KR102036844B1 - Method for preparation of organic germamium from granite - Google Patents
Method for preparation of organic germamium from granite Download PDFInfo
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- KR102036844B1 KR102036844B1 KR1020170050275A KR20170050275A KR102036844B1 KR 102036844 B1 KR102036844 B1 KR 102036844B1 KR 1020170050275 A KR1020170050275 A KR 1020170050275A KR 20170050275 A KR20170050275 A KR 20170050275A KR 102036844 B1 KR102036844 B1 KR 102036844B1
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- 239000010438 granite Substances 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title claims description 9
- 229910052732 germanium Inorganic materials 0.000 claims abstract description 58
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims abstract description 58
- 238000000855 fermentation Methods 0.000 claims abstract description 24
- 239000000463 material Substances 0.000 claims abstract description 22
- 239000000843 powder Substances 0.000 claims abstract description 10
- 238000002156 mixing Methods 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 44
- 238000000746 purification Methods 0.000 claims description 6
- 239000000758 substrate Substances 0.000 claims description 5
- 230000004151 fermentation Effects 0.000 abstract description 14
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 7
- 239000002245 particle Substances 0.000 description 6
- 230000035622 drinking Effects 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 230000009471 action Effects 0.000 description 3
- 235000020188 drinking water Nutrition 0.000 description 3
- 239000003651 drinking water Substances 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- 239000008399 tap water Substances 0.000 description 3
- 235000020679 tap water Nutrition 0.000 description 3
- 241001148471 unidentified anaerobic bacterium Species 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- DIKBFYAXUHHXCS-UHFFFAOYSA-N bromoform Chemical compound BrC(Br)Br DIKBFYAXUHHXCS-UHFFFAOYSA-N 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 229910005793 GeO 2 Inorganic materials 0.000 description 1
- 206010020710 Hyperphagia Diseases 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 210000001124 body fluid Anatomy 0.000 description 1
- 239000010839 body fluid Substances 0.000 description 1
- 235000020118 bottled purified water Nutrition 0.000 description 1
- 235000012206 bottled water Nutrition 0.000 description 1
- 229950005228 bromoform Drugs 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- -1 hydrogen ions Chemical class 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 125000000082 organogermanium group Chemical group 0.000 description 1
- 235000020830 overeating Nutrition 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000001223 reverse osmosis Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P1/00—Preparation of compounds or compositions, not provided for in groups C12P3/00 - C12P39/00, by using microorganisms or enzymes
- C12P1/02—Preparation of compounds or compositions, not provided for in groups C12P3/00 - C12P39/00, by using microorganisms or enzymes by using fungi
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G17/00—Compounds of germanium
- C01G17/04—Halides of germanium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/30—Germanium compounds
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- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mycology (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Microbiology (AREA)
- General Chemical & Material Sciences (AREA)
- Biotechnology (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Inorganic Chemistry (AREA)
- Water Treatment By Sorption (AREA)
- Filtering Materials (AREA)
Abstract
본 발명은 게르마늄 함유 화강암 분말에 혐기성 발효물질을 섞어 40 내지 60℃의 온도에서 6 내지 15일 동안 유지하여 발효시킴으로써 유기게르마늄을 생성하는 단계를 포함하는 천연 화강암으로부터 유기게르마늄 제조방법을 제공한다. The present invention provides a method for producing organic germanium from natural granite comprising the step of mixing the anaerobic fermentation material with germanium-containing granite powder and maintaining the fermentation at a temperature of 40 to 60 ℃ for 6 to 15 days to produce organic germanium.
Description
본 발명은 천연광석인 화강암으로부터 유기게르마늄을 제조하는 방법을 제공하고자 한다. The present invention is to provide a method for producing organic germanium from natural ore granite.
최근 산업발전이 급속히 증가함에 따라 각종 공장 등으로부터 발생되는 산업폐수 등이 식수원에 유입되어 수질이 저하되고 있다. 일반적으로 각 가정에 공급되는 수돗물은 각 하천의 수계에서 취수장을 통하여 취수되어 저수장에서 오염된 물을 정수과정을 거쳐 상수도관을 통하여 공급되고 있다. Recently, as industrial development rapidly increases, industrial wastewater generated from various factories, etc., is introduced into drinking water sources, and water quality thereof is deteriorated. In general, tap water supplied to each household is withdrawn from the water system of each stream through the intake station, and the contaminated water from the reservoir is purified and supplied through the water supply pipe.
