KR100887663B1 - The bio mineral numerous hole body production techniques for which remnant food and drink waste water was used - Google Patents
The bio mineral numerous hole body production techniques for which remnant food and drink waste water was used Download PDFInfo
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- KR100887663B1 KR100887663B1 KR20070100100A KR20070100100A KR100887663B1 KR 100887663 B1 KR100887663 B1 KR 100887663B1 KR 20070100100 A KR20070100100 A KR 20070100100A KR 20070100100 A KR20070100100 A KR 20070100100A KR 100887663 B1 KR100887663 B1 KR 100887663B1
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- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/10—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by using foaming agents or by using mechanical means, e.g. adding preformed foam
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Abstract
Description
본 발명은 남은 음식물 폐수를 이용한 바이오 미네랄 다공체 제조방법에 관한 것으로, 특히 남은 음식물 폐수와 규산염 광물질(맥반석, 흑운모 등) 혹은 일반 광물질, 토양에 이로운 흙(마사토, 황토 등)의 혼합물을 이용하여 사용하고자 하는 용도에 따른 적정량을 혼합하여 규산질 비료, 토지개량제, 수질정화(적ㆍ녹조제거), 미생물 배양, 수경재배, 탈취제 등에 사용할 수 있도록 하는 남은 음식물 폐수를 이용한 바이오 미네랄 다공체 제조방법에 관한 것이다.The present invention relates to a method for producing a bio-mineral porous body using the remaining food waste water, and in particular, by using a mixture of the remaining food waste water and silicate minerals (macbanite, biotite, etc.) or general minerals and soils (masato, ocher, etc.) beneficial to the soil. The present invention relates to a method for producing a bio-mineral porous body using the remaining food waste water to be mixed with an appropriate amount according to the intended use so that it can be used for siliceous fertilizer, land improver, water purification (red and green algae removal), microbial culture, hydroponic cultivation, deodorant, and the like.
2007년 음식물 처리 실태를 보면 음식물 전체 발생량의 60~70% 이상이 음식물 처리시 발생되는 음식물 폐수이며, 이러한 음식물 폐수 처리는 거의 해양 투기에 전적으로 의존하고 있는 실정이다. In 2007, more than 60-70% of the total amount of food waste produced is food wastewater generated from food treatment, and this food wastewater treatment is almost entirely dependent on ocean dumping.
그러나 2007년 7월 1일부터 함수율 95% 이상, 고형물 5% 미만인 음식물 폐수인 경우에만 해양 배출을 허용하도록 규정하고 있다. However, from July 1, 2007, only the food wastewater with a water content of 95% or more and less than 5% of solids is allowed to be discharged from the ocean.
이러한 음식물 폐수의 함수 비율은 물리적이나 화학적으로 처리하기에는 현 실적으로 많은 어려움에 직면하고 있으며, 또한, 지금껏 음식물 폐수처리에 대한 연구개발과 시설 설비의 처리대책은 아직 핵심기술을 찾지 못하고 있는 실정이다. The water content ratio of the food wastewater is currently difficult to deal with physically and chemically, and the research and development of the food wastewater treatment and treatment measures of facility facilities have not yet found core technologies.
더욱이, 음식물 폐수는 매일 많은 양이 배출되고 있으며, 함수율 95% 이상을 충족시키기는 쉽지 않은 상황이고, 음식물 폐수 자체에 염분성분이 다량 함유되어 있어, 대량으로 거름 및 퇴비를 생산, 사용하기에는 많은 어려운 점이 있다. Moreover, food wastewater is released in large quantities every day, and it is not easy to meet the moisture content of more than 95%, and since the food wastewater itself contains a large amount of salt, it is difficult to produce and use manure and compost in large quantities. There is a point.
또한, 종래에는 음식물 폐수를 유기질 비료나 퇴비 발효시 수분조절제로 톱밥을 이용한 미생물 발효 방법을 사용하여 왔다. In addition, conventionally, the microbial fermentation method using sawdust as a moisture control agent for food wastewater organic fertilizer or compost fermentation has been used.
