KR100317515B1 - Purifying medicine and manufacturing method thereof - Google Patents
Purifying medicine and manufacturing method thereof Download PDFInfo
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- KR100317515B1 KR100317515B1 KR1019990048162A KR19990048162A KR100317515B1 KR 100317515 B1 KR100317515 B1 KR 100317515B1 KR 1019990048162 A KR1019990048162 A KR 1019990048162A KR 19990048162 A KR19990048162 A KR 19990048162A KR 100317515 B1 KR100317515 B1 KR 100317515B1
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- biotite
- raw material
- purifying agent
- water
- lime
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 239000003814 drug Substances 0.000 title 1
- 239000002994 raw material Substances 0.000 claims abstract description 26
- 229910052626 biotite Inorganic materials 0.000 claims abstract description 23
- 239000012629 purifying agent Substances 0.000 claims abstract description 17
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims abstract description 15
- 235000011941 Tilia x europaea Nutrition 0.000 claims abstract description 15
- 239000004571 lime Substances 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims abstract description 14
- 238000010298 pulverizing process Methods 0.000 claims abstract description 11
- 238000003756 stirring Methods 0.000 claims abstract description 11
- 238000002156 mixing Methods 0.000 claims abstract description 9
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 8
- 239000011707 mineral Substances 0.000 claims abstract description 8
- 229910010272 inorganic material Inorganic materials 0.000 claims abstract description 7
- 239000011147 inorganic material Substances 0.000 claims abstract description 7
- 239000010445 mica Substances 0.000 claims abstract description 7
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 7
- 230000032683 aging Effects 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims abstract description 5
- 230000005484 gravity Effects 0.000 claims abstract description 4
- 239000000843 powder Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 28
- 230000000694 effects Effects 0.000 abstract description 12
- 238000000746 purification Methods 0.000 abstract description 11
- 241000195628 Chlorophyta Species 0.000 abstract description 9
- 239000002351 wastewater Substances 0.000 abstract description 5
- 244000144972 livestock Species 0.000 abstract description 4
- 239000002440 industrial waste Substances 0.000 abstract description 2
- 239000010419 fine particle Substances 0.000 description 5
- 239000010842 industrial wastewater Substances 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 241000206572 Rhodophyta Species 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 241000251468 Actinopterygii Species 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 239000010840 domestic wastewater Substances 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 230000005070 ripening Effects 0.000 description 2
- 235000015170 shellfish Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000001784 detoxification Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 230000002431 foraging effect Effects 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 230000003211 malignant effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Biological Treatment Of Waste Water (AREA)
- Water Treatment By Sorption (AREA)
Abstract
본 발명은 강이나 바다 등에서 수온의 급격한 변화에 의해 발생되는 적조, 녹조 및 산업현장의 폐수나 일반 축산농가나 가정에서 발생되는 오폐수를 정화하기 위한 무기질 재료를 주원료로 하는 정화제 및 그 제조방법에 관한 것으로서, 이를 좀 더 구체적으로 설명하면, 무기질 재료 중에서 수질정화 효과가 뛰어난 광물질만을 선별하여 이를 일정비율로 혼합하여 일련의 공정을 거쳐 제조하는 것으로서, 오염된 수질의 정화효과가 매우 우수하며, 또 정화제로 인한 수질을 오염시킬 염려가 없는 무기질재료를 주원료로 하는 정화제 및 그 제조방법에 관한 것이다.The present invention relates to a purifying agent comprising a mineral material for the purification of wastewater generated in red tide, green algae, industrial wastes or industrial livestock farms or households caused by rapid changes in water temperature in a river or the sea, and a manufacturing method thereof. As described in more detail, only minerals having excellent water purification effects from inorganic materials are selected and mixed at a predetermined ratio to be manufactured through a series of processes, and the purification effect of contaminated water is very excellent, and a purifying agent The present invention relates to a purifying agent based on an inorganic material which does not have a risk of contaminating water due to water and a method of manufacturing the same.
