JP3040097B2 - Contact purification material and method for producing the same - Google Patents

Contact purification material and method for producing the same

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Publication number
JP3040097B2
JP3040097B2 JP10294776A JP29477698A JP3040097B2 JP 3040097 B2 JP3040097 B2 JP 3040097B2 JP 10294776 A JP10294776 A JP 10294776A JP 29477698 A JP29477698 A JP 29477698A JP 3040097 B2 JP3040097 B2 JP 3040097B2
Authority
JP
Japan
Prior art keywords
volcanic ash
diatomaceous earth
andosol
contact
ash
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP10294776A
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Japanese (ja)
Other versions
JP2000117020A (en
Inventor
艮一 小松
Original Assignee
艮一 小松
小松 玲子
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Filing date
Publication date
Application filed by 艮一 小松, 小松 玲子 filed Critical 艮一 小松
Priority to JP10294776A priority Critical patent/JP3040097B2/en
Publication of JP2000117020A publication Critical patent/JP2000117020A/en
Application granted granted Critical
Publication of JP3040097B2 publication Critical patent/JP3040097B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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  • Biological Treatment Of Waste Water (AREA)
  • Filtering Materials (AREA)
  • Water Treatment By Sorption (AREA)
  • Porous Artificial Stone Or Porous Ceramic Products (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は接触浄化材及びその
製造方法に関し、特にはし尿,汚水,生活排水,工業排
水,河川,池その他の汚水浄化装置や飲料水や工業用水
の浄化装置において使用する濾材としての新規な接触浄
化材及びその製造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a contact purification material and a method for producing the same, and more particularly to a purification device for human waste, sewage, domestic wastewater, industrial wastewater, rivers, ponds and other sewage, and drinking water and industrial water. The present invention relates to a novel contact purifying material as a filtering material to be produced and a method for producing the same.

【0002】[0002]

【従来の技術】全ての企業施設からは量の多寡を問わず
工場排水や浄化槽排水が発生するが、これをそのまま河
川に放流すると、該河川及び地下水が汚染されて地域環
境を悪化させてしまう。そのため各企業にとって効果が
高く、かつ、環境に優しい汚水浄水装置を装備すること
が吃緊の課題となっている。また、家庭用浄化槽や家庭
用排水に起因する河川等の汚染も深刻な問題となってい
る。
2. Description of the Related Art Wastewater from factories and septic tanks is generated from all corporate facilities irrespective of the quantity, but if discharged directly into rivers, the rivers and groundwater will be polluted and the local environment will be deteriorated. . Therefore, it is an urgent task for each company to equip the sewage water purification equipment that is highly effective and environmentally friendly. Pollution of rivers and the like caused by domestic septic tanks and domestic wastewater is also a serious problem.

【0003】従来この種の汚水浄化装置において使用す
る接触浄化材としてはハニカム状の構成を有する化学製
品が主流となっており、これに加えて近時は天然鉱石等
を使用した接触浄化材も提供され始め、その効果は向上
しつつある。
[0003] Conventionally, as a contact purifying material used in this type of sewage purifying apparatus, a chemical product having a honeycomb-like configuration has been mainly used, and recently, a contact purifying material using natural ore or the like has recently been used. Began to be offered and its effectiveness is improving.

【0004】[0004]

【発明が解決しようとする課題】これらの接触浄化材は
汚水中の汚濁物質を接触浄化材に付着させた微生物によ
る生物処理で分解し、汚水を無機物質に還元するもので
ある。そのため、微生物によって消化還元された有害な
無機物質はそのまま放流されているのが現状である。そ
のため、地域の河川や地下水、海、湖等に流入するアン
モニア性窒素、燐、ダイオキシン、トリハロメタン等の
有害な無機物質は年々増加し、河川等の富栄養化が進
み、無機物質による環境汚染は悪化する一方である。
These contact purifying materials decompose pollutants in sewage by biological treatment with microorganisms attached to the contact purifying materials, and reduce the sewage to inorganic substances. Therefore, at present, harmful inorganic substances digested and reduced by microorganisms are discharged as they are. As a result, harmful inorganic substances such as ammonia nitrogen, phosphorus, dioxin, and trihalomethane that flow into local rivers, groundwater, seas, and lakes increase year by year, and eutrophication of rivers and other substances progresses. It is getting worse.

