KR101893012B1 - Method for Manufacturing Soap Containing Fermented Medicinal Herbs Include Ginseng - Google Patents

Abstract

The present invention relates to a method for manufacturing a herbal fermentation soap which is prepared by mixing a fermentation broth, a hot water extract solution and a distillation solution of a herbal material including ginseng with a soap base material and without causing any adverse effect on the skin, .
The oriental fermented soap produced by the method of the present invention is a soap product in which the skin oil component of the oriental material is added to the soap to improve the functionality of the soap and the deterioration of the soap is inhibited even when the soap containing the oriental material is stored for a long period, It is possible to add more useful components to the soap and form a coating film on the particle surface of the useful component to keep the addition effect of the herbal material continuously high even if it is stored for a long period while suppressing the deterioration of the soap.

Description

FIELD OF THE INVENTION [0001] The present invention relates to a method for manufacturing a herbal fermentation soap comprising ginseng,

The present invention relates to a method for manufacturing a herbal fermentation soap which is prepared by mixing a fermentation broth, a hot water extract solution and a distillation liquid of a herbal composition containing ginseng with a soap base material and without causing any adverse effect on the skin, .

Soap is one of life necessities which is used to remove foreign matter such as washing water or body, deodorant, deodorant, skin protection and so on, and it is classified into various kinds according to the state of soap, usage, main ingredient and so on.

Soap refers to a generic term of metal salts such as saturated and unsaturated higher fatty acids, fatty acids such as tofu fatty acid, resin acid and naphthenic acid, and refers to a water-soluble alkali metal salt of a higher fatty acid which is mainly used for cleaning as a concept of consultation.

A typical soap preparation method is to saponify various animal oils or vegetable oils with sodium hydroxide to prepare soap bases, and then, if necessary, to remove unpleasant odors or to moisturize and lubricate the skin And further adding various additives such as a softener and a moisturizer.

The wet process may be divided into a wet process for producing a soap base material and a dry process for mixing the functional additive with the functional additive to the formed soap base material followed by molding and drying. A soap manufacturing process in which sodium hydroxide is added to a fatty acid to produce a soap, and a neutralization process in which a soap is prepared and a fat is treated with methanol to prepare a methyl ester and then reacted with sodium hydroxide to produce a soap And methyl ester saponification.

The soap manufactured as described above has been mainly used for cleaning dirt and foreign matter adhering to the skin of the face or the body. However, in recent years, when the living standard is improved and the beauty of the skin is emphasized, Functional soaps containing various active ingredients have been developed and marketed to provide effects such as antibacterial activity.

That is, in addition to the conventional criteria for selection of soap, such as washing power, skin harmlessness, amount of bubbles, period of use due to abrasion, and the like, Soaps with various functionalities are preferred, and there is a strong tendency to prefer environmentally friendly natural soaps using natural vegetable materials rather than synthetic soaps made of chemical compounds.

For example, various natural pigments and fragrances are added in order to eliminate the characteristic odor of keeping and to increase the value of the product. The fragrance which is mainly used is preferred to the fragrance of natural plant system, Products with the addition of extracts of plants (for example, ginseng, cucumber, apricot, aloe, lemon, citron, mugwort, etc.) or combinations of these plants are being released.

In recent years, it has been known that a soap containing a herb ingredient for prevention and treatment of skin diseases such as acne, dandruff, foot odor, and atopy, a soap having a blood circulation promotion effect and a wastes removal effect, Soap is being proposed.

As an example of such a functional soap, Korean Patent Registration No. 1238820 discloses an invention for producing an environmentally friendly soap harmless to human body by using natural herbal ingredients. In the soap base containing a rice soak fermented liquid, Glycerin, rice flour fermentation liquid, propolis and essential oil are added and coagulated to produce one-way fermentation soap, providing excellent cleaning effect without irritating the skin.

However, the herbal fermentation powder as a component exhibiting functionality in the soap of the present invention is a solid particle, and when it is used as a soap, it is washed away immediately after it comes in contact with the skin together with water, so that it can not be absorbed by the skin.

In order to overcome these disadvantages, Korean Patent Laid-Open Publication No. 2013-0111660 discloses a herbal composition comprising a herbal moisturizing oil (mixed with glycerin, vegetable oil and aromatic oil) Soap was presented.