그러나, 상수도관 역시 관리 부족 및 오염수 등으로 인해 부식이 심각하며, 정수과정에서 다량의 소독약품을 사용하더라도, 별도의 처리없이 그대로 취음할 경우 오취로 인하여 취음시 불쾌감을 유발하는 문제점이 있다. 또한, 정수공장에서 사용되는 염소와 유기물과의 반응으로 소독 부생성물인 클로로폼이나 브로모폼, 트리할로메탄 등의 발암성 물질이 생성되는 문제가 발생할 수 있다. 나아가, IT 관련 공장이나 세탁공장 등에서 사용하는 용제, 세정제에 포함된 화학오염물질인 트리클로로에탄, 테트라클로로에틸렌 등이 오염의 원인 물질이다. However, the water supply pipe is also severely corroded due to lack of management and contaminated water, and even if a large amount of disinfectant is used in the water purification process, there is a problem of causing unpleasant feelings due to odor when ingested without additional treatment. In addition, the reaction of chlorine and organic substances used in the water purification plant may cause a problem in that carcinogenic substances such as chloroform, bromoform, trihalomethane, etc., which are disinfection by-products are generated. Furthermore, solvents used in IT-related factories and laundry factories, trichloroethane, tetrachloroethylene, and the like, which are chemical pollutants included in detergents, are causes of contamination.
이에, 통상, 생수를 식용으로 취음하거나, 수돗물을 취음할 경우에는 정수하여 사용하는 경향이 일반화되고 있다. 그러나, 생수 또는 정수된 물은 미생물로 인해 오염되기 쉽고, 이취(異臭)를 발생한다. Therefore, in general, when drinking water for drinking or drinking tap water, the tendency to use purified water is common. However, bottled water or purified water is susceptible to contamination by microorganisms and generates off-flavor.
상기와 같은 문제점 등을 해결하기 위해 통상 수조가 합성수지제로 형성되고 미세필터에 의하여 정수시키는 역삼투압 정수기를 사용한다. 그러나, 상기와 같은 정수기는 미네랄 등의 인체에 이로운 성분을 더욱 활성화시킬 수 없을 뿐만 아니라, 인체에 해로운 대장균 제거작용과 살균작용 및 탈취작용에 의하여 건강을 해치게 되는 문제가 따르게 되었다. In order to solve the above problems and the like, a conventional water tank is formed of a synthetic resin and uses a reverse osmosis water purifier purified by a fine filter. However, the water purifier as described above is not only able to further activate the beneficial components such as minerals, but also has a problem that harms the health by the E. coli removal action and sterilization action and deodorization action harmful to the human body.
상기와 같은 정수기 및 필터는 수중 유해물질을 제거하고 하천수의 제2 오염을 방지하는 장점은 있으나, 여과필터가 다단계로 형성되어 있어서 각 재료를 여과층으로 처리하는 공정이 요구되며, 상기와 같이 다단으로 형성된 여러 여과층을 통과하여 오히려 물에 함유된 유익한 미네랄도 함께 여과되는 문제가 있다. Water purifiers and filters as described above have the advantage of removing harmful substances in the water and preventing the second pollution of the river water, but because the filter is formed in a multi-stage process of treating each material with a filter layer, as described above Rather, it passes through several filtration layers formed as a problem that the beneficial minerals contained in water are also filtered.
본 발명은 천연 광석으로부터 GeO2 β형의 혐기성 미생물에 의해 용해하여 유기게르마늄을 제조하며, 상기 유기게르마늄이 물에 용출되도록 하여 게르마늄 섭취할 수 있도록 하고자 한다.The present invention is to dissolve by the anaerobic microorganism of the GeO 2 β-type from natural ore to produce an organic germanium, to be ingested by allowing the organic germanium to be eluted in water.
