KR20010088729A - A solid clarifier manufactured by a natural inorganic element - Google Patents

A solid clarifier manufactured by a natural inorganic element Download PDF

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KR20010088729A
KR20010088729A KR1020010051776A KR20010051776A KR20010088729A KR 20010088729 A KR20010088729 A KR 20010088729A KR 1020010051776 A KR1020010051776 A KR 1020010051776A KR 20010051776 A KR20010051776 A KR 20010051776A KR 20010088729 A KR20010088729 A KR 20010088729A
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raw material
solid
natural
natural inorganic
raw materials
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KR1020010051776A
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Korean (ko)
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제창국
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제창국
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    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5263—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using natural chemical compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/007—Contaminated open waterways, rivers, lakes or ponds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/08—Seawater, e.g. for desalination
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00—Use of specific compounds during water treatment

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Water Treatment By Sorption (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

PURPOSE: A solid purifying agent using natural inorganic substance as a main material is provided, which is manufactured in the form of a solid powder, has little dispersal rate and so can be sprayed correctly to an area of red tide and green algae, thereby enhancing purifying efficiency without any secondary water pollution. CONSTITUTION: The manufacturing method is as follows: (i) mix 50-80 wt.% of powder natural inorganic material such as loess, earth and rock, silicious raw material, aluminum silicate raw material, alumina, lime raw material, magnesia raw material and feldspar raw material, 5-15 % of bentonite and 10-15 % of water; and (ii) mold as powder solid in the form of tetragon, sphere and cylinder.

Description

천연 무기질을 주재로 한 고형 정화제{A solid clarifier manufactured by a natural inorganic element}A solid clarifier manufactured by a natural inorganic element

본 발명은 강이나 바다등에서 수온의 급격한 변화등에 의해 발생되는 적조와 녹조 및 선박기름등 각종 오염원에 의해 오염된 바다나 강의 정화를 위해 사용되는 천연무기물을 원료로 한 고형 정화제로서, 더욱 상세하게는 정화제를 알, 환과 같은 고형의 정화제로 성형하여 오염된 해수나 강물에 정확히 침강되어 일정시간 후 분해되게 하므로서 바다, 강, 호수의 오염을 효과적으로 해결하고 또한 정화후 정화력을 가지는 무기염류가 장기간 머물러 해저생물에 필요한 무기염류를 제공하고자 안출한 천연 무기질을 주재로 한 고형 정화제에 관한 것이다.The present invention is a solid purifier made of natural inorganic materials used for the purification of the sea or river contaminated by various sources of pollution such as red tide and green algae and marine oil generated by rapid changes in water temperature in the river or the sea, and more specifically, By forming the purification agent into solid purification agents such as eggs and rings, it is precisely settled in contaminated seawater or river water and decomposed after a certain period of time, effectively solving the pollution of sea, river, and lake. The present invention relates to a solid purifier based on natural minerals designed to provide inorganic salts for living organisms.

일반적으로 수온의 변화에 의해서 발생되는 적조나 녹조는 비교적 빠른 속도로 주변 해역으로 확산되어 어패류 양식장에 치명적인 악영향을 미쳐 어패류의 폐사는 물론 수질을 오염시키게 되고 또 선박이나 침몰된 유조선으로 부터 유출되는 기름과 생활오폐수등으로 바다와 강 및 호수등이 심각할 정도로 오염되어 있음은 주지의 사실로서 근래에는 이를 정화시키기 위한 방법으로 정화효과가 우수한 것으로 잘 알려진 황토를 오염지역에 무작위로 대량 살포하여 적조와 녹조현상을 일부해소하고 있다.In general, red and green algae caused by changes in water temperature are rapidly spreading to surrounding waters, causing a fatal adverse effect on fish and shellfish farms, contaminating the quality of fish and shellfish as well as oil spills from ships or sinking tankers. It is well known that the seas, rivers, and lakes are seriously polluted by water and domestic wastewater, and in recent years, a large quantity of red soil, which is known for its excellent purification effect, is sprayed randomly in red tide and It partially solves the algae phenomenon.

그러나 현재 살포되고 있는 정화용 황토는 황토흙을 바지선등에 실어 살포기로서 무작위로 살포하게 되므로 분말로 된 황토가 분산되어 오염된 목표지점에 정확히 투여되기가 용이하지 않을 뿐 아니라 목표지점에 도달되었다 하더라도 조류에 의해 흘러 쉽게 분산되므로서 정화효과를 크게 얻을 수 없는 문제점이 있었다.However, the presently applied purifying ocher is sprayed randomly as a spreader by placing the loess soil on a barge, etc., so that the powdered ocher is not easily distributed to the polluted target point and is not easily administered to the algae even if the target point is reached. There is a problem that can not be obtained greatly by the flow by being easily dispersed by the flow.

