KR102597626B1 - 개선된 미세구조 및 열팽창 특성을 갖는 투명한, 본질적으로 무색의, 주석-청징된 las 유리-세라믹 - Google Patents
개선된 미세구조 및 열팽창 특성을 갖는 투명한, 본질적으로 무색의, 주석-청징된 las 유리-세라믹 Download PDFInfo
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- KR102597626B1 KR102597626B1 KR1020177037276A KR20177037276A KR102597626B1 KR 102597626 B1 KR102597626 B1 KR 102597626B1 KR 1020177037276 A KR1020177037276 A KR 1020177037276A KR 20177037276 A KR20177037276 A KR 20177037276A KR 102597626 B1 KR102597626 B1 KR 102597626B1
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- South Korea
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- ceramic
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- ceramics
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000002241 glass-ceramic Substances 0.000 title claims abstract description 140
- 239000000203 mixture Substances 0.000 claims abstract description 69
- 229910006404 SnO 2 Inorganic materials 0.000 claims abstract description 41
- 229910018068 Li 2 O Inorganic materials 0.000 claims abstract description 32
- 229910000500 β-quartz Inorganic materials 0.000 claims abstract description 28
- 229910010413 TiO 2 Inorganic materials 0.000 claims abstract description 22
- 239000013078 crystal Substances 0.000 claims abstract description 21
- 229910004298 SiO 2 Inorganic materials 0.000 claims abstract description 16
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims abstract description 13
- 229910001404 rare earth metal oxide Inorganic materials 0.000 claims abstract description 11
- 229910000410 antimony oxide Inorganic materials 0.000 claims abstract description 5
- 229910000413 arsenic oxide Inorganic materials 0.000 claims abstract description 5
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical class [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims abstract description 5
- IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Inorganic materials [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 claims description 17
- 229910000502 Li-aluminosilicate Inorganic materials 0.000 claims description 16
- 239000002243 precursor Substances 0.000 claims description 8
- 238000002834 transmittance Methods 0.000 claims description 7
- 238000004383 yellowing Methods 0.000 claims description 7
- 239000006018 Li-aluminosilicate Substances 0.000 claims description 4
- 229960002594 arsenic trioxide Drugs 0.000 claims description 2
- 229910001392 phosphorus oxide Inorganic materials 0.000 claims description 2
- VSAISIQCTGDGPU-UHFFFAOYSA-N tetraphosphorus hexaoxide Chemical compound O1P(O2)OP3OP1OP2O3 VSAISIQCTGDGPU-UHFFFAOYSA-N 0.000 claims description 2
- KTTMEOWBIWLMSE-UHFFFAOYSA-N diarsenic trioxide Chemical compound O1[As](O2)O[As]3O[As]1O[As]2O3 KTTMEOWBIWLMSE-UHFFFAOYSA-N 0.000 claims 1
- 230000003287 optical effect Effects 0.000 abstract description 24
- 239000006064 precursor glass Substances 0.000 abstract description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 16
- 238000000034 method Methods 0.000 abstract description 12
- 239000011521 glass Substances 0.000 description 28
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 18
- 239000006025 fining agent Substances 0.000 description 18
- 239000002994 raw material Substances 0.000 description 16
- 230000006911 nucleation Effects 0.000 description 14
- 238000010899 nucleation Methods 0.000 description 14
- 238000002468 ceramisation Methods 0.000 description 12
- 238000010438 heat treatment Methods 0.000 description 11
- 230000005540 biological transmission Effects 0.000 description 9
- 238000004031 devitrification Methods 0.000 description 9
- 229910052736 halogen Inorganic materials 0.000 description 8