본 발명은 천연 화강암으로부터 유기게르마늄을 용출시키는 방법에 대한 것으로서, 게르마늄 함유 화강암 분말에 혐기성 발효물질을 섞어 40 내지 60℃의 온도에서 6 내지 15일 동안 유지하여 발효시킴으로써 유기게르마늄을 생성하는 단계를 포함하는 천연 화강암으로부터 유기게르마늄의 용출 방법을 제공한다.The present invention relates to a method of eluting organic germanium from natural granite, comprising mixing anaerobic fermentation material with germanium-containing granite powder and maintaining it at a temperature of 40 to 60 ° C. for 6 to 15 days to produce organic germanium. It provides a method for eluting organic germanium from natural granite.
예를 들어, 상기 유기게르마늄이 생성된 화강암 분말을 물에 담지하여 유기게르마늄을 용출시킬 수 있다.For example, the granular powder from which the organic germanium is produced may be immersed in water to elute the organic germanium.
상기 혐기성 발효 물질은 생이스트, 활성 건조이스트, 인스턴트 이스트 으로 이루어진 그룹으로부터 선택되는 적어도 하나의 이스트를 사용할 수 있다.The anaerobic fermentation material may use at least one yeast selected from the group consisting of fresh yeast, active dry yeast, instant yeast.
상기 혐기성 발효물질은 화강암 100중량부에 대하여 5 내지 50중량부의 함량으로 포함하는 것이 바람직하다.The anaerobic fermentation material is preferably included in an amount of 5 to 50 parts by weight based on 100 parts by weight of granite.
상기 게르마늄 함유 광석 분말은 평균 입자사이즈가 100 내지 500메쉬의 분말을 사용하는 것이 바람직하다.The germanium-containing ore powder is preferably a powder having an average particle size of 100 to 500 mesh.
본 발명은 수돗물에 직접 연결하여 사용할 수 있고, 물속에 용해된 미생물과 중금속 성분을 제거하면서도 유기게르마늄 성분을 동시에 공급할 수 있으므로, 산업사회의 일상생활에 지친 현대인들에게 면역력 및 생명력이 넘치는 신선한 물을 공급할 수 있는 장점이 있다.The present invention can be used by directly connecting to tap water, and can simultaneously supply organic germanium while removing microorganisms and heavy metals dissolved in the water, providing fresh water full of immunity and vitality to modern people tired of daily life in the industrial society. There is an advantage to supply.
본 발명은 물의 정수 중에 유기게르마늄을 물속으로 용출시킬 수 있도록 하기 위해, 화강암 등의 천연 광석으로부터 유기게르마늄을 제조하는 방법을 제공하고자 한다. The present invention is to provide a method for producing an organic germanium from natural ores such as granite in order to be able to elute the organic germanium in water in the purified water.
이를 위해, 본 발명은 게르마늄을 함유하는 천연광석을 발효시켜 유기게르마늄으로 전환시키고, 이를 필터소재로 포함시킴으로써 정수과정에서 유기게르마늄을 물에 용출시킬 수 있게 하는 것이다.To this end, the present invention is to ferment the natural ore containing germanium to be converted to organic germanium, it is possible to elute the organic germanium in water in the water purification process by including it as a filter material.
이를 위해, 본 발명은 게르마늄 공급원으로서 천연광석을 사용한다. 상기 천연광석으로는 게르마늄을 함유하는 것이라면 특별히 한정하지 않고, 본 발명에서 적합하게 사용될 수 있다. 이러한 게르마늄 함유 광석으로는 예를 들면, 화강암을 적합하게 사용할 수 있다. To this end, the present invention uses natural ore as a source of germanium. The natural ore is not particularly limited as long as it contains germanium, and may be suitably used in the present invention. As such germanium containing ore, granite can be used suitably, for example.
상기 게르마늄 함유 광석은 분쇄하여 사용하는 것이 바람직하다. 본 발명은 광석 중에 포함된 게르마늄을 발효시키고자 하는 것으로서, 상기 게르마늄의 원활한 발효를 위해서는 상기 게르마늄 함유 광석을 분쇄하여 사용하는 것이 바람직하다. It is preferable to grind and use the said germanium containing ore. The present invention is intended to ferment the germanium contained in the ore, it is preferable to use the germanium-containing ore pulverized for the smooth fermentation of the germanium.