본 발명의 목적은 화학물질이 아닌 순수한 천연 무기물을 이용하여 정화효과가 뛰어나고 수질에 하등 영향을 미치지 않으면서 오염지점에 정확히 투여시킬 수 있는 알, 환과 같은 입자상의 천연 무기질을 주재로 한 고형 정화제를 제공하는 데 있다.An object of the present invention is to use a solid natural mineral, not a chemical substance, the solid purification agent based on particulate natural minerals, such as eggs and rings that can be precisely administered to the point of contamination without having any effect on the water quality with excellent purification effect To provide.

상기한 목적을 달성하기 위한 본 발명은 황토와 장석같은 천연 무기질 재료 50∼80 중량%에 벤토나이트 5∼15%와 물 10∼15%을 혼합하여 알, 환과 같은 입자상의 고형체로서 성형하여 이루어진다.The present invention for achieving the above object is formed by mixing 50 to 80% by weight of natural inorganic materials such as ocher and feldspar, 5 to 15% bentonite and 10 to 15% of water to form a particulate solid such as eggs and rings.

여기서 천연 무기질 재료는 중금속을 함유하지 않은 황토와 토석, 규산질광물, 규산 알루미늄광물, 알루미나, 석회원료, 마그네시아원료, 장석질원료, 산화인계 원료등이 택일적으로 사용된다.Here, natural mineral materials include ocher, earth, siliceous minerals, aluminum silicates, alumina, stone members, magnesia raw materials, feldspar raw materials, and phosphorus oxide raw materials which do not contain heavy metals.

도 1 내지 도 3은 본 발명의 여러 형태를 도시한 예시도1 to 3 are exemplary views showing various forms of the present invention.

<도면의 주요부분에 대한 부호의 설명><Description of the symbols for the main parts of the drawings>

100 : 고형 정화제100: Solid Purifier

이하 본 발명을 첨부도면에 의거 상술하면 다음과 같다.Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.

도 1 내지 도 3은 본 발명의 형태에 따른 여러 실시예를 도시한 것으로서 본 발명의 고형 정화제(100)는 황토, 토석, 규산질원료, 규산 알루미늄원료, 알루미나, 석회원료, 마그네시아원료, 장석질원료, 산화인계 원료등과 같은 분말상의 천연 무기질 재료 50∼80 중량%에 벤토나이트 5∼15%와 물 10∼15%을 혼합하여 입자상의 고형체로서 성형하여 이루어진다.1 to 3 show various embodiments according to the form of the present invention, the solid purification agent 100 of the present invention is ocher, earth, siliceous raw material, aluminum silicate raw material, alumina, stone member, magnesia raw material, feldspar raw material 50 to 80% by weight of powdery natural inorganic materials such as phosphorus oxide-based raw materials, 5 to 15% of bentonite and 10 to 15% of water are mixed and molded into a particulate solid.

여기서 고형체는 첨부도면의 예시와 같이 구상, 원통형상, 사각형상등 다양한 형태의 입자상으로 구성한다.Here, the solid body is composed of particles of various shapes such as spherical shape, cylindrical shape, and square shape as shown in the accompanying drawings.

이와같이 된 본 발명의 고형 정화제(100)는 적조, 녹조의 발생해역이나 어패류 양식장, 고질적으로 오염된 해양, 강, 호수등에 투입하게 되는 데 정화제가 종래와 같이 분말상으로 되지 않고 일정한 형상을 가지는 고형체로서 이루어져 있으므로 바다에 투여시 오염된 목표지점에 정확한 살포가 가능할 뿐 아니라 살포되어 침강된 후 일정시간이 지나면 자연적으로 풀어져서 오염물질을 흡착하고 분해하게 됨에 따라 오염물질의 정화효과가 매우 크다.The solid purification agent 100 of the present invention is introduced into a red tide, an algae, a sea area or a fish farm, a contaminated sea, a river, a lake, etc., but the solidification agent has a constant shape without becoming a powder as in the prior art. Therefore, it is possible to precisely spray the polluted target point when it is administered to the sea, and it is naturally released after a certain time after being sprayed and settled, so as to adsorb and decompose the pollutants.

