KR102266575B1 - 실란올 관능기를 갖는 커플링에 의해 개질된 디엔 엘라스토머, 이의 합성 방법 및 이를 포함하는 고무 조성물 - Google Patents

실란올 관능기를 갖는 커플링에 의해 개질된 디엔 엘라스토머, 이의 합성 방법 및 이를 포함하는 고무 조성물 Download PDF

Info

Publication number
KR102266575B1
KR102266575B1 KR1020167006060A KR20167006060A KR102266575B1 KR 102266575 B1 KR102266575 B1 KR 102266575B1 KR 1020167006060 A KR1020167006060 A KR 1020167006060A KR 20167006060 A KR20167006060 A KR 20167006060A KR 102266575 B1 KR102266575 B1 KR 102266575B1
Authority
KR
South Korea
Prior art keywords
diene elastomer
elastomer
modified diene
group
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020167006060A
Other languages
English (en)
Korean (ko)
Other versions
KR20160042952A (ko
Inventor
샤를로트 디르
장-마르크 마레샬
마르가리타 도라토
Original Assignee
꽁빠니 제네날 드 에따블리세망 미쉘린
미쉐린 러쉐르슈 에 떼크니크 에스.에이.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 꽁빠니 제네날 드 에따블리세망 미쉘린, 미쉐린 러쉐르슈 에 떼크니크 에스.에이. filed Critical 꽁빠니 제네날 드 에따블리세망 미쉘린
Publication of KR20160042952A publication Critical patent/KR20160042952A/ko
Application granted granted Critical
Publication of KR102266575B1 publication Critical patent/KR102266575B1/ko
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/25—Incorporating silicon atoms into the molecule
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0016—Compositions of the tread
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
    • C08C19/42—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
    • C08C19/44—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/046—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes polymerising vinyl aromatic monomers and isoprene, optionally with other conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/013—Fillers, pigments or reinforcing additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L15/00—Compositions of rubber derivatives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Inorganic Chemistry (AREA)
KR1020167006060A 2013-08-08 2014-07-11 실란올 관능기를 갖는 커플링에 의해 개질된 디엔 엘라스토머, 이의 합성 방법 및 이를 포함하는 고무 조성물 Active KR102266575B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1357889A FR3009560B1 (fr) 2013-08-08 2013-08-08 Elastomere dienique modifie par couplage porteur de fonctions silanol, son procede de synthese et composition de caoutchouc le comprenant.
FR1357889 2013-08-08
PCT/EP2014/064980 WO2015018600A1 (fr) 2013-08-08 2014-07-11 Elastomère diénique modifié par couplage porteur de fonctions silanol, son procédé de synthèse et composition de caoutchouc le comprenant

Publications (2)

Publication Number Publication Date
KR20160042952A KR20160042952A (ko) 2016-04-20
KR102266575B1 true KR102266575B1 (ko) 2021-06-21

Family

ID=49876776

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020167006060A Active KR102266575B1 (ko) 2013-08-08 2014-07-11 실란올 관능기를 갖는 커플링에 의해 개질된 디엔 엘라스토머, 이의 합성 방법 및 이를 포함하는 고무 조성물

Country Status (9)