- 150000002367 halogens Chemical class 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 239000002667 nucleating agent Substances 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 6
- 230000012010 growth Effects 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000006112 glass ceramic composition Substances 0.000 description 5
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 239000003086 colorant Substances 0.000 description 4
- 238000004040 coloring Methods 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000006060 molten glass Substances 0.000 description 4
- 229910011212 Ti—Fe Inorganic materials 0.000 description 3
- 238000013459 approach Methods 0.000 description 3
- 239000006063 cullet Substances 0.000 description 3
- 230000001627 detrimental effect Effects 0.000 description 3
- 230000003993 interaction Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910017493 Nd 2 O 3 Inorganic materials 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- GEIAQOFPUVMAGM-UHFFFAOYSA-N ZrO Inorganic materials [Zr]=O GEIAQOFPUVMAGM-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 230000009970 fire resistant effect Effects 0.000 description 2
- 230000006698 induction Effects 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 239000006104 solid solution Substances 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 231100000167 toxic agent Toxicity 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 238000004017 vitrification Methods 0.000 description 2
- LLQHSBBZNDXTIV-UHFFFAOYSA-N 6-[5-[[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]methyl]-4,5-dihydro-1,2-oxazol-3-yl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)CC1CC(=NO1)C1=CC2=C(NC(O2)=O)C=C1 LLQHSBBZNDXTIV-UHFFFAOYSA-N 0.000 description 1
- -1 F and Br Chemical class 0.000 description 1
- 238000006124 Pilkington process Methods 0.000 description 1
- HCBIBCJNVBAKAB-UHFFFAOYSA-N Procaine hydrochloride Chemical compound Cl.CCN(CC)CCOC(=O)C1=CC=C(N)C=C1 HCBIBCJNVBAKAB-UHFFFAOYSA-N 0.000 description 1
- 238000003991 Rietveld refinement Methods 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- IKWTVSLWAPBBKU-UHFFFAOYSA-N a1010_sial Chemical compound O=[As]O[As]=O IKWTVSLWAPBBKU-UHFFFAOYSA-N 0.000 description 1
- 230000003698 anagen phase Effects 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 238000003279 ceramming Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000002301 combined effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000012916 structural analysis Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
- C03C10/0018—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and monovalent metal oxide as main constituents
- C03C10/0027—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and monovalent metal oxide as main constituents containing SiO2, Al2O3, Li2O as main constituents
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
- C03C3/085—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
- C03C3/087—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal containing calcium oxide, e.g. common sheet or container glass
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Glass Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1554891 | 2015-05-29 | ||
| FR1554891A FR3036700B1 (fr) | 2015-05-29 | 2015-05-29 | Vitroceramiques du type aluminosilicate de lithium, transparentes, essentiellement incolores, affinees a l'etain, avec une microstructure amelioree et des proprietes de dilatation thermique ameliorees |
| PCT/EP2016/062071 WO2016193171A1 (en) | 2015-05-29 | 2016-05-27 | Transparent, essentially colorless, tin-fined las glass-ceramics with improved microstructure and thermal expansion properties |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20180014752A KR20180014752A (ko) | 2018-02-09 |