여기서, 천연 무기질의 하나인 황토는 잘 알려져 있는 바와 같이 원적외선이발산되는 흙으로서 적조현상을 제거하는 데 사용되고 있으며, 벤토나이트는 초미세한 백색 또는 담황갈색 점토로서 물에 녹지 않지만 물에 넣으면 팽윤하여 용적이 약 10배가 되는 것으로 주로 금속주물용 사형의 결합제로서 사용되므로 이를 황토와 혼합하여 일정형상의 형틀에 의해 압축 성형하게 되면 황토가 고형체로서 성형되어 있게 되고 물에 투입시 일정시간이 경과되면 황토가 물에 녹아 풀어짐에 따라 오염물질을 효율적으로 제거할 수 있게 된다.Here, ocher, one of the natural minerals, is used to remove red tide as far-infrared infrared ray, and bentonite is a very fine white or pale yellow brown clay that is insoluble in water but swells when it is put into water. It is about 10 times and it is mainly used as a binder of sand casting for metal castings. When it is mixed with loess and compressed by a mold of a certain shape, the loess is formed as a solid body. As it dissolves in water, it can remove contaminants efficiently.

본 발명의 주재인 천연 무기질 재료는 전기한 황토를 비롯하여 규산질광물, 규산 알루미늄광물, 알루미나, 석회원료, 마그네시아원료, 장석질원료, 산화인계 원료등과 같은 천연광물이 사용될 수 있는 데 규산질 원료는 규산질 광물, 규석, 규사, 규조토, 실리카의 결정등이며, 규산 알루미늄원료는 규산 알루미늄광물, 실리마나이트족광물, 카올린족광물, 엽납석, 점토등이고, 알루미나는 알루미나광물, 함수알루미나광물이며, 석회원료는 석회석, 형석, 규회석, 석회장석, 석고, 인산석회등이고, 마그네시아원료는 마그네사이트, 돌로마이트, 해수 마그네시아계 원료가 있으며, 장석질원료는 장석, 도석, 네펠라인등이 있고, 산화인계원료는 인회석, 인회토, 인산반토광등이 있다.The natural inorganic material, which is the main subject of the present invention, can be used natural minerals such as siliceous mineral, aluminum silicate, alumina, stone member, magnesia raw material, feldspar raw material, phosphorus oxide raw material, etc. Minerals, silica, silica, diatomaceous earth, silica crystals, etc.Aluminum silicate raw material is aluminum silicate mineral, silymanite mineral, kaolin group mineral, chlorophyllite, clay, etc., and alumina is alumina mineral, hydrous alumina mineral. Are limestone, fluorite, wollastonite, limestone, gypsum, phosphate lime, magnesia raw materials include magnesite, dolomite, seawater magnesia-based raw materials, feldspar raw materials include feldspar, pottery stone, nephelline, etc. , Phosphate, alumina phosphate, etc.

이와같은 천연 무기질 재료는 그 성분이 규산(Si02)40∼85%, 알루미나(Al203)10∼30%, 산화제이철(Fe203)0∼5%, 산화칼슘(Ca0)0∼5%, 산화마그네슘(MgO)0∼5%, 산화나트륨(Na20)0∼5%, 산화칼륨(K20)0∼5%, 이글로스(lgloss)0∼5% 등이 함유되어 인체등에 유익한 원적외선의 방사와 통기성, 응집력, 점착력으로 인한 탈취효과 및용존산소량 보존유지로서 정화효과를 크게 얻을 수 있으며 어패류에도 매우 유익하여 어패류의 성장을 촉진시키는 효과도 발휘하게 된다.Such natural inorganic materials include 40 to 85% of silicic acid (Si0 2 ), 10 to 30% of alumina (Al 2 0 3 ), 0 to 5% of ferric oxide (Fe 2 0 3 ), and calcium oxide (Ca0) 0. -5%, magnesium oxide (MgO) 0-5%, sodium oxide (Na20) 0-5%, potassium oxide (K 2 0) 0-5%, lgloss (0-5%), etc. The deodorizing effect of radiation and breathability, cohesion, and cohesiveness of far-infrared rays, etc., which are beneficial to the back, can greatly increase the purification effect as preservation of dissolved oxygen.

이러한 천연 무기질 재료는 택일적으로 또는 복합적으로 사용되는 데 원석, 원토등을 분쇄기로서 약 300메쉬 이하로 분쇄하여 분말화하고 이에 물을 흡수하면 부피 팽창을 하는 결합제인 벤토나이트를 물과 적당량 혼합하여 소망하는 형틀에 의거 일정형상으로 성형하게 되면 입자상의 고형체 정화제(100)를 얻을 수 있다.These natural inorganic materials are used alternatively or in combination, and the raw materials, such as raw materials, raw materials, etc. are pulverized to about 300 mesh or less as a pulverizer, and when absorbed by water, bentonite, which is a binder that expands in volume when mixed with water, is mixed with water. When the mold is molded into a predetermined shape based on the mold, the particulate solid cleaner 100 can be obtained.