그러나 음식물 폐수에 수분조절제로 톱밥의 사용은 음식물 폐수의 수분 흡수율이 떨어지고, 많은 양 톱밥을 배합해 주어야 할 뿐만 아니라 비료화 및 퇴비화하였을 때 부숙 기간이 최소한 1년 이상 소요되고, 수급 양이 절대적으로 부족하여 거의 수입에 의존하는 문제점이 있다. However, the use of sawdust as a moisture control agent for food wastewater has a low water absorption rate of food wastewater, and a large amount of sawdust must be formulated, as well as at least one year of staying time when fertilizing and composting, and supply and demand is absolutely insufficient. There is a problem that almost depends on income.
또한, 수분조절제 및 발효제로 톱밥 사용시 별도로 미생물을 구입하여 배합하여야 하는 문제점이 있다.In addition, when using sawdust as a moisture control agent and a fermentation agent, there is a problem in that to separately purchase a microorganism.
이에, 본 발명은 상기한 바와 같은 제반문제점을 해결하기 위해 안출된 것으로서, 남은 음식물 폐수와 규산염 광물질 혹은 일반광물질, 흙(마사토, 황토 등)의 혼합물 및 석회를 혼합하여, 적정의 수분 흡수율을 가지는 바이오 미네랄 다공체를 제조함으로써, 규산염 광물질이 포함된 다공체는 규산질 비료, 유기질 비료 발효, 수분 조절제, 수질 정화(적조, 녹조제거제), 미생물 배양, 수경재배, 탈취제 등에 사용하고, 일반광물질, 흙(마사토, 황토 등)의 혼합물이 포함된 다공체는 토지개량제, 미생물 배양에 사용할 수 있도록 한 남은 음식물 폐수를 이용한 바이오 미네랄 다공체 제조방법을 제공하는데 그 목적이 있다.Accordingly, the present invention has been made to solve the above-mentioned problems, a mixture of the remaining food wastewater and silicate minerals or general minerals, soil (masato, ocher, etc.) and lime, having a proper water absorption rate By manufacturing the bio mineral porous body, the porous body containing silicate mineral is used for siliceous fertilizer, organic fertilizer fermentation, moisture control agent, water purification (red tide, algae remover), microbial culture, hydroponic cultivation, deodorant, etc. It is an object of the present invention to provide a method for producing a bio-mineral porous body using the remaining food wastewater which can be used for cultivation of land and a microorganism.
상기한 목적을 달성하기 위한 본 발명에 따른 남은 음식물 폐수를 이용한 바이오 미네랄 다공체 제조방법은 남은 음식물 폐수 30 ~ 40중량%와, 규산염 광물질 혹은 일반 광물질, 흙(마사토, 황토)의 혼합물과, 석회를 300 mesh 이상으로 분쇄된 규산염 광물질 혹은 일반 광물질, 흙의 혼합물 40 ~ 60중량%, 석회 10 ~ 20중량%를 혼합하고, 식물성 및 동물성 기포제를 첨가하여 규산염 광물질 혹은 일반광물질, 흙(마사토, 황토)의 혼합물과 석회의 부피를 2~5배로 팽창시켜 발포, 건조, 소성하여 바이오 미네랄 다공체를 제조함을 특징으로 한다.Bio-mineral porous body manufacturing method using the remaining food wastewater according to the present invention for achieving the above object is a mixture of 30-40% by weight of the remaining food wastewater, silicate minerals or general minerals, soil (masato, ocher), and lime Silicate minerals or general minerals, soil (masato, ocher) mixed with 40 to 60% by weight of a mixture of silicate minerals or general minerals and soil, 10 to 20% by weight of lime, and vegetable and animal foaming agents The mixture and the volume of lime is expanded by 2 to 5 times, characterized in that the bio-mineral porous body is prepared by foaming, drying and firing.
상기한 바와 같은 구성으로 이루어진 본 발명에 따른 남은 음식물 폐수를 이용한 바이오 미네랄 다공체 제조방법은 남은 음식물 폐수, 규산염 광물질 혹은 일반광물질, 흙(마사토, 황토)의 혼합물과 석회를 혼합한다. 규산염 광물질이 포함된 바이오 미네랄 다공체는 규산질 비료, 유기질 비료의 발효 및 수분 조절제, 수질정화(적조, 녹조제거제), 미생물 배양, 수경재배, 탈취제 등에 사용이 되고, 일반 광물질, 흙(마사토, 황토 등)의 혼합물이 포함된 바이오 미네랄 다공체는 토지개량제, 미생물 배양 등에 사용할 수 있는 이점이 있다.Bio-mineral porous body manufacturing method using the remaining food wastewater according to the present invention having the configuration as described above is mixed with the mixture of the remaining food wastewater, silicate mineral or general minerals, soil (masato, ocher) and lime. Bio mineral porous body containing silicate mineral is used for fermentation and moisture control of siliceous fertilizer, organic fertilizer, water purification (red tide, algae remover), microbial culture, hydroponic cultivation, deodorant, and general minerals, soil (masato, loess, etc.). Bio-mineral porous body containing a mixture of) has the advantage that can be used in land improver, microbial culture.
