KR20000053019A - 경질 폴리우레탄 발포체 - Google Patents
경질 폴리우레탄 발포체 Download PDFInfo
- Publication number
- KR20000053019A KR20000053019A KR1019990703907A KR19997003907A KR20000053019A KR 20000053019 A KR20000053019 A KR 20000053019A KR 1019990703907 A KR1019990703907 A KR 1019990703907A KR 19997003907 A KR19997003907 A KR 19997003907A KR 20000053019 A KR20000053019 A KR 20000053019A
- Authority
- KR
- South Korea
- Prior art keywords
- isocyanate
- acid
- reactive composition
- reactive
- carboxylic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229920005830 Polyurethane Foam Polymers 0.000 title abstract description 11
- 239000011496 polyurethane foam Substances 0.000 title abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 64
- 229920005906 polyester polyol Polymers 0.000 claims abstract description 32
- 239000003054 catalyst Substances 0.000 claims abstract description 24
- 150000001735 carboxylic acids Chemical class 0.000 claims abstract description 18
- 125000003118 aryl group Chemical group 0.000 claims abstract description 9
- 150000003512 tertiary amines Chemical class 0.000 claims abstract description 6
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 5
- 125000000753 cycloalkyl group Chemical group 0.000 claims abstract description 3
- 125000000524 functional group Chemical group 0.000 claims abstract description 3
- 239000006260 foam Substances 0.000 claims description 51
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 24
- -1 heterocyclic amine Chemical class 0.000 claims description 23
- 239000005056 polyisocyanate Substances 0.000 claims description 21
- 229920001228 polyisocyanate Polymers 0.000 claims description 21
- 239000004604 Blowing Agent Substances 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 12
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 10
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 10
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 10
- 239000001630 malic acid Substances 0.000 claims description 10
- 235000011090 malic acid Nutrition 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 9
- 229920002635 polyurethane Polymers 0.000 claims description 9
- 239000004814 polyurethane Substances 0.000 claims description 9
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- 229920000582 polyisocyanurate Polymers 0.000 claims description 8
- 239000011495 polyisocyanurate Substances 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 8
- 150000001412 amines Chemical class 0.000 claims description 7
- 239000004310 lactic acid Substances 0.000 claims description 5
- 235000014655 lactic acid Nutrition 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- ZMSQJSMSLXVTKN-UHFFFAOYSA-N 4-[2-(2-morpholin-4-ylethoxy)ethyl]morpholine Chemical group C1COCCN1CCOCCN1CCOCC1 ZMSQJSMSLXVTKN-UHFFFAOYSA-N 0.000 claims description 4
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 3
- PSHKMPUSSFXUIA-UHFFFAOYSA-N n,n-dimethylpyridin-2-amine Chemical compound CN(C)C1=CC=CC=N1 PSHKMPUSSFXUIA-UHFFFAOYSA-N 0.000 claims description 3
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims description 2
- MCTWTZJPVLRJOU-UHFFFAOYSA-N 1-methyl-1H-imidazole Chemical compound CN1C=CN=C1 MCTWTZJPVLRJOU-UHFFFAOYSA-N 0.000 claims description 2
