KR101785090B1

KR101785090B1 - Method for producing high concentration hydrogel composition

Info

Publication number: KR101785090B1
Application number: KR1020160033304A
Authority: KR
Inventors: 임동표; 김두환; 정갑택
Original assignee: 주식회사 엠비지
Priority date: 2016-03-21
Filing date: 2016-03-21
Publication date: 2017-11-06
Also published as: KR20170109329A

Abstract

The present invention relates to a method for producing a hydrogenated water mixture, and more particularly, to a method for producing a hydrogenated water by using an alkaline hydrogen sulfide excellent in removal of active oxygen, a mineral which releases a large amount of far infrared rays and anions, Lt; / RTI >

Description

[0001] The present invention relates to a method for producing a high-

In recent years, patients with skin diseases have increased significantly, especially those with dry skin, those with weak skin or lack of resistance, and the symptoms of patients are worsening.

The skin disease is a skin disease caused by various pollutants and bacteria that cause bacteria such as Staphylococcus aureus, and it is particularly susceptible to dry skin or dry skin.

However, various pollutants, bacteria, volatile organic compounds in the air, and ozone, which cause skin hypersensitivity reaction, synergize with each other, thereby deteriorating symptoms of skin diseases.

Skin diseases are accompanied by symptoms such as dermatitis, rhinitis, asthma, conjunctivitis and urticaria.

Although dermatitis has individual differences, it usually involves severe itching, skin dryness, rashes, dirt, scabs, scaly skin, and so on, which can cause emotional anxiety, stress, tension, frustration, Together with other urticaria, metal allergies, asthma and allergic rhinitis, it is becoming a serious social problem that threatens the health of the people today.

Representative drugs known to be effective for dermatitis so far include steroids, antihistamines, antibiotics, non-steroids, sedatives and nerve stabilizers.

Double steroids are excellent for anti-inflammatory and immunosuppressive effects. On the other hand, when used for a long time, the skin elasticity disappears and becomes thinner, and the vaginal opening becomes unstable. In severe cases, systemic symptoms due to hormones, adrenal function decrease, And when the medicine is stopped, the symptoms deteriorate explosively.

Antihistamines are only temporary measures to alleviate the itch symptoms by inhibiting histamine from being liberated from mast cells, and side effects such as insomnia, anxiety and loss of appetite are seen when used for a long time.

In addition, antibiotics are intended to prevent secondary bacterial infections caused by scratches, rather than as a fundamental therapeutic drug for dermatitis. The use of antibiotics increases resistance and gastrointestinal function when used for a long period of time, as well as liver damage, pseudomembranous colitis, Aplastic anemia and the like caused by the function.

In addition, other non-steroids are merely moisturizing agents for relieving symptoms of dermatitis, and sedatives and nystagmus stabilizers are merely supplements for relieving symptoms rather than the purpose of fundamental treatment.

Furthermore, these conventional skin treatment agents have different effects depending on the constitution of an individual, and in particular, the addition and use of an artificial chemical composition during the ingredient and the manufacturing process are premised. As a result, apart from the pharmacological component, It is very difficult to trust its safety.

Korean Patent Laid-Open No. 10-2001-0089716 discloses that a therapeutic agent for skin dryness comprises spirooxathiolan quinuclidine derivative or an acid addition salt thereof as an active ingredient, but for the synthesis of the corresponding derivative, 3-hydroxy-3-mercaptomethylquinuclidine And a chemical treatment such as reaction with a carbonyl compound and isolation.

By contrast, in the case of the present invention, by providing a water-hydrogen mixture using alkali water, which is excellent in the removal of active oxygen, minerals releasing a large amount of far-infrared rays and anions, and medicinal plants and propolis, .

Generally, hydrogenated water refers to water in which hydrogen is dissolved at a high dissolved amount. This hydrogenated water has an antioxidative action of removing active oxygen to prevent aging and to prevent the aging of diabetes, hypertension, arteriosclerosis, cancer, dementia And it is known to be effective for skin aesthetics, diet, fatigue recovery, immunity enhancement, and dermatitis.

Hydrogen water is obtained by dissolving hydrogen gas in raw water. As a dissolving method of hydrogen gas, it is generally used that a hydrogen gas is brought into contact with raw water by using a gas dissolving film filled with a hollow fiber membrane in the cylinder.

As the hydrogen gas supply method, there are a method using hydrogen gas used for semiconductor manufacturing, a method using hydrogen gas bomb, and a method using hydrogen gas generated by electrolysis of water. However, due to the cleanliness of hydrogen gas and the simplicity of facilities, A method using hydrogen gas generated by the hydrogen gas is widely used.

On the other hand, in the present invention, an alkaline hydrogen sulfide excellent in the removal of active oxygen is provided by using ground water or tap water.

Recently, one of the most important causes of adult diseases such as hypertension, diabetes and heart disease is the acidification of the constitution due to excessive intake of acidic foods such as meat and fish. In order to improve the acidic constitution to weak alkaline constitution, And the user is required to be able to adjust the pH concentration of alkaline water in a simple, quick and easy manner suitable for taste, constitution, and the like.

As an apparatus for producing the above-mentioned hydrogenated water, conventionally known techniques are disclosed in Korean Patent Laid-open Publication No. 10-2011-39647, an electrolytic water water producing apparatus, Korean Patent Registration No. 10-1076631, No. 10-0995713 discloses an electrode assembly for electrolysis, an oxygen-hydrogen generator having the same, a device for producing hydrogen-containing water having the same, and a device for producing dissolved water of Korean Patent No. 10-1250470. The problem is that the hydrogen content in the hydrogenated water is too low.