【0005】なお、汚水浄化装置からの処理水中のアン
モニア性窒素や燐等の無機物質を化学薬品を使用した
り、活性炭による濾過等によって除去する試みも行われ
ているが、使用する化学薬品による二次公害や活性炭濾
過による製作費や清掃維持費用等のイニシアルコストの
増加を来しており、有効な解決策となっていない。
Attempts have been made to remove inorganic substances, such as ammoniacal nitrogen and phosphorus, in the treated water from the sewage purification system by using chemicals or by filtering with activated carbon. Initial costs such as secondary pollution and manufacturing costs due to activated carbon filtration and cleaning and maintenance costs are increasing, and are not an effective solution.

【0006】一方汚水の処理にとどまらず、積極的にき
れいなおいしい水を求める動きも活発である。例えば、
食品工場とか酒造、飲料水のメーカーにとって良質の水
源を確保することが商品の品質を高める上で不可欠であ
り、そのための種々の手段が講じられている。更に、一
般の家庭、特に都市部では飲料水がまずいことが従来か
ら指摘されており、おいしい水を容易に得ることが強く
要望されている。また、飲料水のみならず養魚場やプー
ルの水の浄化にも大きな関心が払われている。
On the other hand, there is an active movement to pursue not only sewage treatment but also clean and delicious water. For example,
It is indispensable for food factories, sake brewers and drinking water manufacturers to secure high quality water sources in order to improve the quality of their products, and various measures have been taken to achieve this. Furthermore, it has been pointed out that drinking water is poor in ordinary households, especially in urban areas, and there is a strong demand for easily obtaining delicious water. There is also a great deal of interest in purifying fish farms and pool water as well as drinking water.

【0007】これらの水の浄化に関する問題について
は、将来にわたる生活環境問題を考慮すると、自然界に
存在する天然の原料を用いることが望ましい。そこで、
本発明はし尿,汚水,生活排水,工業排水,河川,池そ
の他の汚水浄化装置や飲料水や工業用水の浄化装置にお
いて使用する濾材としての新規な接触浄化材及びその製
造方法を提供することを課題とするものである。
[0007] Regarding these water purification problems, it is desirable to use natural raw materials that exist in nature in consideration of future living environment problems. Therefore,
The present invention is to provide a novel contact purifying material as a filter material used in human waste, sewage, domestic effluent, industrial effluent, rivers, ponds and other sewage purifying apparatuses, drinking water and industrial water purifying apparatuses, and a method for producing the same. It is an issue.

【0008】[0008]

【課題を解決するための手段】本発明は上記課題を解決
するために、粉砕した黒ボク土、或は粉砕した珪藻土と
黒ボク土を混合したものに火山灰と必要量の水を加えて
混練したものを焼成することにより、火山灰中のガラス
質を溶解させて多孔質としたものを所定の粒状又は塊状
に割砕してなる接触浄化材を提供する。また、黒ボク
、或は珪藻土と黒ボク土を混合したものを所定の粒度
に粉砕し、該粉砕した黒ボク土、或は珪藻土と黒ボク土
を混合したものに火山灰と必要量の水を加えて混練した
ものを乾燥させ、その後に焼成固化させることにより、
火山灰中のガラス質を溶解させて多孔質としたものを所
定の粒状又は塊状に割砕してなる接触浄化材の製造方法
を提供する。そして、珪藻土と黒ボク土を1:1〜2:
1の割合で混合した手段を提供する。
SUMMARY OF THE INVENTION The present invention is to solve the above problems, andosol obtained by pulverizing, or by adding water of volcanic ash and the required amount of a mixture of crushed diatomite and black soil kneading by fired ones, those with a porous by dissolving the glassy in ash predetermined grains or clusters
Provide a contact purifying material that is broken into pieces . Also, I
Soil, or a mixture of diatomaceous earth and black soil and ground to a predetermined particle size, andosol that the milled, or by adding water of volcanic ash and the required amount of a mixture of diatomaceous earth and black soil kneading By drying and then firing and solidifying,
Tokoro those by dissolving the glassy in ash and porous
Provided is a method for producing a contact purifying material which is crushed into a specific particle or lump . And the diatomaceous earth and the ando clay are 1: 1 to 2:
A means of mixing at a ratio of 1 is provided.

