KR102209231B1 - 중합 반응의 제어 파라미터 모니터링 방법 및 이를 실시하기 위한 장치 - Google Patents

중합 반응의 제어 파라미터 모니터링 방법 및 이를 실시하기 위한 장치 Download PDF

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KR102209231B1
KR102209231B1 KR1020167012835A KR20167012835A KR102209231B1 KR 102209231 B1 KR102209231 B1 KR 102209231B1 KR 1020167012835 A KR1020167012835 A KR 1020167012835A KR 20167012835 A KR20167012835 A KR 20167012835A KR 102209231 B1 KR102209231 B1 KR 102209231B1
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polymerization
polymerization reaction
mixture
control parameter
reaction
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KR20160088304A (ko
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프란세스코 보나치니
에릭 맨토바니
안젤로 페란도
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베르살리스 에스.피.에이.
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    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/27—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands using photo-electric detection ; circuits for computing concentration
    • G01N21/272—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands using photo-electric detection ; circuits for computing concentration for following a reaction, e.g. for determining photometrically a reaction rate (photometric cinetic analysis)
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
    • G01N21/359—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light using near infrared light
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
    • G01N21/3577—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing liquids, e.g. polluted water
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F112/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F112/02—Monomers containing only one unsaturated aliphatic radical
    • C08F112/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F112/06—Hydrocarbons
    • C08F112/08—Styrene
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/84—Systems specially adapted for particular applications
    • G01N21/85—Investigating moving fluids or granular solids
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/84—Systems specially adapted for particular applications
    • G01N21/85—Investigating moving fluids or granular solids
    • G01N21/8507—Probe photometers, i.e. with optical measuring part dipped into fluid sample
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2201/00—Features of devices classified in G01N21/00
    • G01N2201/06—Illumination; Optics
    • G01N2201/061—Sources
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2201/00—Features of devices classified in G01N21/00
    • G01N2201/08—Optical fibres; light guides
    • G01N2201/0826—Fibre array at source, distributing
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2201/00—Features of devices classified in G01N21/00
    • G01N2201/12—Circuits of general importance; Signal processing
    • G01N2201/13—Standards, constitution

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  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Pathology (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mathematical Physics (AREA)
  • Theoretical Computer Science (AREA)
  • Investigating Or Analysing Materials By Optical Means (AREA)
  • Polymerisation Methods In General (AREA)
  • Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
KR1020167012835A 2013-11-19 2014-11-18 중합 반응의 제어 파라미터 모니터링 방법 및 이를 실시하기 위한 장치 Active KR102209231B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ITMI2013A001916 2013-11-19
IT001916A ITMI20131916A1 (it) 2013-11-19 2013-11-19 Metodo per monitorare un parametro di controllo di una reazione di polimerizzazione e relativo apparato per attuare detto metodo
PCT/IB2014/066129 WO2015075629A1 (en) 2013-11-19 2014-11-18 Method for monitoring a control parameter of a polymerization reaction and relative apparatus for implementing said method

Publications (2)

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KR20160088304A KR20160088304A (ko) 2016-07-25
KR102209231B1 true KR102209231B1 (ko) 2021-01-29

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KR1020167012835A Active KR102209231B1 (ko) 2013-11-19 2014-11-18 중합 반응의 제어 파라미터 모니터링 방법 및 이를 실시하기 위한 장치

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US (1) US9714899B2 (enExample)
EP (1) EP3071954B1 (enExample)
JP (1) JP6619736B2 (enExample)
KR (1) KR102209231B1 (enExample)
CN (1) CN105659072B (enExample)
BR (1) BR112016007745B1 (enExample)
ES (1) ES2804087T3 (enExample)
HU (1) HUE051229T2 (enExample)
IT (1) ITMI20131916A1 (enExample)
MX (1) MX368418B (enExample)
MY (1) MY185715A (enExample)
PL (1) PL3071954T3 (enExample)
PT (1) PT3071954T (enExample)
RU (1) RU2662039C1 (enExample)
SA (1) SA516371040B1 (enExample)
SI (1) SI3071954T1 (enExample)
WO (1) WO2015075629A1 (enExample)

Families Citing this family (9)

