KR102637671B1 - 그래핀 확산 장벽 - Google Patents
그래핀 확산 장벽 Download PDFInfo
- Publication number
- KR102637671B1 KR102637671B1 KR1020237022970A KR20237022970A KR102637671B1 KR 102637671 B1 KR102637671 B1 KR 102637671B1 KR 1020237022970 A KR1020237022970 A KR 1020237022970A KR 20237022970 A KR20237022970 A KR 20237022970A KR 102637671 B1 KR102637671 B1 KR 102637671B1
- Authority
- KR
- South Korea
- Prior art keywords
- barrier layer
- layer
- electronic devices
- graphene barrier
- tungsten
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
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- H01L21/76841—
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/26—Deposition of carbon only
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/455—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for introducing gases into reaction chamber or for modifying gas flows in reaction chamber
- C23C16/45523—Pulsed gas flow or change of composition over time
- C23C16/45525—Atomic layer deposition [ALD]
- C23C16/45527—Atomic layer deposition [ALD] characterized by the ALD cycle, e.g. different flows or temperatures during half-reactions, unusual pulsing sequence, use of precursor mixtures or auxiliary reactants or activations
- C23C16/45536—Use of plasma, radiation or electromagnetic fields
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- H01L21/28562—
-
- H01L23/53238—
-
- H01L23/53252—
-
- H01L23/53266—
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B69/00—Erasable-and-programmable ROM [EPROM] devices not provided for in groups H10B41/00 - H10B63/00, e.g. ultraviolet erasable-and-programmable ROM [UVEPROM] devices
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P14/00—Formation of materials, e.g. in the shape of layers or pillars
- H10P14/40—Formation of materials, e.g. in the shape of layers or pillars of conductive or resistive materials
- H10P14/412—Deposition of metallic or metal-silicide materials
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P14/00—Formation of materials, e.g. in the shape of layers or pillars
- H10P14/40—Formation of materials, e.g. in the shape of layers or pillars of conductive or resistive materials
- H10P14/418—Formation of materials, e.g. in the shape of layers or pillars of conductive or resistive materials the conductive layers comprising transition metals
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10W—GENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
- H10W20/00—Interconnections in chips, wafers or substrates
- H10W20/01—Manufacture or treatment
- H10W20/031—Manufacture or treatment of conductive parts of the interconnections
- H10W20/032—Manufacture or treatment of conductive parts of the interconnections of conductive barrier, adhesion or liner layers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10W—GENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
- H10W20/00—Interconnections in chips, wafers or substrates
- H10W20/40—Interconnections external to wafers or substrates, e.g. back-end-of-line [BEOL] metallisations or vias connecting to gate electrodes
- H10W20/41—Interconnections external to wafers or substrates, e.g. back-end-of-line [BEOL] metallisations or vias connecting to gate electrodes characterised by their conductive parts
- H10W20/425—Barrier, adhesion or liner layers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P14/00—Formation of materials, e.g. in the shape of layers or pillars
- H10P14/40—Formation of materials, e.g. in the shape of layers or pillars of conductive or resistive materials
- H10P14/42—Formation of materials, e.g. in the shape of layers or pillars of conductive or resistive materials using a gas or vapour
- H10P14/43—Chemical deposition, e.g. chemical vapour deposition [CVD]
- H10P14/432—Chemical deposition, e.g. chemical vapour deposition [CVD] using selective deposition
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Electromagnetism (AREA)
- Inorganic Chemistry (AREA)
- Chemical Vapour Deposition (AREA)
- Electrodes Of Semiconductors (AREA)
