KR102298298B1 - 비스무트계 클로라이드-저장 전극 - Google Patents

비스무트계 클로라이드-저장 전극 Download PDF

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KR102298298B1
KR102298298B1 KR1020197023706A KR20197023706A KR102298298B1 KR 102298298 B1 KR102298298 B1 KR 102298298B1 KR 1020197023706 A KR1020197023706 A KR 1020197023706A KR 20197023706 A KR20197023706 A KR 20197023706A KR 102298298 B1 KR102298298 B1 KR 102298298B1
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electrode
chloride
electrolyte solution
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KR20190102284A (ko
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경신 최
도환 남
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위스콘신 얼럼나이 리서어치 화운데이션
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/4604Treatment of water, waste water, or sewage by electrochemical methods for desalination of seawater or brackish water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/36Accumulators not provided for in groups H01M10/05-H01M10/34
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/44Methods for charging or discharging
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/38Selection of substances as active materials, active masses, active liquids of elements or alloys
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/58Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • H01M4/9041Metals or alloys
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/22Fuel cells in which the fuel is based on materials comprising carbon or oxygen or hydrogen and other elements; Fuel cells in which the fuel is based on materials comprising only elements other than carbon, oxygen or hydrogen
    • H01M8/227Dialytic cells or batteries; Reverse electrodialysis cells or batteries
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • C02F2001/46133Electrodes characterised by the material
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • C02F2001/46152Electrodes characterised by the shape or form
    • C02F2001/46157Perforated or foraminous electrodes
    • C02F2001/46161Porous electrodes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/08Seawater, e.g. for desalination
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Materials Engineering (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Hybrid Cells (AREA)
  • Secondary Cells (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Ceramic Capacitors (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Molecular Biology (AREA)
KR1020197023706A 2017-01-18 2017-10-31 비스무트계 클로라이드-저장 전극 Active KR102298298B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US15/408,980 2017-01-18
US15/408,980 US10414674B2 (en) 2017-01-18 2017-01-18 Bismuth-based chloride-storage electrodes
PCT/US2017/059366 WO2018136130A1 (en) 2017-01-18 2017-10-31 Bismuth-based chloride-storage electrodes

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KR20190102284A KR20190102284A (ko) 2019-09-03
KR102298298B1 true KR102298298B1 (ko) 2021-09-06

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US (2) US10414674B2 (enExample)
EP (2) EP3571165B1 (enExample)
JP (1) JP6959344B2 (enExample)
KR (1) KR102298298B1 (enExample)
CN (1) CN110325481B (enExample)
AU (1) AU2017394846B2 (enExample)
ES (1) ES2911031T3 (enExample)
IL (1) IL268067B2 (enExample)
SG (1) SG11201906646SA (enExample)
WO (1) WO2018136130A1 (enExample)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11289700B2 (en) 2016-06-28 2022-03-29 The Research Foundation For The State University Of New York KVOPO4 cathode for sodium ion batteries
CN111924987B (zh) * 2020-07-16 2022-12-06 中国科学院合肥物质科学研究院 一种硬水中选择性吸附钙离子的方法以及CuHCF的应用
CN111744508B (zh) * 2020-07-20 2023-04-25 铜仁学院 一种光催化剂及其制备方法和应用
US11757140B2 (en) * 2021-02-02 2023-09-12 Wisconsin Alumni Research Foundation Aqueous energy storage systems with desalination capabilities
CN115395010A (zh) * 2021-05-24 2022-11-25 新加坡国立大学 水系双离子电池
CN113620386B (zh) * 2021-08-19 2023-08-08 南方科技大学 一种电极材料及其制备方法与在水体氯离子和钠离子去除中的应用
CN114182269B (zh) * 2021-12-22 2023-05-23 浙江工业大学 一种电化学还原脱氯转化含氯挥发性有机物的方法
CN114669308A (zh) * 2022-04-01 2022-06-28 哈尔滨理工大学 一种借助电化学法原位反应制备BiOCl/Bi24O31Cl10复合粉体的方法
CN116986681A (zh) * 2022-04-25 2023-11-03 哈尔滨工业大学(深圳) 一种铋碳电极材料及其制备方法和应用
CN115626692B (zh) * 2022-10-20 2025-11-18 中南大学 一种cdi电极活性材料及其制备和应用
CN116479441A (zh) * 2023-04-17 2023-07-25 南方科技大学 晶格脱盐法制备BiOX及其电催化产卤素单质的应用
CN117417032B (zh) * 2023-10-11 2024-10-11 华南理工大学 一种高选择性析氯阳极的制备及应用