【0009】上記した本発明によれば、焼成することに
よって火山灰中のガラス質を溶解させることができるた
め、従来困難であった汚水の浄化効果の高い天然鉱物で
ある珪藻土や黒ボク土を原料とする多孔質の接触浄化材
を得ることができる。また、溶解した火山灰の成分が珪
藻土や黒ボク土の粒子間に浸透する。そのため、微生物
による汚水の浄化は勿論、微生物によって消化還元され
た有害な無機物質であるアンモニア性窒素や燐等の無機
物質を吸着することができる。更に、汚水の浄化のみな
らず、飲料水等の濾過材としても効果が大きい。
According to the present invention described above, the vitreous in the volcanic ash can be dissolved by firing, so that diatomaceous earth and black ande soil, which are natural minerals having a high purification effect of sewage, which has been difficult in the past, are used as raw materials. Porous contact purifying material can be obtained. In addition, the dissolved volcanic ash components penetrate between the particles of diatomaceous earth and andosol. Therefore, it is possible to adsorb inorganic substances such as ammonia nitrogen and phosphorus, which are harmful inorganic substances digested and reduced by microorganisms, as well as purification of wastewater by microorganisms. Further, it is not only effective in purifying sewage, but also has a great effect as a filtering material for drinking water and the like.

【0010】[0010]

【発明の実施の形態】以下、本発明にかかる接触浄化材
及びその製造方法の実施の形態を説明する。本発明は粉
砕した天然鉱物に火山灰と必要量の水を加えて混練した
ものを焼成することにより、火山灰中のガラス質を溶解
させて多孔質としたことに特徴を有する。天然鉱物とし
ては浄化作用を有するものであれば特に限定はないが、
珪藻土及び黒ボク土が汚水の浄化効果が高くて適当であ
り、この珪藻土と黒ボク土を単独又は混合して使用す
る。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, embodiments of a contact purifying material and a method for producing the same according to the present invention will be described. The present invention is characterized in that, by adding a volcanic ash and a required amount of water to a crushed natural mineral and kneading the resulting mixture, the glassy material in the volcanic ash is dissolved to make it porous. There is no particular limitation as long as it has a purifying action as a natural mineral,
Diatomaceous earth and Andosol are suitable because they have a high purification effect of sewage, and these diatomaceous earth and Andosol are used alone or in combination.

【0011】珪藻土や黒ボク土は従来より汚水等の浄化
効果が高いことは周知であるが、接触浄化材として不純
物を除去し、多孔質に成形することが困難であった。そ
のため、珪藻土や黒ボク土に粘着性の高い粘土を混合し
焼成することも行われてきたが、賦形のために混合する
粘土によって投機状となり通気性がなく、微生物の生存
に好適で、かつ、吸着能力を有する多孔質のものを得る
ことができなかった。本発明は火山灰を混合して焼成す
ることにより、珪藻土及び/又は黒ボク土を原料として
多孔質の接触浄化材を得ることに特徴を有する。
Although it is well known that diatomaceous earth and andosol have a higher purification effect on sewage and the like than before, it has been difficult to remove impurities as a contact purification material and to form the porous material. For this reason, diatomaceous earth and andosol have been mixed with highly viscous clay and fired, but the clay mixed for shaping becomes speculative and has no air permeability, suitable for the survival of microorganisms, Moreover, a porous material having an adsorption ability could not be obtained. The present invention is characterized in that by mixing and firing volcanic ash, a porous contact purification material is obtained from diatomaceous earth and / or andosol.