본 발명의 제조방법은 원료로 사용되는 흑운모 편마암, 견운모, 황토 및 석회를 분쇄기를 이용하여 325MESH 이상이 되도록 수차례 반복해서 분쇄하여 분말화시키는 분쇄공정(10)과; 상기 원료를 사이로에 투입하여 일정량의 수분이 포함되도록 하는 수분조절공정(20)과; 상기의 원료중 흑운모 편마암을 70%, 석회 15%, 견운모 2%, 황토 13%로의 비율로 무중력 믹서기에 투입하여 5분 동안 혼합하는 교반공정(30)과; 교반후 3시간 동안 자연 숙성시키는 숙성공정(40)을 거쳐 제조되는 것이다.The production method of the present invention comprises a pulverizing step (10) of pulverizing and repeatedly pulverizing several times so that the biotite gneiss, biotite, ocher and lime used as a raw material to be 325MESH or more using a grinder; A moisture control step 20 of inserting the raw material into the passage to include a predetermined amount of moisture; A stirring step 30 of mixing biotite gneiss in the raw material into a zero gravity mixer at a ratio of 70%, lime 15%, mica 2%, and loess 13% for 5 minutes; It is prepared through the aging process 40 for natural aging for 3 hours after stirring.
Description
본 발명은 강이나 바다 등에서 수온의 급격한 변화에 의해 발생되는 적조, 녹조 및 산업현장의 폐수나 일반 축산농가나 가정에서 발생되는 오폐수를 정화하기 위한 무기질 재료를 주원료로 하는 정화제 및 그 제조방법에 관한 것으로서, 이를 좀 더 구체적으로 설명하면, 무기질 재료 중에서 수질정화 효과가 뛰어난 광물질만을 선별하여 이를 일정비율로 혼합하여 일련의 공정을 거쳐 제조하는 것으로서, 오염된 수질의 정화효과가 매우 우수하고, 또 이 정화제로 인한 수질을 오염시킬 염려가 없는 무기질 재료를 주원료로 하는 정화제 및 그 제조방법에 관한 것이다.The present invention relates to a purifying agent comprising a mineral material for the purification of wastewater generated in red tide, green algae, industrial wastes or industrial livestock farms or households caused by rapid changes in water temperature in a river or the sea, and a manufacturing method thereof. As described in more detail, only minerals having excellent water purification effects from inorganic materials are selected and mixed at a predetermined ratio to be manufactured through a series of processes, and the contaminated water quality is very excellent. The present invention relates to a purifying agent containing a mineral material which is not likely to contaminate water quality due to a purifying agent, and a manufacturing method thereof.
일반적으로 수온의 변화에 의해서 발생되는 적조나 녹조는 수온의 급격한 변화에 의해 발생되는 것으로서, 이는 빠른 속도로 주변 해역으로 확산되어 각종 어패류의 양식장에 치명적인 악영향을 미쳐 어패류의 폐사는 물론 수질을 오염시키게 되는 것으로서, 이를 정화하기 위한 다양한 방법이 강구되고 있으며, 그 대표적인 것이 화학약품으로 만들어진 정화제를 오염지역에 대량 살포하여 제거하고 있으나, 이는 수질에 악영향을 미치는 유해성분이 대량으로 함유되어 있어 수질을 재차 오염시킨다고 하는 문제점이 있으며, 또한 축산, 산업의 폐수나 일반 정화시설에서 오폐수를 정화하기 위해서는 정화기능을 갖는 구조물을 이용하고 있으므로 이를 설치하는데 많은 비용이 발생된다고 하는 문제점이 내재되어 있는 것이다.In general, red and green algae caused by changes in water temperature are caused by rapid changes in water temperature, which rapidly spread to surrounding waters and cause a fatal adverse effect on various fish and shellfish farms to contaminate the quality of fish and shellfish. Various methods to purify this have been devised, and the representative one is to remove and remove chemical purifiers by spraying them in a contaminated area, but this contains a large amount of harmful components that adversely affect the water quality and contaminate the water again. In addition, there is a problem in that a large cost is required to install the structure having a purification function in order to purify the waste water in livestock, industrial wastewater or general purification facilities.
본 발명자는 상기의 문제점에 착안하여 수질에 무해한 정화제에 대한 연구를 거듭한 결과, 본 발명을 제안하기에 이른 것으로서, 본 발명이 목적으로 하는 바는 화학물질이 아닌 순수 무기질 재료를 이용하여 정화효과가 뛰어나고 수질에 하등의 영향을 미치지 않는 순수 무기질 재료를 주원료로 하는 정화제 및 그 제조방법을 제공하는데 있다.The present inventors have focused on the above problems and have been pursuing the present invention as a result of pursuing a purifying agent that is harmless to water quality. The present invention has the object of purifying the purifying effect using pure inorganic materials, not chemical substances. The present invention provides a purifying agent and a method for producing the same, which are mainly made of pure inorganic materials which are excellent in quality and do not affect water quality at all.
