KR102445633B1 - 블렌드 조성물의 동적 가황, 이들의 제조 방법 및 이를 포함하는 물품 - Google Patents

블렌드 조성물의 동적 가황, 이들의 제조 방법 및 이를 포함하는 물품 Download PDF

Info

Publication number
KR102445633B1
KR102445633B1 KR1020177016015A KR20177016015A KR102445633B1 KR 102445633 B1 KR102445633 B1 KR 102445633B1 KR 1020177016015 A KR1020177016015 A KR 1020177016015A KR 20177016015 A KR20177016015 A KR 20177016015A KR 102445633 B1 KR102445633 B1 KR 102445633B1
Authority
KR
South Korea
Prior art keywords
composition
ethylene
propylene
crystalline
olefin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020177016015A
Other languages
English (en)
Korean (ko)
Other versions
KR20170091634A (ko
Inventor
위산 후
킴 엘. 월턴
Original Assignee
다우 글로벌 테크놀로지스 엘엘씨
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 다우 글로벌 테크놀로지스 엘엘씨 filed Critical 다우 글로벌 테크놀로지스 엘엘씨
Publication of KR20170091634A publication Critical patent/KR20170091634A/ko
Application granted granted Critical
Publication of KR102445633B1 publication Critical patent/KR102445633B1/ko
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0846Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
    • C08L23/0869Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen with unsaturated acids, e.g. [meth]acrylic acid; with unsaturated esters, e.g. [meth]acrylic acid esters
    • C08L23/0876Salts thereof, i.e. ionomers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/24Crosslinking, e.g. vulcanising, of macromolecules
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/24Crosslinking, e.g. vulcanising, of macromolecules
    • C08J3/242Applying crosslinking or accelerating agent onto compounding ingredients such as fillers, reinforcements
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0025Crosslinking or vulcanising agents; including accelerators
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/14Copolymers of propene
    • C08L23/142Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Ethene-propene or ethene-propene-diene copolymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/08Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00Crosslinking
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00Polymer mixtures characterised by way of preparation
    • C08L2314/06Metallocene or single site catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Laminated Bodies (AREA)
KR1020177016015A 2014-12-02 2015-11-23 블렌드 조성물의 동적 가황, 이들의 제조 방법 및 이를 포함하는 물품 Active KR102445633B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201462086354P 2014-12-02 2014-12-02
US62/086,354 2014-12-02
PCT/US2015/062093 WO2016089647A1 (en) 2014-12-02 2015-11-23 Dynamic vulcanization of a blend composition, methods of manufacture thereof and articles comprising the same

Publications (2)

Publication Number Publication Date
KR20170091634A KR20170091634A (ko) 2017-08-09
KR102445633B1 true KR102445633B1 (ko) 2022-09-21

Family

ID=54782849

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020177016015A Active KR102445633B1 (ko) 2014-12-02 2015-11-23 블렌드 조성물의 동적 가황, 이들의 제조 방법 및 이를 포함하는 물품

Country Status (9)

Country Link
US (1) US10358545B2 (enExample)
EP (1) EP3227380B1 (enExample)
JP (2) JP6903007B2 (enExample)
KR (1) KR102445633B1 (enExample)
CN (1) CN107001734B (enExample)
BR (1) BR112017010971B1 (enExample)
SG (1) SG11201704288RA (enExample)
TW (1) TWI689546B (enExample)
WO (1) WO2016089647A1 (enExample)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102445633B1 (ko) * 2014-12-02 2022-09-21 다우 글로벌 테크놀로지스 엘엘씨 블렌드 조성물의 동적 가황, 이들의 제조 방법 및 이를 포함하는 물품
EP3436485B1 (en) * 2016-03-31 2021-09-22 Dow Global Technologies LLC Polyolefin blends including crystalline block composites for pvc-free wear layers
CN106519635A (zh) * 2016-10-13 2017-03-22 广东省石油化工研究院 一种与abs基材二次包覆成型的表面耐划伤tpv组合物及其制备方法
WO2019159882A1 (ja) * 2018-02-15 2019-08-22 三井・ダウポリケミカル株式会社 成形体用変性樹脂およびゴルフボール
WO2019159881A1 (ja) * 2018-02-15 2019-08-22 三井・ダウポリケミカル株式会社 成形体用変性樹脂およびゴルフボール
WO2019231916A1 (en) * 2018-05-31 2019-12-05 E. I. Du Pont De Nemours And Company Molded articles, and methods thereof
WO2020158873A1 (ja) * 2019-01-30 2020-08-06 凸版印刷株式会社 全固体電池用外装材及びこれを用いた全固体電池
JP7654639B2 (ja) * 2019-08-29 2025-04-01 ダウ グローバル テクノロジーズ エルエルシー 改善された熱特性を有するポリマーブレンド
WO2021188361A1 (en) 2020-03-20 2021-09-23 Exxonmobil Chemical Patents Inc. Linear alpha-olefin copolymers and impact copolymers thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002508424A (ja) 1997-12-18 2002-03-19 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 熱可塑性ポリマー組成物

