KR19990048480A - Capacitor Formation Method - Google Patents
Capacitor Formation Method Download PDFInfo
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- KR19990048480A KR19990048480A KR1019970067202A KR19970067202A KR19990048480A KR 19990048480 A KR19990048480 A KR 19990048480A KR 1019970067202 A KR1019970067202 A KR 1019970067202A KR 19970067202 A KR19970067202 A KR 19970067202A KR 19990048480 A KR19990048480 A KR 19990048480A
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- Prior art keywords
- insulating layer
- layer
- forming
- etching
- polysilicon
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- 238000000034 method Methods 0.000 title abstract description 25
- 239000003990 capacitor Substances 0.000 title abstract description 21
- 230000015572 biosynthetic process Effects 0.000 title 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims abstract description 25
- 238000005530 etching Methods 0.000 claims abstract description 21
- 229920005591 polysilicon Polymers 0.000 claims abstract description 21
- 238000003860 storage Methods 0.000 claims abstract description 21
- 239000012535 impurity Substances 0.000 claims abstract description 17
- 239000004065 semiconductor Substances 0.000 claims description 12
- 239000000758 substrate Substances 0.000 claims description 11
- 229920002120 photoresistant polymer Polymers 0.000 description 15
- 238000004519 manufacturing process Methods 0.000 description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 229910052814 silicon oxide Inorganic materials 0.000 description 8
- 229910052581 Si3N4 Inorganic materials 0.000 description 5
- 238000001312 dry etching Methods 0.000 description 5
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 5
- 238000010586 diagram Methods 0.000 description 4
- 238000009413 insulation Methods 0.000 description 4
- 238000005229 chemical vapour deposition Methods 0.000 description 3
- 238000000059 patterning Methods 0.000 description 3
- 238000000151 deposition Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 1
- 239000003989 dielectric material Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000001039 wet etching Methods 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L28/00—Passive two-terminal components without a potential-jump or surface barrier for integrated circuits; Details thereof; Multistep manufacturing processes therefor
- H01L28/40—Capacitors
- H01L28/60—Electrodes
- H01L28/75—Electrodes comprising two or more layers, e.g. comprising a barrier layer and a metal layer
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/027—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
- H01L21/0271—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising organic layers
- H01L21/0273—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising organic layers characterised by the treatment of photoresist layers
- H01L21/0274—Photolithographic processes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3205—Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
- H01L21/32055—Deposition of semiconductive layers, e.g. poly - or amorphous silicon layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L28/00—Passive two-terminal components without a potential-jump or surface barrier for integrated circuits; Details thereof; Multistep manufacturing processes therefor
- H01L28/40—Capacitors
- H01L28/60—Electrodes
- H01L28/82—Electrodes with an enlarged surface, e.g. formed by texturisation
- H01L28/90—Electrodes with an enlarged surface, e.g. formed by texturisation having vertical extensions
- H01L28/91—Electrodes with an enlarged surface, e.g. formed by texturisation having vertical extensions made by depositing layers, e.g. by depositing alternating conductive and insulating layers
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- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Semiconductor Integrated Circuits (AREA)
- Semiconductor Memories (AREA)
Abstract
본 발명은 스토리지(storage)전극의 표면적을 증가시키어 축전용량(capacitance)을 증가시키기에 적당한 캐패시터 형성방법에 관한 것으로, 게이트전극 및 불순물영역을 포함하는 트랜지스터가 형성된 반도체기판에불순물영역을 노출시키는 제 1절연층을 형성하는 단계와, 제 1절연층 상에 제 1절연층에 대해 다른 식각선택성을 갖는 제 2절연층과 동일 식각선택성을 갖는 제 3절연층을 순차적으로 형성하는 단계와, 제 3절연층과 제 2절연층과 제 1절연층을 상기 불순물영역을 노출시키도록 식각하여 제 2절연층을 제 1절연층과 제 3절연층 사이에 일부 잔류시키는 공정과, 상술한 구조 전면을 덮되, 제 2절연층과 대응된 부위가 제 3절연층과 함께 식각되도록 다결정실리콘층을 형성하는 공정과, 다결정실리콘층을 마스크로 제 3절연층을 제거하여 스토리지전극을 형성하는 것을 특징으로 한다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method of forming a capacitor suitable for increasing the surface area of a storage electrode and increasing a capacitance thereof. Forming a first insulating layer, and sequentially forming a third insulating layer having the same etch selectivity as the second insulating layer having a different etching selectivity with respect to the first insulating layer on the first insulating layer, and Etching the insulating layer, the second insulating layer, and the first insulating layer to expose the impurity region to partially retain the second insulating layer between the first insulating layer and the third insulating layer; Forming a polysilicon layer such that a portion corresponding to the second insulating layer is etched together with the third insulating layer, and removing the third insulating layer using the polysilicon layer as a mask. It is characterized by forming a pole.
