KR102397679B1 - 침강 실리카의 신규 제조 방법, 신규 침강 실리카, 및 특히 중합체 강화를 위한 이의 용도 - Google Patents

침강 실리카의 신규 제조 방법, 신규 침강 실리카, 및 특히 중합체 강화를 위한 이의 용도 Download PDF

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KR102397679B1
KR102397679B1 KR1020167022693A KR20167022693A KR102397679B1 KR 102397679 B1 KR102397679 B1 KR 102397679B1 KR 1020167022693 A KR1020167022693 A KR 1020167022693A KR 20167022693 A KR20167022693 A KR 20167022693A KR 102397679 B1 KR102397679 B1 KR 102397679B1
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acid
precipitated silica
silica
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KR20160122168A (ko
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세드릭 부아뱅
로랑 기
에릭 페랭
킬라니 라미리
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로디아 오퍼레이션스
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/18—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
    • C01B33/187—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates
    • C01B33/193—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates of aqueous solutions of silicates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06—Copolymers with styrene
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C04B14/04—Silica-rich materials; Silicates
    • C04B14/06—Quartz; Sand
    • C04B14/066—Precipitated or pyrogenic silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/28—Compounds of silicon
    • C09C1/30—Silicic acid
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/28—Compounds of silicon
    • C09C1/30—Silicic acid
    • C09C1/3045—Treatment with inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/28—Compounds of silicon
    • C09C1/30—Silicic acid
    • C09C1/3063—Treatment with low-molecular organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2509/00—Use of inorganic materials not provided for in groups B29K2503/00 - B29K2507/00, as filler
    • B29K2509/02—Ceramics
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C01P2002/54—Solid solutions containing elements as dopants one element only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/54—Particles characterised by their aspect ratio, i.e. the ratio of sizes in the longest to the shortest dimension
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/14—Pore volume
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/90—Other properties not specified above
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/002—Physical properties
    • C08K2201/006—Additives being defined by their surface area
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Civil Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Silicon Compounds (AREA)
  • Paints Or Removers (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
KR1020167022693A 2014-02-14 2015-02-12 침강 실리카의 신규 제조 방법, 신규 침강 실리카, 및 특히 중합체 강화를 위한 이의 용도 Expired - Fee Related KR102397679B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1400414 2014-02-14
FR1400414A FR3017609B1 (fr) 2014-02-14 2014-02-14 Nouveau procede de preparation de silices precipitees, nouvelles silices precipitees et leurs utilisations, notamment pour le renforcement de polymeres
PCT/EP2015/052920 WO2015121332A1 (fr) 2014-02-14 2015-02-12 Nouveau procede de preparation de silices precipitees, nouvelles silices precipitees et leurs utilisations, notamment pour le renforcement de polymeres

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Publication Number Publication Date
KR20160122168A KR20160122168A (ko) 2016-10-21
KR102397679B1 true KR102397679B1 (ko) 2022-05-13

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KR1020167022693A Expired - Fee Related KR102397679B1 (ko) 2014-02-14 2015-02-12 침강 실리카의 신규 제조 방법, 신규 침강 실리카, 및 특히 중합체 강화를 위한 이의 용도

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US (1) US11168204B2 (enExample)
EP (1) EP3105182A1 (enExample)
JP (1) JP6567538B2 (enExample)
KR (1) KR102397679B1 (enExample)
CN (1) CN106029568B (enExample)
AR (1) AR099422A1 (enExample)
CA (1) CA2938696A1 (enExample)
FR (1) FR3017609B1 (enExample)
MX (1) MX389843B (enExample)
TW (1) TWI715528B (enExample)
WO (1) WO2015121332A1 (enExample)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3017609B1 (fr) 2014-02-14 2016-03-18 Rhodia Operations Nouveau procede de preparation de silices precipitees, nouvelles silices precipitees et leurs utilisations, notamment pour le renforcement de polymeres
FR3017610B1 (fr) * 2014-02-14 2016-03-18 Rhodia Operations Nouveau procede de preparation de silices precipitees, nouvelles silices precipitees et leurs utilisations, notamment pour le renforcement de polymeres
FR3018071B1 (fr) * 2014-02-28 2016-02-26 Rhodia Operations Nouveau procede de preparation de silices precipitees, nouvelles silices precipitees et leurs utilisations, notamment pour le renforcement de polymeres
FR3018070B1 (fr) * 2014-02-28 2017-09-15 Rhodia Operations Nouveau procede de preparation de silices precipitees, nouvelles silices precipitees et leurs utilisations, notamment pour le renforcement de polymeres
MX2019013165A (es) * 2017-05-05 2019-12-18 Rhodia Operations Silice precipitada y proceso para su fabricacion.
JP7472098B2 (ja) * 2018-07-13 2024-04-22 ローディア オペレーションズ 改良された加工特性を有する沈降シリカ
JP6811750B2 (ja) 2018-08-10 2021-01-13 東ソー・シリカ株式会社 ゴム補強充填用含水ケイ酸
JP6811751B2 (ja) 2018-08-10 2021-01-13 東ソー・シリカ株式会社 ゴム補強充填用含水ケイ酸
KR102819122B1 (ko) * 2018-11-08 2025-06-12 로디아 오퍼레이션스 침전 실리카 및 이의 제조 방법
CN110591416A (zh) * 2019-08-23 2019-12-20 广州凌玮科技股份有限公司 一种无定形二氧化硅防锈颜料的制备方法
JP7473350B2 (ja) 2020-02-05 2024-04-23 東ソー・シリカ株式会社 ゴム補強充填剤用含水ケイ酸および含水ケイ酸含有ゴム組成物
EP3992147A1 (de) * 2020-10-28 2022-05-04 Evonik Operations GmbH Gefällte kieselsäuren, verfahren zur deren herstellung und deren verwendung

