KR102643225B1 - 감소된 골격-외 알루미늄을 가진 제올라이트 - Google Patents

감소된 골격-외 알루미늄을 가진 제올라이트 Download PDF

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KR102643225B1
KR102643225B1 KR1020207009946A KR20207009946A KR102643225B1 KR 102643225 B1 KR102643225 B1 KR 102643225B1 KR 1020207009946 A KR1020207009946 A KR 1020207009946A KR 20207009946 A KR20207009946 A KR 20207009946A KR 102643225 B1 KR102643225 B1 KR 102643225B1
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catalyst
zeolite
metal
catalyst composition
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KR20200040311A (ko
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이반 페트로빅
수브라마니안 프라사드
조셉 팔라마라
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바스프 코포레이션
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    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76Iron group metals or copper
    • B01J29/763CHA-type, e.g. Chabazite, LZ-218
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    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027Powdering
    • B01J37/0036Grinding
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    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404Removing only nitrogen compounds
    • B01D53/9409Nitrogen oxides
    • B01D53/9413Processes characterised by a specific catalyst
    • B01D53/9418Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
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    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/944Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts
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    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9459Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts
    • B01D53/9477Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts with catalysts positioned on separate bricks, e.g. exhaust systems
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    • B01J29/52Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952 containing iron group metals, noble metals or copper
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    • B01J35/50Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
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    • F01N13/16Selection of particular materials
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    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion
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  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
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  • Biomedical Technology (AREA)
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  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Toxicology (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Exhaust Gas After Treatment (AREA)
KR1020207009946A 2017-09-07 2018-09-06 감소된 골격-외 알루미늄을 가진 제올라이트 Active KR102643225B1 (ko)

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US201762555215P 2017-09-07 2017-09-07
US62/555,215 2017-09-07
PCT/IB2018/056818 WO2019049069A1 (en) 2017-09-07 2018-09-06 ZEOLITE WITH REDUCED CONTENT IN ALUMINUM EXTRA-CHARPENTE

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US (1) US11633726B2 (cg-RX-API-DMAC7.html)
EP (1) EP3678774A4 (cg-RX-API-DMAC7.html)
JP (2) JP2020533164A (cg-RX-API-DMAC7.html)
KR (1) KR102643225B1 (cg-RX-API-DMAC7.html)
CN (1) CN111315482B (cg-RX-API-DMAC7.html)
BR (1) BR112020004607B1 (cg-RX-API-DMAC7.html)
CA (1) CA3074818A1 (cg-RX-API-DMAC7.html)
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EP3768638A4 (en) * 2018-03-21 2021-12-29 BASF Corporation Cha zeolite material and related method of synthesis
EP3812034A1 (en) 2019-10-24 2021-04-28 Dinex A/S Durable copper-scr catalyst
EP3885029A1 (de) * 2020-03-24 2021-09-29 UMICORE AG & Co. KG Platin- und zinkhaltiger zeolith
JP2024510113A (ja) * 2021-02-19 2024-03-06 ビーエーエスエフ コーポレーション 耐硫黄性の金属促進小細孔ゼオライト触媒
CN113070097A (zh) * 2021-03-29 2021-07-06 中国科学院生态环境研究中心 一种用于氨选择性催化还原NOx的铜基催化剂及其制备方法
KR102546689B1 (ko) * 2021-04-05 2023-06-22 포항공과대학교 산학협력단 Pst-2 제올라이트 및 그 제조방법
WO2022255383A1 (ja) * 2021-06-02 2022-12-08 東ソー株式会社 Yfi型ゼオライト、その製造方法、炭化水素吸着剤及び炭化水素の吸着方法
KR20240054273A (ko) * 2021-09-13 2024-04-25 쉘 인터내셔날 리써취 마트샤피지 비.브이. 촉매 조성물, 이의 제조 및 용도
CN120908426A (zh) * 2025-10-11 2025-11-07 西昌学院 一种混凝土强度检测方法及系统

