CA2938696A1 - Nouveau procede de preparation de silices precipitees, nouvelles silices precipitees et leurs utilisations, notamment pour le renforcement de polymeres - Google Patents
Nouveau procede de preparation de silices precipitees, nouvelles silices precipitees et leurs utilisations, notamment pour le renforcement de polymeres Download PDFInfo
- Publication number
- CA2938696A1 CA2938696A1 CA2938696A CA2938696A CA2938696A1 CA 2938696 A1 CA2938696 A1 CA 2938696A1 CA 2938696 A CA2938696 A CA 2938696A CA 2938696 A CA2938696 A CA 2938696A CA 2938696 A1 CA2938696 A1 CA 2938696A1
- Authority
- CA
- Canada
- Prior art keywords
- acid
- weight
- polycarboxylic
- mixture
- precipitated silica
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000034 method Methods 0.000 title claims abstract description 47
- 229920000642 polymer Polymers 0.000 title claims description 33
- 230000003014 reinforcing effect Effects 0.000 title description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 273
- 239000002253 acid Substances 0.000 claims abstract description 168
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 135
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 40
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 36
- -1 aluminum compound Chemical class 0.000 claims abstract description 29
- 239000012065 filter cake Substances 0.000 claims abstract description 28
- 239000002535 acidifier Substances 0.000 claims abstract description 27
- 239000000725 suspension Substances 0.000 claims abstract description 24
- 230000008569 process Effects 0.000 claims abstract description 23
- 238000001035 drying Methods 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims description 167
- 150000007513 acids Chemical class 0.000 claims description 50
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 48
- XJMMNTGIMDZPMU-UHFFFAOYSA-N 3-methylglutaric acid Chemical compound OC(=O)CC(C)CC(O)=O XJMMNTGIMDZPMU-UHFFFAOYSA-N 0.000 claims description 40
- 150000007942 carboxylates Chemical class 0.000 claims description 34
- 238000009826 distribution Methods 0.000 claims description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 31
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 28
- 239000012429 reaction media Substances 0.000 claims description 28
- 239000001361 adipic acid Substances 0.000 claims description 24
- 235000011037 adipic acid Nutrition 0.000 claims description 24
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 21
- 238000006243 chemical reaction Methods 0.000 claims description 21
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 21
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 19
- 229910052799 carbon Inorganic materials 0.000 claims description 18
- 239000011148 porous material Substances 0.000 claims description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 16
- 238000001914 filtration Methods 0.000 claims description 16
- 238000002604 ultrasonography Methods 0.000 claims description 16
- RVHOBHMAPRVOLO-UHFFFAOYSA-N 2-ethylbutanedioic acid Chemical compound CCC(C(O)=O)CC(O)=O RVHOBHMAPRVOLO-UHFFFAOYSA-N 0.000 claims description 13
- 150000001991 dicarboxylic acids Chemical class 0.000 claims description 13
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 11
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 claims description 9
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims description 9
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- 239000007789 gas Substances 0.000 claims description 8
- 238000011084 recovery Methods 0.000 claims description 8
- YRTGWRSQRUHPKX-UHFFFAOYSA-N 3-ethyloxolane-2,5-dione Chemical compound CCC1CC(=O)OC1=O YRTGWRSQRUHPKX-UHFFFAOYSA-N 0.000 claims description 7
- 125000001931 aliphatic group Chemical group 0.000 claims description 7
- 239000002585 base Substances 0.000 claims description 7
- 238000001033 granulometry Methods 0.000 claims description 7
- 235000006408 oxalic acid Nutrition 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 238000001556 precipitation Methods 0.000 claims description 6