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
LU61436A1 (enExample) 1970-07-29 1972-04-04
NO141419C (no) * 1974-02-02 1980-03-05 Sigri Elektrographit Gmbh Elektrode for elektrokjemiske prosesser
US20080107965A1 (en) 2004-11-29 2008-05-08 Toshiba Battery Co., Ltd. Battery With Nonaqueous Electrolyte
US7494583B2 (en) 2005-06-29 2009-02-24 Oleh Weres Electrode with surface comprising oxides of titanium and bismuth and water purification process using this electrode
GR1006516B (el) * 2008-06-30 2009-09-02 ΑΡΙΣΤΟΤΕΛΕΙΟ ΠΑΝΕΠΙΣΤΗΜΙΟ ΘΕΣΣΑΛΟΝΙΚΗΣ-ΕΙΔΙΚΟΣ ΛΟΓΑΡΙΑΣΜΟΣ ΑΞΙΟΠΟΙΗΣΗΣ ΚΟΝΔΥΛΙΩΝ ΕΡΕΥΝΑΣ (κατά ποσοστό 40%) Μεθοδος της ηλετροχημικης απομακρυνσης των νιτρικων 'η των νιτρωδων ιοντων απο υδατικα διαλυματα σε καθοδο βισμουθιου
US20110100328A1 (en) 2009-10-29 2011-05-05 Prime Core Tech LLC. Electrolysis apparatus and related devices and methods
WO2012061429A2 (en) 2010-11-02 2012-05-10 Fabio La Mantia Batteries for efficient energy extraction from a salinity difference
SA112330516B1 (ar) 2011-05-19 2016-02-22 كاليرا كوربوريشن انظمة وطرق هيدروكسيد كهروكيميائية مستخدمة لأكسدة المعدن
US20130319876A1 (en) 2011-11-23 2013-12-05 United States Government, As Represented By The Secretary Of The Navy Mercury-free fusible alloy for electrolyzing salts
CN103643254B (zh) * 2013-11-08 2016-04-06 江苏大学 在fto上进行二氧化钛/氯氧化铋复合电极的合成方法
WO2015138816A1 (en) * 2014-03-13 2015-09-17 Eaglepicher Technologies, LLC. Alkali metal halide cells
US20160072128A1 (en) 2014-09-08 2016-03-10 Board Of Trustees Of The Leland Stanford Junior University Manganese hexacyanomanganate as a high-capacity positive electrode for rechargeable batteries
US10396404B2 (en) * 2015-02-27 2019-08-27 Massachusetts Institute Of Technology Electrochemical cell with bipolar faradaic membrane
CN105772044B (zh) * 2016-03-24 2018-02-27 太原理工大学 一种复合薄膜光催化剂BiPO4/BiOCl的电化学制备及应用方法
CN105821436B (zh) 2016-05-09 2018-07-24 复旦大学 一种基于三电极体系的双电解槽两步法氯碱电解方法及装置

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
Hexiang Zhong 외 5인, Bismuth nanodendrites as a high performanceelectrocatalyst for selective conversion of CO2 to formate. Journal of Materials Chemistry A. 18 August 2016. Vol.4. pp 13746-13753. 1부*
Kangwoo Cho 외 2인, Electrochemical treatment of human waste coupledwith molecular hydrogen production. The Royal Society of Chemistry Advances. 29 November 2013. Vol.4. pp 4596-4608. 1부*
Sun Il Park 외 3인, Electrochemical properties of NaTi2(PO4)3 anode for rechargeable aqueous sodium-ion batteries. Journal of the electrochemical Society. 27 July 2011. Vol.158. pp A1067- A1070. 1부*

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EP4019669A1 (en) 2022-06-29
SG11201906646SA (en) 2019-08-27
JP2020507885A (ja) 2020-03-12
US10414674B2 (en) 2019-09-17
EP3571165A4 (en) 2020-01-08
IL268067A (en) 2019-09-26
IL268067B (en) 2022-10-01
US20180201524A1 (en) 2018-07-19
CN110325481A (zh) 2019-10-11
ES2911031T3 (es) 2022-05-17
CN110325481B (zh) 2022-04-26
EP3571165B1 (en) 2022-03-23
AU2017394846B2 (en) 2022-10-13
US20190382288A1 (en) 2019-12-19
IL268067B2 (en) 2023-02-01
WO2018136130A1 (en) 2018-07-26
EP3571165A1 (en) 2019-11-27
JP6959344B2 (ja) 2021-11-02
AU2017394846A1 (en) 2019-08-01
US11498854B2 (en) 2022-11-15
KR20190102284A (ko) 2019-09-03

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