따라서, 본 발명에서는 다결정실리콘을 1회 증착하여 캐패시터의 스토리지전극을 형성함으로써, 그에 따른 식각공정 횟수가 줄어들어 공정이 단순화되는 잇점이 있다.Accordingly, in the present invention, the polysilicon is deposited once to form the storage electrode of the capacitor, thereby reducing the number of etching processes, thereby simplifying the process.
Description
본 발명은 캐패시터(capacitor) 형성방법에 관한 것으로, 특히 그 제조공정이The present invention relates to a method of forming a capacitor (capacitor), in particular the manufacturing process
단순화된 반도체 소자의 캐패시터의 스토리지전극 형성방법에 관한 것이다.The present invention relates to a method for forming a storage electrode of a capacitor of a simplified semiconductor device.
반도체소자의 고집적화에 따라 셀면적이 축소되어도 캐패시터가 일정한 축전용량Capacitors have a constant capacitance even if the cell area is reduced due to the high integration of semiconductor devices.
을 갖도록 축전밀도를 증가시키기 위한 많은 연구가 진행되고 있다.Many studies have been carried out to increase the storage density to have a.
축전밀도를 증가시키기 위해서는 캐패시터를 적층하거나 또는 트렌치를 이용하여 3차원 구조로 형성하는 방법이 있다.In order to increase the storage density, there is a method of stacking capacitors or forming a three-dimensional structure using a trench.
상기 3차원 구조를 갖는 캐패시터 중 적층 구조를 갖는 것은 제조공정이 용이하고 대량 생산성에 적합한 구조로서 축전 용량을 증대시키는 동시에 알파입자에 의한 전하 정보 혼란에 대하여 면역성을 갖는다.The laminated structure among the capacitors having the three-dimensional structure is a structure that is easy to manufacture and suitable for mass productivity, while increasing the storage capacity and being immune to the disturbance of charge information caused by alpha particles.
적층 캐패시터는 스토리지전극의 형태에 따라 2중 적층구조, 핑거(finger)구조 또는 크라운(crown)구조 등으로 구별된다.The stacked capacitors are classified into a double stacked structure, a finger structure, or a crown structure according to the shape of the storage electrode.
도 1a 내지 도 1e 는 종래 기술에 따른 일반적인 캐패시터 제조공정도이다.1A to 1E are general capacitor manufacturing process diagrams according to the prior art.
도 1a 를 참조하면, 반도체기판(100) 상에 소자의 활성영역과 필드영역을 한정하는 필드산화층(102)을 형성한다.Referring to FIG. 1A, a field oxide layer 102 defining an active region and a field region of a device is formed on a semiconductor substrate 100.
그리고 반도체기판(100)의 소자의 활성영역 상에 게이트산화층(104)을 개재시키어 게이트전극(106)을 형성하고, 이 게이트전극(106) 양측의 활성영역에 소오스/드레인(source/drain)영역으로 이용되는 불순물 확산영역(103)을 형성함으로써 트랜지스터(transistor)를 형성한다. 상술한 트랜지스터에는 게이트전극(106) 상부에 캡절연막(108)이 형성되고, 이 캡절연막(108) 및 게이트전극(106) 측면에는 측벽(110)이 형성된다.The gate electrode 106 is formed on the active region of the device of the semiconductor substrate 100 with the gate oxide layer 104 interposed therebetween. A source / drain region is formed in the active regions on both sides of the gate electrode 106. A transistor is formed by forming the impurity diffusion region 103 to be used. In the above-described transistor, a cap insulation layer 108 is formed on the gate electrode 106, and sidewalls 110 are formed on the side surfaces of the cap insulation layer 108 and the gate electrode 106.