【0012】珪藻土は主として珪藻の殻で出来ている淡
色軟質のケイ酸質岩であり、高い吸着能力を有してい
る。原料である珪藻類はプランクトンの二大重要群であ
り、タンパク石質の小殻が2枚組み合って出来た単細胞
藻類であり、これが遺殻となって堆積して軟質岩石又は
粘土として形成されるものである。珪藻土には海成種の
ものと淡水性のものがあり、淡水性のものが品質的に優
れている。純粋な珪藻殻は二酸化珪素94%、水6%で
あるが、天然の珪藻土は不純物を含むため、成分も産地
によって異なってくる。本発明で使用した珪藻土の成分
表を表1に示す。
Diatomaceous earth is a light-colored soft siliceous rock mainly made of diatom shells and has a high adsorption capacity. The diatoms that are the raw materials are the two most important groups of plankton, unicellular algae made by combining two proteinaceous small shells, which are deposited as remains and formed as soft rocks or clay Things. Diatomaceous earth includes marine species and freshwater ones, and freshwater ones are superior in quality. Pure diatom shells are 94% silicon dioxide and 6% water, but natural diatomaceous earth contains impurities, so its components also differ depending on the place of origin. Table 1 shows a composition table of the diatomaceous earth used in the present invention.

【0013】[0013]

【表1】 [Table 1]

【0014】黒ボク土は腐植に富む黒くて膨軟な表層土
を持つ土壌であって、二酸化珪素と酸化アルミニウムを
主成分とする。この黒ボク土は我が国土の約15%を占
めるものであり、約1億年前に火山から噴出した軟質火
山灰が地球上の繁茂したカヤ類等の植物上に厚く降下
し、約5000年以上埋没している間に植物は加水分解
を起こして微酸性の黒色のフミン酸質に変化したもので
ある。本発明で使用した黒ボク土の成分表を表2に示
す。
[0014] Ando soil is a soil having a humus-rich, black and soft surface soil, and contains silicon dioxide and aluminum oxide as main components. This Ando soil occupies about 15% of Japan's land, and soft volcanic ash erupted from a volcano about 100 million years ago thickly drops on overgrown kayaks and other vegetation on the earth, and it has been about 5000 years or more. During burial, the plant undergoes hydrolysis and changes to a slightly acidic black humic substance. Table 2 shows a composition table of the Andosol used in the present invention.

【0015】[0015]

【表2】 [Table 2]

【0016】火山灰は火山噴出物の一種であり、噴出す
る岩石が砕けた粒径4mm以下のものとなっており、そ
の成分も多様であるが、本発明では珪藻土及び黒ボク土
の凝固接着のために使用するものであり、具体的には鹿
児島県産のシラスを使用する。本発明で使用した火山灰
としてのシラスの成分表を表3に示す。
[0016] Volcanic ash is a kind of volcanic eruption product, and the erupting rock has a crushed particle size of 4 mm or less and various components. For this purpose, Shirasu from Kagoshima Prefecture is used. Table 3 shows a composition table of shirasu as volcanic ash used in the present invention.

【0017】[0017]

【表3】 [Table 3]