- Crystallography & Structural Chemistry (AREA)
- Carbon And Carbon Compounds (AREA)
- Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
- Bipolar Transistors (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201862717824P | 2018-08-11 | 2018-08-11 | |
| US62/717,824 | 2018-08-11 | ||
| PCT/US2019/045872 WO2020036819A1 (en) | 2018-08-11 | 2019-08-09 | Graphene diffusion barrier |
| KR1020217006973A KR102554839B1 (ko) | 2018-08-11 | 2019-08-09 | 그래핀 확산 장벽 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020217006973A Division KR102554839B1 (ko) | 2018-08-11 | 2019-08-09 | 그래핀 확산 장벽 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20230106752A KR20230106752A (ko) | 2023-07-13 |
| KR102637671B1 true KR102637671B1 (ko) | 2024-02-15 |
Family
ID=69406405
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020237022970A Active KR102637671B1 (ko) | 2018-08-11 | 2019-08-09 | 그래핀 확산 장벽 |
| KR1020217006973A Active KR102554839B1 (ko) | 2018-08-11 | 2019-08-09 | 그래핀 확산 장벽 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020217006973A Active KR102554839B1 (ko) | 2018-08-11 | 2019-08-09 | 그래핀 확산 장벽 |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US10916505B2 (https=) |
| JP (1) | JP7611814B2 (https=) |
| KR (2) | KR102637671B1 (https=) |
| CN (2) | CN112514031A (https=) |
| SG (1) | SG11202100359SA (https=) |
| TW (2) | TWI807639B (https=) |
| WO (1) | WO2020036819A1 (https=) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112514031A (zh) * | 2018-08-11 | 2021-03-16 | 应用材料公司 | 石墨烯扩散阻挡物 |
| US11251129B2 (en) * | 2020-03-27 | 2022-02-15 | Intel Corporation | Deposition of graphene on a dielectric surface for next generation interconnects |
| US12300497B2 (en) | 2021-02-11 | 2025-05-13 | Applied Materials, Inc. | Method and apparatus of low temperature plasma enhanced chemical vapor deposition of graphene |
| JP7692775B2 (ja) * | 2021-09-16 | 2025-06-16 | 東京エレクトロン株式会社 | 基板処理方法、基板処理装置および半導体構造 |
| KR20230055281A (ko) | 2021-10-18 | 2023-04-25 | 삼성전자주식회사 | 이차원 물질을 포함하는 박막 구조체 및 전자 소자 |
| KR20230071632A (ko) | 2021-11-16 | 2023-05-23 | 삼성전자주식회사 | 메모리 셀 스트링을 포함하는 수직형 비휘발성 메모리 장치 |
| WO2023121714A1 (en) * | 2021-12-22 | 2023-06-29 | General Graphene Corporation | Novel systems and methods for high yield and high throughput production of graphene |
| KR102945432B1 (ko) | 2024-11-28 | 2026-03-31 | 세종대학교산학협력단 | 확산 방지층을 가진 산화갈륨 기반 반도체 장치 및 그 제조 방법 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130113102A1 (en) * | 2011-11-08 | 2013-05-09 | International Business Machines Corporation | Semiconductor interconnect structure having a graphene-based barrier metal layer |
| US20140339700A1 (en) * | 2011-12-20 | 2014-11-20 | University Of Florida Research Foundation, Inc. | Graphene-based metal diffusion barrier |
Family Cites Families (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0691108B2 (ja) * | 1988-03-22 | 1994-11-14 | インタ‐ナシヨナル・ビジネス・マシ‐ンズ・コ‐ポレ‐シヨン | 薄膜電界効果トランジスタの製造方法 |
| JPH0484424A (ja) * | 1990-07-27 | 1992-03-17 | Sony Corp | 半導体装置の製造方法 |
| KR100203896B1 (ko) * | 1995-12-15 | 1999-06-15 | 김영환 | 게이트 전극 형성방법 |
| KR100543653B1 (ko) * | 1998-12-28 | 2006-03-28 | 주식회사 하이닉스반도체 | 반도체 소자의 금속 배선 형성 방법 |
| KR100805843B1 (ko) * | 2001-12-28 | 2008-02-21 | 에이에스엠지니텍코리아 주식회사 | 구리 배선 형성방법, 그에 따라 제조된 반도체 소자 및구리 배선 형성 시스템 |
| KR100968312B1 (ko) * | 2004-06-02 | 2010-07-08 | 인터내셔널 비지네스 머신즈 코포레이션 | 저-k 물질 상의 TaN 확산장벽 영역의 PE-ALD |
| JP5395542B2 (ja) | 2009-07-13 | 2014-01-22 | 株式会社東芝 | 半導体装置 |
| US20120161098A1 (en) | 2009-08-20 | 2012-06-28 | Nec Corporation | Substrate, manufacturing method of substrate, semiconductor element, and manufacturing method of semiconductor element |
| CA2834891A1 (en) | 2011-05-27 | 2012-12-06 | University Of North Texas | Graphene magnetic tunnel junction spin filters and methods of making |
| KR101437142B1 (ko) * | 2011-10-28 | 2014-09-02 | 제일모직주식회사 | 그라핀 층을 함유하는 배리어 필름과 이를 포함하는 플렉시블 기판 및 그 제조방법 |
| TWI645511B (zh) * | 2011-12-01 | 2018-12-21 | 美商應用材料股份有限公司 | 用於銅阻障層應用之摻雜的氮化鉭 |
