Hoechst Ag Verfahren zur herstellung einer polypropylen-formmasse
US5210359A (en) * 1990-01-16 1993-05-11 Mobil Oil Corporation Vulcanizable liquid compositions
DE4005947A1 (de) 1990-02-26 1991-08-29 Basf Ag Loesliche katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen
US5239022A (en) 1990-11-12 1993-08-24 Hoechst Aktiengesellschaft Process for the preparation of a syndiotactic polyolefin
CA2060019A1 (en) 1991-03-04 1992-09-05 Phil Marvin Stricklen Process for producing polyolefins having a bimodal molecular weight distribution
JP3076619B2 (ja) 1991-05-14 2000-08-14 三井化学株式会社 ブロック共重合体の製造方法
ES2095037T3 (es) 1991-12-30 1997-02-01 Dow Chemical Co Polimerizaciones de interpolimeros de etileno.
US6545088B1 (en) 1991-12-30 2003-04-08 Dow Global Technologies Inc. Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
KR950014847B1 (ko) 1992-01-23 1995-12-16 미쓰이세끼유 가가꾸고오교오 가부시끼가이샤 에틸렌계 공중합체의 제조방법
BE1005795A3 (fr) 1992-05-13 1994-02-01 Solvay Procede de polymerisation d'olefines et (co)polymeres a blocs derives d'au moins une olefine.
EP0593221B1 (en) 1992-10-15 1998-08-05 Mitsubishi Chemical Corporation Propylene resin compositions
ES2149262T3 (es) 1993-01-29 2000-11-01 Dow Chemical Co Interpolimerizaciones de etileno.
WO1994019382A1 (fr) 1993-02-24 1994-09-01 Idemitsu Kosan Co., Ltd. Copolymere bloc de propylene, son procede de production et copolymere modifie produit a partir de celui-ci
US5571864A (en) 1993-03-23 1996-11-05 Regents Of The University Of Minnesota Miscible polyolefin blends with modifying polyolefin having matching segment lengths
DE4317655A1 (de) 1993-05-27 1994-12-01 Basf Ag Mehrphasige Blockcopolymerisate des Propylens
EP1209165B1 (en) 1993-06-07 2006-04-19 Mitsui Chemicals, Inc. Propylene elastomer
DE69506821T2 (de) 1994-04-11 1999-06-10 Mitsui Chemicals, Inc., Tokio/Tokyo Verfahren zur herstellung einer propylen-polymerzusammensetzung und propylen-polymerzusammensetzung
CA2157399C (en) 1994-04-11 2003-04-08 Takashi Ueda Process for preparing propylene polymer composition and propylene polymer composition
US5405901A (en) * 1994-07-06 1995-04-11 Union Carbide Chemicals & Plastics Technology Corporation Process of producing ethylene polymer blends in gas phase
CA2162946C (en) 1994-11-21 2004-01-06 Kazuyuki Watanabe Propylene block copolymer and process for producing the same
US5464906A (en) 1994-11-21 1995-11-07 The Dow Chemical Company Ethylene homopolymerization using group 3 metal complexes
US5589539A (en) * 1994-11-23 1996-12-31 Union Carbide Chemicals & Plastics Technology Corporation Process for preparing an in situ polyethylene blend
US5696213A (en) 1995-04-21 1997-12-09 Exxon Chemical Patents Inc. Ethylene-α-olefin-diolefin elastomers solution polymerization process
US5665818A (en) * 1996-03-05 1997-09-09 Union Carbide Chemicals & Plastics Technology Corporation High activity staged reactor process
ATE210688T1 (de) 1996-04-01 2001-12-15 Dow Chemical Co Olefin-lösungspolymerisation
SG67392A1 (en) 1996-05-27 1999-09-21 Sumitomo Chemical Co Propylene/ethylene-alpha-olefin block copolymer and process for producing the same

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