| KR102597626B1 true KR102597626B1 (ko) | 2023-11-02 |
Family
ID=54140597
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020177037276A Active KR102597626B1 (ko) | 2015-05-29 | 2016-05-27 | 개선된 미세구조 및 열팽창 특성을 갖는 투명한, 본질적으로 무색의, 주석-청징된 las 유리-세라믹 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US10961146B2 (enExample) |
| EP (1) | EP3303239B1 (enExample) |
| JP (1) | JP6847861B2 (enExample) |
| KR (1) | KR102597626B1 (enExample) |
| CN (1) | CN107667076B (enExample) |
| DE (1) | DE202016007247U1 (enExample) |
| ES (1) | ES2957216T3 (enExample) |
| FR (1) | FR3036700B1 (enExample) |
| WO (1) | WO2016193171A1 (enExample) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3069240B1 (fr) | 2017-07-21 | 2021-04-23 | Eurokera | Vitroceramiques de spodumene-beta, blanches, opalescentes ou opaques, a faible teneur en titane, affinees a l'etain |
| DE202018102537U1 (de) * | 2017-12-22 | 2018-05-22 | Schott Ag | Einrichtungs- und Ausstattungsgegenstände für Küchen oder Labore mit Leuchtelement |
| JP7574078B2 (ja) * | 2018-07-31 | 2024-10-28 | 日本電気硝子株式会社 | ディスプレイ用基板及びその製造方法 |
| CN113692395B (zh) * | 2019-01-28 | 2023-10-31 | 康宁股份有限公司 | 玻璃陶瓷制品、组合物及其制造方法 |
| US20230159378A1 (en) * | 2020-04-29 | 2023-05-25 | Corning Incorporated | Compositions and methods of making a glass-ceramic article |
| CN112679095B (zh) * | 2020-12-25 | 2022-03-11 | 醴陵旗滨电子玻璃有限公司 | 一种微晶玻璃及其制备方法、智能终端和显示器 |
| EP4059902B1 (en) * | 2021-03-16 | 2023-12-06 | Schott Ag | Glass ceramic having specific thermal expansion characteristics |
| CN113068983A (zh) * | 2021-05-15 | 2021-07-06 | 江苏鑫诚玻璃有限公司 | 一种低膨胀微晶玻璃杯 |
| CN115542456B (zh) * | 2022-09-09 | 2023-04-11 | 中国建筑材料科学研究总院有限公司 | Φ40mm大尺寸高对比度光纤倒像器的制备方法、应用 |
| GB2624492B (en) * | 2022-09-09 | 2025-01-22 | China Building Mat Academy Co Ltd | Fabtication method and use of Ø40 mm large-size and high-contrast fiber optic image inverter |
| CN116332517B (zh) * | 2022-12-30 | 2025-04-15 | 海南海控特玻科技有限公司 | 一种低膨胀系数透明微晶玻璃及其制备方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001316132A (ja) | 2000-05-02 | 2001-11-13 | Nippon Electric Glass Co Ltd | Li2O−Al2O3−SiO2系透明結晶化ガラス物品及びそれを用いた光通信用デバイス |
| JP2001354446A (ja) | 2000-04-08 | 2001-12-25 | Carl Zeiss:Fa | 平板フロートガラス |
| JP2012528063A (ja) | 2009-05-29 | 2012-11-12 | ユーロケラ ソシエテ オン ノーム コレクティフ | ガラスセラミックプレート |
| WO2013171288A1 (en) | 2012-05-15 | 2013-11-21 | Eurokera | Transparent, essentially colorless and non-diffusing beta-quartz glass-ceramics; articles in said glass-ceramics; precursor glasses. |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4438210A (en) | 1982-12-20 | 1984-03-20 | Corning Glass Works | Transparent colorless glass-ceramics especially suitable for use as stove windows |
| FR2657079B1 (fr) | 1990-01-12 | 1993-04-09 | Corning France | Verres precurseurs de vitroceramiques, procede de conversion de ces verres en vitroceramiques a dilation tres faible ou nulle et vitroceramiques obtenues. |
| US5030593A (en) * | 1990-06-29 | 1991-07-09 | Ppg Industries, Inc. | Lightly tinted glass compatible with wood tones |
| ATE431812T1 (de) * | 2000-08-24 | 2009-06-15 | Schott Ag | Transparente, mit vanadiumoxid-zusatz dunkel einfärbbare glaskeramik |
| FR2864071A1 (fr) | 2003-12-17 | 2005-06-24 | Snc Eurokera | Vitroceramiques, verres precurseurs, articles en lesdites vitroceramiques, elaboration desdits vitroceramiques et articles |
| TW200533623A (en) | 2004-01-05 | 2005-10-16 | Schott Ag | Use of glass ceramics |
| CN101427144B (zh) | 2006-03-06 | 2011-12-21 | 安立股份有限公司 | 测试信号发生装置 |
| ES2306312T3 (es) | 2006-03-20 | 2008-11-01 | Schott Ag | Vidrio a base de silicato de litio y aluminio ceramizable, que contiene arsenico y antimonio, obtenido por flotacion y detectable optimamente. |