- 150000003973 alkyl amines Chemical class 0.000 claims description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 229920005862 polyol Polymers 0.000 abstract description 48
- 150000003077 polyols Chemical class 0.000 abstract description 48
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 18
- 238000006243 chemical reaction Methods 0.000 description 17
- 239000002253 acid Substances 0.000 description 14
- 239000011541 reaction mixture Substances 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- 125000001931 aliphatic group Chemical group 0.000 description 8
- 239000006071 cream Substances 0.000 description 8
- 150000002430 hydrocarbons Chemical group 0.000 description 8
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 5
- 239000004721 Polyphenylene oxide Substances 0.000 description 5
- 125000002947 alkylene group Chemical group 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229920000570 polyether Polymers 0.000 description 5
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 4
- SVYKKECYCPFKGB-UHFFFAOYSA-N N,N-dimethylcyclohexylamine Chemical compound CN(C)C1CCCCC1 SVYKKECYCPFKGB-UHFFFAOYSA-N 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 4
- 239000003063 flame retardant Substances 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 230000007704 transition Effects 0.000 description 4
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 150000001414 amino alcohols Chemical class 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 239000000600 sorbitol Substances 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 description 2
- GTEXIOINCJRBIO-UHFFFAOYSA-N 2-[2-(dimethylamino)ethoxy]-n,n-dimethylethanamine Chemical compound CN(C)CCOCCN(C)C GTEXIOINCJRBIO-UHFFFAOYSA-N 0.000 description 2
- WHBMMWSBFZVSSR-UHFFFAOYSA-N 3-hydroxybutyric acid Chemical compound CC(O)CC(O)=O WHBMMWSBFZVSSR-UHFFFAOYSA-N 0.000 description 2
- JVVRCYWZTJLJSG-UHFFFAOYSA-N 4-dimethylaminophenol Chemical compound CN(C)C1=CC=C(O)C=C1 JVVRCYWZTJLJSG-UHFFFAOYSA-N 0.000 description 2
- 229960000549 4-dimethylaminophenol Drugs 0.000 description 2
- VHYFNPMBLIVWCW-UHFFFAOYSA-N 4-dimethylaminopyridine Substances CN(C)C1=CC=NC=C1 VHYFNPMBLIVWCW-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 229920000265 Polyparaphenylene Polymers 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229920003232 aliphatic polyester Polymers 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000007405 data analysis Methods 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- BOLQJTPHPSDZHR-UHFFFAOYSA-N dihydroferulic acid Chemical compound COC1=CC(CCC(O)=O)=CC=C1O BOLQJTPHPSDZHR-UHFFFAOYSA-N 0.000 description 2
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
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- 125000005842 heteroatom Chemical group 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
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- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- PGYPOBZJRVSMDS-UHFFFAOYSA-N loperamide hydrochloride Chemical compound Cl.C=1C=CC=CC=1C(C=1C=CC=CC=1)(C(=O)N(C)C)CCN(CC1)CCC1(O)C1=CC=C(Cl)C=C1 PGYPOBZJRVSMDS-UHFFFAOYSA-N 0.000 description 2
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- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
