KR102479867B1 - 철 제올라이트를 포함하는 촉매 상에서의 알킬기에 의해 위치 2 가 치환된 1차 알콜의 이성질체화 탈수 방법 - Google Patents

철 제올라이트를 포함하는 촉매 상에서의 알킬기에 의해 위치 2 가 치환된 1차 알콜의 이성질체화 탈수 방법 Download PDF

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KR102479867B1
KR102479867B1 KR1020177011472A KR20177011472A KR102479867B1 KR 102479867 B1 KR102479867 B1 KR 102479867B1 KR 1020177011472 A KR1020177011472 A KR 1020177011472A KR 20177011472 A KR20177011472 A KR 20177011472A KR 102479867 B1 KR102479867 B1 KR 102479867B1
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effluent
catalyst
feedstock
primary alcohol
mpa
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KR20170063853A (ko
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톰 비비앙
실비 모리
뱅상 쿠파르
델핀 바제르-바쉬
니콜라이 네스테렌코
나디야 다닐리나
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아이에프피 에너지스 누벨
토탈에너지스 원테크 벨지움
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B01J35/1019—
    • B01J35/1038—
    • B01J35/108—
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/08—Alkenes with four carbon atoms
    • C07C11/09—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767—Changing the number of side-chains
    • C07C5/277—Catalytic processes
    • C07C5/2775—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/34—Reaction with organic or organometallic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020177011472A 2014-09-26 2015-09-22 철 제올라이트를 포함하는 촉매 상에서의 알킬기에 의해 위치 2 가 치환된 1차 알콜의 이성질체화 탈수 방법 Active KR102479867B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1459113A FR3026406B1 (fr) 2014-09-26 2014-09-26 Procede de deshydratation isomerisante d'une charge alcool primaire substitue en position 2 par un groupement alkyl sur un catalyseur comprenant une zeolithe de type fer
FR1459113 2014-09-26
PCT/EP2015/071802 WO2016046242A1 (fr) 2014-09-26 2015-09-22 Procede de deshydratation isomerisante d'une charge alcool primaire substitue en position 2 par un groupement alkyl sur un catalyseur comprenant une zeolithe de type fer

Publications (2)

Publication Number Publication Date
KR20170063853A KR20170063853A (ko) 2017-06-08
KR102479867B1 true KR102479867B1 (ko) 2022-12-21

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KR1020177011472A Active KR102479867B1 (ko) 2014-09-26 2015-09-22 철 제올라이트를 포함하는 촉매 상에서의 알킬기에 의해 위치 2 가 치환된 1차 알콜의 이성질체화 탈수 방법

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Country Link
US (1) US10099969B2 (enExample)
EP (1) EP3197850B1 (enExample)
JP (1) JP6778677B2 (enExample)
KR (1) KR102479867B1 (enExample)
CN (1) CN107001178B (enExample)
BR (1) BR112017005670B1 (enExample)
CA (1) CA2960785C (enExample)
FR (1) FR3026406B1 (enExample)
RU (1) RU2694062C2 (enExample)
WO (1) WO2016046242A1 (enExample)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3058415B1 (fr) * 2016-11-08 2018-12-07 IFP Energies Nouvelles Procede de deshydratation isomerisante d'une charge alcool primaire non lineaire en presence d'injection d'eau et d' un catalyseur comprenant une zeolithe de type fer ou mfs
FR3058413A1 (fr) * 2016-11-08 2018-05-11 IFP Energies Nouvelles Procede de deshydratation isomerisante d'une charge d'un monoalcool primaire non lineaire sur un catalyseur comprenant une zeolithe de type fer et un alcalin
FR3058414B1 (fr) * 2016-11-08 2019-08-16 IFP Energies Nouvelles Procede de deshydratation isomerisante d'un alcool primaire non lineaire sur un catalyseur comprenant une zeolithe de type fer et un liant aluminique
FR3068692B1 (fr) * 2017-07-10 2019-08-16 IFP Energies Nouvelles Procede de deshydratation des alcools en olefines comprenant une etape de selectivation du catalyseur
FR3071250B1 (fr) * 2017-09-19 2019-09-13 IFP Energies Nouvelles Procede de deshydratation des alcools en olefines comprenant le recyclage des alcools
CN108358740A (zh) * 2018-02-09 2018-08-03 安徽海德化工科技有限公司 一种用于异丁醇脱水制备异丁烯的助剂
FR3080546B1 (fr) * 2018-04-25 2022-12-16 Ifp Energies Now Procede de deshydratation isomerisante de monoalcool primaire non lineaire sur un catalyseur zeolithique quadrilobe de type fer
FR3090393B1 (fr) 2018-12-20 2021-04-23 Ifp Energies Now Procédé de traitement d’une charge alcool pour la production d’oléfines
US20240317657A1 (en) * 2023-03-24 2024-09-26 Indian Oil Corporation Limited Process and a system for enhancing the yield of light olefins

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014083260A1 (fr) * 2012-11-27 2014-06-05 IFP Energies Nouvelles Procede de déshydratation de l'éthanol en éthylene a basse consommation énergétique

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Publication number Priority date Publication date Assignee Title
MX2010008723A (es) * 2008-02-07 2010-11-30 Total Petrochemicals Res Feluy Deshidratacion de alcoholes en silicatos cristalinos.
MY158968A (en) * 2010-03-15 2016-11-30 Total Res & Technology Feluy Simultaneous dehydration and skeletal isomerisation of isobutanol on acid catalysts
WO2011161045A1 (en) * 2010-06-23 2011-12-29 Total Petrochemicals Research Feluy Dehydration of alcohols on poisoned acidic catalysts
FR2978146B1 (fr) 2011-07-21 2013-08-30 IFP Energies Nouvelles Procede de deshydratation de l'ethanol en ethylene a basse consommation energetique
FR3001969B1 (fr) * 2013-02-12 2015-08-21 IFP Energies Nouvelles Procede de production d'oxyde d'ethylene a partir d'un flux d'ethanol thermiquement integre
FR3001968B1 (fr) * 2013-02-12 2015-02-27 IFP Energies Nouvelles Procede de production d'oxyde d'ethylene a partir d'un flux d'ethanol thermo-mecaniquement integre
WO2016107759A1 (en) * 2014-12-31 2016-07-07 Total Research & Technology Feluy Process for preparing olefins by dehydrating alcohols with less side effects comprising addition of sulfur containing compounds

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014083260A1 (fr) * 2012-11-27 2014-06-05 IFP Energies Nouvelles Procede de déshydratation de l'éthanol en éthylene a basse consommation énergétique

Also Published As

Publication number Publication date
US20170341996A1 (en) 2017-11-30
FR3026406A1 (fr) 2016-04-01
BR112017005670B1 (pt) 2021-10-26
CN107001178B (zh) 2020-06-05
CA2960785C (fr) 2023-08-15
FR3026406B1 (fr) 2016-12-09
RU2017114374A (ru) 2018-10-26
BR112017005670A2 (pt) 2017-12-12
EP3197850A1 (fr) 2017-08-02
KR20170063853A (ko) 2017-06-08
JP2017534587A (ja) 2017-11-24
US10099969B2 (en) 2018-10-16
RU2017114374A3 (enExample) 2019-02-25
JP6778677B2 (ja) 2020-11-04
EP3197850B1 (fr) 2018-11-21
CN107001178A (zh) 2017-08-01
RU2694062C2 (ru) 2019-07-09
WO2016046242A1 (fr) 2016-03-31
CA2960785A1 (fr) 2016-03-31

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