Country Link
US (1) US9856330B2 (https=)
EP (1) EP3030588B1 (https=)
JP (1) JP2016527370A (https=)
KR (1) KR102266575B1 (https=)
FR (1) FR3009560B1 (https=)
HU (1) HUE037919T2 (https=)
PL (1) PL3030588T3 (https=)
SG (1) SG11201600590SA (https=)
WO (1) WO2015018600A1 (https=)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE112014001128T5 (de) * 2013-03-07 2015-12-10 Toyo Tire & Rubber Co., Ltd. Verfahren zur Herstellung eines modifizierten Polymers und Kautschukzusammensetzung
US9976013B2 (en) * 2013-07-31 2018-05-22 Toyo Tire & Rubber Co., Ltd. Rubber-silica composite and method for producing same, and rubber composition and pneumatic tire
FR3009557B1 (fr) * 2013-08-09 2015-09-11 Michelin & Cie Elastomere dienique modifie comprenant un elastomere dienique couple par un compose aminoalcoxysilane et fonctionnalise amine en extremite de chaine et composition de caoutchouc le comprenant
FR3060452A1 (fr) * 2016-12-20 2018-06-22 Compagnie Generale Des Etablissements Michelin Pneumatique pour vehicule portant des lourdes charges comprenant une nouvelle bande de roulement
FR3060580A1 (fr) 2016-12-21 2018-06-22 Compagnie Generale Des Etablissements Michelin Procede de polymerisation continu d'elastomere dienique avec initiateur amidure de lithium
FR3060578A1 (fr) 2016-12-21 2018-06-22 Compagnie Generale Des Etablissements Michelin Procede de synthese en continu d'elastomere dienique avec initiateur amidure de lithium
FR3060579A1 (fr) 2016-12-21 2018-06-22 Compagnie Generale Des Etablissements Michelin Procede de synthese en continu d'elastomere dienique modifie avec initiateur amidure de lithium
FR3060581A1 (fr) 2016-12-21 2018-06-22 Compagnie Generale Des Etablissements Michelin Procede de polymerisation continu d'elastomere dienique modifie avec initiateur amidure de lithium
KR101857392B1 (ko) 2017-01-03 2018-06-19 주식회사 엘지화학 변성 공액디엔계 중합체 제조방법
US10671083B2 (en) 2017-09-13 2020-06-02 Tusimple, Inc. Neural network architecture system for deep odometry assisted by static scene optical flow
US10552979B2 (en) 2017-09-13 2020-02-04 TuSimple Output of a neural network method for deep odometry assisted by static scene optical flow
WO2019115470A1 (fr) 2017-12-11 2019-06-20 Compagnie Generale Des Etablissements Michelin Procédé de synthèse d'un polymère fonctionnel ou non à structure particulière
EP4495146A3 (en) 2019-05-07 2025-04-09 Bridgestone Americas Tire Operations, LLC Modified high-cis polybutadiene polymer, related methods and rubber compositions
CN113825777B (zh) 2019-05-14 2025-01-28 株式会社普利司通 改性的高顺式聚丁二烯聚合物、相关方法和轮胎部件
CN113574077B (zh) 2019-09-11 2024-01-09 株式会社Lg化学 改性共轭二烯类聚合物、它的制备方法和包含它的橡胶组合物
KR102604539B1 (ko) 2019-09-11 2023-11-22 주식회사 엘지화학 변성 공액디엔계 중합체, 이의 제조방법 및 이를 포함하는 고무 조성물
WO2021049914A1 (ko) 2019-09-11 2021-03-18 주식회사 엘지화학 변성 공액디엔계 중합체 및 이를 포함하는 고무 조성물
TWI845759B (zh) 2019-09-11 2024-06-21 南韓商Ｌｇ化學股份有限公司 改質之共軛二烯系聚合物、其製備方法及包含彼之橡膠組成物
SG11202108200TA (en) 2019-09-11 2021-08-30 Lg Chemical Ltd Modified conjugated diene-based polymer and rubber composition including the same
CN120957875A (zh) 2023-03-28 2025-11-14 米其林集团总公司 包含特定增塑体系的橡胶组合物