Republic of Korea Patent Publication No. 10-2015-0134576, and the arc image composition and a manufacturing method for the atopic symptoms are delivered hydronium ions because of the reduced water by electrolysis of water does not separate the cathode chamber and an anode chamber (H ₃ O ⁺⁾ and There is a problem that the concentration of hydrogen in water is very low due to coexistence of hydroxide ions (OH < ^- & gt ^; ).

In general, oxygen is inhaled into the body by human breathing, which is used in the oxidation process. Some of the oxygen is produced in various metabolic processes, which attack the living body tissue and damage the cells. , Other cellular structures are damaged or lose their function, and physiological functions are lowered to cause diseases such as diabetes, stroke, myocardial infarction, hepatitis, nephritis, skin diseases, Parkinson's disease, ultraviolet radiation and radiation and aging It is known that about 90% of modern diseases are related to active oxygen.

Although it is known that it is good to take a lot of foods such as SOD (active oxygen scavenger) and vitamin C to remove the active oxygen which is the source of all kinds of diseases, the strongest antioxidant power of active oxygen is hydrogen, Hydrogen is in the spotlight.

In order to eliminate such active oxygen, antioxidants such as ascorbic acid (vitamin C) may be ingested. When such ascorbic acid reduces active oxygen, ascorbic acid generates new ascorbic acid oxidized by active oxygen This is known to damage genes.

Thus, in general, antioxidants have the potential to cause some side effects as a result of a series of reduction and oxidation chain reactions.

On the other hand, active hydrogens can be said to be safe because they combine with active oxygen to reduce and remove active oxygen, resulting in only water.

Therefore, it is more effective to take antioxidants in a natural way. Therefore, a water-containing water producing apparatus (Korean Patent Registration No. 10-1076631) has been provided to dissolve hydrogen in water.

It is said that 2% of the oxygen used to inhale oxygen every day is the active oxygen that is harmful to the human body and is the source of all diseases.

In order to remove this active oxygen, it is consumed as food or product containing vitamin C. However, it is known that hydrogen is several hundred times higher in antioxidant power than vitamin C.

Such hydrogen has been reported to be effective in human lifestyle diseases such as diabetes, cancer, obesity, dementia, hyperlipemia, rheumatism, and aging as well as dermatitis (Treatment of atopy dermatitis with hydrogen containing water, shoto-kai medical corporation, MD Yoshikazu Irie).

However, there are many techniques for producing a composition using alkaline ionized water. However, studies using weakly alkaline hydrogenated water and strong alkaline hydrogenated water have not been studied yet, and no technology for preparing a composition has been disclosed.

Far infrared ray is a wave of 6 ~ 15 microns in the wavelength range of 0.76 ~ 1.00 microns in the wavelength range, penetrates deeply into the human body to a depth of 30 ~ 50mm, resonates and resonates to generate self heat, And expels the waste matter and harmful heavy metals in the cell tissue through the sweat glands to the outside of the skin. Accordingly, by facilitating metabolism in the human body, it is possible to improve the natural healing power of the human body, thereby improving the diseases caused in the skin.

Among the natural minerals in Korea, the minerals that are known to emit far-infrared rays are ilite, pozzolan, sericite, loess, silica, diatomaceous earth, alumina and kaolin etc. They are mainly used in ceramics, glass, building bricks, water purification agents, refractories, .

The biomedical effects of far-infrared rays revealed through various researches at home and abroad have shown that the biomedical effect of the far-infrared rays is to promote the growth of the living body, to activate the blood circulation, to maintain the balance of the autonomic nervous system (to help maintain heart homeostasis, Efficacy to relieve pain, such as discharge, shoulder pain, and backache, EEG stabilization effect, and sleeping effect.

Ilrite used as a material of the present invention is a fine clay mineral having an average particle size of 1,136.8 nm mainly composed of SiO ₂ , Al ₂ O ₃ , K ₂ O, FeO, and Fe ₂ O ₃ and adsorbs heavy metals and toxic gases It has deodorizing effect and has antibacterial effect against viruses, bacteria and fungi. It is known that it emits far infrared rays at room temperature, generates anion, and emits oxygen in water.

Illight has antimicrobial properties, so it can prevent the deterioration of the product without adding a chemical preservative.

In addition to reducing the amount of chemical substances that are the main cause of skin irritation, it also prevents the growth of various bacteria and fungi on the skin, which can fundamentally reduce skin troubles.

In addition, since it exhibits excellent adsorption properties, various contaminants such as excess sebum and cosmetic residue in pores such as excess sebum, especially heavy metals, can be effectively removed to maintain a clean skin.

Ilyite penetrates deeply into the skin by transmitting negative ions and heat to maintain smooth and resilient skin. It produces anion exchange with the generation of anion and far-infrared ray radiation to release skin wastes, maintain healthy skin, and maintain moist skin with proper moisturizing effect.

In addition, Illight has been listed on the International Cosmetic Ingredient Dictionary (ICID), and has become available as a raw material for cosmetics.

In the case of the present invention, it is intended to provide a composition containing an ichthyol extract obtained by condensing water vapor generated by heating a water and heating water into a heating furnace, or condensing water vapor passed through the water.

On the other hand, pozzolan is made of volcanic rocks and is known as a kind of pyrophyllite. It is known as an orphan material created during the Cretaceous period and its major origin is the minerals found in the village of Pozori, near Bari Island, Italy. It is the site of the Colosseum Stadium, It was used instead.

These buildings have been preserved in their original form for many years without cracks and corrosion to this day, as the pozzolans have been used by scholars.