상기의 목적을 달성하기 위한 본 발명의 제조방법은, 본 발명의 정화제의 주원료로 이용되는 흑운모 편마암, 견운모, 황토 및 석회를 분쇄기를 이용하여 325MESH 이상이 되도록 반복해서 수차례 분쇄하여 분말화시키는 분쇄공정과; 상기 원재를 사이로에 투입하여 일정량의 수분이 함유되도록 하는 수분조절공정과; 상기의 원재중 흑운모 편마암을 70%, 석회 15%, 견운모 2%, 황토 13%로의 비율로 무중력 믹서기에 투입하여 5분 동안 혼합하는 교반공정과; 교반후 3시간 동안 자연 숙성시키는 숙성공정을 포함하는 공정으로 제조되는 것이다.The manufacturing method of the present invention for achieving the above object is a pulverizing step of pulverizing by repeatedly pulverizing several times so that biotite gneiss, biotite, ocher and lime used as the main raw material of the purifying agent of the present invention to 325MESH or more using a grinder. and; A moisture control step of inserting the raw material through the passage so that a predetermined amount of moisture is contained; A stirring step of mixing the biotite gneiss among the raw materials in a weightless mixer at a rate of 70%, lime 15%, mica 2%, and loess 13% for 5 minutes; It is prepared by a process including a ripening step of natural ripening for 3 hours after stirring.
이하 본 발명의 바람직한 일실시예 및 이로부터 얻게되는 특유의 효과 등에 대하여 첨부도면을 이용하여 상세히 설명하면 하기와 같다.Hereinafter, exemplary embodiments of the present invention and specific effects obtained therefrom will be described in detail with reference to the accompanying drawings.
도 1은 본 발명의 제조공정을 예시한 공정도1 is a process diagram illustrating a manufacturing process of the present invention.
<도면의 주요 부분에 대한 부호의 설명><Explanation of symbols for the main parts of the drawings>
10…분쇄공정 20…수분조절공정 30…교반공정 40…숙성공정10... Grinding process 20... Moisture control process 30... Stirring process 40... Aging process
도 1은 본 발명의 전체적인 제조공정을 나타낸 공정도로서, 동 도면에 예시되어 있는 바와 같이, 본 발명의 전체적인 제조공정은 원료로 이용되는 흑운모 편마암, 견운모, 황토, 석회 등을 미세입자로 분쇄하는 분쇄공정(10)과, 분쇄된 원료를 일정량의 수분을 유지토록 하는 수분조절공정(20) 및 수분이 조절된 각각의 원료를 일정비율로 배합하는 교반공정(30), 그리고 이를 일정시간 숙성시키는 숙정공정(40)으로 제조하게 되는 것이다.1 is a process chart showing the overall manufacturing process of the present invention, as illustrated in the figure, the overall manufacturing process of the present invention is a pulverized grinding fine biotite gneiss, biotite, ocher, lime, etc. used as a raw material pulverized into fine particles Step 10, a moisture control step 20 for maintaining the amount of moisture in the pulverized raw material, a stirring step 30 for mixing each of the raw materials in which the moisture is controlled at a predetermined ratio, and a fermentation for aging for a predetermined time. It is made by the process (40).
상기의 분쇄공정(10)은 오염지역 등에 살포를 용이토록 하기 위하여 원료로 사용되는 흑운모 편마암, 견운모, 황토, 석회를 미세한 입자로 분쇄하는 것으로서, 이는 각 원료를 분쇄기에 넣고 3회 정도의 분쇄를 거쳐 325MESH 이상의 미세한 입자로 분쇄하게 되는 것이다.The pulverization step 10 is to grind the biotite gneiss, biotite, ocher, lime, which are used as raw materials to facilitate spraying in contaminated areas, etc. into fine particles. After pulverizing into fine particles of 325MESH or more.
상기와 같이, 분쇄공정(10)을 완료한 원료는 각각의 사이로에 저장하여 일정량의 수분이 함유되도록 수분의 량을 조절하게 되는 것으로서, 이 수분조절공정(20)에서 수분의 양은 재료량 대비 5%정도의 수분이 유지되도록 하는것이 바람직하다.As described above, the raw material that has completed the grinding step 10 is to be stored in each of the path to adjust the amount of water to contain a certain amount of water, the amount of water in the moisture control step 20 is 5% of the amount of material It is desirable to maintain a degree of moisture.