However, the oriental herbal ingredients are weak and the hot water extract of the oriental herb is added to the soap as it is, which causes side effects on the sensitive skin, and the hot water extract and oil of the oriental herbal material are not mixed with each other, so that the herbal ingredients can not be uniformly mixed in the soap base.

In addition, Korean Patent Laid-Open Publication No. 2011-0046789 discloses a method for preparing soap by adding mineral powder to a soap base together with a red ginseng and oriental herbal concentrate, and a method for preparing soap by adding a mineral complex powder to a liquefied soap base; A herbal material concentrate containing red ginseng; Oils, vitamins, hyaluronic acid, glycerin; Seaweed Extract, Birch Sap, Grain Fermented Juice; By combining soap with heating, stirring, coagulation, cutting, drying, and molding processes while mixing the natural fragrances in sequence, the antioxidant effect of the mineral powder, the far-infrared radiation, Release and so on.

However, in order to exert the effect of the mineral powder on the skin, it is necessary to make long contact with the skin like a cosmetic product. However, since the soap is used to remove foreign substances from the skin, the skin is washed immediately after contact with the skin, There is a problem in that when the soap containing herbal materials is stored for a long period of time, discoloration and swelling occur due to herbal materials, seaweed extract, sap, and the like.

Disclosure of Invention Technical Problem [8] Accordingly, the present invention has been made to solve the above-mentioned problems, and it is an object of the present invention to provide a method for manufacturing a herbal fermented soap which does not deteriorate even after long- .

In order to solve the above-described problems, the present invention provides a method for preparing a medicament for preventing or treating osteoporosis, comprising administering to 100 parts by weight of purified water 3 to 10 parts by weight of ginseng, corn oil, ginseng, 50 to 70 parts by weight of at least one first herbal material selected from the group consisting of 3 to 7 parts by weight of brown rice or brown rice, 40 to 60% by weight of calcium, 20 to 40% by weight of magnesium, 10 to 20% 1 to 5 parts by weight of a mineral concentrate having a hardness of 300 to 400 mg / l, 80 to 120 parts by weight of deep sea water, 0.1 to 1.0 part by weight of leaven, 0.1 to 1.0 part by weight of a mineral composed of 5 to 10% by weight of sodium, 3 to 10 parts by weight and 5 to 15 parts by weight of fermentation broth, fermenting the mixture at room temperature for 1 to 3 months, filtering and heating at 90 to 100 ° C for 30 to 60 seconds to prepare a fermentation broth; Wherein at least one selected from the group consisting of Hwanggi, Porphyra, Pungmyung, Pungmyung, Killer, Seokchangpo, Seokjanghwang, Baekbokryeong, Hwangjeong, Broiler, Red ginseng, Chaga mushroom, Pine nut, Walnut, Licorice, 15 to 25 parts by weight of a second herbal material pulverized to a size of 30 mesh and 0.1 to 5.0 parts by weight of mineral concentrated water, heating the mixture at 70 to 90 DEG C for 100 to 150 hours to extract hot water, and then filtering the mixture to prepare a hot water extract; Adding 1 to 2 times of purified water to the filtrate solid of the fermentation broth and the hot water extract to obtain a distillate; Preparing a mixed solution by mixing 150 to 200 parts by weight of the hot-water extract solution and 50 to 100 parts by weight of the distillate with 100 parts by weight of the fermentation broth; Adding 5 to 10 parts by weight of glycerin to 100 parts by weight of the mixed solution to dissolve the mixture to prepare an aqueous phase, homogenizing the aqueous phase in an oil and drying to obtain a capsule having a glycerin coating film on the surface of the mixed liquid component particles; And mixing the capsules with a soap base material and solidifying them to produce a one-way fermentation soap.

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The oriental fermented soap produced by the method of the present invention is improved in the functionality of the soap by adding the skin oil component of the herbal ingredient to the soap and the deterioration of the soap is inhibited even when the soap containing the herbal ingredient is stored for a long period of time.

Further, the addition of the mineral component can extract more useful components from the herbal materials and add them to the soap, and even when stored for a long time while suppressing the deterioration of the soap by forming a coating film on the particle surface of the useful component, Is maintained constantly.

The present invention relates to a method for producing a fermented product by mixing ginseng and herbal materials, a fermentation broth obtained by fermenting brown rice, a hot water extract obtained by hot extraction of a herbal material, a distillate obtained by distilling the production residue of the fermentation broth and the hot water extract with water, Manufacture one-way fermentation soap.