- 239000012763 reinforcing filler Substances 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- 230000005540 biological transmission Effects 0.000 claims description 5
- 230000006870 function Effects 0.000 claims description 5
- 239000001384 succinic acid Substances 0.000 claims description 5
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 229920006395 saturated elastomer Polymers 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 150000003863 ammonium salts Chemical class 0.000 claims description 2
- 230000004888 barrier function Effects 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 239000003063 flame retardant Substances 0.000 claims description 2
- 150000004965 peroxy acids Chemical class 0.000 claims description 2
- YQLVIOYSGHEJDA-UHFFFAOYSA-N 3-methyloxane-2,6-dione Chemical compound CC1CCC(=O)OC1=O YQLVIOYSGHEJDA-UHFFFAOYSA-N 0.000 claims 1
- 150000008064 anhydrides Chemical class 0.000 claims 1
- 230000003247 decreasing effect Effects 0.000 claims 1
- 238000001356 surgical procedure Methods 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract description 13
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 32
- 239000000523 sample Substances 0.000 description 30
- 238000005259 measurement Methods 0.000 description 22
- 239000000243 solution Substances 0.000 description 21
- 239000007787 solid Substances 0.000 description 18
- 229920001971 elastomer Polymers 0.000 description 14
- 239000002245 particle Substances 0.000 description 13
- 241001441571 Hiodontidae Species 0.000 description 12
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 12
- 229920001577 copolymer Polymers 0.000 description 12
- 229910001388 sodium aluminate Inorganic materials 0.000 description 12
- WXUAQHNMJWJLTG-UHFFFAOYSA-N 2-methylbutanedioic acid Chemical compound OC(=O)C(C)CC(O)=O WXUAQHNMJWJLTG-UHFFFAOYSA-N 0.000 description 10
- 239000000806 elastomer Substances 0.000 description 10
- 230000002787 reinforcement Effects 0.000 description 10
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 10
- 238000004073 vulcanization Methods 0.000 description 10
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 9
- 239000004115 Sodium Silicate Substances 0.000 description 9
- 239000007822 coupling agent Substances 0.000 description 9
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 9
- 229910052911 sodium silicate Inorganic materials 0.000 description 9
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 8
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 8
- 238000005507 spraying Methods 0.000 description 8
- 230000006872 improvement Effects 0.000 description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- 239000002174 Styrene-butadiene Substances 0.000 description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- 235000015165 citric acid Nutrition 0.000 description 6
- 238000000227 grinding Methods 0.000 description 6
- 230000014759 maintenance of location Effects 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 230000009467 reduction Effects 0.000 description 6
- 238000000518 rheometry Methods 0.000 description 6
- 229920003048 styrene butadiene rubber Polymers 0.000 description 6
- 229910052717 sulfur Inorganic materials 0.000 description 6
- BTUDGPVTCYNYLK-UHFFFAOYSA-N 2,2-dimethylglutaric acid Chemical compound OC(=O)C(C)(C)CCC(O)=O BTUDGPVTCYNYLK-UHFFFAOYSA-N 0.000 description 5
- WDBZEBXYXWWDPJ-UHFFFAOYSA-N 3-(2-methylphenoxy)propanoic acid Chemical compound CC1=CC=CC=C1OCCC(O)=O WDBZEBXYXWWDPJ-UHFFFAOYSA-N 0.000 description 5
- 230000005526 G1 to G0 transition Effects 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 5
- 239000011324 bead Substances 0.000 description 5
- 239000008367 deionised water Substances 0.000 description 5
- 229910021641 deionized water Inorganic materials 0.000 description 5
- 239000003792 electrolyte Substances 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- 239000008187 granular material Substances 0.000 description 5
- 239000008188 pellet Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 4
