CA3074818A1 - Zeolite with reduced extra-framework aluminum - Google Patents

Zeolite with reduced extra-framework aluminum Download PDF

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Publication number
CA3074818A1
CA3074818A1 CA3074818A CA3074818A CA3074818A1 CA 3074818 A1 CA3074818 A1 CA 3074818A1 CA 3074818 A CA3074818 A CA 3074818A CA 3074818 A CA3074818 A CA 3074818A CA 3074818 A1 CA3074818 A1 CA 3074818A1
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Canada
Prior art keywords
catalyst composition
catalyst
zeolite
metal
exhaust gas
Prior art date
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Pending
Application number
CA3074818A
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English (en)
French (fr)
Inventor
Ivan Petrovic
Subramanian PRASAD
Joseph PALAMARA
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Corp
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BASF Corp
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Filing date
Publication date
Application filed by BASF Corp filed Critical BASF Corp
Publication of CA3074818A1 publication Critical patent/CA3074818A1/en
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    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027Powdering
    • B01J37/0036Grinding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404Removing only nitrogen compounds
    • B01D53/9409Nitrogen oxides
    • B01D53/9413Processes characterised by a specific catalyst
    • B01D53/9418Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/944Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
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    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9459Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts
    • B01D53/9477Removing one or more of nitrogen oxides, carbon monoxide, or hydrocarbons by multiple successive catalytic functions; systems with more than one different function, e.g. zone coated catalysts with catalysts positioned on separate bricks, e.g. exhaust systems
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/50Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952
    • B01J29/52Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952 containing iron group metals, noble metals or copper
    • B01J29/56Iron group metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01J29/76Iron group metals or copper
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    • B01J35/50Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/70Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
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    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
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    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion
    • F01N3/206Adding periodically or continuously substances to exhaust gases for promoting purification, e.g. catalytic material in liquid form, NOx reducing agents
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    • B01J2229/18After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
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    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
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    • F01N2610/02Adding substances to exhaust gases the substance being ammonia or urea
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Toxicology (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Exhaust Gas After Treatment (AREA)
CA3074818A 2017-09-07 2018-09-06 Zeolite with reduced extra-framework aluminum Pending CA3074818A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201762555215P 2017-09-07 2017-09-07
US62/555,215 2017-09-07
PCT/IB2018/056818 WO2019049069A1 (en) 2017-09-07 2018-09-06 ZEOLITE WITH REDUCED CONTENT IN ALUMINUM EXTRA-CHARPENTE

Publications (1)

Publication Number Publication Date
CA3074818A1 true CA3074818A1 (en) 2019-03-14

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Application Number Title Priority Date Filing Date
CA3074818A Pending CA3074818A1 (en) 2017-09-07 2018-09-06 Zeolite with reduced extra-framework aluminum

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US (1) US11633726B2 (cg-RX-API-DMAC7.html)
EP (1) EP3678774A4 (cg-RX-API-DMAC7.html)
JP (2) JP2020533164A (cg-RX-API-DMAC7.html)
KR (1) KR102643225B1 (cg-RX-API-DMAC7.html)
CN (1) CN111315482B (cg-RX-API-DMAC7.html)
BR (1) BR112020004607B1 (cg-RX-API-DMAC7.html)
CA (1) CA3074818A1 (cg-RX-API-DMAC7.html)
WO (1) WO2019049069A1 (cg-RX-API-DMAC7.html)
ZA (1) ZA202001417B (cg-RX-API-DMAC7.html)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
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EP3768638A4 (en) * 2018-03-21 2021-12-29 BASF Corporation Cha zeolite material and related method of synthesis
EP3812034A1 (en) 2019-10-24 2021-04-28 Dinex A/S Durable copper-scr catalyst
EP3885029A1 (de) * 2020-03-24 2021-09-29 UMICORE AG & Co. KG Platin- und zinkhaltiger zeolith
JP2024510113A (ja) * 2021-02-19 2024-03-06 ビーエーエスエフ コーポレーション 耐硫黄性の金属促進小細孔ゼオライト触媒
CN113070097A (zh) * 2021-03-29 2021-07-06 中国科学院生态环境研究中心 一种用于氨选择性催化还原NOx的铜基催化剂及其制备方法
KR102546689B1 (ko) * 2021-04-05 2023-06-22 포항공과대학교 산학협력단 Pst-2 제올라이트 및 그 제조방법
WO2022255383A1 (ja) * 2021-06-02 2022-12-08 東ソー株式会社 Yfi型ゼオライト、その製造方法、炭化水素吸着剤及び炭化水素の吸着方法
KR20240054273A (ko) * 2021-09-13 2024-04-25 쉘 인터내셔날 리써취 마트샤피지 비.브이. 촉매 조성물, 이의 제조 및 용도
CN120908426A (zh) * 2025-10-11 2025-11-07 西昌学院 一种混凝土强度检测方法及系统