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- 230000035484 reaction time Effects 0.000 description 2
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- AHDSRXYHVZECER-UHFFFAOYSA-N 2,4,6-tris[(dimethylamino)methyl]phenol Chemical compound CN(C)CC1=CC(CN(C)C)=C(O)C(CN(C)C)=C1 AHDSRXYHVZECER-UHFFFAOYSA-N 0.000 description 1
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- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- YSAANLSYLSUVHB-UHFFFAOYSA-N 2-[2-(dimethylamino)ethoxy]ethanol Chemical compound CN(C)CCOCCO YSAANLSYLSUVHB-UHFFFAOYSA-N 0.000 description 1
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- BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical group CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C—CHEMISTRY; METALLURGY
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
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- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0025—Foam properties rigid
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
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- C—CHEMISTRY; METALLURGY
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2115/00—Oligomerisation
- C08G2115/02—Oligomerisation to isocyanurate groups
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Polyesters Or Polycarbonates (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP96117643 | 1996-11-04 | ||
| EP96117643.5 | 1996-11-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20000053019A true KR20000053019A (ko) | 2000-08-25 |
Family
ID=8223363
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019990703907A Withdrawn KR20000053019A (ko) | 1996-11-04 | 1997-10-10 | 경질 폴리우레탄 발포체 |
Country Status (23)
| Country | Link |
|---|---|
| US (2) | US6403665B1 (cs) |
| EP (1) | EP0935624B1 (cs) |
| JP (1) | JP2001503461A (cs) |
| KR (1) | KR20000053019A (cs) |
| CN (1) | CN1134473C (cs) |
| AR (1) | AR010541A1 (cs) |
| AU (1) | AU723069B2 (cs) |
| BR (1) | BR9712860A (cs) |
| CA (1) | CA2268182A1 (cs) |
| CZ (1) | CZ156699A3 (cs) |
| DE (1) | DE69702926T2 (cs) |
| DK (1) | DK0935624T3 (cs) |
| ES (1) | ES2149580T3 (cs) |
| HU (1) | HUP9904499A3 (cs) |
| ID (1) | ID22277A (cs) |
| NZ (1) | NZ335208A (cs) |
| PL (1) | PL333050A1 (cs) |
| RU (1) | RU2189379C2 (cs) |
| SI (1) | SI0935624T1 (cs) |
| SK (1) | SK58299A3 (cs) |
| TR (1) | TR199900970T2 (cs) |
| TW (1) | TW399076B (cs) |
| WO (1) | WO1998020058A1 (cs) |
Families Citing this family (51)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6803495B2 (en) * | 2000-06-28 | 2004-10-12 | World Properties, Inc. | Polyurethane foam composition and method of manufacture thereof |
| US6387972B1 (en) * | 2001-02-15 | 2002-05-14 | Crompton Corporation | Process to enhance polyurethane foam performance |
| US20030039226A1 (en) * | 2001-08-24 | 2003-02-27 | Kwak Joseph A. | Physical layer automatic repeat request (ARQ) |
| AU2008209665B2 (en) * | 2001-08-30 | 2011-08-04 | Huntsman International Llc | Process for making rigid urethane-modified polyisocyanurate foams |
| EP1288239A1 (en) | 2001-08-30 | 2003-03-05 | Huntsman International Llc | Process for making rigid urethane-modified polyisocyanurate foams |
| US6753357B2 (en) * | 2001-12-18 | 2004-06-22 | Foam Supplies, Inc. | Rigid foam compositions and method employing methyl formate as a blowing agent |