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009242788A (ja) 2008-03-10 2009-10-22 Bridgestone Corp ゴム組成物及びそれを用いたタイヤ
JP2010525087A (ja) 2007-04-18 2010-07-22 ソシエテ ド テクノロジー ミシュラン 鎖中央にシラノールを有する単峰性結合ジエンエラストマー、その製造方法、およびそれを含むゴム組成物
JP2012201863A (ja) * 2011-03-28 2012-10-22 Japan Elastomer Co Ltd 変性共役ジエン系重合体組成物及びその製造方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0270071B1 (en) * 1986-12-01 1994-03-02 Sumitomo Chemical Company, Limited Process for preparing modified diene polymer rubbers
ATE427969T1 (de) * 2001-09-27 2009-04-15 Jsr Corp (co)polymerkautschuk auf basis von konjugiertem diolefin, verfahren zur herstellung von (co)polymerkautschuk, kautschukzusammensetzung, verbundwerkstoff und reifen
US6998448B2 (en) 2002-09-16 2006-02-14 The Goodyear Tire & Rubber Company Tire with tread of CIS 1,4-polybutadiene rich rubber composition which contains a functional styrene/butadiene elastomer, silica and coupling agent
ATE493445T1 (de) * 2006-07-24 2011-01-15 Asahi Kasei Chemicals Corp Modifiziertes polymer auf basis von konjugiertem dien und herstellungsverfahren dafür
JP5547058B2 (ja) * 2008-03-10 2014-07-09 株式会社ブリヂストン 変性共役ジエン（共）重合体の製造方法、変性共役ジエン（共）重合体、並びにそれを用いたゴム組成物及びタイヤ
FR2930554B1 (fr) * 2008-04-29 2012-08-17 Michelin Soc Tech Melange elastomerique comprenant majoritairement un elastomere dienique couple par un groupe amino-alcoxysilane, composition de caoutchouc le comprenant et leurs procedes d'obtention.
US8071689B2 (en) * 2008-09-10 2011-12-06 The Goodyear Tire & Rubber Company Methods of making siloxy-amine functionalized rubbery polymers and uses thereof in rubber compositions for tires
EP2700658B1 (en) * 2010-04-16 2017-02-22 Asahi Kasei Kabushiki Kaisha Process for producing modified conjugated diene polymer, modified conjugated diene polymer, and composition of modified conjugated diene polymer
JP6004677B2 (ja) * 2011-03-31 2016-10-12 住友化学株式会社 変性共役ジエン系重合体の製造方法、変性共役ジエン系重合体、及び重合体組成物
JP5728295B2 (ja) * 2011-05-27 2015-06-03 日本エラストマー株式会社 変性共役ジエン系共重合体の製造方法、変性共役ジエン系共重合体及び変性共役ジエン系共重合体組成物
HUE028326T2 (en) * 2011-12-07 2016-12-28 Jsr Corp A method for producing a modified polymer and hydrogen adduct
FR3009559A1 (fr) * 2013-08-08 2015-02-13 Michelin & Cie Elastomere dienique modifie, son procede de synthese et composition de caoutchouc le comprenant
FR3009558B1 (fr) * 2013-08-09 2015-09-04 Michelin & Cie Elastomere dienique couple possedant une fonction silanol en milieu de chaine et fonctionnalise amine en extremite de chaine et composition de caoutchouc le comprenant
FR3009557B1 (fr) * 2013-08-09 2015-09-11 Michelin & Cie Elastomere dienique modifie comprenant un elastomere dienique couple par un compose aminoalcoxysilane et fonctionnalise amine en extremite de chaine et composition de caoutchouc le comprenant

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010525087A (ja) 2007-04-18 2010-07-22 ソシエテ ド テクノロジー ミシュラン 鎖中央にシラノールを有する単峰性結合ジエンエラストマー、その製造方法、およびそれを含むゴム組成物
JP2009242788A (ja) 2008-03-10 2009-10-22 Bridgestone Corp ゴム組成物及びそれを用いたタイヤ
JP2012201863A (ja) * 2011-03-28 2012-10-22 Japan Elastomer Co Ltd 変性共役ジエン系重合体組成物及びその製造方法

Also Published As

Publication number Publication date
JP2016527370A (ja) 2016-09-08
EP3030588A1 (fr) 2016-06-15
HUE037919T2 (hu) 2018-09-28
FR3009560B1 (fr) 2018-01-05
US9856330B2 (en) 2018-01-02
FR3009560A1 (fr) 2015-02-13
US20160362504A1 (en) 2016-12-15
WO2015018600A1 (fr) 2015-02-12
EP3030588B1 (fr) 2018-03-28
SG11201600590SA (en) 2016-02-26
PL3030588T3 (pl) 2018-08-31
KR20160042952A (ko) 2016-04-20