Wherein the fermentation broth comprises ginseng; At least one first herbal material selected from at least one selected from the group consisting of corn oil, ginseng, ginseng, rice bran, bokbunja, dead animal, casualty, gugija, omija, Brown rice or brown rice; Mineral concentrated water; Deep sea water; yeast; microbe; Cho Chung; And purified water, followed by fermentation.

Ginseng has been known for a long time as a representative nourishing tonic, and recently, many scientific studies on its ingredients and its effects have been reported. Therefore, the mysterious effects of ginseng have been illuminated by modern scientific methods. There are various effects such as anti-aging effect, anti-arteriosclerosis, improvement of hyperlipidemia, improvement of liver function, hyperfunction of liver function, protection of radioprotection, immunity enhancement, anti-thrombosis, hyperfunction of brain, antistress, hypoglycemia, hypotension and anticancer effect.

In addition, ginseng contains abundant saponin called ginsenoside. Saponins are classified into three types according to their chemical structure: protopanaxadiol, protopanaxatriol, and oleanolic acid. It has been known that it exerts an excellent effect on control of body function, that is, normalization of physiological function, by having extensive influence on the central nervous system, endocrine system, immune system, metabolism system and the like.

These ginsengs are mainly absorbed through the oral cavity and absorbed by the human body. In the present invention, the ginseng effect is absorbed through skin absorption.

However, saponin, which is the main physiological active substance of ginseng, is present in the form of a glycoside linked to a sugar, and glycosides are low in water absorption rate due to a large molecular size, so they are fermented and mixed with soap. When ginseng is fermented, As an energy source, it is decomposed into non-glycosylated forms. Non-glycosides are smaller in size and higher in activity than glycosides, thus improving skin absorption and efficacy.

Each of the herbal materials has a raw material characteristic such as an antioxidative effect and a moisturizing effect, thereby giving the soap a functional effect such as improvement of wrinkles of the skin and prevention of aging, and is generally a plant material strong in fragrance. So that a beneficial fragrance is added to the soap.

The components contained in the brown rice have antioxidant activity, proliferation effect of fibroblast, promoting collagen synthesis, so that it has excellent wrinkle improving and anti-aging effect, soothing the skin that has been sore and calming the inflammation of the skin. Especially, Gamma oryzanol, linoleic acid, and odontophosphoric acid are abundant in the B group and the nutrients of calcium, iron, phosphorus and plant fiber, so that the skin is glazed with aging prevention, skin beauty, skin regeneration effect and whitening effect It has the advantage of smoothing.

Mineral enriched water and deep sea water are rich in minerals. Minerals react with ginseng, herbal ingredients, and soluble components in brown rice during fermentation to form salts, which can be eluted into water to increase the content of these useful components in the fermentation broth .

The minerals in the mineral concentrated water preferably consist of 40 to 60% by weight of calcium, 20 to 40% by weight of magnesium, 10 to 20% by weight of potassium and 5 to 10% by weight of sodium and have a hardness of 300 to 400 mg / And the seawater contains various inorganic salts that are useful not only for the above components but also for the human body, so that it has an effect of improving the functionality of the soap containing the same, The extraction yield is maximized.

Deep sea water is generally obtained from the ocean at depths of 300 m or more. In the deep sea where sunlight does not reach, there is no phytoplankton that consumes nutrients and photosynthesis does not occur. Deep sea water taken from deep water has nitrogen , Phosphorus, and silicic acid, and various minerals such as magnesium, calcium, potassium, and sodium, and trace elements such as zinc, selenium, and manganese.

In addition, there is no contamination by air or influent, and the number of viable bacteria is not more than that of surface water, and the bacteria are not contaminated. Therefore, it has better cleanliness than surface water or groundwater. The minerals contained in deep seawater such as minerals such as concentrated water increase the effect of extraction of useful components contained in ginseng, oriental herbal ingredients and brown rice, and addition of useful ingredients of deep sea water to herbal materials fermented liquid, There is an effect of improving the functionality.

Nuruk is an enzyme source and fermentation source that decomposes and glycosylates the starch of grains during the fermentation and fermentation of alcohol to produce glucose. It is a natural source of amino acids such as vitamin B1, B2, B6 and folic acid, GABA), peptides that provide vitality to the body, and antioxidant-active polyphenols. It contains antioxidants, whitening, moisturizing and antibacterial properties, kojic acid and whitening pitera ) Ingredient, it functions to adjust nutrition supply of skin and balance of oil and water.

