KR101890270B1 - A method for refining horse oil, the refined horse oil and a cosmetic composition comprising the refined horse oil - Google Patents

Abstract

The present invention relates to a method for purifying horse oil, and a cosmetic composition containing purified horse oil and purified horse oil. In purifying horse oil, the horse oil is separated into a liquid state and a solid state using a filter packed with citrus fruit At the same time, it is possible to provide a method for purifying the hair, which is effective for deodorizing the odor of the hair, and a cosmetic composition containing the purified hair and the purified hair.

Description

TECHNICAL FIELD The present invention relates to a cosmetic composition containing a refined horse meat oil, a refined horse oil, a refined horse oil and a refined horse oil,

The present invention relates to a method for purifying horse oil, and a cosmetic composition containing purified horse oil and purified horse oil. The present invention relates to a cosmetic composition which is effective for deodorizing the odor of horse radish using a filter packed with citrus peel and foil, A liquid unsaturated fatty acid layer containing 56 to 65% of unsaturated fatty acids in the total fatty acid content of Mayu and a saturated fatty acid layer containing 45 to 55% of unsaturated fatty acids in the total fatty acid content of the purified fatty acid, And a cosmetic composition containing the purified hemp oil and the refined hemp oil. In addition, the present invention can be manufactured in a relatively short time by a simple method in which a solid state layer containing a liquid state layer and a saturated fatty acid, which are formed into a liquid state by containing unsaturated fatty acid by filtration through a filter filled with citrus fruit, Is able to utilize the citrus unripe fruit, and it has the effect of recycling resources.

Mayu is an oil of the horse, and it is said that it is rich in vitamin E from the past and it is beneficial for the prevention of fine lines and aging, and it has been used for skin beauty for a long time in folk remedies. Mayu is known to be very effective for burning, which is effective for burning and relieving inflammation. It is a major component of sebum that protects human skin. It contains a large amount of palmitoleic acid, which has strong antimicrobial action. It is known that a protective film is formed to give a high moisturizing effect to the skin.

Until now, hemp has been difficult to provide a liquid state liquid which is formed only in one state such as solid or liquid when it is refined and used as an expensive raw material.

On the other hand, the cultivated area of citrus from South Korea in Jeju increased from 184% in 1980 to 25.802ha in 1996, and the production of citrus increased by 256% from 187,407 to 479,980 tons. The yield is increasing. With the increase in production of these citrus fruits, a variety of citrus processed foods are being developed to suit consumers' preferences. However, to date, most citrus processed foods have been supplied to consumers using ripe citrus fruits.

Every year, we conduct an assortment to obtain a high-quality, reproducible ripe citrus fruit. The enemy is to remove some citrus peel from the citrus tree branches in order to obtain a stable fruiting of the citrus, prevention of the deterioration and the best quality of the citrus fruit. The thus removed citrus fruit (hereinafter referred to as "citrus fruit" It is not suitable for use as a product or food for processing and is disposed of.

As the cultivation area of citrus grows gradually, the yield of citrus unripe is increasing. Studies on the utilization of the uncooked citrus fruits that are disposed of in this way are very limited.

In order to deodorize the smell of Mayu extracted from fat, which is a by-product of the conventional horse, Korean Patent Application No. 10-2014-0187291 prepared citrus peel and purified citrus fruit using purified citrus peel, And it was a single form with no layer separation.

The inventors of the present invention have invented a method for effectively cleansing the hair using the simple process in a short period of time while studying methods and materials capable of removing the odor of hemp, in which the hemp is separated into a liquid state and a solid state and at the same time, the smell of hemp is deodorized .

Another object to be solved by the present invention is to provide a cosmetic composition using purified tablets separated by layer separation.

 Another problem to be solved by the present invention is to provide a method of recycling resources by using abandoned mandarin oranges and leaves.

Another problem to be solved by the present invention is to provide a method of refining customized refined cane according to a customized requirement of a consumer.

The present invention can include the following means in order to solve the above-described problems.

The purified beverage according to an embodiment of the present invention is characterized by including an unsaturated fatty acid layer formed of a liquid state layer containing an unsaturated fatty acid and a saturated fatty acid layer formed of a solid state layer containing a saturated fatty acid.