상술한 구조의 전표면에 화학기상증착(Chemical Vapor Deposition: 이하 CVD라 칭함) 방법으로 산화실리콘을 성장시키어 제 1절연층(112)을 형성하고, 그 상부에 질화실리콘을 얇게 성장시킨 제 2절연층(114)을 순차적으로 적층하여 형성한다. 이 제 2절연층(114) 상에 다시 산화실리콘을 성장시키어 제 3절연층(116)을 형성한다.A second insulating layer in which silicon oxide is grown on the entire surface of the above-described structure by chemical vapor deposition (CVD) to form a first insulating layer 112, and a thin silicon nitride is grown on the upper surface thereof. The layers 114 are formed by sequentially laminating them. Silicon oxide is further grown on the second insulating layer 114 to form a third insulating layer 116.
그리고 제 3절연층(116) 상에 포토레지스트(PR: photoresist)를 도포한 후, 노광 및 현상하여 불순물영역(103) 및 게이트전극(106)의 일측 측벽(110)과 대응되는 부위가 노출되도록 패터닝하여 제 1마스크패턴(118)을 형성한다.After applying a photoresist (PR) on the third insulating layer 116, the photoresist is exposed and developed to expose portions of the impurity region 103 and one sidewall 110 of the gate electrode 106. Patterning is performed to form the first mask pattern 118.
도 1b 를 참조하면, 이 제 1마스크패턴(118)을 마스크로 건식식각 방법을 이용하여 제 3절연층(116) 및 제 2절연층(114) 및 제 1절연층(112)을 제거하여 반도체기판(100)의 일부를 노출시킨다. 이 후에, 제 1마스크패턴(118)을 제거한다.Referring to FIG. 1B, the third insulating layer 116, the second insulating layer 114, and the first insulating layer 112 may be removed using a dry etching method using the first mask pattern 118 as a mask. A portion of the substrate 100 is exposed. After that, the first mask pattern 118 is removed.
그리고 잔류된 제 3절연층(116) 및 노출된 반도체기판(100)의 불순물영역(113) 및 게이트전극(106)의 일측 측벽(108)을 덮도록 제 1 다결정실리콘층(120)을 형성하고, 그 상부에 산화실리콘을 성장시키어 제 4절연층(122)을 순차적으로 적층하여 형성한다.The first polysilicon layer 120 is formed to cover the remaining third insulating layer 116, the impurity region 113 of the exposed semiconductor substrate 100, and the sidewall 108 of the gate electrode 106. The silicon oxide is grown on the upper portion thereof, and the fourth insulating layer 122 is sequentially stacked.
다음에, 제 4절연층(122) 상에 포토레지스트를 도포한 후, 노광 및 현상하여 불순물영역(103) 및 게이트전극(106)의 일측 측벽(108)에 대응되는 부위를 노출시키도록 패터닝하여 제 2마스크패턴(126)을 형성한다.Next, after the photoresist is applied on the fourth insulating layer 122, the photoresist is exposed and developed to pattern the exposed portion corresponding to the impurity region 103 and the sidewall 108 of the gate electrode 106. The second mask pattern 126 is formed.
도 1c 를 참조하면, 이 제 2마스크패턴(126)을 식각마스크로 이용하여 건식식각 방법으로 제 4절연층(122)을 제거하여 제 1다결정실리콘층(120)의 일부를 노출시킨다.Referring to FIG. 1C, using the second mask pattern 126 as an etching mask, a portion of the first polysilicon layer 120 is exposed by removing the fourth insulating layer 122 by a dry etching method.