The microorganisms act to ferment ginseng, herbal ingredients, and brown rice with yeast, and effective microorganisms can be used as microorganisms. The useful microorganisms originally include a plurality of useful microorganisms including lactic acid bacteria, yeast, photosynthetic bacteria, . However, in recent years, useful microorganisms have been developed that can be utilized in food, medical, and cosmetic fields by using microorganisms extracted from traditional fermented foods such as kimchi, cheonggukjang, and salted fish .

Therefore, it is preferable to use a microorganism extracted from Kimchi, Chungkukjang, and Salted Fish as the useful microorganisms used in the present invention. Bacillus subtilis , a Bacillus subtilis strain having high digestive activity against the sugar of ginsenosides contained in ginseng, It is most preferable to use a microorganism extracted from chungkukjang which enriches the microorganism.

The starch is fed to the microorganism so that fermentation can proceed smoothly. The purified water is mixed with the above components and fermented so that the nutrients contained in ginseng, herbal ingredients, and brown rice are dissolved in purified water by yeast and microorganisms during fermentation Mineral water and minerals contained in deep seawater promote the elution of useful ingredients.

3 to 10 parts by weight of ginseng, 50 to 70 parts by weight of a first herbal material, 3 to 7 parts by weight of brown rice or brown rice flour, 100 parts by weight of purified water, 1 to 5 parts by weight of mineral concentrated water; 80-120 parts by weight of deep sea water; 0.1-1.0 parts by weight of yeast; 3 to 10 parts by weight of microorganism; 5 to 15 parts by weight of zeaxanthin can be mixed, and addition of sun salt can be accelerated according to the concentration of concentrated mineral water and the salinity of deep sea water to elute useful components of ginseng, herbal ingredients and brown rice.

The fermentation is preferably carried out at room temperature and fermented for 1 to 3 months. For smooth fermentation, it is necessary to stir at the same time during fermentation. When the fermentation is completed, the fermentation broth is filtered to remove the solids to obtain a fermentation broth.

The fermentation broth can be sterilized by heating to prevent further fermentation, and the heating is briefly heated at a temperature of 90 to 100 ° C for 30 to 60 seconds to minimize destruction of useful components contained in the fermentation broth.

Next, one or two or more selected from the group consisting of Hwanggi, Porphyra, Wonjueong, Killer, Killer, Seokjangpo, Seokjanghwang, Baekbokgyeong, Hwangjeong, Broiler, Red ginseng, Chaga mushroom, Pine nut, Walnut, Licorice, The materials are heated and extracted from the purified water. The hot water extraction is heated at 70 to 90 ° C for 100 to 150 hours to allow the human body oil component contained in the herbal material to be eluted into water while being not destroyed at high temperature. To obtain an extract.

In order to efficiently dissolve the useful ingredient of the herbal material, the herbal material is preferably pulverized and subjected to hot water extraction. The pulverization is preferably carried out at a temperature of 10 to 30 [deg.] C to facilitate elution of the useful ingredient and separation of the herbal material solids and hot water extract solution. It is preferable to crush to the size of a mesh.

The hot water extract can be mixed with 100 parts by weight of purified water and 15 to 25 parts by weight of the second herbal material and it is preferable to use deep sea water as purified water used for hot water extraction in order to accelerate leaching of useful components of herbal materials. It is more preferable to add the mineral concentrated water used for preparing the fermentation broth and the mineral concentrated water may be added in an amount of 0.1 to 5.0 parts by weight based on 100 parts by weight of purified water (or deep sea water).

As the water is heated in the hot water extraction process, the water movement becomes active, and the mineral enriched water and the mineral rich in the deep ocean water act actively according to the movement of the water, and the mineral particles with the increased kinetic energy impact on the ginseng, So that the oil component contained in the water is more eluted into the water.

In addition, when the temperature of the water is over 100 ° C., when a small impact is received from the outside due to the superheating phenomenon, or when foreign matter such as dust enters, sudden bubbles are generated, and the boiling phenomenon occurs by the explosive boiling. Due to the added mineral particles, The generation and destruction are repeated, and the ginseng, herbal materials and brown rice are subjected to vibration, so that the oil component thereof is more eluted into the water. These mineral particles are contained in the water before the water is overheated. Dolby phenomena caused by foreign matter proceed very weakly.