상기 광석의 분쇄는 특별히 한정하지 않으나, 평균 입자사이즈 100 내지 500메쉬의 사이즈로 분쇄하는 것이 바람직하다. 광석의 입자 사이즈가 작을수록 발효에는 보다 바람직하지만, 분쇄에 많은 노력과 비용이 소모되어 바람직하지 않다. 또한, 분쇄된 광석의 입자 사이즈가 크면 발효 효율이 저하되고, 발효에 보다 많은 시간이 소요되어 바람직하지 않다. 따라서, 상기 범위 내의 입자 사이즈를 갖도록 광석을 분쇄하는 것이 보다 바람직하다.Although the grinding of the ore is not particularly limited, it is preferable to grind to an average particle size of 100 to 500 mesh. The smaller the particle size of the ore is, the more preferable it is for fermentation, but it is not preferable because much effort and cost are consumed for grinding. In addition, if the particle size of the crushed ore is large, the fermentation efficiency is lowered, and the fermentation takes more time and is not preferable. Therefore, it is more preferable to grind the ore to have a particle size within the above range.
상기 분쇄된 광석 분말에 발효물질을 첨가하여 혼합한 후 발효시키는 단계를 포함한다. 상기 발효물질은 광석 중에 포함된 게르마늄을 유기 게르마늄으로 변화시킬 수 있는 것이라면 특별히 한정하지 않으나, 혐기성 발효물질(혐기성 균)로서, 예를 들면, 생이스트, 활성 건조이스트 및 인스턴트 이스트 등을 들 수 있다. 이들은 단독으로 사용할 수 있음은 물론, 2 이상을 혼합하여 사용할 수도 있다.And adding fermentation material to the pulverized ore powder, followed by mixing. The fermentation material is not particularly limited as long as it can change the germanium contained in the ore to organic germanium, but as an anaerobic fermentation material (anaerobic bacteria), for example, live yeast, active dry yeast and instant yeast . These can be used independently, of course, can also be used in mixture of 2 or more.
상기 혐기성 발효물질은 예를 들면, 상기 게르마늄 함유 광석 100중량부에 대하여 5 내지 50중량부의 함량으로 첨가하는 것이 바람직하다. 혐기성 발효물질을 5중량부 미만으로 포함하는 경우에는 광석 내에 포함된 게르마늄을 충분히 발효시킬 수 없으며, 50중량부를 초과하여 포함하더라도 추가적인 발효 효과 향상에는 기여하지 못한다. 보다 바람직하게는 5 내지 20중량부의 함량으로 포함할 수 있다. The anaerobic fermentation material is preferably added in an amount of 5 to 50 parts by weight based on 100 parts by weight of the germanium-containing ore. When it contains less than 5 parts by weight of anaerobic fermentation materials, germanium contained in the ore can not be sufficiently fermented, even if it contains more than 50 parts by weight does not contribute to the improvement of further fermentation effect. More preferably, it may be included in an amount of 5 to 20 parts by weight.
상기 분쇄된 광석에 상기 발효물질을 첨가하여 혼합한 후 40 내지 60℃의 온도에서 6 내지 15일 동안 유지하여 발효시킨다. 상기와 같은 온도 및 시간 조건하에서 발효를 수행하는 것이 광석 내에 존재하는 게르마늄을 발효시켜 유기 게르마늄을 생성하는데 바람직하다. 특히, 40℃ 미만의 온도에서는 혐기성 균의 생장이 활발하지 못하며, 60℃ 이상에서는 혐기성 균이 죽어 발효되지 못하게 된다. After the fermentation material is added to the crushed ore and mixed, the fermentation material is maintained at a temperature of 40 to 60 ° C. for 6 to 15 days. It is preferable to carry out the fermentation under the above temperature and time conditions to ferment the germanium present in the ore to produce organic germanium. In particular, the growth of anaerobic bacteria is less active at a temperature below 40 ℃, and anaerobic bacteria die at 60 ℃ or more can not be fermented.
이와 같은 발효과정에 의해 광석 중의 게르마늄이 발효물질에 의해 발효되어 유기게르마늄으로 변화된다. 이러한 유기게르마늄은 예를 들어, 필터 중에 포함된 경우 유기게르마늄이 정수 과정에서 용출되어 유기게르마늄 함유수를 제공할 수 있다. By such fermentation process, germanium in the ore is fermented by fermentation material and is converted into organic germanium. Such organic germanium may, for example, be contained in a filter, and the organic germanium may be eluted during the purification process to provide the organic germanium-containing water.