According to another embodiment of the present invention, the unsaturated fatty acid layer according to the present invention is characterized in that the unsaturated fatty acid content of the unsaturated fatty acid layer contains 56 to 65% of an unsaturated fatty acid.

According to another embodiment of the present invention, the saturated fatty acid layer according to the present invention is characterized in that the saturated fatty acid content of the saturated fatty acid layer contains 45 to 55% of an unsaturated fatty acid.

According to still another embodiment of the present invention, the cosmetic composition according to the present invention is characterized by including the unsaturated fatty acid layer.

According to another embodiment of the present invention, the cosmetic composition according to the present invention is characterized by including the saturated fatty acid layer.

According to another embodiment of the present invention, a method for preparing a muscle oil according to the present invention comprises: preparing a filter for filling a filter with pulverized citrus fruits and poultry; charging a hot water into the filter to warm the filter; A liquid phase fluid feed step of injecting liquid phase fluid into the filter through the primary warming step, a first layer separation step of separating the purified fluid into the water layer and the magnetic layer through the liquid phase filling step, And a second layer separation step of separating the formed magnetic layer into a liquid state layer and a solid state layer.

According to another embodiment of the present invention, in the method for preparing a talarum according to the present invention, the citrus fruit is derived from the citrus fruit which is produced from July to September.

According to another embodiment of the present invention, the method of the present invention is characterized in that the first layer separation step is performed for 12 to 24 hours and the second layer separation step is performed for 48 to 96 hours.

According to another embodiment of the present invention, the method for controlling the horsetail according to the present invention may further include a step of supplying a warm water to the filter after the liquid phase filling step so as to reduce residual fluids, .

According to another embodiment of the present invention, the purified tablet according to the present invention is prepared by the above method.

The present invention utilizes citrus peel and foil as a filter filler when refining maruyu, thereby achieving the effect of layering the liquid medium layer and the solid state layer for a short period of time without further processing.

In addition, the present invention provides an effect of deodorizing the fragrance of marigold by using filler of the filter when refining marigold with immature citrus fruit and foil.

Further, the present invention has an effect of providing a cosmetic composition using a purified oil of an unsaturated fatty acid layer and a saturated fatty acid layer.

In addition, the present invention has the effect of recycling resources that are recycled from unexplored mandarin oranges and leaves.

In addition, it is possible to control the concentration of extract components of immature citrus fruits and foams according to the number of filters, and thus it is possible to produce customized refined beef according to the demand of customers.

Fig. 1 is a reference diagram of a purified liquid phase separated into a liquid state layer and a solid state layer prepared in Example 1
Fig. 2 is a view showing the reference of Mayu produced in Comparative Example 1
3 is a graph showing the content ratios of unsaturated fatty acids and saturated fatty acids in the unsaturated fatty acid layer (liquid state layer) and the saturated fatty acid layer (solid state layer) of Example 1 and Comparative Example 1

Advantages and features of the present invention and methods of achieving them will become apparent with reference to the embodiments described in detail below. The present invention may, however, be embodied in many different forms and should not be construed as being limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art. Is provided to fully convey the scope of the invention to those skilled in the art, and the invention is only defined by the scope of the claims.

Unless defined otherwise, all terms (including technical and scientific terms) used herein may be used in a sense commonly understood by one of ordinary skill in the art to which this invention belongs. And commonly used predefined terms are not ideally or excessively interpreted unless expressly defined otherwise. Meanwhile, 'Citrus unripe and peel' referred to in the present invention is a by-product of Citrus unripe, and refers to wastes including by-products obtained after processing juices and the like. The 'refined beverage' referred to in the present invention refers to the refined beef after being subjected to the second heating step in the refined beef according to the method of the present invention. Also, the 'liquid phase layer' means that the purified fluid is separated into the liquid phase layer through the second layer separation step.

Hereinafter, the present invention will be described in detail.

The purified beverage according to the present invention comprises an unsaturated fatty acid layer formed of a liquid state layer containing an unsaturated fatty acid and a saturated fatty acid layer formed of a solid state layer containing a saturated fatty acid.

The inventors of the present invention discovered that a liquid using a liquefied citrus peel and a filter using liquor was refined to deodorize the odor of the liquor, and the liquor was deodorized and the purified liquor was separated into layers.