수분조절공정(20)을 마친 각 원료는 무중력 믹서기에 투입하여 교반하는 교반공정(30)을 행하게 되는 것으로서, 무중력 공급기에 투입되는 원료의 배합비율은 흑운모 편마암 70%, 석회 15%, 견운모 2%, 황토 13%를 투입하여 5분 정도 교반하여 각 원료가 균일하게 혼합되도록 한다.Each raw material that has completed the moisture control step 20 is subjected to a stirring step 30 which is inputted into a zero gravity mixer and stirred, and the mixing ratio of the raw materials fed into the zero gravity feeder is 70% biotite gneiss, lime 15%, and mica 2%. Add 13% ocher and stir for 5 minutes to ensure that each raw material is mixed evenly.
상기 원료의 혼합비율을 흑운모 편마암 55%, 석회 13%, 견운모 2%, 황토 30%로 배합비율을 달리하여도, 그 효과면에서는 거의 동일한 정화효과를 얻을 수 있는 것이다.Even if the mixing ratio of the raw material is 55% biotite gneiss, lime 13%, mica 2%, ocher 30%, the mixing ratio is almost the same in terms of its effectiveness.
상기와 같이 교반공정(30)을 완료한 혼합원료는 3시간의 숙성공정(40)을 진행하여 이를 별도로 제작한 포대에 넣어 포장하면 일련의 제조작업이 완료되는 것이다.As described above, the mixed raw material that has completed the stirring process 30 is subjected to the aging process 40 of 3 hours, and put into a bag manufactured separately, and a series of manufacturing operations are completed.
상기와 같은 공정으로 제조된 본 발명의 정화제의 파장대가 6∼14m로서 원적외선 방사율이 93%인 방사체로서 이의 특성은,The wavelength range of the purifier of the present invention prepared by the above process is 6-14m and the emitter having a far infrared ray emissivity of 93%.
ㄱ) 악성세재, 중금속, 지방 및 페놀 등을 포착하여 침전시키고, 부분응집분해 중해숙성과 물분자 전자파, 활성유화 암모니아, 일산화탄소 등을 기화 배출시키고,A) capture and settle malignant detergents, heavy metals, fats and phenols, and vaporize and discharge partial coagulation-degrading detoxification and water molecule electromagnetic waves, activated emulsified ammonia and carbon monoxide,
ㄴ) 산화환원반응을 촉진하여 수질중화작용으로 세균착생을 활성화시키고,B) promoting redox reactions to activate bacterial engraftment by water neutralization,
ㄷ) 부패성 세균의 번식억제 및 살균하고,C) suppression and sterilization of perishable bacteria;
ㄹ) Hg, Cu, Pb, Zn, Cr+6, CN, IN, 불소 등과 같은 중금속의 처리가 가능하다.D) It is possible to treat heavy metals such as Hg, Cu, Pb, Zn, Cr + 6, CN, IN, fluorine and the like.
ㅁ) 다공성 물질로서 흡착력이 뛰어나다.ㅁ) As a porous material, it has excellent adsorption power.
등의 고유의 특성을 가지게되어 뛰어난 수질정화효과를 얻게 되는 것이다.It will have the inherent characteristics such as excellent water purification effect will be obtained.
(실시예 1)(Example 1)
미세입자로 분쇄한 각각의 원료중 흑운모 편마암 70%, 석회 15%, 견운모 2%, 황토 13%를 혼합한 본 발명의 정화제를 적조나 녹조의 발생해역에 살포하여 이의 정화효과를 면밀하게 관찰한 결과, 눈으로도 적조나 녹조의 현상이 98%이상 제거됨을 확인할 수 있었으며, 또 20∼30분 후에는 이의 현상이 전혀 발견할 수 없었으며, 또 적조 및 녹조를 제거한 후 당해 수역의 물을 채취하여 이의 성분을 정밀 분석한 결과, 적조나 녹조 외의 해역의 수질과 동일한 수질의 수치를 나타내고 있음을 알 수 있어 본 발명에 의해 제조된 정화제는 적조나 녹조의 제거에 매우 뛰어난 효과가 있음을 알 수 있었으며, 또한 정화제로 인한 수질의 2차 오염이 전혀 없음을 확인할 수 있었다.Of the raw materials pulverized into fine particles, the purifying agent of the present invention mixed with biotite gneiss 70%, lime 15%, mica 2%, and loess 13% was sprayed into the red tide or green algae, and the purification effect thereof was closely observed. As a result, it was confirmed that the phenomenon of red tide and green algae was removed by snow more than 98%, and after 20-30 minutes, the phenomenon was not found at all, and the water of the water was collected after removing the red tide and algae. As a result of the precise analysis of the components, it can be seen that the water quality is the same as that of the waters other than red and green algae. Therefore, the purifying agent prepared according to the present invention has an excellent effect on the removal of red and green algae. It was also confirmed that there was no secondary pollution of the water quality due to the purifying agent.