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5783638A (en) 1991-10-15 1998-07-21 The Dow Chemical Company Elastic substantially linear ethylene polymers
US5206294A (en) * 1991-11-06 1993-04-27 E. I. Du Pont De Nemours And Company Thermoplastic polymer alloy composition
DE69431222T2 (de) 1993-06-07 2003-04-17 Mitsui Chemicals, Inc. Übergangsmetallverbindung, und diese enthaltender Polymerisationkatalysator
US5721314A (en) * 1993-12-07 1998-02-24 E. I. Du Pont De Nemours And Company Thermoformable thermoplastic polymer alloy compositions
RU2178422C2 (ru) 1996-03-27 2002-01-20 Дзе Дау Кемикал Компани Активатор катализаторов полимеризации олефинов, каталитическая система и способ полимеризации
US6525157B2 (en) 1997-08-12 2003-02-25 Exxonmobile Chemical Patents Inc. Propylene ethylene polymers
AU4965299A (en) 1998-07-02 2000-01-24 Exxon Chemical Patents Inc. Propylene olefin copolymers
US6207761B1 (en) 1999-03-18 2001-03-27 A. Schulman, Inc. Ionomer/rubber/polyolefin blend and uses thereof
US6153680A (en) * 1999-06-30 2000-11-28 Delphi Technologies, Inc. Thermoplastic polymer alloy compositions and in-line compounding process for direct sheet extrusion of sheets prepared from the thermoplastic polymer alloy compositions
KR100306491B1 (ko) * 1999-07-24 2001-09-13 신형인 이오노머 첨가에 의한 혼화성이 개선된 열가소성 탄성체 조성물
KR100353066B1 (ko) * 1999-12-31 2002-09-18 현대자동차주식회사 열가소성 수지조성물
US6403721B1 (en) 2000-09-29 2002-06-11 Solvay Engineered Polymers Engineered polyolefin materials with enhanced surface durability
US6646056B2 (en) 2001-10-16 2003-11-11 Solvay Engineered Polymers Thermoplastic elastomer compositions
US6960635B2 (en) 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
US6906160B2 (en) 2001-11-06 2005-06-14 Dow Global Technologies Inc. Isotactic propylene copolymer fibers, their preparation and use
WO2004026913A2 (en) * 2002-09-19 2004-04-01 A. Schulman Inc. Ionomer modified polypropylene compound for superior scratch performance, low blushing, and molded in color with controllable gloss
US6887940B2 (en) 2002-11-27 2005-05-03 Basell Poliolefine Italia S.P.A. Compatibilizing agent for engineering thermoplastic/polyolefin blend
US7015284B2 (en) 2004-01-06 2006-03-21 The Goodyear Tire & Rubber Company Thermoplastic elastomer composition
EP2123706A1 (en) 2008-05-19 2009-11-25 Evonik Degussa GmbH Thermoplastic elastomers
BRPI0914041B1 (pt) 2008-10-06 2018-03-20 Dow Global Technologies Llc “método para cromatografia de um polímero poliolefínico, método de cromatografia líquida melhorado e método para determinar a razão de monômero para comonômero de um copolímero”
US8318896B2 (en) 2009-12-21 2012-11-27 Dow Global Technologies Llc Chromatography of polyolefin polymers
US8822598B2 (en) 2010-06-21 2014-09-02 Dow Global Technologies Llc Crystalline block composites as compatibilizers
CN103180379B (zh) * 2010-06-21 2015-07-08 陶氏环球技术有限责任公司 用作增容剂的结晶嵌段复合材料
BR112012032683B1 (pt) * 2010-06-21 2020-12-29 Dow Global Technologies Llc composição
KR101820183B1 (ko) * 2010-06-21 2018-01-18 다우 글로벌 테크놀로지스 엘엘씨 상용화제로서 결정질 블록 복합물
US8916249B2 (en) 2010-09-30 2014-12-23 Dow Global Technologies Llc Polymeric composition with sealant layer with same
SG11201402933PA (en) * 2011-12-14 2014-07-30 Dow Global Technologies Llc Functionalized block composite and crystalline block composite compositions as compatibilizers
KR102445633B1 (ko) * 2014-12-02 2022-09-21 다우 글로벌 테크놀로지스 엘엘씨 블렌드 조성물의 동적 가황, 이들의 제조 방법 및 이를 포함하는 물품

