KR102850983B1 - 단량체 조성물, 메타크릴계 수지 조성물 및 수지 성형체 - Google Patents

단량체 조성물, 메타크릴계 수지 조성물 및 수지 성형체

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Publication number
KR102850983B1
KR102850983B1 KR1020247006587A KR20247006587A KR102850983B1 KR 102850983 B1 KR102850983 B1 KR 102850983B1 KR 1020247006587 A KR1020247006587 A KR 1020247006587A KR 20247006587 A KR20247006587 A KR 20247006587A KR 102850983 B1 KR102850983 B1 KR 102850983B1
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South Korea
Prior art keywords
methyl
mass
composition
resin composition
methacrylic
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KR1020247006587A
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English (en)
Korean (ko)
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KR20240033122A (ko
Inventor
히로아키 이토
유스케 히라노
잇세이 다니구치
마나부 이소무라
고우이치 가네모리
Original Assignee
미쯔비시 케미컬 주식회사
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Publication of KR20240033122A publication Critical patent/KR20240033122A/ko
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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54Acrylic acid esters; Methacrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/44Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10Esters
    • C08F20/12Esters of monohydric alcohols or phenols
    • C08F20/14Methyl esters, e.g. methyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/14Methyl esters, e.g. methyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/101Esters; Ether-esters of monocarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10Homopolymers or copolymers of methacrylic acid esters
    • C08L33/12Homopolymers or copolymers of methyl methacrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/14Organic medium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
KR1020247006587A 2021-05-20 2022-05-19 단량체 조성물, 메타크릴계 수지 조성물 및 수지 성형체 Active KR102850983B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JPJP-P-2021-085291 2021-05-20
JP2021085291 2021-05-20
KR1020237043048A KR102749709B1 (ko) 2021-05-20 2022-05-19 단량체 조성물, 메타크릴계 수지 조성물 및 수지 성형체
PCT/JP2022/020784 WO2022244835A1 (ja) 2021-05-20 2022-05-19 単量体組成物、メタクリル系樹脂組成物及び樹脂成形体

Related Parent Applications (1)

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KR1020237043048A Division KR102749709B1 (ko) 2021-05-20 2022-05-19 단량체 조성물, 메타크릴계 수지 조성물 및 수지 성형체

Publications (2)

Publication Number Publication Date
KR20240033122A KR20240033122A (ko) 2024-03-12
KR102850983B1 true KR102850983B1 (ko) 2025-08-27

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KR1020247006448A Active KR102828115B1 (ko) 2021-05-20 2022-05-19 단량체 조성물, 메타크릴계 수지 조성물 및 수지 성형체
KR1020237043049A Active KR102733199B1 (ko) 2021-05-20 2022-05-19 단량체 조성물, 메타크릴계 수지 조성물 및 수지 성형체
KR1020237043047A Active KR102647117B1 (ko) 2021-05-20 2022-05-19 단량체 조성물, 메타크릴계 수지 조성물 및 수지 성형체
KR1020247006587A Active KR102850983B1 (ko) 2021-05-20 2022-05-19 단량체 조성물, 메타크릴계 수지 조성물 및 수지 성형체
KR1020237043048A Active KR102749709B1 (ko) 2021-05-20 2022-05-19 단량체 조성물, 메타크릴계 수지 조성물 및 수지 성형체

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KR1020247006448A Active KR102828115B1 (ko) 2021-05-20 2022-05-19 단량체 조성물, 메타크릴계 수지 조성물 및 수지 성형체
KR1020237043049A Active KR102733199B1 (ko) 2021-05-20 2022-05-19 단량체 조성물, 메타크릴계 수지 조성물 및 수지 성형체
KR1020237043047A Active KR102647117B1 (ko) 2021-05-20 2022-05-19 단량체 조성물, 메타크릴계 수지 조성물 및 수지 성형체

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Country Status (8)

Country Link
US (3) US20240084055A1 (enExample)
EP (3) EP4353754A4 (enExample)
JP (6) JP7318828B2 (enExample)
KR (5) KR102828115B1 (enExample)
CN (3) CN117321137A (enExample)
MX (3) MX2023013613A (enExample)
TW (6) TWI845944B (enExample)
WO (3) WO2022244835A1 (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102828115B1 (ko) * 2021-05-20 2025-07-03 미쯔비시 케미컬 주식회사 단량체 조성물, 메타크릴계 수지 조성물 및 수지 성형체
WO2023210564A1 (ja) * 2022-04-27 2023-11-02 住友化学株式会社 組成物
WO2024106530A1 (ja) * 2022-11-18 2024-05-23 三菱ケミカル株式会社 単量体組成物、樹脂組成物、樹脂組成物の製造方法、樹脂成形体及び樹脂成形体の製造方法

Family Cites Families (21)