| DE502006007025D1 (de) | 2006-03-20 | 2010-07-08 | Schott Ag | Lithium-Aluminium-Silikatglas mit kurzen Keramisierungszeiten |
| FR2909373B1 (fr) | 2006-11-30 | 2009-02-27 | Snc Eurokera Soc En Nom Collec | Vitroceramiques de beta-quartz, transparentes et incolores, exemptes de tio2 ; articles en lesdites vitroceramiques ; verres precurseurs, procedes d'elaboration. |
| FR2909374B1 (fr) | 2006-11-30 | 2016-11-25 | Soc En Nom Collectif Dite : Eurokera | Vitroceramiques de beta-quartz, transparentes et incolores, a faible teneur en tio2; articles en lesdites vitroceramiques ; verres precurseurs, procedes d'elaboration |
| US7507681B2 (en) * | 2007-02-28 | 2009-03-24 | Eurokera | Glass-ceramic, articles and fabrication process |
| JP5673909B2 (ja) * | 2008-05-19 | 2015-02-18 | 日本電気硝子株式会社 | 結晶性ガラス及びこれを結晶化させてなる結晶化ガラス |
| DE102009013127C5 (de) | 2009-03-13 | 2024-12-19 | Schott Ag | Transparente, eingefärbte Kochfläche und Verfahren zum Anzeigen eines Betriebszustandes einer solchen |
| JP6202775B2 (ja) | 2010-08-11 | 2017-09-27 | 日本電気硝子株式会社 | Li2O−Al2O3−SiO2系結晶化ガラス |
| JP2012106887A (ja) | 2010-11-18 | 2012-06-07 | Nippon Electric Glass Co Ltd | Li2O−Al2O3−SiO2系結晶性ガラスおよびそれを結晶化させてなるLi2O−Al2O3−SiO2系結晶化ガラス |
| FR2975391A1 (fr) * | 2011-05-16 | 2012-11-23 | Eurokera | Vitroceramiques de quartz-beta avec courbe de transmission controlee ; articles en lesdites vitroceramiques, verres precurseurs. |
| JP5377607B2 (ja) | 2011-09-26 | 2013-12-25 | ショット アクチエンゲゼルシャフト | 酸化バナジウムを使用することにより暗色化できる透明ガラスセラミック |
| DE102012202697A1 (de) * | 2012-02-22 | 2013-08-22 | Schott Ag | Transparente farbarme Lithiumaluminiumsilikat-Glaskeramik und deren Verwendung |
| FR3025793B1 (fr) * | 2014-09-12 | 2016-12-02 | Eurokera | Plaque en vitroceramique |
| DE102014222645A1 (de) | 2014-11-06 | 2016-05-12 | Schott Ag | Hochkristalline Lithiumaluminiumsilikat-Glaskeramik und ihre Verwendung |
-
2015
- 2015-05-29 FR FR1554891A patent/FR3036700B1/fr active Active
-
2016
- 2016-05-27 ES ES16725173T patent/ES2957216T3/es active Active
- 2016-05-27 EP EP16725173.5A patent/EP3303239B1/en active Active
- 2016-05-27 WO PCT/EP2016/062071 patent/WO2016193171A1/en not_active Ceased
- 2016-05-27 US US15/577,980 patent/US10961146B2/en active Active
- 2016-05-27 DE DE202016007247.2U patent/DE202016007247U1/de active Active
- 2016-05-27 CN CN201680031408.2A patent/CN107667076B/zh active Active
- 2016-05-27 KR KR1020177037276A patent/KR102597626B1/ko active Active
- 2016-05-27 JP JP2017561826A patent/JP6847861B2/ja active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001354446A (ja) | 2000-04-08 | 2001-12-25 | Carl Zeiss:Fa | 平板フロートガラス |
| JP2001316132A (ja) | 2000-05-02 | 2001-11-13 | Nippon Electric Glass Co Ltd | Li2O−Al2O3−SiO2系透明結晶化ガラス物品及びそれを用いた光通信用デバイス |
| JP2012528063A (ja) | 2009-05-29 | 2012-11-12 | ユーロケラ ソシエテ オン ノーム コレクティフ | ガラスセラミックプレート |
| WO2013171288A1 (en) | 2012-05-15 | 2013-11-21 | Eurokera | Transparent, essentially colorless and non-diffusing beta-quartz glass-ceramics; articles in said glass-ceramics; precursor glasses. |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107667076B (zh) | 2022-01-18 |
| JP6847861B2 (ja) | 2021-03-24 |
| KR20180014752A (ko) | 2018-02-09 |
| EP3303239A1 (en) | 2018-04-11 |
| US20180290919A1 (en) | 2018-10-11 |
| FR3036700B1 (fr) | 2021-04-16 |
| DE202016007247U1 (de) | 2016-12-21 |
| CN107667076A (zh) | 2018-02-06 |
| EP3303239B1 (en) | 2023-07-19 |
| ES2957216T3 (es) | 2024-01-15 |
| FR3036700A1 (fr) | 2016-12-02 |
| WO2016193171A1 (en) | 2016-12-08 |
| US10961146B2 (en) | 2021-03-30 |
| JP2018523624A (ja) | 2018-08-23 |
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