따라서, 상기 유기게르마늄 함유 광석을 필터 소재에 적용될 수 있다. 상기 필터 소재는 일반적으로 사용되는 것이라면 본 발명에 적합하게 사용할 수 있는 것으로서, 특별히 한정하지 않으나, 예를 들면, 부직포, 활성탄, 제올라이트, 세라믹볼, 화강암 및 천연미네랄 광석 등을 들 수 있다. Therefore, the organic germanium-containing ore may be applied to the filter material. The filter material may be suitably used in the present invention as long as it is generally used, but is not particularly limited, and examples thereof include nonwoven fabrics, activated carbon, zeolites, ceramic balls, granite, and natural mineral ores.
상기와 같은 필터 소재에 대하여 유기게르마늄 함유 광석을 적용함에 있어서는, 예를 들어, 필터 카트리지 내에 다공성 기재와 함께 충진하거나, 하나의 다공성 기재상에 유기게르마늄을 분산시키고 그 위에 다른 다공성 기재를 적층하는 방법을 반복함으로써 수행할 수 있으며, 활성탄의 기공 내에 유기 게르마늄 함유 광석을 내재시키는 방법에 의해 필터를 제조할 수 있다.In applying the organogermanium-containing ore to the filter material as described above, for example, a method of filling with a porous substrate in a filter cartridge, or dispersing the organic germanium on one porous substrate and laminating another porous substrate thereon. It can be carried out by repeating, and the filter can be prepared by a method of embedding the organic germanium-containing ore in the pores of the activated carbon.
이때, 필요에 따라서는 상기 유기게르마늄은 바인더에 분산시킨 후 상기 필터 소재 표면에 도포하는 등의 방법으로 적용할 수도 있다. 이외에 다양한 공지의 방법을 적용할 수도 있다.At this time, if necessary, the organic germanium may be applied by a method such as dispersing in a binder and then applying to the surface of the filter material. In addition, various known methods may be applied.
상기와 같은 방법으로 필터 소재 표면에 유기게르마늄 함유 광석이 담지된 유기게르마늄 용출성 필터를 얻을 수 있으며, 상기 필터에 의해 정수 과정에서 유기게르마늄이 용출되어, 유기게르마늄 함유수를 제공할 수 있다. 이와 같은 게르마늄 함유수를 음용함으로써 게르마늄으로 인한 유익한 효과를 얻을 수 있다. In the same manner as above, an organic germanium-elutable filter on which an organic germanium-containing ore is supported on the surface of the filter material may be obtained, and the organic germanium may be eluted in the purification process by the filter to provide an organic germanium-containing water. By drinking such germanium-containing water, the beneficial effect of germanium can be obtained.
현대인은 누구나 공해, 스트레스, 과음, 과식, 과로 등으로 인해 체질이 쉽게 산성화될 뿐 아니라 성인병에 걸리기 쉽게 되는데, 이와 같은 현대사회에서 본 발명에서 제공되는 게르마늄 함유수를 음용함으로써 게르마늄을 섭취할 수 있게 되어 건강에 유익한 효과를 얻을 수 있다. 예를 들어, 체질이 산성화될 때 발생한 수소이온을 중화시키는 것이 산소인데, 본 발명의 유기게르마늄 함유 수를 음용하면 체액을 정상적인 알칼리성으로 회복시켜 줄 수 있다.Anyone in modern times is not only acidified easily due to pollution, stress, heavy drinking, overeating, and overwork, but is also susceptible to adult diseases. In such a modern society, germanium can be ingested by drinking water containing germanium provided in the present invention. It can be beneficial to your health. For example, it is oxygen to neutralize the hydrogen ions generated when the constitution is acidified, and drinking the organic germanium-containing water of the present invention can restore the body fluid to normal alkalinity.