Pozzolan emits 90 ~ 97% of far infrared rays, which are beneficial for human health, at a wavelength of 5 ~ 20 ㎛ and is useful for restoring fatigue, promoting blood circulation, activating circulation system of the human body, skin health of microvascular vessels, restoring fatigue such as muscles and limbs, Elimination of headache due to air purification, sterilization, heavy metal neutralization, water purification, air purification, and odor removal.

In particular, the pozzolans from Italy and Korea emit a very high number of anions from natural minerals because of the large release effect of germanium or far-infrared rays, providing effects of oxygen supply, sterilization and deodorization from plant to human body and natural environment .

A coating agent containing natural pozzolan as an active ingredient can be easily prepared in any form according to a conventional production method.

For example, when preparing a cream type coating agent, the natural pozzolana of the present invention is contained in a cream base of a general water type (O / W) or water type (W / O), and a flavor, a chelating agent, a colorant, an antioxidant, Etc. may be used as needed, and synthetic or natural materials such as proteins, minerals, and vitamins may be used in combination for the purpose of improving physical properties.

On the other hand, the sericite contained in the skin improving composition using natural materials is a kind of clay minerals, the color of which is silver-white, and the silk gloss is strong.

Mineralogically, it belongs to the mica group. Its chemical composition and crystal structure are similar to muscovite, the far-infrared emissivity is about 93%, the anion generation is about 700 / cc and the safest anion, It has a function to adsorb various harmful substances.

In addition, sericite is a far-infrared ray emitter, which is a mineral that emits far-infrared rays as shown in the report of the Ministry of Science and Technology, "Research on raw materials and rocks used as far-infrared radiations" or "Study on the value-added improvement of nonmetal minerals" Have.

The ginseng extract is effective in improving the side effects of saponin by removing excess cholesterol and triglyceride in the blood and helping to improve the blood flow. Therefore, the vitamin B complex (B ₁ , B ₂ , B ₁₂ , C ), Nicotinic acid, pantothenic acid, folic acid, biotin, and the like.

Korean Patent Laid-Open No. 10-2003-78093 discloses a composition for treating skin diseases containing processed ginseng or an extract thereof as an active ingredient.

Such a skin disease relieving composition containing ginseng extract has an effect of alleviating symptoms of various skin diseases due to inherent characteristics of ginseng.

The green tea leaves contain a large amount of catechin, and are excellent in various adult disease prevention, anti-cancer and sterilization functions, and are rich in vitamin C, vitamin E, beta carotene, plant fiber, minerals and chlorophyll.

Aloe is a plant belonging to the genus Aloe, which has germicidal power against bacteria and fungi and contains aloe tine which neutralizes toxins, aloe vera effective for ulcers, and anti-cancer alumitin.

Other ingredients include steroids, amino acids, saponins, wound healing hormones, and minerals.

If you cut off the leaves of aloe, a yellowish substance flows out, which is particularly effective for constipation. In the private sector, aloe leaf juice is used for gastrointestinal diseases and is also used for trauma and burns. It also neutralizes dry and oily skin, and has a moisturizing effect on the skin, making it a cosmetic ingredient.

In the present invention, the composition comprises the aloe juice, which is an extract of the liquid component extracted by pulverizing the aloe leaves to form an aloe crushed product, and filtering the aloe crushed product.

In addition to covering the body of the body and protecting the whole body, skin is a tissue that is responsible for crust, respiration, excretion, secretion, body temperature control, immune response, and other important functions.

The most ideal skin pH of humans is 4.7 ~ 5.75, which is mildly acidic. If the acidity of the skin is close to acid, it is called oily skin and if it is close to alkaline, it is dry skin.

The skin is weakly acidic by the secretions of low fatty acids, ascorbic acid, lactic acid, amino acids and the like secreted from sebaceous glands and glands (sweat glands).

The thin acid film on the surface of the skin is a natural protective film that protects the skin from external physical and chemical damage. In general, bacteria such as bacteria are alkaline, so they do not survive in a weakly acidic environment of the skin.

The pH of the skin is closely related to the skin condition, the protective film, and the keratin condition. When the pH range of the skin is out of the normal range, the balance is broken and skin disease occurs.

If the acidity of the skin gets closer to alkaline, it will be easily damaged by external stimuli, and the trouble will become more easily.

It is easily infiltrated by various bacteria and becomes less sensitive to skin immunity.

In addition, the balance of the skin water balance is broken. The sebum is secreted vigorously and secreted sebum may block the pores to cause troubles, or dry acne may occur which is caused by the lack of moisture and the horny pores blocking the pores.

It is known that the pH of acne skin is increased to 7.5 and that of atopic skin to pH 8.0.

On the other hand, if the skin pH is in a normal range with a weak acidity, the weakly acidic membrane forms a skin barrier to protect the skin from external harmful substances.

Generally, it is known that bacteria do not survive well below pH 6.0, so it is difficult for bacteria to grow in weakly acidic skin.

Accordingly, there is an increasing demand for a cosmetic composition for controlling skin pH balance.

Generally, in order to adjust the pH, a chemical substance called a pH adjusting agent or a buffering agent is added. Examples of the controlling agent used in cosmetics include sodium phosphate, citric acid, stearic acid, disodium citrate, disodium phosphate, sodium citrate, triethanolamine, And phosphoric acid caries.

However, long-term use of these ingredients may cause irritation to the skin, especially when triethanolamine accumulates in the body for a long time and is known to have a detrimental effect on eye-related diseases.

Accordingly, in the present invention, the present invention provides Korean Patent Application No. 10-2016-0031831 filed in 2016, which is an apparatus for producing high-concentration hydrogen water useful for improvement of atopy and an acidic water Can be used as a pH regulator by using an acidic water obtained from an anode through electrolysis to remove the pH value of the skin.