| GB0222522D0 (en) | 2002-09-27 | 2002-11-06 | Controlled Therapeutics Sct | Water-swellable polymers |
| US6869543B2 (en) * | 2003-02-21 | 2005-03-22 | Bayer Polymers Llc | Amine-initiated polyether polyols and a process for their production |
| EP1577332A1 (en) * | 2004-03-15 | 2005-09-21 | Huntsman International Llc | Process for making rigid polyurethane foams |
| PT1773902T (pt) * | 2004-08-04 | 2018-01-25 | Foam Supplies Inc | Desvio de reactividade e degradação de catalizador na espuma de poliuretano |
| AU2012200194B2 (en) * | 2004-08-04 | 2013-12-05 | Foam Supplies, Inc. | Reactivity drift and catalyst degradation in polyurethane foam |
| GB0417401D0 (en) | 2004-08-05 | 2004-09-08 | Controlled Therapeutics Sct | Stabilised prostaglandin composition |
| US8501828B2 (en) * | 2004-08-11 | 2013-08-06 | Huntsman Petrochemical Llc | Cure rebond binder |
| US20060141239A1 (en) * | 2004-12-28 | 2006-06-29 | Gilder Stephen D | Method for making a bonded foam product suitable for use as an underlayment for floor coverings |
| PL2574640T3 (pl) | 2005-07-26 | 2023-05-29 | Knauf Insulation Gmbh | Spoiwa i materiały z nich wykonane |
| GB0613333D0 (en) | 2006-07-05 | 2006-08-16 | Controlled Therapeutics Sct | Hydrophilic polyurethane compositions |
| GB0613638D0 (en) | 2006-07-08 | 2006-08-16 | Controlled Therapeutics Sct | Polyurethane elastomers |
| JP2008074880A (ja) * | 2006-09-19 | 2008-04-03 | Nippon Polyurethane Ind Co Ltd | 硬質ポリウレタンスラブフォームの製造方法、硬質ポリウレタンスラブフォームおよび配管用断熱材 |
| GB0620685D0 (en) | 2006-10-18 | 2006-11-29 | Controlled Therapeutics Sct | Bioresorbable polymers |
| ES2574128T3 (es) * | 2007-01-19 | 2016-06-15 | Huntsman Petrochemical Llc | Aminas terciarias bloqueadas con ácidos poliméricos |
| DK2108006T3 (da) | 2007-01-25 | 2020-12-21 | Knauf Insulation Gmbh | Bindemidler og materialer lavet dermed |
| US20100086726A1 (en) | 2007-01-25 | 2010-04-08 | Roger Jackson | Mineral fibre board |
| WO2008089847A1 (en) | 2007-01-25 | 2008-07-31 | Knauf Insulation Limited | Composite wood board |
| WO2008127936A2 (en) | 2007-04-13 | 2008-10-23 | Knauf Insulation Gmbh | Composite maillard-resole binders |
| GB0715100D0 (en) | 2007-08-03 | 2007-09-12 | Knauf Insulation Ltd | Binders |
| US9453115B2 (en) * | 2007-10-12 | 2016-09-27 | Honeywell International Inc. | Stabilization of polyurethane foam polyol premixes containing halogenated olefin blowing agents |
| KR20110036037A (ko) * | 2008-06-12 | 2011-04-06 | 3에이 테크놀로지 앤드 메니지먼트 리미티드 | 발포 폴리에스테르 및 그 제조 방법 |
| WO2011015946A2 (en) | 2009-08-07 | 2011-02-10 | Knauf Insulation | Molasses binder |
| JP6223823B2 (ja) | 2010-05-07 | 2017-11-01 | ナフ インサレーション エセペーアールエル | 炭水化物ポリアミン結合剤およびそれを用いて作製される材料 |
| AU2011249760B2 (en) | 2010-05-07 | 2015-01-15 | Knauf Insulation | Carbohydrate binders and materials made therewith |
| US20130082205A1 (en) | 2010-06-07 | 2013-04-04 | Knauf Insulation Sprl | Fiber products having temperature control additives |
| US20140186635A1 (en) | 2011-05-07 | 2014-07-03 | Knauf Insulation | Liquid high solids binder composition |
| CN106832170A (zh) * | 2012-02-28 | 2017-06-13 | 巴斯夫欧洲公司 | 制备硬质聚合物泡沫的方法 |
| GB201206193D0 (en) | 2012-04-05 | 2012-05-23 | Knauf Insulation Ltd | Binders and associated products |
