KR19980033476A - Water Purification Method Using Loess - Google Patents
Water Purification Method Using Loess Download PDFInfo
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- KR19980033476A KR19980033476A KR1019980013741A KR19980013741A KR19980033476A KR 19980033476 A KR19980033476 A KR 19980033476A KR 1019980013741 A KR1019980013741 A KR 1019980013741A KR 19980013741 A KR19980013741 A KR 19980013741A KR 19980033476 A KR19980033476 A KR 19980033476A
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Abstract
본 발명은 황토에 여러 가지 성분을 혼합하여 분말형태로 가공함으로써 살포가 용이하도록 하여 기름, 적조, 녹조, 부영양화 및 오염된 수질을 정화 또는 개선시킬 수 있도록 하는 황토를 이용한 수질정화제 제조방법에 관한 것이다.The present invention relates to a method for producing a water purification agent using ocher to mix the various components in the loess and process it in powder form to facilitate spraying to purify or improve oil, red tide, green algae, eutrophication and contaminated water quality. .
이를 위하여 본 발명은, 수분 5% 미만인 분말형태의 황토 55~65%과, 입자의 크기가 0.5~2mm로 분쇄된 활성탄 23~18%과, 분말형태의 게르마늄 12~7%과, 분말형태의 쑥 4~2%, 분말형태의 맥반석 6~8%를 혼합하여 형성된 것이다.To this end, the present invention, 55 to 65% of the clay in powder form of less than 5% moisture, 23 to 18% of activated carbon pulverized to a particle size of 0.5 to 2mm, 12 to 7% of powdered germanium, and powder Mugwort 4 ~ 2%, it is formed by mixing 6-8% of the powdery gangue.
Description
본 발명은 황토를 이용한 수질정화제 제조방법에 관한 것으로서, 더욱 상세하게는 황토와 여러 가지 성분을 혼합하여 분말형태로 가공함으로써 살포가 용이하도록 하여 기름, 적조, 녹조, 부영양화 및 오염된 수질을 정화 또는 개선시킬 수 있도록 하는 황토를 이용한 수질정화제 제조방법에 관한 것이다.The present invention relates to a method for producing water purifier using ocher, and more particularly, by mixing ocher and various components and processing them in powder form to facilitate spraying to purify oil, red tide, green algae, eutrophication and contaminated water quality. It relates to a water purification agent using a loess to improve.
일반적으로 바다에서는 선박으로부터 배출되는 기름 또는 플랑크톤의 이상증식으로 인한 적조현상에 의해 오염이 이루어지며, 또한 강이나 담수 및 양식장에서는 녹조식물의 이상증가로 인한 녹조현상이나, 생활하수나 공장폐수 등이 흘러들어 물속의 영양 염류인 질소나 인 등의 양이 늘어나는 부영양화 현상에 의해 오염되고 있다.In general, the sea is polluted by red tide phenomena due to abnormal growth of oil or plankton discharged from ships.In rivers, fresh water, and farms, green algae phenomena due to abnormal increase of green algae, living sewage and factory wastewater It is polluted by eutrophication, which flows in and increases the amount of nutrients such as nitrogen and phosphorus in the water.
따라서 바다 오염의 주된 원인인 기름이 선박으로 부터 유출될 경우 중화제를 다량 살포하여 제거하고 있으며, 바다에서 발생되는 적조현상이나 강, 양식장, 댐에 저장된 담수에서 발생되는 녹조현상 또는 부영양화 현상으로 발생되는 오염을 제거하기 위해 화학물질을 투입하여 제거토록 하고 있으나, 이와 같은 중화제나 화학물질 등을 사용하여 넓은 지역의 오염원인을 제거할 경우 막대한 비용과 시간이 이 소요될 뿐만아니라 새로운 2차 환경오염의 원인이 되어 생태계를 파괴할 수 있는 요인이 되는 것이다.Therefore, when oil, which is the main cause of sea pollution, flows out of ships, it is removed by spraying a large amount of neutralizers, and it is caused by red algae generated in the sea or green algae or eutrophication generated in fresh water stored in rivers, farms and dams. In order to remove the pollution, chemicals are put in to remove them. However, if the causes of pollution in large areas are removed using such neutralizers or chemicals, it is not only enormous cost and time, but also causes of new secondary environmental pollution. This becomes a factor that can destroy the ecosystem.