이 후, 식각 공정이 완료되면, 제 2마스크패턴(126)을 제거한다.Thereafter, when the etching process is completed, the second mask pattern 126 is removed.
그리고 잔류된 제 4절연층(122) 및 노출된 제 1다결정실리콘층(120)을 덮도록 제 2다결정실리콘층(124)을 적층하여 형성한다.The second polysilicon layer 124 is stacked to cover the remaining fourth insulating layer 122 and the exposed first polysilicon layer 120.
다음에, 제 2다결정실리콘층(124) 상에 포토레지스트(PR: 128)를 도포한 후, 상술한 방법대로 노광 및 현상하여 불순물영역(103) 및 게이트전극(106)의 일부와 대응된 부위를 가리도록 패터닝하여 제 3마스크패턴(128)을 형성한다.Next, a photoresist (PR) 128 is coated on the second polysilicon layer 124, and then exposed and developed according to the above-described method to correspond to a part of the impurity region 103 and the gate electrode 106. Patterning to cover the to form a third mask pattern (128).
도 1d를 참조하면, 제 3마스크패턴(128)을 식각마스크로 사용하여 제 2다결정실리콘층(124) 및 잔류된 제 4절연층(122) 및 제 1다결정실리콘층(120)을 제거하여 하부에 잔류된 제 제 3절연층(116)을 노출시킨다.Referring to FIG. 1D, the second polysilicon layer 124, the remaining fourth insulating layer 122, and the first polysilicon layer 120 are removed by using the third mask pattern 128 as an etching mask. The third insulating layer 116 remaining in the portion is exposed.
상기 구조를 선택적으로 식각하여 잔류된 제 2다결정실리콘층(124) 및 제 1다결정실리콘층(120) 사이에 잔류된 제 4절연층(122)을 제거하여 스토리지 전극(130)을 형성한다. 이 스토리지전극(130)은 통상의 크라운 구조보다 바깥쪽에 굴곡진 표면적으로 인해 축전용량이 증가된다.The structure may be selectively etched to remove the fourth insulating layer 122 remaining between the remaining second polysilicon layer 124 and the first polysilicon layer 120 to form the storage electrode 130. The storage electrode 130 has an increased capacitance due to a curved surface area on the outside of the conventional crown structure.
도면에 도시되지 않았지만, 이 후에 스토리지전극(130) 상에 질화실리콘을 얇게 성장시키어 유전체를 형성하고, 그 상부에 다결정실리콘을 증착하여 플레이트전극을 형성함으로써 캐패시터의 제조를 완료한다.Although not shown in the drawings, a thin silicon nitride is then grown on the storage electrode 130 to form a dielectric, and polycrystalline silicon is deposited thereon to form a plate electrode to complete the manufacture of the capacitor.
그러나, 종래의 캐패시터 제조방법에서는 스토리지전극을 형성하기 위해 다결정실리콘층을 2회 증착함으로써 그에 따른 식각공정이 여러 차례 진행되고, 또한, 포토 공정 시, 오정렬 발생 및 디포커스로 인한 콘택불량을 야기시키는 문제점이 발생되었다.However, in the conventional capacitor manufacturing method, by etching the polysilicon layer twice to form the storage electrode, the etching process is performed several times. Also, during the photo process, the contact process due to misalignment and defocus is caused. A problem has occurred.
따라서, 본 발명의 목적은 스토리지전극 제조공정이 단순화된 캐패시터 형성방법을 제공함에 있다.Accordingly, it is an object of the present invention to provide a method of forming a capacitor in which the storage electrode manufacturing process is simplified.
본 발명은 스토리지전극 형성용 다결정실리콘층을 한 번 증착함으로써 그에 따른 식각공정을 줄임으로써 보다 제조공정을 단순화하려는 것이다.The present invention is intended to simplify the manufacturing process by reducing the etching process according to the deposition of the polysilicon layer for forming the storage electrode once.