Korean Patent Laid-Open Publication No. 10-2002-46329 discloses an external skin composition for improving dermatitis, which contains a natural nonionic surfactant, a higher alcohol, a moisturizing ingredient, an anti-inflammatory ingredient and an itch inhibiting ingredient.

Korean Patent Laid-Open Publication No. 10-2004-46776 discloses a composition for improving dermatitis including sodium silicate, castor oil, calcium chloride, magnesium sulfate and purified water.

Korean Patent Publication No. 10-431076 discloses a cosmetic having antibacterial, moisturizing, anti-inflammatory, and free radical scavenging effect, which has an effect of improving healing of skin, which includes white wool, barley, echinacea and fermented soybean extract .

Korean Patent Laid-Open Publication No. 10-2006-118809 discloses a functional composition for relieving dermatitis comprising various herbal medicines such as Killer, Gobon, Kwakyang, Gakyung, and the like.

The functional composition for relieving dermatitis containing such a herbal medicine has the effect of alleviating dermatitis by moderating the hypersensitivity symptoms of the skin by the herbal medicine.

Further, in the studies on the dermatitis-releasing composition, there has not yet been disclosed a technique of applying a water-soluble propolis.

Korean Patent Publication No. 10-2001-0089716 Korean Patent Publication No. 10-2015-0134576

SUMMARY OF THE INVENTION Accordingly, the present invention has been made keeping in mind the above problems occurring in the prior art,

It is an object of the present invention to provide a hydrogen-water mixture using alkaline hydrogen peroxide, and to thereby improve irritation of the skin due to abnormal skin conditions.

More particularly, the present invention relates to a method for preparing an alkaline water or a strong alkaline water by using an anion exchange resin as raw water such as groundwater or tap water, An aqueous solution of alkaline hydrogen water, a mineral material which emits a large amount of far-infrared rays and anions, and a natural material which improves skin irritation by using a medicinal plant.

In the conventional method for producing hydrogen water by electrolysis of water, the most problematic is that the pH of the water of the final product is not constant because the pH of the water is not constant due to the influence of the pH of the raw water. It is intended to solve.

When the raw water is electrolyzed, scales caused by mineral substances such as calcium contained in tap water, ground water or natural water are prevented from occurring on the electrode and the inner surface of the main body, and residual chlorine and hypochlorite ions To suppress the generation of odor and to inhibit the production of total trihalomethanes.

In order to achieve the object of the present invention,

A method for producing a hydro-condensate according to an embodiment of the present invention includes:

(S100) of producing alkaline deionized (-) ionized water by using a weakly basic anion exchange resin and a strongly basic anion exchange resin,

A step S200 of electrolyzing the alkali deionized water to prepare weak alkaline hydrogen water (pH 7.2 to 9.5), strong alkaline hydrogen water (pH 9.5 to 13.0) and acidic ionized water (pH 1.0 to 6.0) ,

Pozzolan powder and sericite powder of 8,000 to 12,000 mesh formed by pulverizing alumina, ilite, pozzolan and sericite at a super-high speed of about 7,000 rpm in a pulverizer (S300)

(S400) mixing the natural ore water powder with the weakly alkaline hydrogen water to prepare a natural ore water mixture,

10 to 20 parts by weight of ginseng, 5 to 15 parts by weight of fine green tea leaf powder of 8,000 to 12,000 mesh formed by nano-milling dried green tea leaves at an ultra-high speed of 7,000 rpm in a nano mill, and 2 to 4 parts by weight of aloe leaf extract Step S500,

(S600) mixing the medicinal plant mixture with weakly alkaline hydrogen water to prepare a medicinal plant mixture,

(S700) mixing 20 to 50 parts by weight of the natural ore water mixture, 20 to 50 parts by weight of the medicinal plant mixture and 0.1 to 5 parts by weight of propolis based on 100 parts by weight of alkaline hydrogen water,

Stirring the mixture for 100 to 150 minutes, recovering and re-introducing the alkaline hydrogen fluoride to form a gel composition (S800)

(S900) of rapidly quenching the gel composition to room temperature and aging the quenched gel at room temperature for 120 hours to obtain a water-containing mixture,
Wherein electrolytic decomposition of the raw water is inhibited from occurring on the inner surface of the electrode and the main body due to a mineral substance contained in tap water, ground water or natural water,
The weakly basic anion exchange resin is used to make the weakly alkaline water (pH 7.2 to 9.5), and the strongly basic anion exchange resin is used to make the strong alkaline aqueous solution (pH 9.5 to 13.0) And,
Acidic ionized water (pH 1 to 6) produced in a positive (+) polar room is used as a pH regulator of a hydrogenated mixture when alkaline water is produced by electrolysis of water.

delete

A method for producing a hydrogen-water mixture according to the present invention comprises:

A small amount of the produced hydrogen peroxide mixture is added to the ointment or cream, for example, and is used for the removal of active oxygen, alkali water, a mineral which emits a large amount of far infrared rays and anions, and a medicinal plant mainly used in one medicine. At the same time, the volatile organic compound is anionized by using propolis and the ozone molecule is decomposed to provide an effect of improving the abnormal skin condition.

In addition, it is possible to produce alkaline water with a small scale, preventing scales due to mineral substances such as calcium contained in raw water such as tap water, ground water or natural water from occurring on the surface of the electrode and the inside of the body, thereby improving production efficiency.

That is, it is possible to suppress the generation of odor and to suppress the production of total trihalomethane by removing residual chlorine and hypochlorous acid ions generated during electrolysis of water.