이하, 본 발명을 첨부한 예시도면을 참조하여 상세히 설명한다.Hereinafter, with reference to the accompanying drawings, the present invention will be described in detail.
도 1은 본 발명에 따른 남은 음식물 폐수를 이용하여 바이오 미네랄 다공체를 제조하는 공정을 도시한 공정도이며, 도 2는 본 발명에 따른 남은 음식물 폐수를 이용한 바이오 미네랄 다공체의 양생시 거푸집 몰드를 도시한 예시도 이며, 도 3은 본 발명에 따른 남은 음식물 폐수를 이용한 바이오 미네랄 다공체를 도시한 단면도이다.1 is a process chart showing a process for producing a bio-mineral porous body using the remaining food waste water according to the present invention, Figure 2 is an illustration showing a mold mold during curing of the bio-mineral porous body using the remaining food waste water according to the present invention. 3 is a cross-sectional view showing a bio mineral porous body using the remaining food wastewater according to the present invention.
이들 도면에 도시된 바와 같이, 본 발명에 따른 남은 음식물 폐수를 이용한 바이오 미네랄 다공체 제조방법은 남은 음식물 폐수 30 ~ 40중량%와, 규산염 광물질 혹은 일반 광물질, 흙(마사토, 황토)의 혼합물과, 석회를 300 mesh 이상으로 분쇄된 규산염 광물질 혹은 일반 광물질, 흙의 혼합물 40 ~ 60중량%와, 석회 10 ~ 20 중량%를 혼합하고, 식물성 및 동물성 기포제를 첨가하여 규산염 광물질 혹은 일반광물질, 흙(마사토, 황토)의 혼합물과 석회의 부피를 2~5배로 팽창시켜 발포, 건조, 소성하여 바이오 미네랄 다공체를 제조한다.As shown in these figures, the method for producing a bio-mineral porous body using the remaining food wastewater according to the present invention is 30-40% by weight of the remaining food wastewater, a mixture of silicate minerals or ordinary minerals, soil (masato, loess), lime 40 to 60% by weight of a mixture of silicate minerals or general minerals and soil ground to 300 mesh or more, and 10 to 20% by weight of lime, and by adding vegetable and animal foaming agents, silicate minerals or general minerals, soil (masato, A mixture of yellow soil and lime is expanded by 2 to 5 times to foam, dry and calcined to prepare a bio mineral porous body.
여기서, 상기 규산염 광물질 혹은 일반 광물질, 흙(마사토, 황토)의 혼합물은 용도에 맞게 어느 하나를 선택적으로 사용한다.Here, the mixture of silicate minerals or general minerals, soil (masato, ocher) is optionally used according to the purpose.
또한, 상기 일반 광물질에 기포제를 섞어 거푸집에 넣고 발포 팽창하여 케이크 모양으로 굳었을 때 꺼내 형상을 잘라 고압소독기(Autoclave) 내에서 적정온도인 170~200℃, 10기압으로 양생한다. In addition, the foaming agent is mixed with the general mineral material into a mold and expanded to expand and expand when foamed and solidified into a cake shape, and is cured at a proper temperature of 170 to 200 ° C. and 10 atm in an autoclave.
즉, 본 발명에 따른 남은 음식물 폐수를 이용한 바이오 미네랄 다공체 제조방법은 규산염 및 일반 광물질 혹은 흙(마사토, 황토 등)의 혼합물을 이용한 바이오 미네랄은 대부분 미세한 기포(습도조절능력)로 구성되며, 원료 1㎥에서 2~5㎥의 미생물 배양과 수분 흡수 바이오 미네랄 다공체를 제조할 수 있다.That is, the bio-mineral porous body manufacturing method using the remaining food wastewater according to the present invention, the bio-mineral using a mixture of silicate and general minerals or soil (masato, ocher, etc.) is composed of mostly fine bubbles (humidity control ability), raw material 1 From 3 m 3 to microbial culture and water absorption bio mineral porous body can be prepared.