Similar Documents

Publication Publication Date Title
KR102266575B1 (ko) 실란올 관능기를 갖는 커플링에 의해 개질된 디엔 엘라스토머, 이의 합성 방법 및 이를 포함하는 고무 조성물
US10093750B2 (en) Modified diene elastomer comprising a diene elastomer coupled by an aminoalkoxysilane compound and having an amine function at the chain end, and rubber composition comprising same
US10233312B2 (en) Modified diene elastomer, synthesis method for same, and rubber composition comprising modified diene elastomer
CN102933613B (zh) 改性聚合物组合物
JP6709157B2 (ja) 変性ジエンエラストマーおよびそれを含有するゴム組成物
DK3280766T3 (en) Elastomeric copolymers based on [bis (trihydrocarbylsilyl) aminosilyl] functionalized styrene and their use in the production of rubber
CN102933609B (zh) 改性聚合物组合物
KR102195791B1 (ko) [비스(트리하이드로카르빌실릴)아미노실릴]-관능화 스티렌 기반의 탄성 공중합체 및 고무 제조에서의 그의 용도
CN104603157B (zh) 改性共轭二烯聚合物、其制备方法及包含所述改性共轭二烯聚合物的橡胶组合物
CN108473620B (zh) 改性共轭二烯类聚合物及其制备方法
CN111201255A (zh) 改性共轭二烯类聚合物和包含该改性共轭二烯类聚合物的橡胶组合物
US10093751B2 (en) Modified diene elastomer predominantly comprising a diene elastomer coupled by an alkoxysilane compound bearing an epoxide group and amine-functionalized at the end of the chain
KR102220057B1 (ko) 공액 다이엔계 고무의 제조방법 및 해당 고무의 복합체
JP6964184B2 (ja) 変性共役ジエン系重合体およびそれを含むゴム組成物
CN106068286A (zh) 改性共轭二烯聚合物，包含其的改性橡胶组合物，以及制备该改性共轭二烯聚合物的方法
KR20180081440A (ko) 아민 화합물, 이로부터 유래된 작용기를 포함하는 변성 공액디엔계 중합체 및 변성 공액디엔계 중합체의 제조방법
JP5728295B2 (ja) 変性共役ジエン系共重合体の製造方法、変性共役ジエン系共重合体及び変性共役ジエン系共重合体組成物
KR102923648B1 (ko) 변성 공액디엔계 중합체, 이의 제조방법 및 이를 포함하는 고무 조성물
CN108323167B (zh) 改性共轭二烯类聚合物及其制备方法
KR102821407B1 (ko) 이민기 함유 실록산계 화합물, 이의 유래 작용기를 포함하는 변성 공액디엔계 중합체 및 상기 중합체를 포함하는 고무 조성물
KR101615004B1 (ko) 변성 공액디엔계 중합체와 제조방법 및 변성 공액디엔계 중합체 조성물
EP2604631A1 (en) Modified conjugated diene rubber, method and composition thereof
EP2604630A2 (en) Conjugated Diene Rubber Modified With Polar Alkoxysilane, Method and Composition Thereof
KR20130067217A (ko) 극성 알콕시실란에 의해 변성된 공액 다이엔 고무, 그의 제조 방법 및 조성물
KR20210031261A (ko) 변성 공액디엔계 중합체, 이의 제조방법 및 이를 포함하는 고무 조성물

Legal Events

Date Code Title Description
PA0105 International application

Patent event date: 20160307

Patent event code: PA01051R01D

Comment text: International Patent Application

PG1501 Laying open of application
A201 Request for examination
PA0201 Request for examination

Patent event code: PA02012R01D

Patent event date: 20190710

Comment text: Request for Examination of Application

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

Comment text: Notification of reason for refusal

Patent event date: 20200731

Patent event code: PE09021S01D

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

Patent event code: PE07011S01D

Comment text: Decision to Grant Registration

Patent event date: 20210428

GRNT Written decision to grant
PR0701 Registration of establishment

Comment text: Registration of Establishment

Patent event date: 20210614

Patent event code: PR07011E01D

PR1002 Payment of registration fee

Payment date: 20210615

End annual number: 3

Start annual number: 1

PG1601 Publication of registration