상기의 목적을 달성하고자, 본 발명의 캐패시터 제조방법은 게이트전극 및 불순물영역을 포함하는 트랜지스터가 형성된 반도체기판에불순물영역을 노출시키는 제 1절연층을 형성하는 단계와, 제 1절연층 상에 제 1절연층에 대해 다른 식각선택성을 갖는 제 2절연층과 동일 식각선택성을 갖는 제 3절연층을 순차적으로 형성하는 단계와, 제 3절연층과 제 2절연층과 제 1절연층을 상기 불순물영역을 노출시키도록 식각하여 제 2절연층을 제 1절연층과 제 3절연층 사이에 일부 잔류시키는 공정과, 상술한 구조 전면을 덮되, 제 2절연층과 대응된 부위가 제 3절연층과 함께 식각되도록 다결정실리콘층을 형성하는 공정과, 다결정실리콘층을 마스크로 제 3절연층을 제거하여 스토리지전극을 형성하는 것을 특징으로 한다.In order to achieve the above object, the capacitor manufacturing method of the present invention comprises the steps of: forming a first insulating layer exposing an impurity region on a semiconductor substrate on which a transistor including a gate electrode and an impurity region is formed; Sequentially forming a third insulating layer having the same etch selectivity as the second insulating layer having a different etching selectivity with respect to the first insulating layer, and forming a third insulating layer, a second insulating layer and a first insulating layer in the impurity region. Partially etching the second insulating layer between the first insulating layer and the third insulating layer to cover the entire surface of the structure, wherein the portion corresponding to the second insulating layer is formed together with the third insulating layer. Forming a polysilicon layer to be etched, and removing the third insulating layer using the polysilicon layer as a mask to form a storage electrode.
도 1a 내지 도 1d 는 종래 기술에 따른 캐패시터 제조공정도이고,1a to 1d is a manufacturing process diagram of a capacitor according to the prior art,
도 2a 내지 도 2e 는 본 발명에 따른 캐패시터 제조공정도이다.2A to 2E are diagrams illustrating a capacitor manufacturing process according to the present invention.
* 도면의 주요 부분에 대한 부호의 설명 *Explanation of symbols on the main parts of the drawings
100, 200. 반도체기판 102, 202. 필드산화막100, 200. Semiconductor substrate 102, 202. Field oxide film
103, 203. 불순물영역103, 203. Impurity regions
104, 204. 게이트산화막 106, 206. 게이트전극104, 204. Gate oxide films 106, 206. Gate electrodes
108, 208. 캡절연막 110, 210. 측벽108, 208. Cap insulation films 110, 210. Sidewalls
120, 124, 227. 다결정실리콘층 130, 230. 스토리지전극120, 124, 227. Polysilicon layers 130, 230. Storage electrodes
232. 유전체 234. 플레이트전극232. Dielectrics 234. Plate Electrodes
112, 114, 116, 122, 212, 214, 216, 222, 226. 절연층112, 114, 116, 122, 212, 214, 216, 222, 226. Insulation layer
118, 126, 128, 218, 224, 228. 마스크패턴118, 126, 128, 218, 224, 228.mask pattern
이하, 첨부된 도면을 참조하여 본 발명을 상세히 설명하겠다.Hereinafter, with reference to the accompanying drawings will be described in detail the present invention.
도 2a 내지 도 2e 는 본 발명의 기술에 따른 캐패시터 제조공정도이다.2a to 2e are capacitor manufacturing process diagrams according to the technique of the present invention.
도 2a를 참조하면, 종래에 기술한 바와 같은 방법대로, 반도체기판(200) 상에 소자의 활성영역과 필드영역을 한정한 필드산화층(202)을 형성한다. 그리고 반도체기판(200)의 소자의 활성영역 상에 게이트전극(206)을 형성하는데, 반도체기판(200)과 게이트전극(206) 사이에는 게이트절연층(204)이 개재된다.Referring to FIG. 2A, a field oxide layer 202 defining an active region and a field region of a device is formed on a semiconductor substrate 200 in the same manner as described above. The gate electrode 206 is formed on the active region of the device of the semiconductor substrate 200, and a gate insulating layer 204 is interposed between the semiconductor substrate 200 and the gate electrode 206.