특히 최근에 들어 적조와 녹조현상에 의해 발생되는 오염을 제거하기 위해서 바다와 강 또는 양식장에 황토를 투입하여 적조와 녹조를 제거하고 있으며, 이러한 황토는 생리활성 물질로서 박테리아를 제거하는 물질을 방출 및 오염물질을 분해하는 성질을 갖고 있는 것으로 알려짐에 따라 소형선박 등 기타 여러곳에 황토를 실은 후 삽으로 투입하거나 수압을 가함으로써 흘러내리도록 하여 바다 및 강의 오염된 부분에 무작위로 투입하였던 것이다.In particular, recently, in order to remove the pollution caused by red tide and green algae phenomena, the red tide and green algae have been removed from the sea, rivers, or fish farms. As it is known to have the property of decomposing pollutants, it was randomly injected into the contaminated parts of the sea and rivers by loading it with shovel or by applying water pressure after loading ocher in small places such as small ships.
그러나 상기와 같은 방법으로 황토를 투입할 경우에는 다량의 황토가 필요함은 물론 많은 인력과 시간이 필요하게 되어 넓은 범위의 오염지역에 황토를 고르게 투입한다는 것은 사실상 불가능할 뿐만아니라 황토자체 만을 투여함에 따라 기름제거, 악취제거, 중금속제거 등의 수질개선 효과에는 한계가 있는 것이다.However, when the ocher is added in the above manner, a large amount of ocher is required as well as a lot of manpower and time, so it is virtually impossible to inject the ocher evenly over a wide range of contaminated areas. Water quality improvement effects such as removal, odor removal, and heavy metal removal are limited.
본 발명은 상기와 같은 문제점을 해소하기 위해 황토를 건조 및 분쇄하여 수분 5%미만의 분말형태로 형성하고, 이 황토분말에 활성탄, 게르마늄, 쑥, 백반석을 적정비율로 혼합하여 수질정화제를 제조함으로서 적조와 녹조제거는 물론 기름유출에 의한 오염제거, 부영양화에 의한 악취제거, 중금속제거 등 수질개선에 현저한 효과를 얻을 수 있을 뿐만아니라 분말형태로 제조됨에 따라 오염지역이 넓을 경우항공살포가 가능하여 빠른 시간내에 광범위한 지역의 수질을 개선할 수 있는 황토를 이용한 수질정화제 제조방법을 제공하는데 본 발명의 목적이 있는 것이다.The present invention is dried and pulverized ocher in order to solve the above problems to form a powder form less than 5% moisture, by mixing the activated carbon, germanium, mugwort, alumite at an appropriate ratio in the ocher powder to prepare a water purification agent. By removing the red tide and the algae, as well as improving the water quality, such as the removal of pollution by oil spills, the removal of odors by eutrophication, and the removal of heavy metals. It is an object of the present invention to provide a method for preparing a water purifier using loess, which can improve water quality in a wide area within a short time.
이와 같은 목적을 실현하기 위한 본 발명은 수분 5% 미만인 분말형태의 황토 55~65%과, 입자의 크기가 0.5~1.2mm로 분쇄된 활성탄 23~18%와, 분말형태의 게르마늄 12~7%와, 분말형태의 쑥 4~2%와, 분말형태의 맥반석 6~8%를 혼합하여 형성된 것에 특징이 있다.The present invention for achieving the above object is 55 to 65% of the clay in powder form of less than 5% moisture, 23 to 18% of activated carbon pulverized to 0.5 ~ 1.2mm particle size, and 12 to 7% in powder germanium And, it is characterized by being formed by mixing 4 to 2% of the wormwood in powder form, and 6 to 8% of the powdery gangue stone.
이하 첨부된 도면에 의해 상세히 설명하면 다음과 같다.Hereinafter, described in detail by the accompanying drawings as follows.