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005500238A (ja) 2001-08-13 2005-01-06 ロディア・シミ シリカの製造方法、特定の細孔寸法及び／又は粒度分布を有するシリカ並びにそれらの特に重合体強化のための使用
JP2008542163A (ja) 2005-05-27 2008-11-27 ロディア・シミ 沈降シリカの製造方法、それにより得られる沈降シリカ、特にシリコン母材において充填剤としての使用
JP2010513200A (ja) 2006-12-22 2010-04-30 ロディア オペレーションズ 高速ブレンダーを使用した沈降シリカの新規な製造方法
WO2013092745A1 (fr) 2011-12-23 2013-06-27 Rhodia Operations Procede de preparation de silices precipitees

Family Cites Families (8)

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Publication number Priority date Publication date Assignee Title
FR2622565B1 (fr) * 1987-11-04 1990-11-09 Rhone Poulenc Chimie Silice pour compositions dentifrices compatible notamment avec le zinc
FR2732328B1 (fr) * 1995-03-29 1997-06-20 Rhone Poulenc Chimie Nouveau procede de preparation de silice precipitee, nouvelles silices precipitees contenant de l'aluminium et leur utilisation au renforcement des elastomeres
US6086669A (en) * 1998-04-09 2000-07-11 Ppg Industries Ohio, Inc. Dispersible free flowing particulate silica composition
US6482884B1 (en) * 2000-02-28 2002-11-19 Pirelli Pneumatici S.P.A. Silica reinforced rubber compositions of improved processability and storage stability
EP1674520A1 (en) * 2004-12-23 2006-06-28 Rhodia Chimie Elastomeric composition comprizing functionalized butadienic elastomers and high dispersible aluminium-based silica
FR2957914B1 (fr) * 2010-03-25 2015-05-15 Rhodia Operations Nouveau procede de preparation de silices precipitees contenant de l'aluminium
US20130178569A1 (en) * 2010-04-01 2013-07-11 Dow Corning Corporation Use of precipitated silica containing aluminium and 3-acryloxy-propyltriethoxysilane in an isoprenic elastomer composition
FR3017609B1 (fr) 2014-02-14 2016-03-18 Rhodia Operations Nouveau procede de preparation de silices precipitees, nouvelles silices precipitees et leurs utilisations, notamment pour le renforcement de polymeres

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005500238A (ja) 2001-08-13 2005-01-06 ロディア・シミ シリカの製造方法、特定の細孔寸法及び／又は粒度分布を有するシリカ並びにそれらの特に重合体強化のための使用
JP2008542163A (ja) 2005-05-27 2008-11-27 ロディア・シミ 沈降シリカの製造方法、それにより得られる沈降シリカ、特にシリコン母材において充填剤としての使用
JP2010513200A (ja) 2006-12-22 2010-04-30 ロディア オペレーションズ 高速ブレンダーを使用した沈降シリカの新規な製造方法
WO2013092745A1 (fr) 2011-12-23 2013-06-27 Rhodia Operations Procede de preparation de silices precipitees

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Publication number Publication date
US11168204B2 (en) 2021-11-09
CN106029568B (zh) 2019-11-12
US20170058111A1 (en) 2017-03-02
CA2938696A1 (fr) 2015-08-20
TWI715528B (zh) 2021-01-11
CN106029568A (zh) 2016-10-12
FR3017609A1 (fr) 2015-08-21
MX2016010476A (es) 2016-10-31
EP3105182A1 (fr) 2016-12-21
MX389843B (es) 2025-03-20
JP2017514773A (ja) 2017-06-08
KR20160122168A (ko) 2016-10-21
AR099422A1 (es) 2016-07-20
WO2015121332A1 (fr) 2015-08-20
TW201544456A (zh) 2015-12-01
FR3017609B1 (fr) 2016-03-18
JP6567538B2 (ja) 2019-08-28

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