실시예Example
이하, 본 발명을 실시예를 들어 보다 구체적으로 설명한다. 이하의 실시예는 본 발명의 구체적인 실시태양을 나타내는 것으로서, 이에 의해 본 발명을 한정하고자 하는 것은 아니다. Hereinafter, an Example is given and this invention is demonstrated more concretely. The following examples illustrate specific embodiments of the present invention and are not intended to limit the present invention.
실시예Example 1 One
화강암 400g을 입자사이즈가 200 내지 400메쉬로 되도록 분쇄하였다. 400 g of granite was ground to a particle size of 200 to 400 mesh.
상기 분쇄된 화강암 분말에 혐기성 발효물질 35g 첨가하여 균질하게 섞이도록 60분간 교반하였다. To the crushed granite powder was added 35 g of anaerobic fermentation material and stirred for 60 minutes to mix homogeneously.
이어 상기 화강암과 혐기성 발효물질의 혼합물을 반응기 내에 넣고, 36 내지 40℃ 범위 내에서 15일 동안 유지하여 발효시켰다. Subsequently, the mixture of the granite and anaerobic fermentation material was placed in a reactor and kept in a range of 36 to 40 ° C. for 15 days for fermentation.
상기 유기게르마늄이 함유된 화강암 분말을 부직포 기재에 균질하게 담지시켜 필터를 제조한 후, 상기 필터를 통해 물(Ge 미검출)을 통과시켰다. The granite powder containing the organic germanium was homogeneously supported on a nonwoven substrate to prepare a filter, and then water (Ge not detected) was passed through the filter.
상기 필터를 통과한 후의 물의 성분을 분석하였다. 상기 분석은 상기 필터를 최초로 통과한 물 10리터(처음 필터 통과수)에 대하여 수행하였으며, 또한 물 3650리터를 처리한 후에 상기 필터를 통과한 물 10리터(3650L 통과수)에 대하여 수행하였다. (이는 4인 가족 기준으로 하루에 10리터의 물을 사용하는 것을 가정하여, 1년 후에 필터의 성능을 평가하기 위한 것이다.) The water component after passing through the filter was analyzed. The analysis was performed on 10 liters of water that passed through the filter for the first time (first filter pass water) and 10 liters of water that passed through the filter (3650L pass water) after treating 3650 liters of water. (This is to evaluate the performance of the filter after one year, assuming 10 liters of water per day for a family of four.)
그 평가 결과를 아래의 표 1에 나타내었다.The evaluation results are shown in Table 1 below.
상기 표 1로부터 알 수 있는 바와 같이, Ge가 미검출된 물 속에 게르마늄이 검출되었으며, 3650L의 물을 필터링한 후에도 물속에 100ppb가 검출되어, 게르마늄 용출 성능을 장기간 유지할 수 있음을 알 수 있었다.As can be seen from Table 1, germanium was detected in Ge-undetected water, and 100ppb was detected in water even after filtering 3650L of water, indicating that the germanium elution performance could be maintained for a long time.
나아가, 상기 표 1로부터, 일반적으로 물속에는 포함되지 않는 Se, La, Cr 등의 성분도 미량 검출되는 결과로부터, 본 발명에 따르면, Ge 이외의 금속 성분도 함께 용출되어 인체에 유용한 효과를 제공할 수 있는 물을 얻을 수 있다.Furthermore, according to the present invention, from Table 1, trace amounts of components such as Se, La, Cr, etc., which are not generally included in water, are also detected. According to the present invention, metal components other than Ge may also be eluted together to provide useful effects to the human body. You can get water.
Claims (5)
상기 천연 화강암 중의 게르마늄이 유기게르마늄으로 변화된 천연 화강암 분말을 부직포 기재에 담지시켜 필터를 제조하는 단계; 및
상기 필터를 정수필터로 사용하여 유기게르마늄이 용출된 물을 얻는 단계로 이루어진 천연 화강암을 이용한 정수방법.
Mixing the anaerobic fermentation material with germanium-containing granite powder and maintaining it at a temperature of 40 to 60 ° C. for 6 to 15 days to convert the germanium in natural granite into organic germanium;
Preparing a filter by supporting a natural granite powder in which germanium in the natural granite is converted to organic germanium on a nonwoven substrate; And
The water purification method using natural granite consisting of using the filter as a water filter to obtain water eluted organic germanium.
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