먼저 본 발명에 따른 수질개선제의 주원료이며 생리활성물질로 분리되는 황토의 성분은 규소 68%, 산화마그네슘 27%, 산화칼슘 5%로 이루어지고, 황토의 효능은 그 속에 존재하는 미생물에 의해 좌우되는 것으로 알려져 있으며, 3~5g의 황토에 2억마리 이상의 박테리아가 서식하고 있어 물질세포가 안고 있는 유해성물질을 방출하는 효과가 있음은 물론, 황토안에는 여러 종류의 효소가 있는데 그 중에서 프로테아제 효소는 냄새와 노폐물 등의 오염물질을 분해하는 기능이 있으며, 또한 카탈라아제 효소는 과산화지질을 중화시키고 기름을 흡수 및 침전하여 수질을 조절하는 이외에도 환경에 유익한 많은 효소들이 존재하고 있다.First, the main ingredient of the water improver according to the present invention and the component of ocher to be separated into bioactive substance is made of 68% silicon, 27% magnesium oxide, 5% calcium oxide, and the efficacy of the ocher depends on the microorganisms present therein. It is known that more than 200 million bacteria inhabit 3 to 5 g of loess, which has the effect of releasing harmful substances contained in material cells, and there are various kinds of enzymes in loess. It has a function of decomposing contaminants such as waste products, and catalase enzymes neutralize lipid peroxide, absorb and settle oil, and regulate water quality.
이러한 황토가 갖는 효과로서는 적조의 소멸과 녹조의 생성을 억제시키며, 수은, 카드늄, 납 등의 중금속을 분리 및 축출하는 작용을 하며, 곰팡이와 같은 세균의 억제와 탈취제거의 효과가 있는 것으로 널리 알려져 있다.It is widely known that such yellow soil has the effect of suppressing the disappearance of red tide and the formation of green algae, separating and removing heavy metals such as mercury, cadmium and lead, and inhibiting and deodorizing bacteria such as molds. .
따라서 이와 같은 황토를 이용하여 본 발명에 따른 수질정화제 제조과정을 살펴보면 다음과 같다.Therefore, looking at the water purification agent production process according to the present invention using such ocher as follows.
먼저 일정량의 황토를 건조장치내에 투입하여 50~70℃의 온도에서 1~2시간 동안 열을 가하여 수분을 제거한 다음 분쇄시킨 후 굵은 입자상태의 황토와 덩어리 상태의 황토를 선별하는 1차 건조 및 분쇄과정을 실행한다.First, a certain amount of loess is put into a drying apparatus, and heat is removed for 1 to 2 hours at a temperature of 50 to 70 ° C. to remove moisture, and then pulverized, and then primary drying and pulverizing to select coarse loess and lump loess. Run the process.
이후 덩어리 상태의 황토는 어느 정도의 수분을 포함하고 있는 상태이므로 다시 건조장치에 투입하여 50~70℃의 온도에서 1~2시간 동안 열을 가하여 수분을 제거한 다음 분쇄시킨 후 굵은 입자상태의 황토와 덩어리 상태의 황토를 선별하는 2차 건조 및 분쇄과정을 실행한다.Since the loess in the agglomerate state contains a certain amount of moisture, it is put into the drying apparatus again, heated at 50 to 70 ° C. for 1 to 2 hours to remove moisture, and then pulverized. Secondary drying and pulverization is carried out to screen the loess in lumps.
따라서 상기 제1, 제 2 건조 및 분쇄과정을 거치게 되면 덩어리 상태의 황토는 거의 굵기가 큰 입자상태로 되며, 이러한 입자상태의 황토를 다시 건조장치 내에 투입하여 50~70℃의 온도에서 1~2시간 동안 열을 가하여 수분이 5% 미만으로 유지되도록 수분을 제거한 다음 분쇄시킴으로서 미세한 분말상태의 미립자 형태로 형성하는 3차 건조 및 분쇄과정을 실행한다.Therefore, when the first and second drying and grinding processes are carried out, the loess in the form of agglomerate becomes almost large grains, and the loess of such particles is put into the drying apparatus again at a temperature of 50 to 70 ° C. at 1 to 2 degrees. The third drying and pulverization process is performed to remove the moisture to keep the moisture less than 5% by applying heat for a period of time and then to grind it to form fine powder particles.
상기 과정에서 형성된 수분 5% 미만인 분말형태의 황토 55~65%에 활성탄 23~18%, 그리고 게르마늄 12~7%, 쑥 4~2%, 맥반석 6~8%를 각각 혼합한다.In the above process, less than 5% of the moisture formed in the powdery clay 55-65%, activated carbon 23-18%, and germanium 12-7%, mugwort 4-2%, ganbanite 6-8%, respectively.