The herbal materials are relatively expensive, and the solids, which are the filtration residues produced in the fermentation broth and the hot water extract, remain a lot of herbal ingredients, and herbal ingredients are generally fragrant plant materials. The solids are distilled in the present invention to recover fragrance components of the herbal ingredients and added to the soap production.

The solid of the fermentation broth and the solid of the hot water extract solution are combined and then one to two times of purified water is poured and distilled in a distiller to obtain a distillate, and deep sea water may be used instead of purified water used for distillation.

When the fermentation broth, hot water extract solution and distilled solution are prepared as described above, the mixed solution is mixed with a soap base material and solidified by pouring into a mold, and then cut to a size suitable for use as needed and dried to produce a one-component fermentation soap.

The mixing ratio of the fermentation broth, the hot water extract solution and the distillation solution is not particularly limited and may be appropriately adjusted depending on the use of the soap. To 100 parts by weight of the fermentation broth is mixed with 150-200 parts by weight of the hot water extract, 50 to 100 parts by weight is suitable for application in common universal applications.

The soap base material may be manufactured by a known method of purchasing a product distributed on the market or by saponification reaction of vegetable oil or animal oil with sodium hydroxide. The soap base material is melted and mixed with the mixture to form a soap Or soap may be prepared by mixing the above mixed solution in a trace state in which trace is left on the surface when the soap base is gradually thickened by saponification reaction during the production of the soap base.

Soap with main ingredient of preservation causes color change and odor due to rancidity after a long period of time. Oriental herb has antimicrobial and antioxidant ability to prevent or reduce such rancidity, so that the storage stability of oriental fermented soap .

However, when the preservative is not added, the effect of increasing the storage stability is limited. In addition, there is a disadvantage that the aroma of the herbal material is volatilized during storage and the efficacy and merchantability are lowered. To overcome this disadvantage, .

The encapsulation may be performed by adding glycerin to the mixed solution, dissolving the same, homogenizing the oil in the oil used in the production of the soap base material, and drying the saponin. The saponin of the ginseng contains both a hydrophilic group and a hydrophilic group, Because it is an amphipathic molecule, the mixture with glycerin acts as a water phase, the oil acts as an oil phase, saponin of ginseng acts as an emulsifier, and the mixture is dispersed in oil. When it is dried, As the oily oil is removed, glycerin is coated on the surface of the useful component particles in the mixed solution to form a coating film.

The coating film protects useful components of ginseng, oriental herb, and brown rice from external factors such as oxygen to prevent active breakdown of useful ingredients and prevent volatilization of herbal ingredients. In addition, glycerin has strong water absorbing properties, When the soaps containing the encapsulated oil component are used, the glycerin coating film dissolves in the water and exposes the oil component. Thus, the effect of the useful ingredient is maximized and the dissolved glycerin provides the moisturizing effect to the skin.

Glycerin is preferably in a range of 5 to 10 parts by weight based on 100 parts by weight of the mixed solution, and the range is the minimum range in which glycerin can form a coating film on the surfaces of useful component particles of ginseng, herbal materials, and brown rice, and homogenization is carried out using a homomixer or high pressure It is preferable to use a homogenizer and the above-mentioned drying is a freeze-drying method which minimizes destruction of the useful ingredient.

Further, since the lipophilic block of ginseng saponin is externally oriented in the capsule, it can be uniformly dispersed in the oil of the soap base under the saponification reaction, so that there is also an effect that the oil component of the mixture solution is uniformly mixed with the soap.

Hereinafter, the present invention will be described in more detail with reference to the following examples, comparative examples and test examples.

It is to be understood, however, that the invention is not to be construed as being limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art. Will be apparent to those skilled in the art to which the present invention pertains.

≪ Example 1 >

250 g ginseng, 250 g ginseng, 250 g ginseng, 250 g ginseng, 250 g ginseng, 250 g ginseng, 250 g ginseng, 250 g ginseng, 250 g ginseng, 250 g ginseng and 250 g ginseng were prepared and thoroughly washed in 5 ℓ of purified water. 250 g of Angelica gigas Nakai, 250 g of Puerariae radix, 100 g of Euglena gum, 100 g of gum arabic, 250 g of ground brown rice, 100 ml of concentrated mineral water having a hardness of 350 mg / l, 5 l of deep seawater, 25 g of koji, 300 ml of microorganisms extracted from Chungkukjang, 500 g of cornstarch and 20 g of sodium chloride were mixed. The mixture was allowed to stand at room temperature for 50 days, and stirred at intervals of 3 days.

