KR101760820B1 - 높은 비에너지를 가진 리튬-황 전지 - Google Patents

높은 비에너지를 가진 리튬-황 전지 Download PDF

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Publication number
KR101760820B1
KR101760820B1 KR1020087008462A KR20087008462A KR101760820B1 KR 101760820 B1 KR101760820 B1 KR 101760820B1 KR 1020087008462 A KR1020087008462 A KR 1020087008462A KR 20087008462 A KR20087008462 A KR 20087008462A KR 101760820 B1 KR101760820 B1 KR 101760820B1
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lithium
sulfur
electrolyte
polysulfide
cell
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Expired - Fee Related
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Korean (ko)
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KR20080053493A (ko
Inventor
블라디미르 콜로스니친
엘레나 카라세바
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옥시스 에너지 리미티드
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/134Electrodes based on metals, Si or alloys
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566Liquid materials
    • H01M10/0569Liquid materials characterised by the solvents
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/58Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566Liquid materials
    • H01M10/0568Liquid materials characterised by the solutes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/137Electrodes based on electro-active polymers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/38Selection of substances as active materials, active masses, active liquids of elements or alloys
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/58Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581Chalcogenides or intercalation compounds thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/58Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581Chalcogenides or intercalation compounds thereof
    • H01M4/5815Sulfides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
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    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/60Selection of substances as active materials, active masses, active liquids of organic compounds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)
KR1020087008462A 2005-09-26 2006-09-21 높은 비에너지를 가진 리튬-황 전지 Expired - Fee Related KR101760820B1 (ko)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
GB0519491.5 2005-09-26
GB0519491A GB2430542B (en) 2005-09-26 2005-09-26 Lithium-sulphur battery with high specific energy
US72106205P 2005-09-28 2005-09-28
US60/721,062 2005-09-28
US73432005P 2005-11-08 2005-11-08
US60/734,320 2005-11-08
PCT/GB2006/050300 WO2007034243A1 (en) 2005-09-26 2006-09-21 Lithium-sulphur battery with high specific energy

Related Child Applications (1)

Application Number Title Priority Date Filing Date
KR1020137031637A Division KR20140006085A (ko) 2005-09-26 2006-09-21 높은 비에너지를 가진 리튬-황 전지

Publications (2)

Publication Number Publication Date
KR20080053493A KR20080053493A (ko) 2008-06-13
KR101760820B1 true KR101760820B1 (ko) 2017-07-24

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US (3) US20070072076A1 (enExample)
EP (1) EP1941568A1 (enExample)
JP (2) JP5442257B2 (enExample)
KR (1) KR101760820B1 (enExample)
WO (1) WO2007034243A1 (enExample)

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GB0615870D0 (en) * 2006-08-10 2006-09-20 Oxis Energy Ltd An electrolyte for batteries with a metal lithium electrode
EP2076936B1 (en) * 2006-10-25 2018-07-18 Oxis Energy Limited A lithium-sulphur battery with a high specific energy and a method of operating same
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KR101725650B1 (ko) 2014-10-29 2017-04-12 주식회사 엘지화학 리튬 황 전지
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US12237498B2 (en) 2019-07-22 2025-02-25 University Of Wyoming Apparatus and methods for fabrication of carbon foams and silicon-carbon composite anodes
KR102864155B1 (ko) * 2020-01-03 2025-09-26 주식회사 엘지에너지솔루션 리튬 이차전지
KR20220130199A (ko) * 2020-01-22 2022-09-26 코나믹스 인코포레이티드 황 이차 전지용 염 첨가제
CN111564602B (zh) * 2020-05-23 2023-03-07 江西理工大学 一种电位控制直接制备锂硫电池液态正极的方法
IT202100000704A1 (it) 2021-01-15 2022-07-15 Milano Politecnico Fluorurazione superficiale con fluoro elementare di litio metallico usato come anodo in batterie a litio metallico
KR20230075579A (ko) * 2021-11-23 2023-05-31 주식회사 엘지에너지솔루션 에너지 밀도 및 출력이 개선된 리튬-황 전지
CN114865076A (zh) * 2022-05-30 2022-08-05 远景动力技术(江苏)有限公司 电解质材料及其应用

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GB2438890B (en) * 2006-06-05 2011-01-12 Oxis Energy Ltd Lithium secondary battery for operation over a wide range of temperatures
GB0615870D0 (en) * 2006-08-10 2006-09-20 Oxis Energy Ltd An electrolyte for batteries with a metal lithium electrode
EP2076936B1 (en) * 2006-10-25 2018-07-18 Oxis Energy Limited A lithium-sulphur battery with a high specific energy and a method of operating same

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US4410609A (en) 1980-09-19 1983-10-18 Emanuel Peled Electrochemical cell
US5789108A (en) 1994-11-23 1998-08-04 Polyplus Battery Company, Inc. Rechargeable positive electrodes
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JP2005108724A (ja) * 2003-09-30 2005-04-21 Sanyo Electric Co Ltd 非水電解質二次電池

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JP2009510684A (ja) 2009-03-12
US20100231168A1 (en) 2010-09-16
WO2007034243A1 (en) 2007-03-29
JP2014067717A (ja) 2014-04-17
JP5947774B2 (ja) 2016-07-06
EP1941568A1 (en) 2008-07-09
US9123975B2 (en) 2015-09-01
US20070072076A1 (en) 2007-03-29
US8647769B2 (en) 2014-02-11
KR20080053493A (ko) 2008-06-13
US20140120428A1 (en) 2014-05-01
JP5442257B2 (ja) 2014-03-12

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