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4544538A (en) 1982-07-09 1985-10-01 Chevron Research Company Zeolite SSZ-13 and its method of preparation
US5118482A (en) * 1989-06-30 1992-06-02 Shell Oil Company Process for realuminating zeolites
US5879433A (en) * 1997-07-31 1999-03-09 Union Oil Company Of California Method and apparatus for reducing the acid gas and/or inert particulate content of steam
US6576587B2 (en) * 2001-03-13 2003-06-10 Delphi Technologies, Inc. High surface area lean NOx catalyst
US6709644B2 (en) 2001-08-30 2004-03-23 Chevron U.S.A. Inc. Small crystallite zeolite CHA
US6914026B2 (en) * 2001-09-07 2005-07-05 Engelhard Corporation Hydrothermally stable metal promoted zeolite beta for NOx reduction
BRPI0619944B8 (pt) 2005-12-14 2018-03-20 Basf Catalysts Llc método para preparar um catalisador de zeólito promovido por metal, catalisador de zeólito, e, método para reduzir nox em uma corrente de gás de exaustão ou gás combustível
US7998423B2 (en) * 2007-02-27 2011-08-16 Basf Corporation SCR on low thermal mass filter substrates
PL2117707T5 (pl) * 2007-02-27 2019-01-31 Basf Corporation Katalizatory zeolit cha -miedź
EP2297036B1 (en) 2008-05-21 2014-04-16 Basf Se Process for the direct synthesis of cu containing zeolites having cha structure
EP2308596B1 (en) * 2009-10-07 2016-09-21 Ford Global Technologies, LLC Cu/zeolite SCR catalyst for NOx reduction in exhaust gases and manufacture method thereof
JP5833560B2 (ja) 2009-11-24 2015-12-16 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se Cha構造を有するゼオライトの製造方法
US8293198B2 (en) 2009-12-18 2012-10-23 Basf Corporation Process of direct copper exchange into Na+-form of chabazite molecular sieve, and catalysts, systems and methods
EP2374781A1 (en) * 2010-04-09 2011-10-12 Total Petrochemicals Research Feluy Simultaneous dehydration and skeletal isomerisation of isobutanol on acid catalysts
CN102892729B (zh) * 2010-03-15 2015-08-05 道达尔研究技术弗吕公司 异丁醇在酸性催化剂上的同时脱水和骨架异构化
US8101146B2 (en) 2011-04-08 2012-01-24 Johnson Matthey Public Limited Company Catalysts for the reduction of ammonia emission from rich-burn exhaust
US9242239B2 (en) * 2011-04-08 2016-01-26 Johnson Matthey Public Limited Company Catalysts for the reduction of ammonia emission from rich-burn exhaust
JP6324895B2 (ja) * 2011-11-11 2018-05-16 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se ゼオライト系材料の製造方法、合成ゼオライト系材料及び合成ゼオライト系材料の使用方法
US9636667B2 (en) * 2012-06-04 2017-05-02 Basf Se CHA-type zeolite materials and methods for their preparation using cycloalkyammonium compounds
US20160038929A1 (en) 2013-05-09 2016-02-11 Exxonmobil Chemical Patents Inc. Regeneration of Aromatic Alkylation Catalyst Using Ozone
US20150290632A1 (en) * 2014-04-09 2015-10-15 Ford Global Technologies, Llc IRON AND COPPER-CONTAINING CHABAZITE ZEOLITE CATALYST FOR USE IN NOx REDUCTION
CN106660022B (zh) * 2014-06-18 2020-09-22 巴斯夫公司 分子筛催化剂组合物、催化剂复合材料、体系和方法
NO20140934A1 (no) * 2014-07-23 2016-01-25 Yara Int Asa Bikake-monolittstruktur
BR112017006109A2 (pt) * 2014-09-26 2017-12-19 Ifp Energies Now aluminosilicato cristalino modificado para desidratação de álcoois
US20160107119A1 (en) * 2014-10-16 2016-04-21 Battelle Memorial Institute CATALYSTS FOR ENHANCED REDUCTION OF NOx GASES AND PROCESSES FOR MAKING AND USING SAME
MY193820A (en) * 2015-02-27 2022-10-27 Basf Corp Exhaust gas treatment system
JP6616101B2 (ja) 2015-05-15 2019-12-04 イビデン株式会社 ゼオライト、該ゼオライトの製造方法、該ゼオライトを使用したハニカム触媒及び排ガス浄化装置
RU2731218C2 (ru) * 2015-08-21 2020-08-31 Басф Корпорейшн Катализаторы для обработки выхлопного газа
JP6949842B2 (ja) * 2015-12-09 2021-10-13 ビーエーエスエフ コーポレーション Cha型ゼオライト材料、並びにシクロアルキル−、及びエチルトリメチルアンモニウム化合物の組み合わせを用いるそれらの製造方法
BR112018015842B1 (pt) * 2016-02-03 2022-10-11 Basf Corporation Composição catalisadora, métodos para produzir um catalisador e para reduzir o nível de nox em um gás de escape, artigo catalisador e sistema de tratamento de emissão

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