특히, 상기한 규산염 광물질이 포함된 바이오 미네랄 다공체는 규산질 비료, 유기질 비료의 발효 및 수분 조절제, 수질정화(적조, 녹조제거제), 미생물 배양, 수경재배, 탈취제 등에 사용되고, 일반 광물질, 흙(마사토, 황토)의 혼합물이 포함된 바이오 미네랄 다공체는 토지개량제, 미생물 배양 등에 사용된다.In particular, the bio mineral porous body containing the silicate mineral is used in siliceous fertilizer, organic fertilizer fermentation and moisture control agent, water purification (red tide, algae remover), microbial culture, hydroponic cultivation, deodorant, general minerals, soil (masato, Bio-mineral porous body containing a mixture of loess) is used for land improver, microbial culture, etc.
한편, 상기한 바와 같은 단계로 이루어지는 본 발명에 따른 남은 음식물 폐수를 이용한 바이오 미네랄 다공체 제조방법은 크게 자연적인 성형방법과 기계적인 성형방법 두 가지 방법으로 제조된다.On the other hand, the bio-mineral porous body manufacturing method using the remaining food waste water according to the present invention consisting of the steps as described above are largely produced by two methods of natural molding and mechanical molding.
전자인, 자연건조 성형방법은 발포 및 팽창을 위하여 양생시 거푸집 몰드를 10~20㎝ 두께로 타설하여 양생한다. 바이오 미네랄 성형을 위한 슬러리 타설시 작업이 용이하도록 작은 판자를 이용하여 양생 후 분리가 용이하도록 타설시 매립하여 둔다. 2~3일 양생 후 파쇄기에 넣어 요구되는 용도에 따라 파쇄, 선별하게 된다. The former, natural dry molding method is cured by pouring a mold mold 10 ~ 20cm thick during curing for foaming and expansion. When laying slurry for bio-mineral molding, it is buried at the time of pouring for easy separation after curing using a small board to facilitate the work. After curing for 2-3 days, it is crushed and sorted according to the required use in the crusher.
후자인, 기계적인 건조 성형방법은 고압소독기(Autoclave)를 이용하는 방법으로 양생시 적정온도는 170~200℃이며, 가장 바람직한 온도는 180℃이다. The latter, a mechanical dry molding method is a method using a high-pressure sterilizer (Autoclave), the optimum temperature during curing is 170 ~ 200 ℃, the most preferred temperature is 180 ℃.
증기 양생 시간은 2~3시간이며, 증기양생과정에서 사용되는 수증기는 여러 번 재사용 되며, 이와 같은 증기 양생 방법은 공기, 물, 토양 등에 어떤 해로운 유해물질도 발생하지 않는다. 이러한 바이오 미네랄 다공체는 음식물 폐수, 실리카(SiO2)가 성분이 많은 규산염 광물질과 일반 광물질 혹은 흙(마사토, 황토 등)의 혼합물과 석회를 혼합하여 제조한다. 혼합된 슬러리에 기포제를 섞어 거푸집에 넣고 발포 팽창시켜 케이크 모양으로 굳었을 때 꺼내 이것을 고압소독기에 넣고 180℃, 10기압으로 양생한다. 성형화된 다공체 바이오 미네랄은 비중 0.7~0.9로서 흡수 건조할 때 용적변형이 다공성(공극율 80% 이상)이어서 미생물 배양이나 수분흡수가 탁월하다. Steam curing time is 2 to 3 hours, the steam used in the steam curing process is reused several times, this steam curing method does not generate any harmful harmful substances such as air, water, soil. The bio mineral porous body is prepared by mixing lime with a mixture of food wastewater, silica (SiO 2 ) -rich silicate mineral and general mineral or soil (masato, ocher, etc.). After mixing the foaming agent in the mixed slurry into the formwork and foam expansion and expansion to remove the cake when it is hardened into a high-pressure sterilizer to cure at 180 ℃, 10 atm. Molded porous bio minerals have a specific gravity of 0.7 to 0.9, which is excellent in cultivating microorganisms and absorbing water because the volumetric deformation is porous (more than 80% of porosity) when absorbed and dried.