After the fermentation was completed, the mixture was heated at a temperature of 95 캜 for 40 seconds to inactivate koji and microorganisms, and the mixture was filtered through a 50 mesh filter net to obtain a fermentation broth and a fermented filtrate solid.

The following is washed thoroughly and ground to a size of 20 mesh. 250 g of Hwanggi, 250 g of Porphyry, 250 g of Pungchung, 250 g of raw paper, 250 g of keel, 250 g of Seokchangpo, 250 g of Sukjangpo 250 g, 250 g of ginseng, 250 g of red ginseng, 250 g of pine nut, 250 g of pine nut, 250 g of walnut, 200 g of licorice and 200 g of black potato were mixed, and 50 ml of mineral concentrated water and 20 ℓ of deep sea water were added thereto. After heating, it was filtered through a filter mesh of 50 mesh to obtain a hot water extract and a hot water extraction filtrate solid.

The fermented filtrate solid and hot water extraction filtrate solid were combined, poured 10 L of deep ocean water into the distiller, and the distillate obtained by cooling and condensing the vapor of the distiller was heated and heated.

Next, 2 kg of a sodium hydroxide aqueous solution having a concentration of 50% by weight was gradually poured into 1 kg of purified water to prepare an aqueous solution of sodium hydroxide having a sodium hydroxide content of 33% by weight, followed by cooling to room temperature, heating 7 kg of palm oil to 50 캜, The mixture was put into a mixing container, and the stirrer was operated. Then, 3 kg of the aqueous sodium hydroxide solution was mixed.

200 g of the fermentation broth, 350 g of the hot water extract and 150 g of the distillate were mixed with the excipient (base material of soap), poured into a mold, mixed thoroughly, and allowed to stand for 1 day And solidified.

The solidified solidified material was cut to a size suitable for use and dried for one month in a shade at room temperature to prepare a one-side fermented soap.

≪ Example 2 >

50 g of glycerin was mixed with 200 g of the fermentation broth prepared in Example 1, 350 g of the hot water extract and 150 g of the distillate, homogenized at 1500 rpm for 5 minutes using a homomixer, and the homogenized mixture was vacuum- And dried at -38 캜 under a vacuum of 20 torr to obtain a capsule powder in which glycerin forms a film on the surfaces of useful components of fermentation broth, hot water extract and distillate.

A one-way fermentation soap was prepared in the same manner as in Example 1, except that the capsule powder was mixed with the soap base material in the traced state of Example 1.

≪ Comparative Example 1 &

In Example 1, a one-way fermentation soap was prepared in the same manner as in Example 1, except that the fermentation broth was not mixed with the soap base material and only the hot water extract and the distillate were mixed and solidified in a mold.

≪ Comparative Example 2 &

In Example 1, a one-way fermentation soap was prepared in the same manner as in Example 1, except that only the fermentation broth and the distillate were mixed without solidifying the hot water extractant into the soap base material and solidified in a mold.

≪ Comparative Example 3 &

In Example 1, a one-way fermentation soap was prepared in the same manner as in Example 1, except that only the fermentation broth and the hot water extract solution were mixed with each other without mixing the distillate with the soap base material and solidified in a mold.

≪ Test Example 1 > Evaluation of property stability of soap

To confirm the property stability of the oriental fermented soap prepared in Examples 1 and 2 and Comparative Examples 1 to 3, the manufactured soap was stored at 25 ° C., 45 ° C. and daylight, The appearance changes were observed and the results are shown in Table 1 below.