그리고 오폐수 및 산업폐수를 처리하는 정화조에 본 발명의 정화제를 살포기를 이용하여 살포한 후 일정시간 경과후, 수질을 채취하여 이의 성분을 분석한 결과 뛰어난 효과를 정화효과가 있음이 수치로서 확인할 수 있었다.After spraying the purifying agent of the present invention to a septic tank for treating wastewater and industrial wastewater using a sprayer, after a certain time, the water quality was collected and the components thereof were analyzed. .
(실시예 2)(Example 2)
미세입자로 분쇄한 각각의 원료중 흑운모 편마암 55%, 석회 13%, 견운모 2%, 황토 30%를 혼합하여 제조한 본 발명의 정화제를 적조나 녹조의 발생해역과 산업폐수나 생활 오폐수를 정화하는 정화조에 살포하여 이의 정화 효과를 관찰한 결과, 실시예 1과 동일한 효과를 확인할 수 있었다.Purifying agent of the present invention prepared by mixing 55% biotite gneiss, 13% lime, 2% mica and 30% ocher among the raw materials pulverized into fine particles is used to purify the sea area of red tide and green algae, industrial wastewater and domestic wastewater. As a result of spraying the septic tank and observing its purification effect, the same effect as in Example 1 could be confirmed.
상기와 같이 본 발명은 순수 무기질 재료인 흑운모 편마암, 견운모, 황토, 석회의 원료를 미세분말로 처리하여 이를 일정한 공정을 거쳐 제조하여 적조, 녹조의 발생해역이나 축산 폐수, 산업폐수 및 생활 오폐수를 정화하는 정화조 등에 광범위하게 사용하여 뛰어난 수질정화 효과가 얻을 수 있고, 또 정화제를 구성하는 원료가 순수 무기질인 광물질이므로 수질을 재차 오염시킬 염려가 없는 매우 유용한 발명인 것이다.As described above, the present invention treats raw materials of biotite gneiss, biotite, ocher, and lime as fine powders, and manufactures them through a specific process to purify red tide, green algae, livestock wastewater, industrial wastewater and domestic wastewater. It is a very useful invention that can be used extensively in a septic tank or the like to obtain an excellent water purification effect, and since the raw material constituting the clarifier is a mineral that is pure mineral, there is no fear of contaminating the water quality again.
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KR100450882B1 (en) * | 2001-12-27 | 2004-10-02 | 강철호 | Organic waste cleanser and method of recycling organic waste |
KR100484561B1 (en) * | 2001-09-28 | 2005-04-22 | 주식회사 대동그린산업 | The Composition and Manufacturing Method of Inorganic Materials using a Waters Purification |
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KR20010088729A (en) * | 2001-03-15 | 2001-09-28 | 제창국 | A solid clarifier manufactured by a natural inorganic element |
KR20030039632A (en) * | 2001-11-14 | 2003-05-22 | 용 정 | Use of illite as algae-coagulator and algae-coagulator composition comprising illite as main ingredient |
KR100819869B1 (en) | 2007-07-27 | 2008-04-08 | 디에스케이엔지니어링(주) | Food improvement of water quality for which trash and a barley rice stone were used system production technique |
KR100887663B1 (en) * | 2007-10-05 | 2009-03-11 | 디에스케이엔지니어링(주) | The bio mineral numerous hole body production techniques for which remnant food and drink waste water was used |
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KR100484561B1 (en) * | 2001-09-28 | 2005-04-22 | 주식회사 대동그린산업 | The Composition and Manufacturing Method of Inorganic Materials using a Waters Purification |
KR100450882B1 (en) * | 2001-12-27 | 2004-10-02 | 강철호 | Organic waste cleanser and method of recycling organic waste |
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