It is possible to easily produce weak alkaline hydrogen water having a pH of 7.2 to 9.5 and strong alkaline hydrogen water having a redox potential higher than that of a pH of 9.5 to 13.0 and acidic ionized water having a pH of 1 to 6, It can be used as a composition for improving skin condition, food for drinking, beverage, medical, agricultural and industrial use (disinfection, disinfection, pH adjusting agent).

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a process diagram showing a method for producing a hydrogen-water mixture according to an embodiment of the present invention; FIG.
FIGS. 2 to 6 are comparative photographs of skin when a hydro-mixed water according to an embodiment of the present invention is provided to an abnormal skin condition site.

Hereinafter, embodiments of the method for producing a hydrogen-water mixture according to the present invention will be described in detail.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a process diagram showing a method for producing a hydrogen-water mixture according to an embodiment of the present invention; FIG.

As shown in Fig. 1, the method for producing a hydro-

A step (S300) of producing a natural ore water powder selected from the group consisting of diatomite, zeolite, zeolite, pozzolan, sericite,

Mixing the ginseng, green tea leaves and aloe leaf extract (S500)

(S900) of quenching the gel composition to room temperature, and aging the quenched gel at room temperature for 120 hours to obtain a water-containing mixture (S900).

Specifically, the raw water is made alkaline deionized water (S100) by using a weakly basic anion exchange resin and a strong basic anion exchange resin, and the alkaline deionized water is electrolyzed to produce weak alkaline water (pH 7 (PH9.5 ~ 13.0) and acidic ionized water (pH 1.0 ~ 6.0) are prepared (S200).

The step of producing the alkaline hydrogen water is disclosed in detail in Korean Patent Application No. 10-2016-0031831 filed in 2016 by the present invention through a device and a method for producing high-concentration hydrogen water useful for improvement of atopy.

Therefore, a detailed description will be omitted.

Thereafter, a natural ore water powder selected from the group consisting of ilite, pozzolan, sericite, or a mixture thereof is prepared (S300), and the natural ore water powder is mixed with weakly alkaline hydrofluoric acid to prepare a natural ore water mixture (S400) do.

Then, ginseng, green tea leaves and aloe leaf extract are mixed (S500), and the medicinal plant mixture is mixed with weakly alkaline hydrogen water to prepare a medicinal plant mixture (S600).

Thereafter, 20 to 50 parts by weight of the natural ore water mixture, 20 to 50 parts by weight of the medicinal plant mixture and 0.1 to 5 parts by weight of propolis are mixed to form a mixture (S700) on the basis of 100 parts by weight of alkaline hydrogen water, Is stirred for 100 to 150 minutes, and the alkaline hydrogenated water to be evaporated is recovered and re-introduced to form a gel composition (S800).

Thereafter, the gel composition is quenched to room temperature, and the quenched gel is aged at room temperature for 120 hours to obtain a water-containing mixture (S900).

On the other hand, the present invention relates to a pharmaceutical composition comprising 20 to 50 parts by weight of a natural ore selected from the group consisting of ilite, pozzolan, sericite or a mixture thereof, based on 100 parts by weight of an alkali hydrogen water, 20 to 50 parts by weight of a herbal medicine 20 To 50 parts by weight.

Preferably, 10 to 20 parts by weight of ginseng, 5 to 15 parts by weight of green tea leaves, and 2 to 4 parts by weight of aloe leaf extract are prepared.

Then, a mixture containing 0.05 to 5 parts by weight of propolis is used to make a hydrogen-water mixture using a natural material.

The hydrogenated water mixture according to one embodiment of the present invention includes 20 to 50 parts by weight of a natural ore selected from the group consisting of ilite, pozzolan, sericite, and mixtures thereof based on 100 parts by weight of alkaline hydrogen water.

The natural ore water may be processed into powder, for example, and used in the present invention.

At this time, the larger the surface area per unit weight of the natural ore water powder, the smaller the size of the powder, the more the contact area with air increases, thereby improving the anionization function and the moisturizing function of ozone.

In the present invention, fine inorganic powder, pozzolan powder, and sericite powder of 8,000 to 12,000 mesh, preferably 10,000 mesh, formed by pulverizing allyl, pozzolan and sericite at an ultra-high speed of about 7,000 rpm in a pulverizer are preferably used .

Thus, the hydrogen-water mixture containing a natural ore water powder selected from the group consisting of anilite powder, pozzolan powder, sericite powder or mixtures thereof, which is finely pulverized to 8,000 to 12,000 mesh and emits anion and far-infrared rays, To make the ozone molecule anionized.

When the average particle size of the natural ore water powder is less than 8,000 mesh, the contact area with the air is decreased to decrease the anionization function of the ozone. If the average particle size of the natural ore water powder exceeds 12,000 mesh, It is not improved and only the manufacturing cost and the manufacturing time are increased.

If the content of the natural ore water contained in the hydrous mixture of the present invention is less than 20 parts by weight, the anionization function and the moisturizing function of the ozone of the composition deteriorate. If the content of the natural ore water exceeds 50 parts by weight, , The tactile feel of the prepared composition is deteriorated.

Further, in addition to natural ore water such as ilite, pozzolana, and sericite, the hydrogen-water mixture of the present invention further contains an alkaline hydrogen water for improving anion release, ginseng, green tea leaves and aloe leaf extract, And the effect of moisturizing the skin of the human body is excellent, so that the satisfaction of the user of the composition can be improved.

The hydrous water mixture using a natural material according to an embodiment of the present invention may contain 10 to 20 parts by weight of ginseng based on 100 parts by weight of alkaline hydrogen water.