Until now, refined marrow has been formed into a single phase, or even if it is formed of two layers in a liquid state and a solid state, an excessive time or process is required, or a state in which the amount of liquid in the liquid state is small and the layer separation is insufficient It has been difficult to provide a liquid state liquid used as an expensive raw material. In the present invention, it is possible to provide a simple liquid state process and two types of liquid state liquid state in a short time. Liquid state hemp oil is excellent in absorbing power of skin, easy to use in cosmetics, advantageous in processing, and has a merit in that it can be used as an expensive raw material because of a large amount of unsaturated fatty acid. In addition, the liquid conditioner may be easily formed into a nano-emulsion or a nanoliposome when manufacturing cosmetics, so that a formulation can be formed to facilitate skin penetration.

The unsaturated fatty acid layer preferably contains a large amount of unsaturated fatty acids and is formed into a liquid-state layer. Preferably, the unsaturated fatty acid layer contains 56 to 65% of unsaturated fatty acids in the total fatty acid content of the unsaturated fatty acid layer. This is because when the unsaturated fatty acid content is less than 56%, it becomes a solid state, and when the unsaturated fatty acid content is 65% or more, it is unstable and it is difficult to store.

The saturated fatty acid layer is formed in a solid state, and it is preferable that the unsaturated fatty acid content in the total fatty acid content of the saturated fatty acid layer is 45 to 55%. This is because when the content of the unsaturated fatty acid is less than 45%, the specific gravity is too low to absorb the skin, and when the content exceeds 55%, the liquid becomes a liquid state.

The cosmetic composition according to another embodiment of the present invention comprises the unsaturated fatty acid layer or the saturated fatty acid layer.

The unsaturated fatty acid layer is in a liquid state, and the saturated fatty acid layer is in a solid state, and the touch and specific gravity of each are different. In particular, the unsaturated fatty acid layer in the liquid state layer is excellent in the ability to absorb skin by oil and can be used as an expensive cosmetic composition, and the unsaturated fatty acid layer in the solid state layer can be used as a cosmetic composition by providing a strong protective function to dry skin. That is, when the unsaturated fatty acid layer in the liquid state layer and the saturated fatty acid layer in the solid state layer are used as a cosmetic composition, they can be used in various forms depending on their properties and efficacy.

The cosmetics prepared from the cosmetic composition containing the unsaturated fatty acid layer or the saturated fatty acid layer of the present invention as an active ingredient can be prepared in the form of a general emulsified formulation and a solubilized formulation. Cosmetics of emulsified form include nutrition lotion, cream, essence, etc., and cosmetics of solubilized form have softening longevity. In addition to the cosmetic composition containing the unsaturated fatty acid layer or saturated fatty acid layer of the present invention, it can be prepared in the form of an adjuvant which can be applied topically or systemically, which is conventionally used in the field of dermatology by containing a dermatologically acceptable medium or base have.

Suitable cosmetic formulations include, for example, solutions, gels, solid or kneaded anhydrous products, emulsions obtained by dispersing the oil phase in water, suspensions, microemulsions, microcapsules, microgranules or ionic (liposomes) In the form of a foliar dispersant, in the form of a cream, a skin, a lotion, a powder, an ointment, a spray or a conceal stick. It can also be prepared in the form of a foam or an aerosol composition further containing a compressed propellant.

The cosmetic composition of the present invention may further contain at least one selected from the group consisting of fatty substances, organic solvents, solubilizers, thickeners and gelling agents, softening agents, antioxidants, suspending agents, stabilizers, foaming agents, perfumes, Or any other conventionally used in cosmetics such as nonionic emulsifiers, fillers, sequestering and chelating agents, preservatives, vitamins, barrier agents, wetting agents, essential oils, dyes, pigments, hydrophilic or lipophilic active agents, ≪ RTI ID = 0.0 > cosmetics < / RTI > such as botanical ingredients, or adjuvants conventionally used in the field of dermatology. And, the above ingredients can be introduced in amounts commonly used in the field of dermatology.