Statistical stability evaluation result division Immediately after manufacture After 1 week after 2 weeks After 3 weeks After 4 weeks Example 1 25 ℃ ○ ○ ○ ○ ○ 45 ° C ○ ○ ○ ○ ○ daylight ○ ○ ○ ○ ◑ Example 2 25 ℃ ○ ○ ○ ○ ○ 45 ° C ○ ○ ○ ○ ○ daylight ○ ○ ○ ○ ○ Comparative Example 1 25 ℃ ○ ○ ○ ○ ○ 45 ° C ○ ○ ◑ ▣ ◑ ■ daylight ○ ○ ◑ ◑ ● ▣ Comparative Example 2 25 ℃ ○ ○ ○ ○ ○ 45 ° C ○ ○ ○ ▣ ▣ daylight ○ ○ ○ ◑ ▣ Comparative Example 3 25 ℃ ○ ○ ○ ○ ○ 45 ° C ○ ○ ○ ▣ ▣ daylight ○ ○ ○ ◑ ▣  ○: No change, ◑: Weak discoloration, ▣: Weak discoloration, ●: Discoloration, ■:

As shown in Table 1 above, no discoloration or irritation occurred in all the groups at 25 ° C, so that when the fermentation broth, hot water extract, or distillate were mixed, the properties of the soap were stably maintained due to the antioxidant effect of ginseng and herbal materials. .

In Example 2, no discoloration or quenching occurred at 25 ° C, 45 ° C, and daylight conditions in Example 2 in which particles of useful components of the fermentation broth, hot water extract, and distilled liquid were encapsulated with a glycerin coating film. , Slight discoloration occurred at 4 weeks under daylight.

Comparative Example 1, which was not mixed with the fermentation broth, exhibited the first discoloration. At 4 weeks, the fermentation broth was largely changed in a high temperature environment at 45 ° C., and discoloration was observed under the sunlight condition From these results, it can be presumed that addition of a fermentation broth obtained by fermenting a herbal ingredient inhibits the deterioration of soap, thereby enabling long-term storage.

Therefore, it is known that the use of fermentation broth, hot water extract, and distillation liquid of herbal materials including ginseng in the production of soap inhibits discoloration and deterioration of soap to improve shelf life. It is effective to protect the ingredients and improve the storage stability of the soap.

≪ Test Example 2 >

To evaluate the antioxidative activity, the free radical scavenging activity of DPPH (1,1-diphenyl-2-picrylhydrazyl) radicals of the oriental fermented soap prepared in the above Examples and Comparative Examples was measured.

To each soap kept at 45 ° C for 4 weeks, 100 μl of a 0.4 mM solution of soap prepared in each group and DPPH in ethanol was added to a 96-well plate as shown in Table 2 below, and the mixture was allowed to stand at 37 ° C for 30 minutes Absorbance was measured at 517 nm using an ELISA reader.

DPPH free radical scavenging activity was calculated using the following equation using distilled water instead of soap as a control.

DPPH free radical scavenging activity (%) = {1- (absorbance of sample / absorbance of control)} x 100

Results of DPPH free radical scavenging analysis (unit:%) Concentration (ppm) 50 100 500 1000 Example 1 3.5 5.1 17.8 28.4 Example 2 3.8 5.6 20.1 33.6 Comparative Example 1 1.5 2.7 12.8 23.6 Comparative Example 2 2.2 3.9 15.3 25.0 Comparative Example 3 3.1 4.8 17.2 26.8

As shown in Table 2 above, Example 2 in which the useful ingredient particles of the fermentation broth, hot water extract solution, and distilled solution were encapsulated showed higher DPPH free radical scavenging ability than that of Example 1 which was not encapsulated. When these components were encapsulated, The antioxidant activity is maintained at a high level even after storage for a long period of time.

The DPPH free radical scavenging activity of the Comparative Example was lower than that of the Example. It can be seen that mixing the fermentation liquid, the hot water extract, and the distillation liquid into the soap base material can keep the antioxidative activity of the soap high, Comparative Example 3 in which the liquid was not mixed showed a high result because the volatile fragrance component of the herbal material was contained in the distillate liquid in a large amount and the volatile fragrance ingredient naturally volatilized during the storage of the one-way fermentation soap, The longer the storage period, the more likely the effect of adding the distillate will disappear.

≪ Test Example 3 > Skin irritation test

The results of the patch test of the herbal fermentation soap prepared in the above Examples and Comparative Examples are shown in Table 3 below.

Each soap was dissolved in sterilized water to prepare a soap solution. 15 ㎕ of each was added to Finn Chamber (SmartPractice, USA) on a scan tape.

The inner part of the upper left part of the subject was wiped with 70% ethanol and dried. After attaching Finn chambers to each of the above groups, the patches were removed after 24 hours and marking areas were marked with a marking pen. After 30 minutes, After 24 hours and 48 hours, the test site was observed.

According to the criteria of the International Contact Dermatitis Research Group (ICDRG), the degree of skin irritation was classified, and the mean score was calculated according to the average skin response calculation formula. Respectively.