【0018】これらの珪藻土及び黒ボク土を適宜の粒径
に粉砕する。粒径は特に限定はないが、好ましくは火山
灰の粒径4mmと同程度のものが好ましい。まず、これ
らの珪藻土及び黒ボク土を単独で或いは両者を混合した
ものを火山灰と混合し、適宜の水を加えて成形する。成
形は乾燥を容易とするため、板状とすることが適当であ
る。この成形品を乾燥させた後に焼成する。焼成手段は
限定ないが、1200℃以上の温度で焼成することが必
要である。1200℃以上で焼成することにより、火山
灰中のガラス質が溶解して多孔質となるためである。そ
のため、焼成時間も火山灰中のガラス質が溶解するのに
十分な時間、具体的には3〜4時間焼成することが適当
である。そして、焼成後に十分に熱が下がった後に所定
の粒状又は塊状に割砕して多孔質の接触浄化材を得る。
The diatomaceous earth and the andosol are ground to an appropriate particle size. The particle size is not particularly limited, but is preferably approximately the same as the volcanic ash particle size of 4 mm. First, these diatomaceous earths and an orchard earth alone or a mixture of both are mixed with volcanic ash and formed by adding appropriate water. In order to facilitate drying, it is appropriate to form a plate. After the molded article is dried, it is fired. The firing means is not limited, but firing at 1200 ° C. or higher is required. By firing at 1200 ° C. or more, the glassy material in the volcanic ash is dissolved to become porous. Therefore, it is appropriate that the firing time is sufficient for the glassy in the volcanic ash to be melted, specifically, firing for 3 to 4 hours. Then, after the heat is sufficiently reduced after firing, the powder is broken into predetermined granules or blocks to obtain a porous contact purifying material.

【0019】得られた接触浄化材は珪藻土及び/又は黒
ボク土を原料とし、かつ、多孔質のものである。よっ
て、汚水浄化のための微生物の生存に好適であると共
に、接触浄化材そのものが高い吸着作用を有し、微生物
によって消化還元された有害な無機物質を吸着除去する
ことができる。また、飲料水等の浄化に使用しても好適
である。更に、脱臭効果をも有しており、悪臭物質であ
るアンモニアメチルカプタン、硫化水素、硫化メチル等
を吸着して脱臭することができる。なお、使用する汚水
浄化装置等は従来のものを使用することができ、従来の
接触材に代えて本発明に係る接触浄化材を使用すればよ
い。更に本発明にかかる接触浄化材を汚水タンク、飲料
水タンクや容器等に適量投入しておくだけでもよい。
The obtained catalytic purifying material is made of diatomaceous earth and / or andosol and is porous. Therefore, while being suitable for the survival of microorganisms for sewage purification, the contact purification material itself has a high adsorption action, and can adsorb and remove harmful inorganic substances digested and reduced by microorganisms. It is also suitable for use in purifying drinking water and the like. Further, it also has a deodorizing effect, and can deodorize by adsorbing malodorous substances such as ammonia methyl captan, hydrogen sulfide, methyl sulfide and the like. In addition, a conventional sewage purification device or the like can be used, and the contact purification material according to the present invention may be used instead of the conventional contact material. Furthermore, the contact purifying material according to the present invention may be merely charged into a sewage tank, a drinking water tank, a container, or the like in an appropriate amount.

【0020】[0020]

【実施例】粉砕した珪藻土及び黒ボク土と火山灰を1.
5:1:1の割合で混合し、これに適量の水を加えて混
ぜ合わせ、圧縮機で板状にプレスした。これを火力或い
は天火にて乾燥させ、乾燥させたものを焼成機で3〜4
時間、1200℃以上の温度で焼成した。そして、十分
に熱が下がった後に所定の粒状又は塊状に割砕して多孔
質の接触浄化材を得た。
EXAMPLES Example 1 Ground diatomaceous earth and andosol and volcanic ash were used.
The mixture was mixed at a ratio of 5: 1: 1, an appropriate amount of water was added thereto, mixed, and pressed into a plate by a compressor. This is dried by heat or sky, and the dried product is fired in a baking machine for 3 to 4 times.
Firing was performed at a temperature of 1200 ° C. or more for a time. Then, after the heat was sufficiently reduced, it was broken into predetermined granules or blocks to obtain a porous contact purifying material.