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4544538A (en) 1982-07-09 1985-10-01 Chevron Research Company Zeolite SSZ-13 and its method of preparation
US5118482A (en) * 1989-06-30 1992-06-02 Shell Oil Company Process for realuminating zeolites
US5879433A (en) * 1997-07-31 1999-03-09 Union Oil Company Of California Method and apparatus for reducing the acid gas and/or inert particulate content of steam
US6576587B2 (en) * 2001-03-13 2003-06-10 Delphi Technologies, Inc. High surface area lean NOx catalyst
US6709644B2 (en) 2001-08-30 2004-03-23 Chevron U.S.A. Inc. Small crystallite zeolite CHA
US6914026B2 (en) * 2001-09-07 2005-07-05 Engelhard Corporation Hydrothermally stable metal promoted zeolite beta for NOx reduction
BRPI0619944B8 (pt) 2005-12-14 2018-03-20 Basf Catalysts Llc método para preparar um catalisador de zeólito promovido por metal, catalisador de zeólito, e, método para reduzir nox em uma corrente de gás de exaustão ou gás combustível
US7998423B2 (en) * 2007-02-27 2011-08-16 Basf Corporation SCR on low thermal mass filter substrates
PL2117707T5 (pl) * 2007-02-27 2019-01-31 Basf Corporation Katalizatory zeolit cha -miedź
EP2297036B1 (en) 2008-05-21 2014-04-16 Basf Se Process for the direct synthesis of cu containing zeolites having cha structure
EP2308596B1 (en) * 2009-10-07 2016-09-21 Ford Global Technologies, LLC Cu/zeolite SCR catalyst for NOx reduction in exhaust gases and manufacture method thereof
JP5833560B2 (ja) 2009-11-24 2015-12-16 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se Cha構造を有するゼオライトの製造方法
US8293198B2 (en) 2009-12-18 2012-10-23 Basf Corporation Process of direct copper exchange into Na+-form of chabazite molecular sieve, and catalysts, systems and methods
EP2374781A1 (en) * 2010-04-09 2011-10-12 Total Petrochemicals Research Feluy Simultaneous dehydration and skeletal isomerisation of isobutanol on acid catalysts
CN102892729B (zh) * 2010-03-15 2015-08-05 道达尔研究技术弗吕公司 异丁醇在酸性催化剂上的同时脱水和骨架异构化
US8101146B2 (en) 2011-04-08 2012-01-24 Johnson Matthey Public Limited Company Catalysts for the reduction of ammonia emission from rich-burn exhaust
US9242239B2 (en) * 2011-04-08 2016-01-26 Johnson Matthey Public Limited Company Catalysts for the reduction of ammonia emission from rich-burn exhaust
JP6324895B2 (ja) * 2011-11-11 2018-05-16 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se ゼオライト系材料の製造方法、合成ゼオライト系材料及び合成ゼオライト系材料の使用方法
US9636667B2 (en) * 2012-06-04 2017-05-02 Basf Se CHA-type zeolite materials and methods for their preparation using cycloalkyammonium compounds
US20160038929A1 (en) 2013-05-09 2016-02-11 Exxonmobil Chemical Patents Inc. Regeneration of Aromatic Alkylation Catalyst Using Ozone
US20150290632A1 (en) * 2014-04-09 2015-10-15 Ford Global Technologies, Llc IRON AND COPPER-CONTAINING CHABAZITE ZEOLITE CATALYST FOR USE IN NOx REDUCTION
CN106660022B (zh) * 2014-06-18 2020-09-22 巴斯夫公司 分子筛催化剂组合物、催化剂复合材料、体系和方法
NO20140934A1 (no) * 2014-07-23 2016-01-25 Yara Int Asa Bikake-monolittstruktur
BR112017006109A2 (pt) * 2014-09-26 2017-12-19 Ifp Energies Now aluminosilicato cristalino modificado para desidratação de álcoois
US20160107119A1 (en) * 2014-10-16 2016-04-21 Battelle Memorial Institute CATALYSTS FOR ENHANCED REDUCTION OF NOx GASES AND PROCESSES FOR MAKING AND USING SAME
MY193820A (en) * 2015-02-27 2022-10-27 Basf Corp Exhaust gas treatment system
JP6616101B2 (ja) 2015-05-15 2019-12-04 イビデン株式会社 ゼオライト、該ゼオライトの製造方法、該ゼオライトを使用したハニカム触媒及び排ガス浄化装置
RU2731218C2 (ru) * 2015-08-21 2020-08-31 Басф Корпорейшн Катализаторы для обработки выхлопного газа
JP6949842B2 (ja) * 2015-12-09 2021-10-13 ビーエーエスエフ コーポレーション Cha型ゼオライト材料、並びにシクロアルキル−、及びエチルトリメチルアンモニウム化合物の組み合わせを用いるそれらの製造方法
BR112018015842B1 (pt) * 2016-02-03 2022-10-11 Basf Corporation Composição catalisadora, métodos para produzir um catalisador e para reduzir o nível de nox em um gás de escape, artigo catalisador e sistema de tratamento de emissão

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