이 게이트전극(206) 양측의 활성영역에 소오스/드레인영역으로 이용되는 불순물 확산영역(203)을 형성함으로써 트랜지스터를 형성한다.Transistors are formed by forming impurity diffusion regions 203 used as source / drain regions in the active regions on both sides of the gate electrode 206.
상기에서 트랜지스터는 게이트전극(206) 상부에는 질화실리콘을 이용한 캡절연층(208)이 형성되고, 이 캡절연층(208) 및 게이트전극(206) 측면에 측벽(210)이 형성되어 있다.In the transistor, a cap insulating layer 208 using silicon nitride is formed on the gate electrode 206, and sidewalls 210 are formed on the side of the cap insulating layer 208 and the gate electrode 206.
상술한 구조의 전표면에 CVD 방법으로 산화실리콘을 증착하여 제 1절연층(212)을 형성하고, 그 상부에 질화실리콘을 얇게 증착하여 제 2절연층(214)을 순차적으로 적층하여 형성한다. 이 제 2절연층(214)은 산화실리콘인 제 1절연층(212)에 대해 식각선택성을 가지고 이 후의공정에서 식각저지층으로써 사용된다.Silicon oxide is deposited on the entire surface of the above-described structure by CVD to form a first insulating layer 212, and a thin layer of silicon nitride is deposited thereon to sequentially stack the second insulating layer 214. This second insulating layer 214 has an etch selectivity with respect to the first insulating layer 212 which is silicon oxide, and is used as an etch stop layer in a subsequent step.
다음에, 제 2절연층(214)에 포토레지스트를 도포한 후, 노광 및 현상하여 불순물영역(203) 및 게이트전극(206)의 일측 측벽(212)과 대응되는 부위가 노출되도록패터닝하여 제 1마스크패턴(PR: 218)을 형성한다.Next, after the photoresist is applied to the second insulating layer 214, the photoresist is exposed and developed to pattern the first region to expose portions of the impurity region 203 and the sidewall 212 of the gate electrode 206. A mask pattern PR 218 is formed.
도 2b를 참조하면, 제 1마스크패턴(218)을 식각용 마스크로 이용하여 제 2절연층(214)을 건식 식각방법으로 제거하여 제 1절연층(212)을 일부 노출시킨다.Referring to FIG. 2B, the first insulating layer 212 is partially exposed by removing the second insulating layer 214 using a dry etching method using the first mask pattern 218 as an etching mask.
이 후, 제 1마스크패턴(218)을 제거한다.Thereafter, the first mask pattern 218 is removed.
잔류된 제 2절연층(214) 및 노출된 제 1절연층(212)을 덮도록 산화실리콘을 증착시키어 제 3절연층(216)을 형성하고, 그 상부에 충분한 두께로 HSG(222)를 형성한다.Silicon oxide is deposited to cover the remaining second insulating layer 214 and the exposed first insulating layer 212 to form a third insulating layer 216, and the HSG 222 is formed to a sufficient thickness thereon. do.
도 2c를 참조하면, 이 HSG(222) 상에 산화실리콘을 이용하여 제 4절연층(226)을 형성하는 데, 이 HSG(222)는 제 3, 제 4절연층(216)(226)에 대해 식각선택비가 높은 점을 이용하여 이 후의 공정에서 유용하게 사용된다.Referring to FIG. 2C, a fourth insulating layer 226 is formed on the HSG 222 using silicon oxide, which is formed on the third and fourth insulating layers 216 and 226. It has a high etching selectivity, which is useful in subsequent processes.
제 4절연층(226) 상에 상술한 방법대로, 포토레지스트를 도포 및 노광, 현상공정을 거쳐서 불순물영역(203) 및 게이트전극(206)의 일측 측벽(212)과 대응되는 부위가 노출되도록 패터닝하여 제 2마스크패턴(PR: 224)을 형성한다.On the fourth insulating layer 226, as described above, the photoresist is coated, exposed, and developed to pattern the impurity region 203 and a portion corresponding to one side wall 212 of the gate electrode 206 to be exposed. As a result, a second mask pattern PR 224 is formed.