Examples of products to which the cosmetic composition of the present invention can be added include cosmetics such as astringent lotion, softening longevity lotion, nutrition lotion, various creams, essences, packs, foundation and the like, cleansing, cleanser, soap, .

As a specific formulation of the cosmetic composition of the present invention, there may be mentioned a skin lotion, a skin softener, a skin toner, an astringent, a lotion, a milk lotion, a moisturizing lotion, a nutrition lotion, a massage cream, And includes formulations such as soap, shampoo, cleansing foam, cleansing lotion, cleansing cream, body lotion, body cleanser, milky lotion, press powder, loose powder, eye shadow and the like.

In addition, the purified tablet according to the present invention does not exclude that it is used as a raw material for food or medicine.

In another embodiment of the present invention, a method for refining a horse meat comprises the steps of preparing a filter for filling a filter by crushing a citrus fruit and a foil, charging the hot water into the filter to cause the filter to warm up, A liquid phase fluid feed step of injecting liquid phase fluid into the filter, a first layer separation step of separating the liquid layer into a water layer and a magnetic layer through the liquid phase filling step, and a liquid phase layer and a solid phase layer And a second layer separating step of separating the first layer and the second layer.

When the talc is refined using filler of immature and thin citrus peel filter, the odor of the margarine is removed, and the short-term inner layer separation is carried out with the liquid-state layer and the solid-state layer.

On the other hand, the above-mentioned phenomenon that the tablets are separated from each other is a problem in that a layer separation phenomenon occurs very little when the filler of the filter used in the refining process is used as the citrus peel, but not the citrus fruit.

As shown in the following Table 1, it can be seen from the following table 1 that the sweet potatoes of the present invention, which are enriched in July to September, .

sugars
(g / 100 g) Date of harvest 7/15 8/15 9/15 10/10 10/28 11/11 11/23 12/12 Citrus juice 2.1 2.2 2.7 4.15 6.21 7.85 7.78 7.72

In other words, it is not only low in sugar content but also relatively low in acidity in July to September, which affects the layer separation phenomena of tablets see. In the present invention, preferably, the premature lot is used in July to September.

 Especially, from July to September, it has been shown that it has a great effect on the whitening activity and the inhibition of fatty liver because it contains a large amount of functional substances having higher efficacy than Hesperidin and NARAGEN,

Citrus peel is generally about 50% of the whole fruit. It contains a lot of physiologically active ingredients such as dietary fiber, essential oil, carotenoid, flavonoid, pectin, limonoid, It is known that it exhibits higher antioxidant activity than pulp.

The filter preparation step is a step of filling crushed mandarin oranges with the filter in a filter. There is no limitation on the method of crushing mandarin or mandarin orange, and a blender may be used in general. At this time, the porosity in the filter is changed according to the pulverization size of the filler material, and accordingly, the permeability is affected when hot water or liquid paraffin is passed therethrough, preferably 0.1 cm to 3 cm, Cut to about 2cm and use.

In the primary heating step, hot water is prepared and passed through the filter to allow the citrus fruit and the foil to uniformly warm in the filter. It is important that the whole of the filter is heated rather than only a part of the filled filter. When hot water is used, the filter is uniformly heated. This makes it possible to prevent solidification of the liquid liquor, which will be described later, when it is put into the filter.

The liquid phase filling step is a step of putting the liquid phase oil into the filter, and has fluidity enough to pass through the filter when the liquid is passed through the filter. As the fluid passes through the filter, The effective ingredient for the deodorization is extracted. At this time, the water passing through the filter is heated by the hot water, and the temperature of the hot water is preferably 50 to 75 ° C. There is no limit to the number of times the liquid horse meat is put into the filter, and as the number of times of application to the filter is increased, the content of the active ingredient of the citrus fruit is increased and the concentration of the extract ingredient of the citrus fruit is decreased Can be adjusted to produce customized tablets.

The first layer separation step is a step of separating the hot water and the liquid oil introduced into the heating step and the liquid oil introduced through the liquid phase filling step. The water and the oil are not mixed with each other. , Preferably 12 to 24 hours, and is suitably separated. It is not meaningful that water and oil are not sufficiently separated when they are less than 12 hours, and there is no change when they are 24 hours. In this case, a variety of methods including separating funnels are possible.