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Publication number Priority date Publication date Assignee Title
GB201704447D0 (en) * 2017-03-21 2017-05-03 Asterope Ltd Wire coating determination
AU2019283225B2 (en) * 2018-06-07 2022-02-10 Yokogawa Electric Corporation Optical analysis system and optical analysis method
CN108872144B (zh) * 2018-09-13 2021-02-12 中国农业大学 一种用于厌氧消化过程的在线监测装置
EP3711852A1 (de) * 2019-03-21 2020-09-23 Covestro Deutschland AG Verfahren und vorrichtung zur quantitativen überwachung der zusammensetzung einer oligomer-/monomermischung
JP7857225B2 (ja) * 2020-10-13 2026-05-12 株式会社日本触媒 予測方法、予測装置
IT202100033053A1 (it) * 2021-12-30 2023-06-30 Versalis Spa Processo di pirolisi per la produzione di un olio di pirolisi adatto al riciclo a ciclo chiuso (“closed loop recycling”), relativo apparato, prodotto ed uso del medesimo
JP7603629B2 (ja) * 2022-03-14 2024-12-20 Dic株式会社 樹脂物性値予測装置及び樹脂物性値の予測方法
CN117309793B (zh) * 2023-10-25 2024-05-07 连云港石化有限公司 一种苯乙烯装置聚合物测定方法
CN118908788A (zh) * 2024-06-28 2024-11-08 北京理工大学 Pbx炸药制备关键阶段确定方法和应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5898056A (en) 1995-09-25 1999-04-27 Solvay (Societe Anonyme) Process and device for monitoring the quality of latices of halogen-containing vinyl polymers
KR100879443B1 (ko) 2006-03-13 2009-01-20 주식회사 엘지화학 1-알켄-아크릴레이트계 공중합체
KR101187973B1 (ko) * 2003-12-09 2012-10-05 피나 테크놀러지, 인코포레이티드 중합체의 제조 방법

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5604132A (en) * 1995-01-23 1997-02-18 Olin Corporation Process flow injection analyzer and method
DE19805612A1 (de) * 1998-02-12 1999-08-19 Bayer Ag Verfahren zur kontrollierten Herstellung oder Modifizierung von polymeren Produkten mittels IR-ATR-Spektroskopie
JP2000159897A (ja) * 1998-11-27 2000-06-13 Mitsui Chemicals Inc 高分子化合物の不良品分離方法
JP2002194079A (ja) * 2000-12-22 2002-07-10 Mitsubishi Gas Chem Co Inc ポリアミドの製造方法
EP1727838B1 (en) * 2004-03-24 2013-04-17 ExxonMobil Chemical Patents Inc. Process for making ethylene interpolymers and interpolymers made thereby; compositions and electrical devices containing such interpolymers
CA2470887C (en) * 2004-06-14 2014-10-21 Nova Chemicals Corporation Detection of gels in a solution polymerization
US8843324B2 (en) * 2011-02-03 2014-09-23 Nova Chemicals (International) S.A. Double derivative NIR process control
CN102288575B (zh) * 2011-07-25 2013-03-06 哈尔滨工业大学 在线监测甲氨基阿维菌素反应的装置

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5898056A (en) 1995-09-25 1999-04-27 Solvay (Societe Anonyme) Process and device for monitoring the quality of latices of halogen-containing vinyl polymers
KR101187973B1 (ko) * 2003-12-09 2012-10-05 피나 테크놀러지, 인코포레이티드 중합체의 제조 방법
KR100879443B1 (ko) 2006-03-13 2009-01-20 주식회사 엘지화학 1-알켄-아크릴레이트계 공중합체

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MY185715A (en) 2021-05-31
RU2016116157A (ru) 2017-12-25
CN105659072B (zh) 2020-02-14
SI3071954T1 (sl) 2020-08-31
MX2016005767A (es) 2016-07-18
CN105659072A (zh) 2016-06-08
SA516371040B1 (ar) 2017-12-03
JP2016538536A (ja) 2016-12-08
RU2662039C1 (ru) 2018-07-23
PL3071954T3 (pl) 2020-10-05
JP6619736B2 (ja) 2019-12-11
EP3071954B1 (en) 2020-04-08
US9714899B2 (en) 2017-07-25
KR20160088304A (ko) 2016-07-25
ITMI20131916A1 (it) 2015-05-20
EP3071954A1 (en) 2016-09-28
US20160231230A1 (en) 2016-08-11
MX368418B (es) 2019-10-02
PT3071954T (pt) 2020-07-09
HUE051229T2 (hu) 2021-03-01
WO2015075629A1 (en) 2015-05-28
ES2804087T3 (es) 2021-02-03
BR112016007745B1 (pt) 2020-11-24

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