| US9598548B2 (en) * | 2012-08-09 | 2017-03-21 | Basf Se | Producing polymer foams comprising imide groups |
| GB201214734D0 (en) | 2012-08-17 | 2012-10-03 | Knauf Insulation Ltd | Wood board and process for its production |
| US10023681B2 (en) * | 2012-10-24 | 2018-07-17 | Evonik Degussa Gmbh | Delay action catalyst for improving the stability of polyurethane systems having halogen containing blowing agents |
| PL2928936T3 (pl) | 2012-12-05 | 2022-12-27 | Knauf Insulation Sprl | Spoiwo |
| WO2015120252A1 (en) | 2014-02-07 | 2015-08-13 | Knauf Insulation, Llc | Uncured articles with improved shelf-life |
| GB201408909D0 (en) | 2014-05-20 | 2014-07-02 | Knauf Insulation Ltd | Binders |
| GB201412709D0 (en) | 2014-07-17 | 2014-09-03 | Knauf Insulation And Knauf Insulation Ltd | Improved binder compositions and uses thereof |
| JP6816016B2 (ja) * | 2015-04-07 | 2021-01-20 | コベストロ、ドイチュラント、アクチエンゲゼルシャフトＣｏｖｅｓｔｒｏ Ｄｅｕｔｓｃｈｌａｎｄ Ａｇ | 硬質ポリウレタンフォーム用ポリオールプレミックス組成物 |
| GB201517867D0 (en) | 2015-10-09 | 2015-11-25 | Knauf Insulation Ltd | Wood particle boards |
| GB201610063D0 (en) | 2016-06-09 | 2016-07-27 | Knauf Insulation Ltd | Binders |
| GB201701569D0 (en) | 2017-01-31 | 2017-03-15 | Knauf Insulation Ltd | Improved binder compositions and uses thereof |
| CN107337778A (zh) * | 2017-08-07 | 2017-11-10 | 冯运成 | 聚氨酯泡沫组合物及由其制备的聚氨酯泡沫塑料 |
| CN111065706B (zh) * | 2017-09-05 | 2023-04-18 | 亨斯迈石油化学有限责任公司 | 用于含氢卤烯烃发泡剂的多元醇预混料的催化剂体系 |
| GB201804908D0 (en) | 2018-03-27 | 2018-05-09 | Knauf Insulation Ltd | Binder compositions and uses thereof |
| GB201804907D0 (en) | 2018-03-27 | 2018-05-09 | Knauf Insulation Ltd | Composite products |
| JP2023519336A (ja) * | 2020-03-27 | 2023-05-10 | ハンツマン ペトロケミカル エルエルシー | ポリウレタン発泡体用の酸ブロックアルキルアミノピリジン触媒 |
| CN115572361B (zh) * | 2021-06-21 | 2025-02-18 | 万华化学（宁波）容威聚氨酯有限公司 | 一种酸性聚氨酯硬质泡沫及其制备方法 |
Family Cites Families (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE545745A (cs) | 1955-03-04 | |||
| NL103386C (cs) * | 1958-03-12 | |||
| US3645925A (en) | 1970-07-31 | 1972-02-29 | Jefferson Chem Co Inc | 4 4'-dimorpholinodiethyl ether catalyst for polyurethane preparation |
| US3661808A (en) | 1970-07-31 | 1972-05-09 | Jefferson Chem Co Inc | Catalyst combination for polyurethanes |
| US3980594A (en) | 1975-04-23 | 1976-09-14 | The General Tire & Rubber Company | Trimerization of aromatic isocyanates catalyzed by certain ammonium salts |
| DE2607999C2 (de) | 1976-02-27 | 1983-02-03 | Bayer Ag, 5090 Leverkusen | Urethan- und Isocyanuratgruppen aufweisende Schaumstoffe und ein Verfahren zu ihrer Herstellung |
| US4228248A (en) | 1979-02-12 | 1980-10-14 | Texaco Development Corp. | Morpholine derivatives and use as polyurethane catalyst |
| SU1274273A1 (ru) * | 1983-12-13 | 1994-11-30 | Всесоюзный научно-исследовательский институт синтетических смол | Способ получения полиуретанмочевинных дисперсий |
| US5688834A (en) * | 1991-08-30 | 1997-11-18 | Alliedsignal, Inc. | Catalysts which stabilize hydrohalocarbon blowing agent in polyurethane foam formulations |
| US4760101A (en) * | 1986-08-25 | 1988-07-26 | Ashland Oil, Inc. | Polyurethane-forming binder compositions containing certain carboxylic acids as bench life extenders |