여기서 활성탄은 목재, 갈탄, 무연탄 및 야자껍질 등을 재료로 하며 입자의 크기를 0.5~2mm로 잘게 분쇄하며, 게르마늄과 맥반석은 황토입자와 동일하게 분말상태로 형성하고, 쑥은 건조 분쇄하여 분말상태로 만든다.Activated carbon is made of wood, lignite, anthracite and palm bark, and finely pulverized to 0.5 ~ 2mm in size.Germanium and elvan are formed in the same powder state as ocher particles. Make it.
따라서 분말형태인 황토 55~65%과 게르마늄 12~7%, 쑥 4~2%, 맥반석 6~8%, 그리고 입자형태의 활성탄 23~18%을 교반기에 투입하여 일정시간 혼합함으로서 본 발명에 따른 황토를 이용한 수질정화제의 제조를 완료하게 된다.Therefore, 55 to 65% of the ocher powder, 12 to 7% germanium, 4 to 2% of mugwort, 6 to 8% of elvan, and 23 to 18% of activated carbon in the form of particles are mixed in a stirrer and mixed according to the present invention. The preparation of water purification agent using ocher is completed.
이와 같이 제조된 분마로형태의 수질정화제를 오염된 기름이나 적조 및 녹조현상에 의해 오염된 지역에 살포할 경우 수질이 개선되는 효과를 얻게된다.When spraying the water purification agent of the powder form of the powder powder thus prepared to contaminated area by contaminated oil or red tide and green algae, the water quality is improved.
즉, 분말상태인 황토는 전술한 바와 같이 황토에 존재하는 박테리아에 의해물질세포가 안고 있는 유해성물질을 방출하여 수질을 개선시킴과 동시에 존재하는 프로테아제효소 및 카탈라아제효소에 의하여 냄새와 노폐물 등의 오염물질을 분해하고 과산화지질을 중화시켜 기름을 흡수 및 침전시킴으로서 수질을 향상시키게 된다.That is, the powdered ocher releases harmful substances contained in the material cells by bacteria present in the ocher as described above, improving water quality and contaminants such as odors and waste products by protease and catalase enzymes. It improves water quality by decomposing and neutralizing lipid peroxide to absorb and precipitate oil.
또한 활성탄은 목재, 갈탄, 무연탄 및 야자껍질 등을 원료로 미세한 세공이 수없이 형성된 무정형 탄소의 집합체로서 활성화 과정에서 분자크기 정도의 미세한 세공에 의해 큰 내부 표면적을 가지는 오염물질을 흡착하는 흡착제의 기능을 갖게되는 것으로서 1g당 1,000㎡ 이상의 표면적을 가짐에 따라 표면에 존재하는 탄소원자의 관능기가 주위의 액체 또는 기체에 인력을 가하여 피흡착물질의 분자인 기름, 악취 등의 오염물질을 흡착하게 된다.Activated carbon is an aggregate of amorphous carbon with numerous fine pores formed from wood, lignite, anthracite and palm bark, and functions as an adsorbent to adsorb contaminants having a large internal surface area by fine pores of molecular size during activation. As having a surface area of 1,000 m 2 or more per g, functional groups of carbon atoms present on the surface attract the surrounding liquid or gas to adsorb contaminants such as oil, odor, etc., molecules of the substance to be adsorbed.
그리고 게르마늄은 효능이 이미 널리 알려진 바와 같이 기름을 중화시키고 중금속을 흡착하는 한편, 유익한 세균의 활동을 활성화시킴으로서 유해한 세균을 잠식하게 되며, 쑥은 오염된 물에서 발생되는 악취제거와 항균작용을 하고, 맥반석은 강한 흡착작용과 미네날의 용해산도(pH) 조절기능을 가짐으로서 용존산소를 풍부하게 만들고 중금속의 흡수 및 살균작용을 하게 되는 것이다.And germanium neutralizes oil and adsorbs heavy metals as well known, while encouraging the action of beneficial bacteria, encroaching on harmful bacteria, wormwood removes odor and antibacterial activity from contaminated water, Elvan has strong adsorption action and mineral solubility pH (pH) control function to enrich dissolved oxygen and to absorb and sterilize heavy metals.