The ginseng extract is effective in improving side effects by removing extra cholesterol and triglyceride in blood by supporting saponin in the blood stream. Therefore, the ginseng extract provides sufficient nutrition and oxygen to the skin cells and alleviates symptoms of various skin diseases.

5 to 15 parts by weight of green tea leaves may be included in the hydrogen-water mixture using a natural material according to one embodiment of the present invention based on 100 parts by weight of alkaline hydrogen water.

The green tea leaves contain a large amount of catechin and are excellent in various adult disease prevention, anticancer, and antiseptic functions, and are rich in vitamin C, vitamin E, beta carotene, plant fiber, minerals and chlorophyll.

Such green tea leaves may be used in the present invention in the form of extract or powder.

When the green tea leaves are used in the form of an extract, green tea leaves are washed with acidic water, and the washed green tea leaves are ground to prepare green tea leaf pulverized material. The green tea leaf pulverized material is pressed to extract liquid components And filtered to obtain a green tea leaf extract which is a liquid component.

When the green tea leaves are used in the form of powders, the green tea leaves are washed, naturally dried until the water disappears on the surface of the green tea leaves, and the dried green tea leaves are dried at 8,000 It is preferable to use fine green tea leaf powder of ~ 12,000 mesh.

When the content of the green tea leaf powder contained in the hydrogen-water mixture of the present invention is less than 5 parts by weight, various kinds of adult diseases preventive function, anticancer function and sterilizing function of the composition are lowered. When the content of green tea leaf powder is more than 15 parts by weight, Is not gelled properly.

If the amount of the aloe juice contained is less than 2 parts by weight based on 100 parts by weight of the alkaline hydrogen water in the hydrous water mixture using the natural material according to one embodiment of the present invention, And the content of the aloe juice is 4 parts by weight, the water-containing mixture is provided with sufficient pollutant neutralizing function and sterilizing function.

If the content of propolis contained is less than 0.05 part by weight based on 100 parts by weight of alkaline hydrogen water in the hydrolyzate mixture using a natural material according to an embodiment of the present invention, the sterilizing function of the water- Is less than 5 parts by weight, the sterilization function of the hydrogen-water mixture is less effective.

Hereinafter, the present invention will be described in detail with reference to the preferred embodiments.

It should be noted, however, that the present invention is not limited to the following examples.

Example 1 Hydrophobic production process

May be the tongtap the SV 40 to DIAION SA21A resin column of a strongly basic anion exchange resins, cations such as Ca ⁺² ion as shown in Table 1 is not removed, the sound, such as ^{_{^{Cl -1, PO 4 -3 (-}}} ) ion was only possible to obtain the removal of pH 9.5 ~ 13.0 water, cations such as weakly basic anion exchange resin DIAION WA20 tongtap to the resin column with SV 30 Ca ⁺² ion is not removed, Cl ^-1, PO ₄ ^-3, such as a negative (-) ions only and the pH to obtain the removal of water of 7.2 ~ 9.3.

Raw water SA20A processed water WA20 processed number Remarks pH 7.7 9.5 to 13.0 7.2 to 9.5 Redox potential + 3.40 mV -480mV -300mV Ca < ² > (ppm) 18.04 18.04 18.04

Cation

Mg ^{+ 2} (ppm) 4.6 4.6 4.6 Mn ^{+ 2} (ppm) 0.01 0.01 0.01 Zn ^{+ 2} (ppm) 0.01 0.01 0.01 Fe ⁺³ (ppm) 0.02 0.02 0.02 Al ⁺³ (ppm) 0.06 0.06 0.06 Cl- ¹ (ppm) 10.3 0 0 Anion SO ₄ ^-2 (ppm) 9.3 0 0 PO ₄ ^-3 (ppm) 0.007 0 0

In order to make the deionized water having a pH of 7.2 to 9.5 obtained in Example 1 to be acidic and hydrogenated, Korean Patent Application No. 10-2016-0031831 filed by the present invention, which is an electrolysis disclosed in a device for producing high- Is sent to the electrolyzer (310) of the process (300).

The electrolytic cell is divided into an anode chamber electrode and the cathode chamber electrode by the diaphragm can pass only ions with electrical properties, when a voltage is applied to the as anion removing of pH 7.2 ~ 9.5 the number of electrolysis cathode compartment hydrogen and OH ^- And an alkaline aqueous solution is generated. At the same time, oxygen and H are generated in the anode chamber to generate acidic water.

The alkaline water produced in the cathode chamber is converted into a high concentration of hydrogen peroxide through the activated carbon porous material adsorbent 410, which is an adsorption condensing facility, to obtain alkaline hydrogen water having a pH of 7.2 to 9.5 including the 1,600 ppb hydrogen dissolved amount, And is stored in the hydrogenated water storage tank 510.

At this time, the acidic water generated in the anode chamber is sent to a separate acidic water (pH 1-6) storage tank 530, which is used as a sterilizing water for washing the composition materials and a pH adjuster for the final product of the composition.

Similarly, the deionized water having a pH of 9.3 to 13.0 is sent to the electrolytic bath of the electrolysis step (300) to produce acidic water and hydrogenated water.

When the voltage is applied to the electrolytic cell, the deionized water of pH 9.5 ~ 13.0 is electrolyzed, and hydrogen and OH ^- are generated in the cathode chamber, and alkaline water is produced. At the same time, oxygen and H ⁺ are generated in the anode chamber and acidic water is generated.

The alkaline water produced in the cathode chamber is converted into a high concentration of hydrogen peroxide through the activated carbon porous material adsorption unit, which is an adsorption condensing facility, so that alkaline hydrogen water having a pH of 9.5 to 13.0 including the hydrogen dissolved amount of 1,800 ppb is obtained, (520).

At this time, the acidic ionized water (pH 1 to 6) generated in the anode chamber is sent to the separate acidic water storage tank 530.

These acidic waters are mainly used as washing sanitizer disinfectant and pH regulator.

Natural ore water Step of preparing the mixture

Using a nano-pulverizer (ATOMIZER, FUJI PAUDAL, Japan), pulverized at a super-high speed of 7,000 rpm to obtain 10,000 mesh of anilite, pozzolan and sericite powders.

A natural ore water mixture was obtained by mixing 200 g of diatomite powder, 200 g of pozzolan powder and 200 g of sericite powder in 1,000 g of alkaline hydrogen water having a pH of 7.2 to 9.5.

The step of preparing the medicinal plant mixture

The ginseng was washed with acidic water obtained from the positive (+) electrode in the electrolysis and naturally dried until the water disappears on the surface. The dried ginseng was nano-milled at a high speed of 7,000 rpm in a nano mill to prepare a 10,000 mesh ginseng powder &Lt; / RTI >

Green tea leaves are washed with acidic water and dried naturally until the water disappears

The green tea leaves of 10,000 mesh were formed by nano milling the dried green tea leaves at a high speed of 7,000 rpm in a nano mill.

The aloe leaves were washed with acidic water and pulverized, and the resulting pulverized product was filtered to obtain a liquid component extract, aloe juice.

Step of preparing water-soluble propolis powder

The propolis collected from the honeycomb was immersed in two volumes of ethanol for 6 weeks and then filtered through a filter to obtain propolis (EEP) extracted with ethanol.

The mixture of EEP and water in the reaction tank was mixed at a ratio of 1: 1 and reacted for 24 hours to separate into REEP (Residue of Ethanol Extracted Propo1is) separated into the upper layer and WEP (Water Extracted Propolis) separated into the lower layer.

The upper layer was removed and the lower layer of water-soluble propolis was obtained and powdered to prepare a water-soluble propolis powder.

After mixing 1 g of propolis in a reactor capable of recovering liquid alkaline water of 1,000 g, ginseng powder of 300 g, green tea leaf powder of 150 g, and aloe juice of 40 g in a liquid phase evaporator, acidic water Was used as a pH regulator to obtain a mixture having a pH of 4.7 to 5.75.

The mixture of the natural ore and the medicinal plant was agitated at 85 rpm at 500 rpm for 120 minutes to obtain a gel composition. The alkaline hydrogen peroxide solution was recovered and gelled while re-introduced to obtain a gel composition.

The gel composition was placed in a quencher and forcedly quenched at room temperature. The gel was aged at room temperature for 120 hours to obtain a water-containing mixture.

The hydrophobic mixture prepared in Example 1 was applied to the hands of a person without skin disease for 15 days in a size of 5 × 5 cm 2, covered with gauze for 1 hour and sufficiently absorbed, and skin condition was confirmed.

Since no specificity was found in the skin after 15 days, it was confirmed that the water-miscible mixture did not cause toxicity or adverse effects on human skin.

In addition, it was confirmed that the dry feeling on the skin on which the burned and water-containing mixture was applied was reduced, and thus it was confirmed that it had moisture resistance against moisture.

In order to confirm the improvement effect of the hydrolyzed mixture, a test was conducted by applying a water-containing mixture to the skin area having abnormal skin conditions.

The application method was to apply thinly to the lesion, then repeated several times, and massage it so as to exert an anion effect.

&Lt; Comparative Example 1 &

A hydrous mixture was prepared under the same conditions as in Example 1 except that the natural mineral water mixed powder of the diol, pozzolan and sericite of Example 1 was not added.

&Lt; Comparative Example 2 &

Hydrogen water mixtures were prepared under the same conditions as in Example 1 except that the medicinal plant mixtures of Example 1 were not added.

&Lt; Comparative Example 3 &

A hydrogen-water mixture was prepared under the same conditions as in Example 1, except that 1,000 g of alkaline ionized water was added instead of 1,000 g of the alkaline aqueous solution of Example 1 to obtain a hydrogen-water mixture.

&Lt; Comparative Example 4 &

A hydrogen-water mixture was prepared under the same conditions as in Example 1 except that 1,000 g of tap water was added instead of 1,000 g of the aqueous alkaline hydrogen hydroxide of Example 1 to obtain a hydrogen-water mixture.

&Lt; Comparative Example 5 &

Hydrogen water mixture was prepared under the same conditions as in Example 1 except that 1 ml of propolis in Example 1 was not added to obtain a hydrogenated water mixture.

Far-infrared and anion emission

The infrared emissivity and anion emission test of Example 1 and Comparative Examples 1 to 5 were carried out.

The anion emission test was conducted in accordance with KICM-FIR-1042, an anion emission test method commonly used in the Korea Testing and Research Institute of Korea. The far infrared ray emission amount was measured according to KCIM-FIR-1005 The results are shown in Table 2.

Example 1 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Far infrared ray
Emissivity (%) 92.3 82.6 88.7 82.8 80.6 90.5 Anion
(Dogs / cc) 11,000 8.000 10,000 7.000 6.800 10,200

As a result of the measurement of the far infrared ray and anion emission amount, the hydrogen-water mixture of the present invention had an infrared ray emissivity exceeding 90% or more and an anion index of 6.000 or more at a wavelength of 5 to 20 탆.

Improvement test for dermatitis

A total of 40 patients with dermatitis were subjected to a test for one month for each of the compositions of Example 1 and Comparative Examples 1 to 5.

For the symptoms such as side effects, tingling, and aggravation of symptoms during the experimental period, the test was stopped immediately and the overall evaluation was evaluated for improvement of the itching status within 1 month and evaluated as shown in Table 3 below.

Table 3 below shows the dermatitis relief (improvement) effect by visual determination.

score Example 1 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 High improvement 10 8 3 4 2 One One Intermediate line 7.5 2 4 4 6 4 4 Low improvement 5 0 3 2 2 5 4 No improvement 2.5 0 0 0 0 One Sum 95 75 80 75 65.0 62.5 Average 9.5 7.5 8.0 7.5 6.5 6.3

In Table 3, it can be seen that when the area of the area where the dermatitis appears visually almost disappears, the improvement is high, and when the area is more than 3/4 (75%), And when the difference between the area of the site where the dermatitis occurred and the difference between the areas before and after the experiment was little, the improvement was judged as no improvement.

As can be seen from Table 3 above, the composition comprising alkaline hydrogen water, natural ore water mixture, medicinal plant mixture, and propolis may be any one of alkaline hydrogen water, natural ore water mixture, medicinal plant mixture, Showed an improvement effect of dermatitis superior to the composition added.

As shown in Tables 2 and 3, the hydrogen-water mixture using the natural material of the present invention is excellent in moisturizing property and can be used as an anion ozone which does not affect the ozone molecule which promotes dermatitis by releasing a large amount of anion and far- It was found that the symptoms of dermatitis could be improved by switching. Therefore, it may be used as an application for improving the abnormal skin condition.

2 to 6 are comparative photographs of skin when a hydro-mixed water according to an embodiment of the present invention is applied to an abnormal skin symptom region.

FIG. 2 shows a photograph of a patient with severe dermatological symptoms at the foot area. It was confirmed that the hydro-alcoholic mixture of the present invention was improved after 2 months, and it was confirmed that the improvement was remarkable after 3 months.

In the case of FIG. 3, the photographs of the patients with severe skin abnormalities in the shin and thigh region of the 2-year-old infant were improved, and it was confirmed that the water-miscible mixture of the present invention was improved after 2 months from being given to the affected area. It was confirmed that it was improved.

FIG. 4 shows a photograph of a patient with severe skin abnormality on the knee area of a 5-year-old child. It was confirmed that the water-miscible mixture of the present invention was improved after 2 months from being given to the affected area, I could confirm.

FIG. 5 shows a photograph of a patient with severe skin abnormality on the foot area of a 30-year-old adult, and it was confirmed that the hydrolyzate of the present invention was improved two months after being provided to the affected area. I could confirm.

In the case of FIG. 6, the photograph of the patient with severe skin abnormality on the upper half of the 8-year-old child showed that the improvement of the water-in-water mixture of the present invention was provided one month after the injection, I could confirm.

As shown in FIGS. 2 to 6, patients with severe skin abnormalities such as ankle, instep, shin, thigh, and whole body were severely affected. However, when the hydro-alcoholic solution according to the present invention is provided for at least one month In the case of the US.

It will be appreciated by those skilled in the art that the present invention may be embodied in other specific forms without departing from the spirit or essential characteristics thereof. It is to be understood, therefore, that the embodiments described above are to be considered in all respects as illustrative and not restrictive.

The scope of the present invention is defined by the appended claims rather than the detailed description and all changes or modifications derived from the meaning and scope of the claims and their equivalents are to be construed as being included within the scope of the present invention do.

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Claims

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In the method for producing a hydrogenated mixture,
(S100) of producing alkaline deionized (-) ionized water by using a weakly basic anion exchange resin and a strongly basic anion exchange resin,
A step S200 of electrolyzing the alkali deionized water to prepare weak alkaline hydrogen water (pH 7.2 to 9.5), strong alkaline hydrogen water (pH 9.5 to 13.0) and acidic ionized water (pH 1.0 to 6.0) ,
A step (S300) of producing 8,000 to 12,000 fine fine powder, pozzolan powder, and sericite powder formed by pulverizing alite, pozzolan and sericite at an ultra-high speed of 7,000 rpm in a pulverizer,
(S400) mixing the powders with the weakly alkaline hydrofluoric acid to prepare a natural ore water mixture,
10 to 20 parts by weight of ginseng, 5 to 15 parts by weight of fine green tea leaf powder of 8,000 to 12,000 mesh formed by nano-milling dried green tea leaves at an ultra-high speed of 7,000 rpm in a nano mill, and 2 to 4 parts by weight of aloe leaf extract Step S500,
Preparing a medicinal plant mixture by mixing the mixture with weakly alkaline hydrofluoric acid (S600)
(S700) mixing 20 to 50 parts by weight of the natural ore water mixture, 20 to 50 parts by weight of the medicinal plant mixture and 0.1 to 5 parts by weight of propolis based on 100 parts by weight of alkaline hydrogen water,
Stirring the mixture for 100 to 150 minutes, recovering and re-introducing the alkaline hydrogen fluoride to form a gel composition (S800)
(S900) of rapidly quenching the gel composition to room temperature and aging the quenched gel at room temperature for 120 hours to obtain a water-containing mixture,
Wherein electrolytic decomposition of the raw water is inhibited from occurring on the inner surface of the electrode and the main body due to a mineral substance contained in tap water, ground water or natural water,
The weakly basic anion exchange resin is used to make the weakly alkaline water (pH 7.2 to 9.5), and the strongly basic anion exchange resin is used to make the strong alkaline aqueous solution (pH 9.5 to 13.0) And,
Wherein the acidic ionized water (pH 1 to 6) produced in the positive (+) polar room is used as a pH regulator of the hydrogenated water mixture when the water is electrolyzed to produce the alkaline hydrogen water.