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002508424A (ja) 1997-12-18 2002-03-19 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 熱可塑性ポリマー組成物

Also Published As

Publication number Publication date
SG11201704288RA (en) 2017-06-29
JP2018501341A (ja) 2018-01-18
JP2021073334A (ja) 2021-05-13
BR112017010971B1 (pt) 2022-12-20
CN107001734B (zh) 2021-02-05
JP6903007B2 (ja) 2021-07-14
US20170355840A1 (en) 2017-12-14
EP3227380A1 (en) 2017-10-11
EP3227380B1 (en) 2019-09-04
TW201620976A (zh) 2016-06-16
US10358545B2 (en) 2019-07-23
KR20170091634A (ko) 2017-08-09
WO2016089647A1 (en) 2016-06-09
TWI689546B (zh) 2020-04-01
BR112017010971A2 (pt) 2018-02-14
CN107001734A (zh) 2017-08-01

Similar Documents

Publication Publication Date Title
KR102445633B1 (ko) 블렌드 조성물의 동적 가황, 이들의 제조 방법 및 이를 포함하는 물품
EP3262115B1 (en) Roofing compositions comprising propylene-based elastomers
CN107922686B (zh) 包括增容剂的聚烯烃共混物
CN104797424B (zh) 基于聚烯烃的多层膜
EP2895326B1 (en) Polyolefin based films suitable for thermoforming
EP3089870B1 (en) Multilayered films, methods of manufacture thereof and articles comprising the same
KR19980081564A (ko) 하나 이상의 프로필렌 그라프트 공중합체 층을 포함하는공압출된 적층물
US6306518B1 (en) High surface gloss, co-extruded sheets from propylene polymer materials
CN106133052B (zh) 聚烯烃基组合物、粘合剂,以及由其制备的相关多层结构
EP3436485B1 (en) Polyolefin blends including crystalline block composites for pvc-free wear layers
US11485840B2 (en) Polymer blends for use in multilayer structure and multilayer structures comprising the same
KR101955743B1 (ko) 조성물 및 그로부터 형성된 제품
EP1040162B1 (en) Thermoplastic polymer compositions
CN114466744B (zh) 柔性多层膜
JP2005097559A (ja) プロピレン共重合体組成物およびそのフィルム
JPH0948098A (ja) ポリプロピレン系樹脂積層体

Legal Events

Date Code Title Description
PA0105 International application

Patent event date: 20170612

Patent event code: PA01051R01D

Comment text: International Patent Application

PG1501 Laying open of application
A201 Request for examination
PA0201 Request for examination

Patent event code: PA02012R01D

Patent event date: 20201109

Comment text: Request for Examination of Application

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

Comment text: Notification of reason for refusal

Patent event date: 20211214

Patent event code: PE09021S01D

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

Patent event code: PE07011S01D

Comment text: Decision to Grant Registration

Patent event date: 20220615

PR0701 Registration of establishment

Comment text: Registration of Establishment

Patent event date: 20220916

Patent event code: PR07011E01D

PR1002 Payment of registration fee

Payment date: 20220919

End annual number: 3

Start annual number: 1

PG1601 Publication of registration