| US4758605A (en) * | 1987-03-12 | 1988-07-19 | The Dow Chemical Company | Stabilization of reactivity of polyester polyol based polyurethane foam components |
| DE3824354A1 (de) | 1988-07-19 | 1990-01-25 | Basf Ag, 67063 Ludwigshafen | Verfahren zur herstellung von zellhaltigen kunststoffen nach dem polyisocyanat-polyadditionsverfahren mittels lagerstabiler, treibmittelhaltiger emulsionen und diese emulsionen |
| US4983320A (en) | 1989-05-18 | 1991-01-08 | Akzo N.V. | Dialkyl dicarbonates as blowing agents for polymers |
| KR0177154B1 (ko) | 1989-06-06 | 1999-05-15 | 야마구찌 도시아끼 | 경질 폴리우레탄포움의 제조방법 |
| DD300436A5 (de) | 1989-06-28 | 1992-06-11 | Bosch Siemens Hausgeraete | Hartschaumstoff sowie verfahren zur herstellung desselben |
| US4981879A (en) | 1989-08-28 | 1991-01-01 | Jim Walter Research Corp. | Rigid foam with improved "K" factor from perfluorinated hydrocarbons |
| JPH03160015A (ja) | 1989-11-16 | 1991-07-10 | Bridgestone Corp | 硬質ポリウレタンフォームの製造方法 |
| GB9102362D0 (en) | 1991-02-04 | 1991-03-20 | Ici Plc | Polymeric foams |
| AU652034B2 (en) | 1991-04-03 | 1994-08-11 | Imperial Chemical Industries Plc | Manufacture of rigid foams and compositions therefor |
| US5395859A (en) | 1991-06-21 | 1995-03-07 | Alliedsignal Inc. | Catalysts which stabilize hydrohalocarbon blowing agent in polyisocyanurate foam formulations during polymerization |
| JP3160015B2 (ja) | 1991-07-12 | 2001-04-23 | 株式会社ガスター | 浴槽洗浄方法 |
| WO1993015121A1 (de) | 1992-01-31 | 1993-08-05 | Henkel Kommanditgesellschaft Auf Aktien | Verfahren zur herstellung von kunststoffen mit amid-gruppen |
| JPH05222146A (ja) | 1992-02-14 | 1993-08-31 | Daikin Ind Ltd | 硬質ポリウレタンフォームの製造法 |
| US5591781A (en) | 1993-10-27 | 1997-01-07 | Tosoh Corporation | Process for producing polyurethane foam with high curing rate |
| US5489618A (en) * | 1993-11-29 | 1996-02-06 | Osi Specialties, Inc. | Process for preparing polyurethane foam |
| JP3061717B2 (ja) | 1993-12-03 | 2000-07-10 | 日清紡績株式会社 | 変性ポリイソシアヌレート発泡体の製造法 |
| US5539008A (en) | 1993-12-29 | 1996-07-23 | Minnesota Mining And Manufacturing Company | Foamable composition containing unsaturated perfluorochemical blowing agent |
| US5559161A (en) | 1994-02-18 | 1996-09-24 | Air Products And Chemicals, Inc. | Hydroxy-functional triamine catalyst compositions for the production of polyurethanes |
| DE69509690T2 (de) | 1994-03-18 | 1999-09-23 | Air Products And Chemicals, Inc. | Amin-Katalysatoren mit niedrigem Geruch für auf Polyester-Polyole basierte Polyurethan-Blockweichschaumstoffe |
| CA2144490A1 (en) | 1994-03-28 | 1995-09-29 | Michael J. Skowronski | Catalyst for polyisocyanurate foams made with alternative blowing agents |
| US5430071A (en) | 1994-07-08 | 1995-07-04 | Basf Corporation | Dimensionally stable closed cell rigid polyisocyanate based foam prepared from a froth foaming mixture |
| DE4444249C2 (de) * | 1994-12-13 | 2003-12-24 | Basf Schwarzheide Gmbh | Katalysatorzusammensetzung für die Herstellung von nichtzelligen Polyurethanen nach dem Polyisocyanat-Polyadditionsverfahren |
| US5464562A (en) | 1995-04-24 | 1995-11-07 | Basf Corporation | Polyoxyalkylene polyether monool polyurethane foam additive |
-
1997
- 1997-10-10 PL PL97333050A patent/PL333050A1/xx unknown
- 1997-10-10 CN CNB971993998A patent/CN1134473C/zh not_active Expired - Fee Related