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DE2913853A1 (de) 1979-04-06 1980-10-23 Roehm Gmbh Verfahren zum polymerisieren von methylmethacrylat
DE3004467A1 (de) * 1980-02-07 1981-08-13 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von methylmethacrylat durch umsetzung von methylpropionat und methanol
JPS579739A (en) * 1980-06-20 1982-01-19 Asahi Chem Ind Co Ltd Purification of methyl methacrylate
US4410723A (en) * 1982-08-09 1983-10-18 Ashland Oil, Inc. Oxydehydrogenation process
JPH0611732B2 (ja) * 1985-11-25 1994-02-16 三井東圧化学株式会社 メタクリル酸メチルの精製法
JPH0794506B2 (ja) * 1989-01-18 1995-10-11 株式会社クラレ 透明性に優れたメタクリル系樹脂、その樹脂組成物およびそれらの製造方法
JP2859682B2 (ja) * 1989-03-31 1999-02-17 三井化学株式会社 メタクリル酸メチルの精製方法及び製造方法
JPH11171833A (ja) * 1997-12-11 1999-06-29 Mitsubishi Rayon Co Ltd β−ヒドロキシイソ酪酸エステルの製造方法
MY122724A (en) * 1999-04-13 2006-04-29 Mitsui Chemicals Inc Method for preparing living polymer in the presence of phosphazenium salt
JP3672818B2 (ja) 2000-12-26 2005-07-20 三菱レイヨン株式会社 (メタ)アクリル酸エステルの精製方法
US7407998B2 (en) * 2004-09-28 2008-08-05 Arkema France Stabilized UV transparent acrylic composition
EP1702934B1 (en) * 2005-03-14 2015-05-06 Mitsubishi Gas Chemical Company, Inc. Method of producing hydrogenated polymers
GB0905257D0 (en) * 2009-03-27 2009-05-13 Lucite Int Uk Ltd Process for the treatment of an ion exchange resin
EP3450422A1 (de) * 2017-08-29 2019-03-06 Evonik Röhm GmbH Verfahren zur herstellung optischer formmassen
EP3798202A1 (de) * 2019-09-25 2021-03-31 Röhm GmbH Verfahren zur aufreinigung von methylmethacrylat von leichtsiedenden komponenten
JP7359667B2 (ja) 2019-11-29 2023-10-11 三和シヤッター工業株式会社 開閉体
JP6889322B1 (ja) * 2020-09-30 2021-06-18 住友化学株式会社 組成物
EP4332080A4 (en) * 2021-04-28 2025-01-22 Mitsubishi Chemical Corporation COMPOSITION CONTAINING METHYL METHACRYLATE
KR20240006654A (ko) * 2021-05-10 2024-01-15 룀 게엠베하 황색도 지수 감소 및 안정화를 위한 불포화 에스테르 함유 첨가제
KR102828115B1 (ko) * 2021-05-20 2025-07-03 미쯔비시 케미컬 주식회사 단량체 조성물, 메타크릴계 수지 조성물 및 수지 성형체
CN117355501A (zh) * 2021-11-30 2024-01-05 三菱化学株式会社 含有甲基丙烯酸甲酯的组合物、含有甲基丙烯酸甲酯的组合物的保存方法和甲基丙烯酸甲酯聚合物的制造方法

Also Published As

Publication number Publication date
JP7338797B2 (ja) 2023-09-05
KR102733199B1 (ko) 2024-11-25
WO2022244834A1 (ja) 2022-11-24
TW202302519A (zh) 2023-01-16
US20240083835A1 (en) 2024-03-14
KR102647117B1 (ko) 2024-03-14
KR20240008349A (ko) 2024-01-18
TWI845944B (zh) 2024-06-21
TWI882591B (zh) 2025-05-01
US20240084055A1 (en) 2024-03-14
EP4353779A4 (en) 2024-10-16
TWI845943B (zh) 2024-06-21
CN117321138A (zh) 2023-12-29
KR20240007271A (ko) 2024-01-16
TW202302518A (zh) 2023-01-16
TWI845945B (zh) 2024-06-21
WO2022244835A1 (ja) 2022-11-24
TWI882590B (zh) 2025-05-01
JP7318828B2 (ja) 2023-08-01
CN117321137A (zh) 2023-12-29
EP4353754A1 (en) 2024-04-17
MX2023013613A (es) 2023-11-30
KR20240033122A (ko) 2024-03-12
MX2023013617A (es) 2023-11-30
US20240158552A1 (en) 2024-05-16
KR102828115B1 (ko) 2025-07-03
EP4353775A4 (en) 2024-12-04
EP4353754A4 (en) 2024-12-04
WO2022244833A1 (ja) 2022-11-24
TWI882589B (zh) 2025-05-01
CN117412996A (zh) 2024-01-16
TW202302517A (zh) 2023-01-16
JPWO2022244835A1 (enExample) 2022-11-24
JP2023084157A (ja) 2023-06-16
KR102749709B1 (ko) 2025-01-07
KR20240033105A (ko) 2024-03-12
TW202421681A (zh) 2024-06-01
JP7272512B2 (ja) 2023-05-12
JP2023096058A (ja) 2023-07-06
JPWO2022244834A1 (enExample) 2022-11-24
EP4353779A1 (en) 2024-04-17
MX2023013618A (es) 2023-11-30
JPWO2022244833A1 (enExample) 2022-11-24
TW202421680A (zh) 2024-06-01
JP2023089218A (ja) 2023-06-27
KR20240007270A (ko) 2024-01-16
TW202417409A (zh) 2024-05-01
EP4353775A1 (en) 2024-04-17

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