| US8927415B2 (en) * | 2011-12-09 | 2015-01-06 | Intermolecular, Inc. | Graphene barrier layers for interconnects and methods for forming the same |
| KR101357046B1 (ko) * | 2011-12-20 | 2014-02-04 | (재)한국나노기술원 | 금속 확산 방지용 그래핀 층이 구비된 전자 소자 및 제조 방법. |
| CN102593097A (zh) * | 2012-02-27 | 2012-07-18 | 北京大学 | 一种集成电路金属互连结构及其制备方法 |
| US9472450B2 (en) | 2012-05-10 | 2016-10-18 | Samsung Electronics Co., Ltd. | Graphene cap for copper interconnect structures |
| JP5972735B2 (ja) | 2012-09-21 | 2016-08-17 | 株式会社東芝 | 半導体装置 |
| CN103121670B (zh) * | 2013-02-19 | 2015-04-29 | 西安交通大学 | 远程等离子体增强原子层沉积低温生长石墨烯的方法 |
| JP2015138901A (ja) | 2014-01-23 | 2015-07-30 | 株式会社東芝 | 半導体装置及びその製造方法 |
| JP6129772B2 (ja) | 2014-03-14 | 2017-05-17 | 株式会社東芝 | 半導体装置及び半導体装置の製造方法 |
| US9418889B2 (en) * | 2014-06-30 | 2016-08-16 | Lam Research Corporation | Selective formation of dielectric barriers for metal interconnects in semiconductor devices |
| KR102371295B1 (ko) * | 2015-02-16 | 2022-03-07 | 삼성전자주식회사 | 확산 방지층을 포함하는 층 구조물 및 그 제조방법 |
| WO2016156659A1 (en) * | 2015-04-01 | 2016-10-06 | Picosun Oy | Ald-deposited graphene on a conformal seed layer |
| KR20160120891A (ko) * | 2015-04-09 | 2016-10-19 | 삼성전자주식회사 | 반도체 장치 |
| KR20160124958A (ko) * | 2015-04-20 | 2016-10-31 | 서울대학교산학협력단 | 반도체 소자 및 그 제조 방법 |
| CN104810476A (zh) * | 2015-05-07 | 2015-07-29 | 中国科学院微电子研究所 | 非挥发性阻变存储器件及其制备方法 |
| JP2017050503A (ja) | 2015-09-04 | 2017-03-09 | 株式会社東芝 | 半導体装置とその製造方法 |
| CN105355620B (zh) * | 2015-12-17 | 2018-06-22 | 上海集成电路研发中心有限公司 | 一种铜互连结构及其制造方法 |
| US11139308B2 (en) * | 2015-12-29 | 2021-10-05 | Asm Ip Holding B.V. | Atomic layer deposition of III-V compounds to form V-NAND devices |
| US10319632B2 (en) * | 2016-12-14 | 2019-06-11 | Taiwan Semiconductor Manufacturing Co., Ltd. | Semiconductor interconnect structure having a graphene barrier layer |
| JP2018152413A (ja) * | 2017-03-10 | 2018-09-27 | 株式会社東芝 | 半導体装置及びその製造方法 |
| US10164018B1 (en) * | 2017-05-30 | 2018-12-25 | Taiwan Semiconductor Manufacturing Co., Ltd. | Semiconductor interconnect structure having graphene-capped metal interconnects |
| KR102496377B1 (ko) * | 2017-10-24 | 2023-02-06 | 삼성전자주식회사 | 저항변화 물질층을 가지는 비휘발성 메모리소자 |
| CN112514031A (zh) * | 2018-08-11 | 2021-03-16 | 应用材料公司 | 石墨烯扩散阻挡物 |
-
2019
- 2019-08-09 CN CN201980050230.XA patent/CN112514031A/zh active Pending
- 2019-08-09 WO PCT/US2019/045872 patent/WO2020036819A1/en not_active Ceased
- 2019-08-09 US US16/536,603 patent/US10916505B2/en active Active
- 2019-08-09 CN CN202511049659.0A patent/CN121096851A/zh active Pending
- 2019-08-09 KR KR1020237022970A patent/KR102637671B1/ko active Active
- 2019-08-09 JP JP2021506675A patent/JP7611814B2/ja active Active
- 2019-08-09 KR KR1020217006973A patent/KR102554839B1/ko active Active
- 2019-08-09 SG SG11202100359SA patent/SG11202100359SA/en unknown
- 2019-08-12 TW TW111105370A patent/TWI807639B/zh active
- 2019-08-12 TW TW108128545A patent/TWI758629B/zh active
-
2021
- 2021-02-09 US US17/171,432 patent/US11621226B2/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130113102A1 (en) * | 2011-11-08 | 2013-05-09 | International Business Machines Corporation | Semiconductor interconnect structure having a graphene-based barrier metal layer |
| US20140339700A1 (en) * | 2011-12-20 | 2014-11-20 | University Of Florida Research Foundation, Inc. | Graphene-based metal diffusion barrier |
Also Published As
| Publication number | Publication date |
|---|---|
| TW202223138A (zh) | 2022-06-16 |
| CN112514031A (zh) | 2021-03-16 |
| WO2020036819A1 (en) | 2020-02-20 |
| KR20210031763A (ko) | 2021-03-22 |
| JP2021534572A (ja) | 2021-12-09 |
| US20200051920A1 (en) | 2020-02-13 |
| TWI758629B (zh) | 2022-03-21 |
| CN121096851A (zh) | 2025-12-09 |
| US10916505B2 (en) | 2021-02-09 |
| TWI807639B (zh) | 2023-07-01 |
| JP7611814B2 (ja) | 2025-01-10 |
| KR20230106752A (ko) | 2023-07-13 |
| US20210167021A1 (en) | 2021-06-03 |
| US11621226B2 (en) | 2023-04-04 |
| KR102554839B1 (ko) | 2023-07-11 |
| SG11202100359SA (en) | 2021-02-25 |
| TW202009135A (zh) | 2020-03-01 |
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