【0021】得られた接触浄化材は1200℃以上の高
温で焼成することによって、火山灰中のガラス質が溶解
して多孔質となるとともに、その溶解成分が珪藻土や黒
ボク土の成分間に浸透して固化する。また、珪藻土や黒
ボク土の不純物も焼成によって除去されるため、吸着性
と通気性に優れた溶岩状の組成となる。得られた接触浄
化材の成分を表4に示す。
The obtained contact purifying material is fired at a high temperature of 1200 ° C. or more, whereby the vitreous material in the volcanic ash is dissolved to become porous, and the dissolved component penetrates between the components of diatomaceous earth and andosol. And solidify. In addition, since impurities in diatomaceous earth and andosol are also removed by firing, a lava-like composition having excellent adsorptivity and air permeability is obtained. Table 4 shows the components of the obtained contact purification material.

【0022】[0022]

【表4】 [Table 4]

【0023】この得られた接触浄化材25cm3を総有
効量50cm3の浄化装置内に充填し、河川の水(環境
水)を1日の処理水2.8m3として毎分2cm3の割合
で通過させて処理した結果を表5に示す。表5に示すよ
うに顕著な浄化効果を有している。
25 cm 3 of the obtained contact purification material was filled in a purification device having a total effective amount of 50 cm 3 , and the river water (environmental water) was treated as 2.8 m 3 of treated water per day at a rate of 2 cm 3 per minute. Table 5 shows the results of processing by passing through. As shown in Table 5, it has a remarkable purification effect.

【0024】[0024]

【表5】 [Table 5]

【0025】[0025]

【発明の効果】以上記載した本発明にかかる接触浄化材
及びその製造方法によれば、生物の遺骸である珪藻土及
び/又は腐植土である黒ボク土に火山灰を混合して焼成
することにより、火山灰中のガラス質が溶解して多孔質
となるとともに、溶解した火山灰の成分が珪藻土や黒ボ
ク土の粒子間に浸透する。そのため、原料中の成分であ
る陽イオン物質が陰イオン物質に反応して電磁エネルギ
ーとなりアンモニア性窒素、燐等の有害な無機物質を吸
着することとなる。よって、汚水浄化のための微生物の
生存に好適であると共に、接触浄化材そのものが高い吸
着作用を有し、微生物によって消化還元された有害な無
機物質を吸着除去することができる。また、飲料水等の
浄化に使用しても好適である。更に、脱臭効果をも有し
ており、悪臭物質であるアンモニアメチルカプタン、硫
化水素、硫化メチル等を吸着して脱臭することができ
る。なお、使用する汚水浄化装置等は従来のものを使用
することができ、従来の接触材に代えて本発明に係る接
触浄化材を使用すればよい。更に本発明にかかる接触浄
化材を汚水タンク、飲料水タンクや容器等に適量投入し
ておくだけでもよい。
According to the contact purifying material and the method for producing the same according to the present invention described above, volcanic ash is mixed with diatomaceous earth, which is the remains of living organisms, and / or black soil, which is humus, and fired. The vitreous material in the volcanic ash melts and becomes porous, and the dissolved volcanic ash component penetrates between the particles of diatomaceous earth and andosol. Therefore, the cation substance, which is a component in the raw material, reacts with the anion substance to become electromagnetic energy, thereby adsorbing harmful inorganic substances such as ammoniacal nitrogen and phosphorus. Therefore, while being suitable for the survival of microorganisms for sewage purification, the contact purification material itself has a high adsorption action, and can adsorb and remove harmful inorganic substances digested and reduced by microorganisms. It is also suitable for use in purifying drinking water and the like. Further, it also has a deodorizing effect, and can deodorize by adsorbing malodorous substances such as ammonia methyl captan, hydrogen sulfide, methyl sulfide and the like. In addition, a conventional sewage purification device or the like can be used, and the contact purification material according to the present invention may be used instead of the conventional contact material. Furthermore, the contact purifying material according to the present invention may be merely charged into a sewage tank, a drinking water tank, a container, or the like in an appropriate amount.

───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.7,DB名) C02F 3/10 C02F 1/28 JICSTファイル(JOIS)──────────────────────────────────────────────────続 き Continued on the front page (58) Field surveyed (Int.Cl. 7 , DB name) C02F 3/10 C02F 1/28 JICST file (JOIS)

Claims (6)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 粉砕した黒ボク土に火山灰と必要量の水
を加えて混練したものを焼成することにより、火山灰中
のガラス質を溶解させて多孔質とするとともに溶解した
火山灰の成分を黒ボク土の粒子間に浸透させたものを所
定の粒状又は塊状に割砕してなることを特徴とする接触
浄化材。
1. A by adding water ash and the required amount of Andisol obtained by pulverizing fired those kneaded in Ash
Dissolved the vitreous and made it porous
The thing where the component of volcanic ash was infiltrated between the particles of Andosol
A contact purifying material characterized by being broken into fixed particles or blocks .
【請求項2】 粉砕した珪藻土及び黒ボク土に火山灰と
必要量の水を加えて混練したものを焼成することによ
り、火山灰中のガラス質を溶解させて多孔質とするとと
もに溶解した火山灰の成分を珪藻土及び黒ボク土の粒子
間に浸透させたものを所定の粒状又は塊状に割砕してな
ることを特徴とする接触浄化材。
2. A method in which volcanic ash and a required amount of water are added to a crushed diatomaceous earth and an orchard earth and kneaded, followed by firing, whereby glassy in the volcanic ash is dissolved to make it porous.
Dissolved volcanic ash components in diatomaceous earth and andosol particles
Do not crush the material that has been infiltrated into
A contact purifying material , characterized in that:
【請求項3】 珪藻土と黒ボク土を1:1〜2:1の割
合で混合した請求項記載の接触浄化材。
3. The contact purifying material according to claim 2, wherein the diatomaceous earth and the andosol are mixed at a ratio of 1: 1 to 2: 1.
【請求項4】 ボク土を所定の粒度に粉砕し、該粉砕
た黒ボク土に火山灰と必要量の水を加えて混練したも
のを乾燥させ、その後に焼成することにより、火山灰中
のガラス質を溶解させて多孔質とするとともに溶解した
火山灰の成分を黒ボク土の粒子間に浸透させたものを所
定の粒状又は塊状に割砕することを特徴とする接触浄化
材の製造方法。
The 4. Andosols ground to a predetermined particle size, dried those kneaded by adding water ash and the required amount of Andisol that the pulverized <br/>, by firing thereafter In the volcanic ash
Dissolved the vitreous and made it porous
The thing where the component of volcanic ash was infiltrated between the particles of Andosol
A method for producing a contact purifying material, which comprises crushing into a fixed particle or lump .
【請求項5】 珪藻土及び黒ボク土を所定の粒度に粉砕
し、該粉砕した珪藻土及び黒ボク土に火山灰と必要量の
水を加えて混練したものを乾燥させ、その後に焼成する
ことにより、火山灰中のガラス質を溶解させて多孔質と
するとともに溶解した火山灰の成分を珪藻土及び黒ボク
土の粒子間に浸透させたものを所定の粒状又は塊状に割
砕することを特徴とする接触浄化材の製造方法。
5. A diatomaceous earth and an orchard ground to a predetermined particle size, a mixture obtained by adding volcanic ash and a required amount of water to the crushed diatomaceous earth and the andosol, drying the mixture, and then calcining the mixture. Dissolve glassy material in volcanic ash to make it porous
And dissolve the dissolved volcanic ash components in diatomaceous earth and
The material that has been infiltrated between the soil particles is divided into specified granules or blocks.
A method for producing a contact purifying material, comprising crushing .
【請求項6】 珪藻土と黒ボク土を1:1〜2:1の割
合で混合した請求項記載の接触浄化材の製造方法。
6. The method for producing a contact purification material according to claim 5, wherein diatomaceous earth and andosol are mixed at a ratio of 1: 1 to 2: 1.
JP10294776A 1998-10-16 1998-10-16 Contact purification material and method for producing the same Expired - Fee Related JP3040097B2 (en)

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KR20080065573A (en) * 2008-06-24 2008-07-14 박기호 Eco-friendly active natural mineral water quality improvement composition and its manufacturing method
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