- 1997-10-10 DK DK97911214T patent/DK0935624T3/da active
- 1997-10-10 CZ CZ991566A patent/CZ156699A3/cs unknown
- 1997-10-10 AU AU48668/97A patent/AU723069B2/en not_active Ceased
- 1997-10-10 KR KR1019990703907A patent/KR20000053019A/ko not_active Withdrawn
- 1997-10-10 DE DE69702926T patent/DE69702926T2/de not_active Expired - Lifetime
- 1997-10-10 RU RU99111765/04A patent/RU2189379C2/ru not_active IP Right Cessation
- 1997-10-10 CA CA002268182A patent/CA2268182A1/en not_active Abandoned
- 1997-10-10 WO PCT/EP1997/005610 patent/WO1998020058A1/en not_active Ceased
- 1997-10-10 SK SK582-99A patent/SK58299A3/sk unknown
- 1997-10-10 TR TR1999/00970T patent/TR199900970T2/xx unknown
- 1997-10-10 ID IDW990264D patent/ID22277A/id unknown
- 1997-10-10 SI SI9730089T patent/SI0935624T1/xx unknown
- 1997-10-10 JP JP52098898A patent/JP2001503461A/ja active Pending
- 1997-10-10 HU HU9904499A patent/HUP9904499A3/hu unknown
- 1997-10-10 ES ES97911214T patent/ES2149580T3/es not_active Expired - Lifetime
- 1997-10-10 EP EP97911214A patent/EP0935624B1/en not_active Expired - Lifetime
- 1997-10-10 BR BR9712860-0A patent/BR9712860A/pt active Search and Examination
- 1997-10-10 NZ NZ335208A patent/NZ335208A/xx unknown
- 1997-10-16 TW TW086115257A patent/TW399076B/zh not_active IP Right Cessation
- 1997-10-17 US US08/953,363 patent/US6403665B1/en not_active Expired - Lifetime
- 1997-11-04 AR ARP970105132A patent/AR010541A1/es not_active Application Discontinuation
-
2002
- 2002-03-06 US US10/090,783 patent/US6528549B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CN1235617A (zh) | 1999-11-17 |
| CA2268182A1 (en) | 1998-05-14 |
| US6528549B2 (en) | 2003-03-04 |
| SK58299A3 (en) | 2000-02-14 |
| BR9712860A (pt) | 1999-12-07 |
| CZ156699A3 (cs) | 1999-08-11 |
| AR010541A1 (es) | 2000-06-28 |
| AU723069B2 (en) | 2000-08-17 |
| PL333050A1 (en) | 1999-11-08 |
| DE69702926T2 (de) | 2001-02-22 |
| US20020123598A1 (en) | 2002-09-05 |
| JP2001503461A (ja) | 2001-03-13 |
| CN1134473C (zh) | 2004-01-14 |
| TR199900970T2 (en) | 1999-07-21 |
| TW399076B (en) | 2000-07-21 |
| SI0935624T1 (en) | 2001-02-28 |
| EP0935624B1 (en) | 2000-08-23 |
| EP0935624A1 (en) | 1999-08-18 |
| DE69702926D1 (en) | 2000-09-28 |
| HUP9904499A2 (hu) | 2000-05-28 |
| HUP9904499A3 (en) | 2000-12-28 |
| RU2189379C2 (ru) | 2002-09-20 |
| NZ335208A (en) | 2000-11-24 |
| ES2149580T3 (es) | 2000-11-01 |
| ID22277A (id) | 1999-09-30 |
| US6403665B1 (en) | 2002-06-11 |
| AU4866897A (en) | 1998-05-29 |
| DK0935624T3 (da) | 2000-12-18 |
| WO1998020058A1 (en) | 1998-05-14 |
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Legal Events
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| PA0105 | International application |
Patent event date: 19990503 Patent event code: PA01051R01D Comment text: International Patent Application |
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| N231 | Notification of change of applicant | ||
| PN2301 | Change of applicant |
Patent event date: 20000519 Comment text: Notification of Change of Applicant Patent event code: PN23011R01D |
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| PG1501 | Laying open of application | ||
| PC1203 | Withdrawal of no request for examination | ||
| WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |