KR101632601B1 - A method for refining horse oil, the refined horse oil and a cosmetic composition comprising the refined horse oil - Google Patents

Abstract

The present invention relates to a horse oil refining method, refined horse oil, and a cosmetic composition containing the refined horse oil. More specifically, provided is a horse oil refining method which is effective in the deodorization of a horse oil extract, by using tangerine peel and unripe tangerine in the refinement of horse oil. Also provided are refined horse oil and a cosmetic composition containing the refined horse oil.

Description

TECHNICAL FIELD The present invention relates to a cosmetic composition containing a refined horse oil and a refined horse oil and a refined horse oil,

The present invention relates to a method for purifying horse oil and a cosmetic composition containing refined horse oil and refined horse oil. In the process of purifying horse oil, the present invention relates to a method for purifying horse oil using floral water and essential oil derived from citrus peel, It is possible to provide a method for refining a muscle oil which is effective for deodorization, and a cosmetic composition containing the refined horse oil and the refined horse oil. Further, the present invention can omit the step of removing the material used for deodorizing the odor of the hemp oil, and further prevent the odor of the hemp oil from being deodorized at a high temperature, It is possible to produce the cosmetic composition by a simple process so that the production cost can be reduced.

The cultivation area of citrus fruits in Jeju was increased from 189% to 18,802 hectares in 1980 to 14,80 hectares in 1996, and the resulting citrus production increased by 256% from 187,407 to 479,980 tons. The cultivation area and yield of these citrus fruits It is increasing gradually. With the increase in production of these citrus fruits, a variety of citrus processed foods are being developed to suit consumers' preferences. However, to date, most citrus processed foods have been supplied to consumers using ripe citrus fruits (hereinafter referred to as "citrus fruit juice").

On the other hand, it conducts annual insemination every year to obtain a high quality reproduction ripe citrus fruit. The enemy is to remove some citrus peel from the citrus tree branches to obtain a stable fruiting of citrus, prevent the avalanche and to obtain the finest citrus fruit ripe fruit. The citrus fruit which is thus removed is suitable for use as a product or a processing food Do not dispose of it.

As the cultivation area of citrus grows gradually, the yield of citrus unripe is increasing. Studies on the utilization of the uncooked citrus fruits that are disposed of in this way are very limited.

On the other hand, Mayu is an oil of horses and it is said to be beneficial for the prevention of fine lines and aging due to abundant vitamin E, and has been used for skin aesthetics for a long time in folk remedies. Mayu is known to be very effective for burning, which is effective for burning and relieving inflammation. It is a major component of sebum that protects human skin. It contains a large amount of palmitoleic acid, which has strong antimicrobial action. It is known that a protective film is formed to give a high moisturizing effect to the skin. It also contains a large amount of Vitamin E, which makes the blood circulating. It is also used in beauty cosmetics because oil itself can act as a good cosmetic product. In addition, Maou is the closest component to sebum, and because it has almost the same composition ratio, fatty acid composition and moisture balance, it has high affinity with human skin and contains about 60% or more of unsaturated fatty acid. It is known as a substance.

However, due to the unique odor of horse radish extracted from fat, which is a by-product of horse, deodorization is required for use as a cosmetic composition. In the existing Korean Patent Registration No. 10-0912706, active clay and activated carbon are used but they are used at high temperature to cause problems such as oxidization and compositional change of horseradish, and further, acid clay or activated carbon used for deodorization There is a problem in that a production cost is increased due to the necessity of a step of removing the catalyst.

In addition, in 2014, Jeju region was designated as a special zone for horse industry, and has been developing, developing and securing many horse related industries. Mayu, which is a by-product of horse, is made into pure oil form through refining process and goes through defection and deoxidation in refining process. Generally, phosphoric acid and hydrochloric acid are mainly used for the deodorization process, and caustic soda is used for treatment and neutralization of acid residues in the deoxidation process. However, since the process of removing them is essential, the production cost is also increased There is a problem that skin irritation can be caused by acid clay, activated charcoal, phosphoric acid, hydrochloric acid, caustic soda which can not be removed, and there is still a limit to remove the unpleasant smell of Maeyu.

The present inventors have studied a method and a material capable of eliminating the odor of hemp, and have found that the process is simple, without using hydrochloric acid and phosphoric acid, and is effective for purifying the odor of hemp oil, To provide a cosmetic composition.

Another problem to be solved by the present invention is to eliminate the step of removing the material used for deodorizing the odor of maize and further to prevent the oxidation and composition change of the bean oil without deodorizing the odor of the maize at a high temperature And a cosmetic composition containing the hemp purified by the method.

Another object to be solved by the present invention is to provide a method for purifying horse meat using by-products and a cosmetic composition containing the horse oil purified by the method.

The present invention can include the following means in order to solve the above-described problems.

The method for preparing a citrus peel extract according to the present invention comprises: a citrus peel extract forming step of forming a citrus peel extract in a citrus peel; A flower water extracting step of forming citrus peel floral water from the citrus peel extract; A first step of extracting a first step oil extract by pulverizing horse meat, mixing crushed horse meat fat and the citrus peel floral water; And a purification step of purifying the primary milk extract.

In the primary tea oil extraction step, the crushed horse meat fat and citrus peel floral water are mixed at a weight ratio of 1: 0.5 to 2, and the mixture is heated to 90 to 130 ° C to extract the primary tea oil extract.

According to another embodiment of the present invention, the citrus peel extract-forming step is characterized in that citrus peel and water are mixed at a weight ratio of 1: 1 to 2 to form citrus peel extract at 40 to 60 ° C.

Wherein the step of purifying comprises the step of adding a citrus juicy extract and an extract having a pH of 2.5 to 4 to the first-order milk-derived extract to form a second-order milk-like extract by adding hot water at 50 to 90 ° C.

The purification step further comprises a pH adjustment step of further mixing the citrus-derived extract extracted from the fruit of the citrus series.

The citrus-derived extract is characterized in that it is derived from one or more selected from among lemon, citrus fruit, orange, avocado, lime, grapefruit, and their immature.

The purifying step may further include a step of removing impurities by using a microfilter of the extract of the secondary oil extract formed after the soaking step.

The method of the present invention further comprises an essential oil extraction step of forming citrus peach essential oil in the citrus peel extract forming step, wherein the citrus peach essential oil is added to an extract of essential oil Further comprising the steps of:

The essential addition step may further include an essential oil derived from one or more selected from lemon, citrus fruit, orange, avocado, lime, grapefruit, and their immature seeds.

According to another embodiment of the present invention, the method further comprises a stabilization step to stabilize the tablet media, the stabilization step comprising: cooling the tablet media to form cooled tablet media; A cold-aging step of firstly aging the cooled purified tablet; And aging at room temperature for secondary aging after the refrigeration aging step.

The purified tablet according to another embodiment of the present invention is prepared by the above method.

The cosmetic composition according to still another embodiment of the present invention contains the purified tablet prepared by the above method.

The purified tablet according to another embodiment of the present invention is formed so as to contain citrus peel floral water so as to suppress the odor of marigold.

Wherein the refined mayonnaise further comprises citrus peach essential oil.

Wherein the purified tablet further comprises an extract of Citrus unripe and having a pH of 2.5 to 4.

The cosmetic composition according to another embodiment of the present invention contains the aforementioned citrus peel floral water or citrus peach essential oil or purified citrus peel containing citrus peel and extract.

The present invention has the effect of recycling resources by using citrus peel and citrus peel which are discarded as waste in purifying horse meat.

Furthermore, the use of floral water and essential oils derived from citrus peel, and citrus fruit, is effective in deodorizing the scent of horse radish extract.

Further, the present invention can omit the step of removing the material used for deodorizing the odor of the hemp oil, and further prevent the odor of the hemp oil from being deodorized at a high temperature, It is possible to produce the cosmetic composition by a simple process so that the production cost can be reduced.

In addition, there is an effect of providing purified tablet and cosmetic composition which has a high preference and can be absorbed well on the skin.

Advantages and features of the present invention and methods of achieving them will become apparent with reference to the embodiments described in detail below. The present invention may, however, be embodied in many different forms and should not be construed as being limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art. Is provided to fully convey the scope of the invention to those skilled in the art, and the invention is only defined by the scope of the claims.

Unless defined otherwise, all terms (including technical and scientific terms) used herein may be used in a sense commonly understood by one of ordinary skill in the art to which this invention belongs. And commonly used predefined terms are not ideally or excessively interpreted unless expressly defined otherwise. In the meantime, 'refined beverage' referred to in the present invention can be interpreted to include not only refined beef by the method of the present invention but also refined beef by a generally known method.

Hereinafter, the present invention will be described in detail.

The method for preparing a horsebean oil according to the present invention includes a step of forming a citrus peel extract, a step of extracting a primary tea oil, and a step of purification.

The citrus peel extract-forming step is a step of forming a citrus peel extract from citrus peel. The citrus peel used in the present invention refers to a by-product obtained after processing citrus fruit juice and the like, and corresponds to waste. The present invention makes it possible to remove the specific odor of the horse radish extract by using the citrus peel to be discarded.

The citrus peel extract may be extracted by various extraction methods. Preferably, the citrus peel and water are mixed at a weight ratio of 1: 1 to 2, and the mixture is put into an extractor and decompressed to form a citrus peel extract at 40 to 60 ° C. Can prevent the useful components contained in the citrus peel from being altered.

The citrus peel extract forming step includes a step of extracting a flower water and a step of extracting an essential oil.

The step of extracting the floral water is a step of forming a lower layer of floral water, that is, a citrus peach floral water, having a relatively high density by collecting mainly water-soluble components in the citrus peel extract. .

The essential oil extraction step is to form an essential oil, i.e., citrus peach essential oil, which is an upper layer fraction having a relatively low density by collecting mainly lipophilic components in the citrus peel extract, and adding the purified essential oil to the purified oil, It plays a role of taking out.

The first step of extracting the primary milk extract is a step of grinding horse meat, mixing the ground horse meat with crushed horse meat and the citrus peel flower water to extract a primary tea extract, and extracting the primary water from the citrus peel- , The unpleasant odor of Maeyu can be effectively deodorized. In the primary tea oil extraction step, it is preferable to mix the crushed horse meat fat and citrus peel floral water at a weight ratio of 1: 0.5 ~ 2, and heat the mixture at 90 to 130 ° C for 4 to 7 hours to extract the primary tea oil extract.

On the other hand, the citrus peel floral water is added to the extract of primary tea leaves extracted in the primary tea oil extracting step and the process is repeated 2 ~ 5 times to remove impurities such as deodorizing and trehalose.

The purification step may include purifying citrus fruit oil extract, immature citrus fruits, an extract forming step, a mixing step, and an impurity removing step. The citrus immature and extract forming step is a step of forming an extract of Citrus unripe and citrus fruit in the Citrus unripe lotus, and it is found that the citrus citrus fruit of the present invention contains about 4 times as many polyphenols as the ripe lotus, It has citric acid and vitamin C and is known to have high acidity. In particular, it was found that the effective amount of the functional substance which is more effective than Hesperidin and Naringin, which has been reported in the Wonju citron mite area, which is effective from July to September, has a great effect on the whitening activity and the inhibition of fatty liver, In particular, it is known that rats administered with the immature and extract have excellent effects in improving blood lipids and prevention of fatty liver.

Meanwhile, it is preferable that the immature fruit of the citrus fruit and the extract are generally used in the period from July to September, and it is preferable that the pH is set to 2.5 to 3.5 in order to facilitate the removal of impurities at a later time. The citrus immature and extract-forming steps may further comprise a precipitation step, a citrus immature fruit filtration step and a pH control step.

The precipitation step is a step in which citrus fruit juice is squeezed to precipitate the fiber to precipitate citrus fruit juice. The precipitation of the fiber while keeping the citrus fruit juice in the refrigerator for 6 hours or more can remove the contaminants more easily, Do.

In the citrus fruit immature fruit filtration step, the citrus fruit juice formed in the precipitation step is filtered using a nonwoven fabric or the like to form an immature fruit and extract.

In the pH control step, when the citrus fruit and the extract have an acidity of 2.5 to 4, the citrus fruits and the extract are not only adjusted to pH, but also citrus fruit Wherein the citrus-based extract is derived from one or more selected from among lemon, citrus, orange, avocado, lime, grapefruit, and their immature. There is no need of a step of removing the pH adjusting agent again, and specific components of the citrus type are adhered to the ground Maul particles to further suppress the odor peculiar to the Maul and to give a refreshing feeling, which is suitable for use.

The mixing step is a step of mixing the first-order milk extract and the citrus fruit with the extract to form a mixture. The components of the citrus fruit and the extract can suppress the odor peculiar to the tea and improve refreshing feeling, thereby enhancing the feeling of use.

Meanwhile, in the mixing step, the extract of the first order milk oil and the extract of the citrus fruit are preferably mixed at a weight ratio of 1: 0.1-0.4. In the mixing step, the reaction step and the bathing step May be further included.

The reaction step is a step for increasing the degree of deodorization by mixing the extract of the first order milk oil with the citrus fruit and extract, The reaction is carried out for 6 to 36 hours.

The above-mentioned water-bathing step is a step of adding extracts of citrus peaches having a pH of 2.5 to 4 to the above-mentioned first-order milk-derived extract and forming a second-order milk-like extract by hot water bath at 50 to 90 ° C, whereby protein or phospholipid is agglomerated , It becomes possible to facilitate the contaminant removal step later. In addition, it is preferable to maintain the temperature at 50 to 90 캜 so that citric acid and citric acid vitamin C contained in the extract are not deformed as much as possible.

The contaminant removing step is a step of removing contaminants from the mixture formed in the mixing step through a sieve or the like.

Meanwhile, according to another embodiment of the present invention, the method for purifying the muscle oil comprises the steps of: removing the secondarily remaining impurities using a microfilter, which can be purchased from the market, and finely crushing the oil, And an impurity removing step for increasing the purity can be further included.

The method of removing the impurity and removing the impurities to finely pulverize the extract of the crude oil extract and purifying the impurities may be repeated 2 to 5 times to further finely purify the purified oil and increase the purity. And should be construed as falling within the scope of the invention.

According to another embodiment of the present invention, the method further comprises an essential addition step of adding the citrus pea essential oil derived from citrus peel to the extract of the secondary oil extracted through the impurity removing step It can exhibit a higher effect in deodorizing the odor of Maeyu. Further, the essential addition step may further include an essential oil derived from one or more selected from among lemon, citrus fruit, orange, avocado, lime, grapefruit, and immature seeds thereof to further enhance the deodorizing effect.

Meanwhile, according to another embodiment of the present invention, the method for preparing a muscle oil may further comprise a stabilization step for stabilizing the purified muscle oil. The stabilizing step may include a cooling step, a refrigeration aging step, and a room temperature aging step.

The cooling step is a step of cooling to -20 캜 or lower for about 24 hours, thereby preventing the fragrance from flying and preventing the separation of oil from being caused.

In the refrigeration-aging step, the cooled tableted milk is firstly aged for about 5 days in a refrigerated state at 5 ° C or less. When the refrigerated aged step is not performed, the shape of the sol is closer to liquid than gel at room temperature And is not easy to use.

At the room temperature aging step, after the refrigeration aging step, it is aged at room temperature for 15 days to gel the purified tablet, thereby facilitating handling and use.

The present invention does not use a material such as acidic clay or activated carbon to deodorize the odor of horse radish by the method described above, and can eliminate the step of removing such a material. Furthermore, since the odor of horse radish is not deodorized at high temperature, It is possible to prevent the oxidation and the component change of the catalyst. Furthermore, it is possible to provide a cosmetic composition capable of deodorizing a specific odor of a horse radish extract by a simple process in producing a cosmetic composition containing a horse radish extract.

The purified hemp oil prepared by the above method can be used as a raw material for foods, medicines and cosmetics because it can catch the unique odor of hemp.

In addition, the refined hemp oil containing the citrus peel floral water can suppress the odor of the marrow oil, and the effect is further enhanced when the citrus peach essential oil or citrus peel immature or extract is additionally included.

In addition, the purified tablet may be effectively contained in the cosmetic composition.

The cosmetic composition of the present invention may contain at least one active ingredient which exhibits the same or similar functions in addition to the purified tablet.

Cosmetics made from the cosmetic composition containing the extract of the present invention as an active ingredient can be prepared in the form of a general emulsified formulation and a solubilized formulation. Cosmetics of emulsified form include nutrition lotion, cream, essence, etc., and cosmetics of solubilized form have softening longevity. In addition to cosmetics containing the extract of the present invention, it can also be prepared in the form of an adjuvant which can be applied topically or systemically, which is conventionally used in the field of dermatology by containing a dermatologically acceptable medium or base.

Suitable cosmetic formulations include, for example, solutions, gels, solid or kneaded anhydrous products, emulsions obtained by dispersing the oil phase in water, suspensions, microemulsions, microcapsules, microgranules or ionic (liposomes) In the form of a foliar dispersant, in the form of a cream, a skin, a lotion, a powder, an ointment, a spray or a conceal stick. It can also be prepared in the form of a foam or an aerosol composition further containing a compressed propellant.

The cosmetic composition of the present invention may further contain at least one selected from the group consisting of fatty substances, organic solvents, solubilizers, thickeners and gelling agents, softening agents, antioxidants, suspending agents, stabilizers, foaming agents, perfumes, Or any other conventionally used in cosmetics such as nonionic emulsifiers, fillers, sequestering and chelating agents, preservatives, vitamins, barrier agents, wetting agents, essential oils, dyes, pigments, hydrophilic or lipophilic active agents, ≪ RTI ID = 0.0 > cosmetics < / RTI > such as botanical ingredients, or adjuvants conventionally used in the field of dermatology. And, the above ingredients can be introduced in amounts commonly used in the field of dermatology.

Examples of products to which the cosmetic composition of the present invention can be added include cosmetics such as astringent lotion, softening longevity lotion, nutrition lotion, various creams, essences, packs, foundation and the like, cleansing, cleanser, soap, .

As a specific formulation of the cosmetic composition of the present invention, there may be mentioned a skin lotion, a skin softener, a skin toner, an astringent, a lotion, a milk lotion, a moisturizing lotion, a nutrition lotion, a massage cream, And includes formulations such as soap, shampoo, cleansing foam, cleansing lotion, cleansing cream, body lotion, body cleanser, milky lotion, press powder, loose powder, eye shadow and the like.

Hereinafter, preferred embodiments and experimental examples are provided to facilitate understanding of the present invention. However, the following examples and experimental examples are provided only for the purpose of easier understanding of the present invention, and the present invention is not limited by the examples.

[ Example  One] Refined Mayu  Produce

1 kg of horse meat fat was crushed and pressed, 1 kg of floral water extracted from citrus peel was mixed, and primary muscle oil was extracted with steam at 100 ° C.

The jujube juice was squeezed out on July 21, washed with juice, stored in refrigerator for more than 6 hours to precipitate the fiber, and the juice was filtered using nonwoven fabric and the liquid component was stored at 8 ° C or less.

The primary extracts were mixed with chilled and stored immature fruit juice at a ratio of 1: 0.3, reacted for 24 hours, and liquified at 60 ℃.

After removing the contaminants through a screen, they were cooled at -25 ° C for 24 hours, refrigerated at 4 ° C for 5 days, and then aged at room temperature for 15 days to prepare tablets.

[Example 2] Production of purified tablets

1 kg of horse meat fat was crushed and pressed, 1 kg of floral water extracted from citrus peel was mixed, and primary muscle oil was extracted with steam at 100 ° C.

The jujube juice was squeezed out on July 21, washed with juice, stored in refrigerator for more than 6 hours to precipitate the fiber, and the juice was filtered using nonwoven fabric and the liquid component was stored at 8 ° C or less.

The primary extracts were mixed with chilled and stored immature fruit juice at a ratio of 1: 0.3, reacted for 24 hours, and liquified at 60 ℃.

The crude extracts were removed by removing impurities and foreign substances by removing the contaminants through a screen and putting them in a microfilter.

Essential oil extracted from citrus peel was added 0.5% of the total weight of the secondary tea oil extract to the second horse radish extract.

It was cooled at -25 ° C for 24 hours, refrigerated at 4 ° C for 5 days, and then aged at room temperature for 15 days to prepare tablets.

[ Experimental Example  1] Deodorizing effect sensory test

With respect to the above Examples 1 and 2 and the commercially available purified tablets as a comparative example, 20 men and 20 women in their 20s to 40s were examined for the odor of Maehyu and the degree of stickiness when they were applied to the skin, The sensory test was performed by the scale method and the results are shown in Table 1 below.

Example 1 Example 2 Comparative Example Degree of deodorization 4.6 4.9 1.2 Likelihood 4.4 4.9 1.3 Degree of stickiness 2.6 4.2 2.1

[Review]

As can be seen from the above Table 1, the degree of deodorization and preference specific to Maey were high in Examples 1 and 2 according to the present invention. However, the degree of tackiness in the skin patch test was not significantly different from that of the comparative example in Experimental Example 1, but the degree of tackiness was significantly better in Example 2 using the microfilter than the comparative example. This is presumed to be a result of the microfilter being finely pulverized and permeating the skin.

Claims (16)

A citrus peel extract forming step of forming a citrus peel extract from the citrus peel;
A flower water extracting step of forming citrus peel floral water from the citrus peel extract;
A first step of extracting a first step oil extract by pulverizing horse meat, mixing crushed horse meat fat and the citrus peel floral water;
And a purification step of purifying the primary milk extract. 2. The method according to claim 1,
Wherein the pulverized horse meat fat and citrus peel floral water are mixed at a weight ratio of 1: 0.5 to 2 and heated to 90 to 130 캜 to extract the first-order oil-extracted extract. The method according to claim 1, wherein the citrus peel extract-
Wherein the citrus peel and water are mixed at a weight ratio of 1: 1 to 2 to form a citrus peel extract at 40 to 60 ° C. The method according to claim 1,
To the above primary milk extract, immature citrus fruits and extracts having a pH of 2.5 to 4 were added,
And a step of adding water to the extract to form a secondary tea oil extract. 5. The method of claim 4,
Further comprising a pH adjusting step of further mixing the citrus-derived extract extracted from the fruit of the citrus series. 6. The method according to claim 5, wherein the citrus-
Lemon, citrus fruit, orange, avocado, lime, grapefruit, and their immature seeds. 5. The method of claim 4,
Further comprising a step of removing impurities by using a microfilter after extracting the secondary oil extracted from the second step. 8. The method according to claim 7,
Further comprising an essential oil extracting step of forming citrus peach essential oil in the citrus peel extract forming step,
Further comprising an essential addition step of adding the citrus pea essential oil to the extract of the secondary tea oil that has undergone the impurity removal step. 9. The method according to claim 8,
An essential oil derived from one or more selected from among lemon, citrus fruit, orange, avocado, lime, grapefruit, and their immature seeds. 10. The method according to claim 9,
Further comprising a stabilization step to stabilize the purified tablet,
Wherein the stabilizing step comprises:
Cooling the purified tablets to form cooled tablet tablets;
A cold-aging step of firstly aging the cooled purified tablet;
And aging at room temperature for the second aging after the refrigeration-aging step. 10. A purified tablet prepared by the method according to any one of claims 1 to 10. 12. The cosmetic composition according to claim 11, wherein the composition comprises the tablet of the present invention. Citrus peel Contains floral water to form a soap that can suppress the odor of maruyu. 14. The method of claim 13,
A purified tablet characterized by further comprising citrus peel essential oil. 14. The method of claim 13,
characterized in that it further comprises an immature and extract of citrus fruits having a pH of 2.5 to 4. 16. A cosmetic composition comprising purified tablet according to any one of claims 13 to 15.