- ODBLHEXUDAPZAU-ZAFYKAAXSA-N D-threo-isocitric acid Chemical compound OC(=O)[C@H](O)[C@@H](C(O)=O)CC(O)=O ODBLHEXUDAPZAU-ZAFYKAAXSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- ODBLHEXUDAPZAU-FONMRSAGSA-N Isocitric acid Natural products OC(=O)[C@@H](O)[C@H](C(O)=O)CC(O)=O ODBLHEXUDAPZAU-FONMRSAGSA-N 0.000 description 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- 229910004298 SiO 2 Inorganic materials 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- 230000009471 action Effects 0.000 description 4
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 4
- 235000006708 antioxidants Nutrition 0.000 description 4
- 229910052681 coesite Inorganic materials 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 229910052906 cristobalite Inorganic materials 0.000 description 4
- 230000001186 cumulative effect Effects 0.000 description 4
- 229910003460 diamond Inorganic materials 0.000 description 4
- 239000010432 diamond Substances 0.000 description 4
- 230000000670 limiting effect Effects 0.000 description 4
- 239000001630 malic acid Substances 0.000 description 4
- 235000011090 malic acid Nutrition 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 4
- 239000005077 polysulfide Substances 0.000 description 4
- 229920001021 polysulfide Polymers 0.000 description 4
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- 230000005070 ripening Effects 0.000 description 4
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- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 4
- 229960002447 thiram Drugs 0.000 description 4
- ODBLHEXUDAPZAU-UHFFFAOYSA-N threo-D-isocitric acid Natural products OC(=O)C(O)C(C(O)=O)CC(O)=O ODBLHEXUDAPZAU-UHFFFAOYSA-N 0.000 description 4
- KQTIIICEAUMSDG-UHFFFAOYSA-N tricarballylic acid Chemical compound OC(=O)CC(C(O)=O)CC(O)=O KQTIIICEAUMSDG-UHFFFAOYSA-N 0.000 description 4
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- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
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- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 3
- 244000043261 Hevea brasiliensis Species 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
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- BTGRAWJCKBQKAO-UHFFFAOYSA-N adiponitrile Chemical compound N#CCCCCC#N BTGRAWJCKBQKAO-UHFFFAOYSA-N 0.000 description 3
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- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 2
- WVUYYXUATWMVIT-UHFFFAOYSA-N 1-bromo-4-ethoxybenzene Chemical compound CCOC1=CC=C(Br)C=C1 WVUYYXUATWMVIT-UHFFFAOYSA-N 0.000 description 2
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- 239000007900 aqueous suspension Substances 0.000 description 2
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- 230000008901 benefit Effects 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
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- 239000001307 helium Substances 0.000 description 2
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- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
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- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- RLAWWYSOJDYHDC-BZSNNMDCSA-N lisinopril Chemical compound C([C@H](N[C@@H](CCCCN)C(=O)N1[C@@H](CCC1)C(O)=O)C(O)=O)CC1=CC=CC=C1 RLAWWYSOJDYHDC-BZSNNMDCSA-N 0.000 description 2
- 238000000691 measurement method Methods 0.000 description 2
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Classifications
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- C—CHEMISTRY; METALLURGY
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/18—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
- C01B33/187—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates
- C01B33/193—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates of aqueous solutions of silicates
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/06—Quartz; Sand
- C04B14/066—Precipitated or pyrogenic silica
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/28—Compounds of silicon
- C09C1/30—Silicic acid
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/28—Compounds of silicon
- C09C1/30—Silicic acid