이 제 2마스크패턴(224)을 식각용 마스크로 이용하여 제 4절연층(226)을 건식식각 방법으로 제거한 후, HSG(222)를 습식식각 방법으로 제거하고, 다시, 잔류된 제 3절연층(216) 및 제 1절연층(212)을 건식식각 방법 제거함으로써 반도체기판(200)의 불순물영역(203) 및 게이트전극(206)의 측벽(210) 일부를 노출시킨다.Using the second mask pattern 224 as an etching mask, the fourth insulating layer 226 is removed by a dry etching method, the HSG 222 is removed by a wet etching method, and the remaining third insulating layer is again removed. A portion of the sidewalls 210 of the impurity region 203 of the semiconductor substrate 200 and the gate electrode 206 is exposed by removing the 216 and the first insulating layer 212 by a dry etching method.
이 때, HSG(222)는 산화실리콘인 제 4절연층(226)과 잔류된 제 3절연층(216)과 제 1절연층(212)에 대해 식각선택비가 높기 때문에 식각 시, 도면에 도시된 바와 같이, 측면으로 움푹 파이게 된다.At this time, since the HSG 222 has high etching selectivity with respect to the fourth insulating layer 226 which is silicon oxide, the remaining third insulating layer 216 and the first insulating layer 212, As shown, it is pitted laterally.
도 2d를 참조하면, 제 2마스크패턴(224)을 제거한다.Referring to FIG. 2D, the second mask pattern 224 is removed.
상기 구조 전면을 덮도록 제 1다결정실리콘층(227)을 형성하고, 그 상부에 포토레지스트를 도포 및 노광, 현상공정을 거쳐서 개구된 부위를 덮되, HSG(222) 측벽에 형성된 제 1다결정실리콘층(227)이 잔류되도록 패터닝하여 제 3마스크패턴(PR: 228)을 형성한다.The first polysilicon layer 227 is formed to cover the entire surface of the structure, and the first polysilicon layer formed on the sidewall of the HSG 222 is covered by the photoresist on the upper portion of the structure through the process of applying, exposing, and developing the photoresist. The second mask pattern PR 228 is formed by patterning the 227 to remain.
도 2e를 참조하면, 이 3마스크패턴(228)을 식각용 마스크로 이용하여 제 1다결정실리콘층(227) 및 제 4절연층(226) 및 HSG(222)을 제거하여 제 3절연층(216)의 일부를 노출시킨다. 이 후에, 제 3마스크패턴(228)을 제거하여 스토리지전극(230)을 형성한다. 본 발명의 스토리지전극(230)은 내측에 굴곡진 부위의 표면적 증가로 인해 축전용량이 증대된다. 이 후에, 스토리지전극(230) 상에 질화실리콘을 얇게 성장시키어 유전체(232)를 형성하고, 그 상부에 다결정실리콘을 증착하여 플레이트전극(234)을 형성함으로써 캐패시터의 제조를 완료한다.Referring to FIG. 2E, the first polycrystalline silicon layer 227, the fourth insulating layer 226, and the HSG 222 are removed by using the three mask pattern 228 as an etching mask. Part of the Thereafter, the third mask pattern 228 is removed to form the storage electrode 230. The storage electrode 230 of the present invention has an increased capacitance due to an increase in the surface area of the bent portion inside. Thereafter, silicon nitride is thinly grown on the storage electrode 230 to form the dielectric 232, and polycrystalline silicon is deposited on the storage electrode 230 to form the plate electrode 234, thereby completing the manufacture of the capacitor.
상술한 바와 같이, 본 발명의 캐패시터 제조방법에서는 다결정실리콘을 1회 증착하여 캐패시터의 스토리지전극을 형성함으로써, 그에 따른 식각공정 횟수가 줄어들어 공정이 단순화되는 잇점이 있다.As described above, in the capacitor manufacturing method of the present invention, by depositing polycrystalline silicon once to form a storage electrode of the capacitor, the number of etching processes is reduced, thereby simplifying the process.
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