Skin Info Test Results Reactivity ^{Note 1)} (persons) Mean score ^{Note 2) Note 3)} - ± + ++ +++ Example 1 30 minutes 28 2 0 0 0 0.37 No stimulation 24 hours 30 0 0 0 0 48 hours 30 0 0 0 0 Example 2 30 minutes 30 0 0 0 0 0 No stimulation 24 hours 30 0 0 0 0 48 hours 30 0 0 0 0 Comparative Example 1 30 minutes 25 5 0 0 0 1.11 Irritation 24 hours 29 One 0 0 0 48 hours 0 0 0 0 0 Comparative Example 2 30 minutes 0 0 0 0 0 0 No stimulation 24 hours 0 0 0 0 0 48 hours 0 0 0 0 0 Comparative Example 3 30 minutes 28 2 0 0 0 0.37 No stimulation 24 hours 0 0 0 0 0 48 hours 0 0 0 0 0 (Score: 0), ±: irritation (uncertain or mild reaction and erythema) (score: 0.5), +: light stimulus (weak erythema, (Score: 2), +++: severe irritation (severe erythema, hardening and algebra) (score: 3)
(+ Score × number of subjects) + (+ score × number of subjects) + (+ score × number of subjects) + (++ score × number of subjects) Number of subjects to be examined)} / (maximum stimulus value x total number of subjects x evaluation number) x 100
Note 3) Judgment: 0.00 to 0.75 (no irritation), 0.76 to 1.50 (irritation), 1.51 to 2.50 (irritation), 2.51 to 4.00 (irritation)

As shown in Table 3, the mean scores of Example 1 and Comparative Example 3 were 0.37, and the results of Example 2 and Comparative Example 2 were judged to be unstimulated as 0 and 1.11 in Comparative Example 1, .

From the result of the measurement of the mean score of Comparative Example 2 in which the hot water extract was not mixed, it was estimated that the influence of the hot water extract was the largest factor that stimulates the skin from the result of the measurement, and only the hot water extract and the distillate were mixed It was judged that the fermentation liquid relieved the skin irritation of the hot-water extract solution from the result of the micro stimulation in Comparative Example 1.

Claims (7)

Wherein at least one selected from the group consisting of ginseng, ginseng, ginseng, ginseng, ginseng, ginseng, ginseng, ginseng, acacia, ginseng, 50 to 70 parts by weight of a first herbal material, 3 to 7 parts by weight of brown rice or brown rice, 40 to 60% by weight of calcium, 20 to 40% by weight of magnesium, 10 to 20% by weight of potassium and 5 to 10% 1 to 5 parts by weight of mineral concentrated water having a hardness of 300 to 400 mg / l, 80 to 120 parts by weight of deep sea water, 0.1 to 1.0 part by weight of yeast, 3 to 10 parts by weight of microorganisms extracted from chungkukjang, And fermenting the mixture at room temperature for 1 to 3 months, filtering and heating the mixture at a temperature of 90 to 100 ° C for 30 to 60 seconds to prepare a fermentation broth;
Wherein at least one selected from the group consisting of Hwanggi, Porphyra, Pungmyung, Pungmyung, Killer, Seokchangpo, Seokjanghwang, Baekbokryeong, Hwangjeong, Broiler, Red ginseng, Chaga mushroom, Pine nut, Walnut, Licorice, 15 to 25 parts by weight of a second herbal material pulverized to a size of 30 mesh and 0.1 to 5.0 parts by weight of mineral concentrated water, heating the mixture at 70 to 90 DEG C for 100 to 150 hours to extract hot water, and then filtering the mixture to prepare a hot water extract;
Adding 1 to 2 times of purified water to the filtrate solid of the fermentation broth and the hot water extract to obtain a distillate;
Preparing a mixed solution by mixing 150 to 200 parts by weight of the hot-water extract solution and 50 to 100 parts by weight of the distillate with 100 parts by weight of the fermentation broth;
Adding 5 to 10 parts by weight of glycerin to 100 parts by weight of the mixed solution to dissolve the mixture to prepare an aqueous phase, homogenizing the aqueous phase in an oil and drying to obtain a capsule having a glycerin coating film on the surface of the mixed liquid component particles; And
Mixing the capsules with a soap base material and solidifying them to produce a one-way fermentation soap. delete delete delete delete delete delete