- C09C1/3045—Treatment with inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/28—Compounds of silicon
- C09C1/30—Silicic acid
- C09C1/3063—Treatment with low-molecular organic compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2509/00—Use of inorganic materials not provided for in groups B29K2503/00 - B29K2507/00, as filler
- B29K2509/02—Ceramics
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
- C01P2002/54—Solid solutions containing elements as dopants one element only
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/54—Particles characterised by their aspect ratio, i.e. the ratio of sizes in the longest to the shortest dimension
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/14—Pore volume
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/90—Other properties not specified above
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/006—Additives being defined by their surface area
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Civil Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicon Compounds (AREA)
- Paints Or Removers (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1400414A FR3017609B1 (fr) | 2014-02-14 | 2014-02-14 | Nouveau procede de preparation de silices precipitees, nouvelles silices precipitees et leurs utilisations, notamment pour le renforcement de polymeres |
| FR1400414 | 2014-02-14 | ||
| PCT/EP2015/052920 WO2015121332A1 (fr) | 2014-02-14 | 2015-02-12 | Nouveau procede de preparation de silices precipitees, nouvelles silices precipitees et leurs utilisations, notamment pour le renforcement de polymeres |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2938696A1 true CA2938696A1 (fr) | 2015-08-20 |
Family
ID=50639689
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2938696A Abandoned CA2938696A1 (fr) | 2014-02-14 | 2015-02-12 | Nouveau procede de preparation de silices precipitees, nouvelles silices precipitees et leurs utilisations, notamment pour le renforcement de polymeres |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US11168204B2 (enExample) |
| EP (1) | EP3105182A1 (enExample) |
| JP (1) | JP6567538B2 (enExample) |
| KR (1) | KR102397679B1 (enExample) |
| CN (1) | CN106029568B (enExample) |
| AR (1) | AR099422A1 (enExample) |
| CA (1) | CA2938696A1 (enExample) |
| FR (1) | FR3017609B1 (enExample) |
| MX (1) | MX389843B (enExample) |
| TW (1) | TWI715528B (enExample) |
| WO (1) | WO2015121332A1 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3017609B1 (fr) | 2014-02-14 | 2016-03-18 | Rhodia Operations | Nouveau procede de preparation de silices precipitees, nouvelles silices precipitees et leurs utilisations, notamment pour le renforcement de polymeres |
| FR3017610B1 (fr) * | 2014-02-14 | 2016-03-18 | Rhodia Operations | Nouveau procede de preparation de silices precipitees, nouvelles silices precipitees et leurs utilisations, notamment pour le renforcement de polymeres |
| FR3018070B1 (fr) * | 2014-02-28 | 2017-09-15 | Rhodia Operations | Nouveau procede de preparation de silices precipitees, nouvelles silices precipitees et leurs utilisations, notamment pour le renforcement de polymeres |
| FR3018071B1 (fr) * | 2014-02-28 | 2016-02-26 | Rhodia Operations | Nouveau procede de preparation de silices precipitees, nouvelles silices precipitees et leurs utilisations, notamment pour le renforcement de polymeres |
| BR112019023218A2 (pt) * | 2017-05-05 | 2020-05-26 | Rhodia Operations | Sílica precipitada e processo para sua fabricação |
| EP3820816A1 (en) * | 2018-07-13 | 2021-05-19 | Rhodia Operations | Precipitated silica with improved processing properties |
| JP6811750B2 (ja) | 2018-08-10 | 2021-01-13 | 東ソー・シリカ株式会社 | ゴム補強充填用含水ケイ酸 |
| JP6811751B2 (ja) | 2018-08-10 | 2021-01-13 | 東ソー・シリカ株式会社 | ゴム補強充填用含水ケイ酸 |
| US12145853B2 (en) * | 2018-11-08 | 2024-11-19 | Rhodia Operations | Precipitated silica and process for its manufacture |
| CN110591416A (zh) * | 2019-08-23 | 2019-12-20 | 广州凌玮科技股份有限公司 | 一种无定形二氧化硅防锈颜料的制备方法 |
| JP7473350B2 (ja) | 2020-02-05 | 2024-04-23 | 東ソー・シリカ株式会社 | ゴム補強充填剤用含水ケイ酸および含水ケイ酸含有ゴム組成物 |
| EP3992147A1 (de) * | 2020-10-28 | 2022-05-04 | Evonik Operations GmbH | Gefällte kieselsäuren, verfahren zur deren herstellung und deren verwendung |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2622565B1 (fr) * | 1987-11-04 | 1990-11-09 | Rhone Poulenc Chimie | Silice pour compositions dentifrices compatible notamment avec le zinc |
| FR2732328B1 (fr) * | 1995-03-29 | 1997-06-20 | Rhone Poulenc Chimie | Nouveau procede de preparation de silice precipitee, nouvelles silices precipitees contenant de l'aluminium et leur utilisation au renforcement des elastomeres |
| US6086669A (en) * | 1998-04-09 | 2000-07-11 | Ppg Industries Ohio, Inc. | Dispersible free flowing particulate silica composition |
| US6482884B1 (en) * | 2000-02-28 | 2002-11-19 | Pirelli Pneumatici S.P.A. | Silica reinforced rubber compositions of improved processability and storage stability |
| US20050032965A1 (en) * | 2001-08-13 | 2005-02-10 | Remi Valero | Method of preparing silicas, silicas with specific pore-size and/or particle-size distribution, and the uses thereof, in particular for reinforcing polymers |
| EP1674520A1 (en) * | 2004-12-23 | 2006-06-28 | Rhodia Chimie | Elastomeric composition comprizing functionalized butadienic elastomers and high dispersible aluminium-based silica |
| FR2886285B1 (fr) * | 2005-05-27 | 2008-05-30 | Rhodia Chimie Sa | Procede de preparation de silice precipitee, silice precipitee et utilisations, notamment comme charge dans les matrices silicones |
| FR2910459B1 (fr) * | 2006-12-22 | 2010-09-17 | Rhodia Recherches & Tech | Nouveau procede de preparation de silices precipitees par mise en oeuvre d'un melangeur rapide |
| FR2957914B1 (fr) * | 2010-03-25 | 2015-05-15 | Rhodia Operations | Nouveau procede de preparation de silices precipitees contenant de l'aluminium |
| CN102869521A (zh) * | 2010-04-01 | 2013-01-09 | 罗地亚管理公司 | 含有铝的沉淀二氧化硅和3-丙烯酰氧基丙基三乙氧基硅烷在异戊二烯弹性体组合物中的用途 |
| AU2012357112A1 (en) * | 2011-12-23 | 2014-07-10 | Rhodia Operations | Precipitated-silica production method |
| FR3017609B1 (fr) | 2014-02-14 | 2016-03-18 | Rhodia Operations | Nouveau procede de preparation de silices precipitees, nouvelles silices precipitees et leurs utilisations, notamment pour le renforcement de polymeres |
-
2014
- 2014-02-14 FR FR1400414A patent/FR3017609B1/fr not_active Expired - Fee Related
-
2015
- 2015-02-12 US US15/118,695 patent/US11168204B2/en not_active Expired - Fee Related
- 2015-02-12 MX MX2016010476A patent/MX389843B/es unknown
- 2015-02-12 EP EP15704522.0A patent/EP3105182A1/fr not_active Withdrawn
- 2015-02-12 KR KR1020167022693A patent/KR102397679B1/ko active Active
- 2015-02-12 WO PCT/EP2015/052920 patent/WO2015121332A1/fr not_active Ceased
- 2015-02-12 JP JP2016551744A patent/JP6567538B2/ja not_active Expired - Fee Related
- 2015-02-12 CN CN201580008499.3A patent/CN106029568B/zh not_active Expired - Fee Related
- 2015-02-12 CA CA2938696A patent/CA2938696A1/fr not_active Abandoned
- 2015-02-13 AR ARP150100436A patent/AR099422A1/es active IP Right Grant
- 2015-02-13 TW TW104105164A patent/TWI715528B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CN106029568A (zh) | 2016-10-12 |
| CN106029568B (zh) | 2019-11-12 |
| TWI715528B (zh) | 2021-01-11 |
| FR3017609A1 (fr) | 2015-08-21 |
| EP3105182A1 (fr) | 2016-12-21 |
| JP6567538B2 (ja) | 2019-08-28 |
| KR102397679B1 (ko) | 2022-05-13 |
| WO2015121332A1 (fr) | 2015-08-20 |
| TW201544456A (zh) | 2015-12-01 |
| AR099422A1 (es) | 2016-07-20 |
| MX2016010476A (es) | 2016-10-31 |
| KR20160122168A (ko) | 2016-10-21 |
| JP2017514773A (ja) | 2017-06-08 |
| US11168204B2 (en) | 2021-11-09 |
| FR3017609B1 (fr) | 2016-03-18 |
| MX389843B (es) | 2025-03-20 |
| US20170058111A1 (en) | 2017-03-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |
Effective date: 20200113 |
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| EEER | Examination request |
Effective date: 20200113 |
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| FZDE | Discontinued |
Effective date: 20230404 |
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| FZDE | Discontinued |
Effective date: 20230404 |