The second layer separation step is a step of separating the liquid into a liquid state and a solid state, and separating the liquid-state layer and the solid-state layer at a predetermined time after the water removed in the first layer separation step . And preferably 48 to 96 hours. This means that the separation into the liquid-phase layer and the solid-state layer is in progress for less than 48 hours, and it is not meaningful that the separation has already been completed for more than 96 hours. At this time, the layer separation is performed by storing the surface of the first layer separated step for a predetermined time.

According to another method for the remedy of the present invention, it is possible to further include a step of performing a second warming after the step of applying liquid milk.

The second heating step is to flow the hot water again to flow the remaining fluid in the filler in the filter after the liquid phase filling step, thereby reducing the amount of the remaining fluid in the filler, thereby preventing waste of the material. It also has the advantage of being able to recycle filters.

FIG. 1 is a reference view of purified liquid separated into a liquid state layer and a solid state layer prepared in Example 1. FIG.

3 is a graph showing the content ratios of unsaturated fatty acids and saturated fatty acids in the unsaturated fatty acid layer (liquid state layer) and the saturated fatty acid layer (solid state layer) of Example 1 and Comparative Example 1.

The contents of unsaturated fatty acids and saturated fatty acids contained in the upper and lower layers were determined by passing the dried citrus fruits and leaves through the different drying methods such as natural drying, hot air drying and freeze drying. In Fig. 3, 'Mi-a-prize' represents the content of the upper layer of the layered trehalose using naturally dried citrus peel and pak, and each of the ' When the dried material is dried by the method of lyophilization, the layered upper layer is indicated. In the case of using natural drying, hot air drying and freeze drying, the contents of the lower layer of the layer separated by each of the methods are indicated. Also, the contents of Comparative Example 1 using 'potato,' 'heat-sensitive,' and 'impressed' were compared with those of ripe and citrus fruits.

The content of the unsaturated fatty acid as the upper layer of A, B and C in FIG. 3 is 57%, 59%, and 57% of the total fatty acid content of the unsaturated fatty acid layer, 54%, 55%, and 55% of the total fatty acid content of the layer, and the solid state layer of Comparative Example 1 also contained unsaturated fatty acid contents of 55%, 54%, and 53% It is considered that the formed muscle oil should be formed at 56% or more of the total fatty acid content.

Hereinafter, preferred embodiments and experimental examples are provided to facilitate understanding of the present invention. However, the following examples and experimental examples are provided only for the purpose of easier understanding of the present invention, and the present invention is not limited by the examples.

[ Example 1 ] Mandarin and citrus fruit  Through the filter Refined Mayu  Produce

The citrus fruits and leaves were dried by hot air drying in August, and the water was removed. The fruits were cut into 2 cm by using a grinder, and the uncooked citrus fruits and wheat flour were charged into the filters to 500 g.

In addition, hemp milk was dissolved in water at 60 캜 in water to prepare liquid hemp milk.

Then, the filter was heated by flowing hot water of 60 ° C first through the filter packed with the citrus peeler and the foil.

 After passing 300 ml of hot water, the liquid phase was immediately passed through. After 12 hours of storage, the water was removed from the filter through the filter and stored at room temperature for 72 hours to prepare purified liquids separated into a liquid phase layer and a solid phase layer.

As a result, the upper layer was separated into a liquid state and the lower layer was separated into a solid state, and the results are shown in Fig.

[ Comparative Example 1 ] Mandarin and berries  Through the filter Refined Mayu  Produce

After ripening, dried fruits and leaves were dried by hot air drying to remove water, and then cut into 2cm pieces using a grinder. 500g of the crushed citrus fruits and pomace were packed in a filter to prepare a citrus fruit ripening and thin filter.

In addition, hemp milk was dissolved in water at 60 캜 in water to prepare liquid hemp milk.

Then, the filter was heated by flowing hot water of 60 ° C first through the filter packed with the mandarin and peach.

 After passing 300 ml of hot water, Mao was immediately passed. After passing through the filter for 12 hours, the water was removed and stored at room temperature for 72 hours.

As a result, the layer was separated into a liquid state and a solid state very little, and the results are shown in Fig.