이와같이 본 발명의 고형 정화제(100)는 오염물질의 정화효과가 큰 황토를 비롯한 천연 무기질 재료를 주재로 하여 입자상의 고형체로 제조된 것이므로 살포시 종래의 분말과는 달리 분산율이 매우 적어 적조, 녹조의 발생해역 등에 정확히 살포할 수 있게 되므로서 수질의 2차 오염없이 정화효과를 크게 높일 수 있고 살포 후 일정시간이 경과하면 쉽게 분해되어 오염물질을 정화하게 되며 침강후 바닥에 장기간 정체되어 해저생물의 먹이가 될 수 있는 등 그 효과가 매우 크다.As described above, since the solid purification agent 100 of the present invention is made of a solid solid having natural mineral materials including loess, which has a large purifying effect of contaminants, the dispersion rate is very small unlike the conventional powder during spraying, resulting in red tide and green algae. As it can be sprayed precisely in sea areas, it can greatly enhance the purification effect without secondary pollution of water quality, and after a certain time after spraying, it is easily decomposed and cleans the pollutants. The effect is very big.

Claims (3)

황토, 토석, 규산질원료, 규산 알루미늄원료, 알루미나, 석회원료, 마그네시아원료, 장석질원료, 산화인계 원료등과 같은 분말상의 천연 무기질 재료 50∼80 중량%에 벤토나이트 5∼15%와 물 10∼15%을 혼합하여 입자상의 고형체로서 성형하여 이루어지는 천연 무기질을 주재로 한 고형 정화제.Bentonite 5-15% and water 10-15 in 50-80% by weight of powdery natural mineral materials such as ocher, earth, siliceous raw materials, aluminum silicate raw materials, alumina, stone membership materials, magnesia raw materials, feldspar raw materials and phosphorus oxide raw materials A solid purifier based on natural minerals obtained by mixing% to form a particulate solid. 제 1 항에 있어서, 천연 무기질 재료가 황토, 토석, 규산질원료, 규산 알루미늄원료, 알루미나, 석회원료, 마그네시아원료, 장석질원료, 산화인계 원료에 속하는 광물그룹으로 부터 하나 이상 선택되는 천연 무기질을 주재로 한 고형 정화제.The method according to claim 1, wherein the natural inorganic material comprises at least one natural mineral selected from the group consisting of loess, earth, siliceous raw material, aluminum silicate raw material, alumina, stone member, magnesia raw material, feldspar raw material, phosphorus oxidized raw material. Solid cleanser made with. 제 1 항에 있어서, 정화제가 사각, 구상, 원통형상으로 부터 택일되는 형상으로 이루어지는 천연 무기질을 주재로 한 고형 정화제.2. The solid purifier according to claim 1, wherein the purifier is formed of a natural inorganic material having a shape alternative from a square, a spherical shape, and a cylindrical shape.
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KR20040034017A (en) * 2002-10-16 2004-04-28 (주) 룩스팜 The manufacturing method of the water quality purificatory materials and Red and green tide Eliminator through the pure mineral raw materials
KR100651007B1 (en) * 2004-07-27 2006-11-29 부산대학교 산학협력단 New material for mitigation of harmful algal blooms by using rock powder and organo­bentonite
KR100818547B1 (en) * 2006-09-20 2008-04-02 제창국 Tidal Flat Purifying Agent
CN105314693A (en) * 2015-12-01 2016-02-10 仇颖超 Method for preparing compound water purifying agent from waste aluminum ash

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* Cited by examiner, † Cited by third party
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KR20040034017A (en) * 2002-10-16 2004-04-28 (주) 룩스팜 The manufacturing method of the water quality purificatory materials and Red and green tide Eliminator through the pure mineral raw materials
KR100651007B1 (en) * 2004-07-27 2006-11-29 부산대학교 산학협력단 New material for mitigation of harmful algal blooms by using rock powder and organo­bentonite
KR100818547B1 (en) * 2006-09-20 2008-04-02 제창국 Tidal Flat Purifying Agent
CN105314693A (en) * 2015-12-01 2016-02-10 仇颖超 Method for preparing compound water purifying agent from waste aluminum ash

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