이상에서 상술한 바와 같이 본 발명은, 황토를 건조 및 분쇄하여 수분 5%미만의 분말형태로 형성하고, 이 황토분말에 활성탄, 게르마늄, 쑥, 백반석을 적정비율로 혼합하여 수질정화제를 제조함으로서 적조와 녹조제거는 물론 기름유출에 의한 오염제거, 부영양화에 의한 악취제거, 중금속제거 등 수질개선에 현저한 효과를 얻을 수 있을 뿐만아니라 분말형태로 제조됨에 따라 살포가 용이하고 오염지역이 넓을 경우 항공살포가 가능하여 빠른 시간내에 광범위한 지역의 수질을 개선할 수 있는 것이다.As described above, the present invention, by drying and pulverizing the loess to form a powder form of less than 5% moisture, by mixing the activated carbon, germanium, wormwood, alumite at an appropriate ratio to the ocher powder to prepare a water purification agent Not only can the red algae and green algae be removed, but also the remarkable effect of water quality improvement such as decontamination by oil spill, deodorization by eutrophication, heavy metal removal, etc. It is possible to improve water quality in a wide range of areas in a short time.
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KR19990078990A (en) * | 1999-08-24 | 1999-11-05 | 김종대 | Refined alkali water and process for preparation of the same |
KR20000074946A (en) * | 1999-05-27 | 2000-12-15 | 박재홍 | Waterworks the quality of water improvement purification powder making method |
KR20010077795A (en) * | 2000-02-08 | 2001-08-20 | 조익환 | Get rid of red tide and daitomic and clean water, mud |
KR100325396B1 (en) * | 1999-11-08 | 2002-03-04 | 김봉경 | Exclusion Method For Microorganism of Seawater change color |
KR20030026782A (en) * | 2001-09-26 | 2003-04-03 | 이진구 | Compound organic germanium making mettod |
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KR100425521B1 (en) * | 2000-08-31 | 2004-03-30 | 주식회사 청우네이처 | Odor Removal Method of Septic Tank |
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KR19990015582A (en) * | 1997-08-02 | 1999-03-05 | 안갑환 | Development of ocher filter media for water purifiers |
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- 1998-04-17 KR KR1019980013741A patent/KR19980033476A/en active Search and Examination
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KR20000074946A (en) * | 1999-05-27 | 2000-12-15 | 박재홍 | Waterworks the quality of water improvement purification powder making method |
KR19990078990A (en) * | 1999-08-24 | 1999-11-05 | 김종대 | Refined alkali water and process for preparation of the same |
KR100325396B1 (en) * | 1999-11-08 | 2002-03-04 | 김봉경 | Exclusion Method For Microorganism of Seawater change color |
KR20010077795A (en) * | 2000-02-08 | 2001-08-20 | 조익환 | Get rid of red tide and daitomic and clean water, mud |
KR100425521B1 (en) * | 2000-08-31 | 2004-03-30 | 주식회사 청우네이처 | Odor Removal Method of Septic Tank |
KR20030026782A (en) * | 2001-09-26 | 2003-04-03 | 이진구 | Compound organic germanium making mettod |
KR20040014103A (en) * | 2002-08-09 | 2004-02-14 | 최명부 | The manugacture of electric wires able to intercept the electromagnetic waves |
KR100819869B1 (en) | 2007-07-27 | 2008-04-08 | 디에스케이엔지니어링(주) | Food improvement of water quality for which trash and a barley rice stone were used system production technique |
KR100940922B1 (en) * | 2009-07-02 | 2010-02-08 | (주)그린유화 | Environment friendly functional defoaming agent including hwangtoh |
WO2011002196A2 (en) * | 2009-07-02 | 2011-01-06 | (주)그린유화 | Environmentally-friendly functional antifoaming agent using loess |
WO2011002196A3 (en) * | 2009-07-02 | 2011-04-14 | (주)그린유화 | Environmentally-friendly functional antifoaming agent using loess |
US8920671B2 (en) | 2009-07-02 | 2014-12-30 | Green Chemical Co., Ltd. | Environmentally-friendly functional antifoaming agent using loess |
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