[ Experimental Example 1 ] Layer separation component  Research experiment

Fatty acid analysis of unsaturated fatty acids and saturated fatty acids was commissioned on the liquid state layer as the upper layer of the purified oil prepared in Example 1 and the solid state layer as the lower layer and the solid state layer as the lower layer of the emulsion prepared in Comparative Example 1. The amount of the liquid-phase layer as the upper layer of Comparative Example 1 was too small to be excluded from the investigation.

 The results are shown in FIG. 3, wherein the content of unsaturated fatty acids in the liquid-state layer and the solid-state layer of Example 1 and the content of unsaturated fatty acid and saturated fatty acid contained in the lipid of Comparative Example 1 were different.

[Review]

1 and 2, the purified liquid prepared in Example 1 and Comparative Example 1 was examined. As a result, as shown in FIG. 1, in Example 1, the upper layer was a liquid state layer and the lower layer was a solid state layer (Comparative Example 1), as shown in FIG. 2, it was confirmed that the layer separation was extremely insufficient (the upper transparent portion).

In other words, when using citrus fruit and peel, the layer separation phenomenon occurs very little between the liquid state layer and the solid state layer because the sugar content and acidity affect the active ingredient of the extract contained in the main oil .

As can be seen from FIG. 3, the content of the unsaturated fatty acids in the liquid state layer (A, B, C) and the solid state layer (D, E, F) (D, E, F) contains 55% or less of unsaturated fatty acid, and thus the composition ratio of the unsaturated fatty acid is different. In addition, the unsaturated fatty acid content of Comparative Example 1 (G, H, I) was 55% or less and it can be confirmed that there is a difference in content with the liquid state layer of Example 1.

The difference in the state of the layers depending on the content of unsaturated fatty acids seems to be due to the lower melting point of the unsaturated fatty acids than saturated fatty acids. These unsaturated fatty acids and saturated fatty acids have different melting points, and therefore, when they contain a large amount of unsaturated fatty acids, they remain in a liquid state.

[ Comparative Example 2 ] Citrus Series Fruit berries  Manufacture of maize mixed with extract

400 g of distilled water was mixed with 500 g of citrus fruit and 500 g of starch, and the mixture was distilled under reduced pressure of 0.8 torr at 40 ° C to prepare citrus peel.

Also, prepare a liquid form by dissolving horse oil in a bath of water at 60 ° C. 100 ml of liquid horse radish, 50 ml of immature citrus peel and night extract were mixed and distilled under reduced pressure of 0.8 torr at 40 ° C to prepare horse oil.

[ Experimental Example 2 ] Deodorizing effect sensory test

The results are shown in Table 1. In Example 1, Comparative Example 2 and commercially available Mayu (J Co.) as Comparative Example 3, 20 men and 20 women in their 20s to 40s, And the results are shown in Table 2 below.

Example 1 (liquid state layer) Example 1 (solid state layer) Comparative Example 2 Comparative Example 3 Degree of deodorization 4.3 4.2 3.8 3

[Review]

As can be seen from the above Table 2, it can be confirmed that the liquid state layer and the solid state layer of Example 1 according to the present invention have a considerably large effect on the deodorization degree of Maehu odor in comparison with Comparative Example 3 in which no treatment is performed , And that the deodorizing effect was further improved as compared with Comparative Example 2 in which citrus fruit pot extracts (Citrus unripe and thin) were mixed with Mayu.

Claims (10)

delete delete delete delete delete A filter preparation step of crushing the citrus fruits and pulp and filling the filter
A step of supplying the hot water to the filter to warm the filter,
A liquid phase feed step of injecting liquid phase oil into the filter that has undergone the primary warming step
A first layer separation step of separating the fluid after passing through the liquid phase fluid feeding step into a water layer and a magnetic fluid layer;
And a second layer separation step of separating the magnetic layer formed in the first layer separation step into a liquid state layer and a solid state layer 7. The method of claim 6,
Characterized in that it is derived from the citrus unripe fruit produced in July to September The method according to claim 6, wherein the first layer separation step is performed for 12 to 24 hours and the second layer separation step is performed for 48 to 96 hours 7. The method of claim 6,
Further comprising a second heating step of adding hot water to the filter after the liquid phase filling step so as to reduce remaining residual oil, delete

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