특히, 규산염 광물질에는 실리카(SiO2)가 50% 이상 포함되어 있어 규산질 비료로서 아주 적합하다. In particular, silicate minerals contain more than 50% of silica (SiO 2 ) is very suitable as a siliceous fertilizer.
그리고 상기 바이오 미네랄 다공체는 유기질인 음식물 폐수와 천연광물질을 이용하므로 값이 저렴하고, 다공기능으로 인해 통기성이 양호함으로 호기성 미생물 배양에 효과적이다. In addition, the bio mineral porous body is inexpensive because it uses organic food wastewater and natural minerals, and is highly effective for cultivating aerobic microorganisms due to good ventilation due to its porous function.
또한, 규산질 비료, 유기질 비료, 퇴비 생산, 수분 조절제, 발효제, 탈취제 등으로 대체가능하며 광물질이 수분을 흡수하므로 수분량에 전혀 문제가 없으며 퇴비화 기간은 7~15일 정도로 부숙 기간을 단축할 수 있다.In addition, it can be replaced by siliceous fertilizer, organic fertilizer, compost production, moisture control agent, fermentation agent, deodorant, etc., because the mineral absorbs moisture, there is no problem in the amount of moisture and the composting period can be shortened to 7-15 days.
이하, 본 발명에 따른 남은 음식물 폐수를 이용한 바이오 미네랄 다공체에 대한 성분에 대해 설명한다.Hereinafter, the components for the bio mineral porous body using the remaining food waste water according to the present invention will be described.
<바이오 미네랄 다공체 성분분석><Bio mineral porous body composition analysis>
<맥반석 성분분석>Elvan rock component analysis
<흑운모 성분분석>Biotite component analysis
<규산염 광물질 다공체 원적외선 방사율 ><Silicate Mineral Porous Far-infrared Emissivity>
<규산염 광물질 다공체 탈취시험 ><Silicate mineral porous body deodorization test>
- 시험가스명: 암모니아Test gas name: Ammonia
- Blank는 시료를 넣지 않은 상태에서 측정한 것임-Blank is measured without sample.
<규산염 광물질 다공체 항곰팡이 시험><Silicate Mineral Porous Antifungal Test>
- 곰팡이 균주: 혼합균주Fungal Strains: Mixed Strains
- 대장균, 녹농균에 의한 항균시험-Antibacterial test by Escherichia coli, Pseudomonas aeruginosa
도 1은 본 발명에 따른 남은 음식물 폐수를 이용하여 바이오 미네랄 다공체를 제조하는 공정을 도시한 공정도,1 is a process chart showing a process for producing a bio mineral porous body using the remaining food waste water according to the present invention,
도 2는 본 발명에 따른 남은 음식물 폐수를 이용한 바이오 미네랄 다공체의 양생시 거푸집 몰드를 도시한 예시도,Figure 2 is an exemplary view showing a mold during curing of the bio-mineral porous body using the remaining food waste water according to the present invention,
도 3은 본 발명에 따른 남은 음식물 폐수를 이용한 바이오 미네랄 다공체를 도시한 단면도.3 is a cross-sectional view showing a bio mineral porous body using the remaining food waste water according to the present invention.
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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KR19990014365A (en) * | 1998-07-02 | 1999-02-25 | 박영일 | Manufacturing method of multifunctional porous ceramics |
KR20010045052A (en) * | 1999-11-02 | 2001-06-05 | 김동진 | Purifying medicine and manufacturing method thereof |
KR20020003338A (en) * | 2001-12-11 | 2002-01-12 | 이종래 | A porosity ceramic |
KR20040007383A (en) * | 2003-12-30 | 2004-01-24 | 규 재 유 | Lime and Organic Lime Fertilizer Utilizing Lime Sludge and Organic Wastes and Its Manufacturing Method |
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Publication number | Priority date | Publication date | Assignee | Title |
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KR19990014365A (en) * | 1998-07-02 | 1999-02-25 | 박영일 | Manufacturing method of multifunctional porous ceramics |
KR20010045052A (en) * | 1999-11-02 | 2001-06-05 | 김동진 | Purifying medicine and manufacturing method thereof |
KR20020003338A (en) * | 2001-12-11 | 2002-01-12 | 이종래 | A porosity ceramic |
KR20040007383A (en) * | 2003-12-30 | 2004-01-24 | 규 재 유 | Lime and Organic Lime Fertilizer Utilizing Lime Sludge and Organic Wastes and Its Manufacturing Method |
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