KR101753922B1 - 수소의 전기화학적 분리 및 수소의 물로의 전기화학적 반응을 포함하는, 탄화수소의 아미노탄화수소로의 직접 아미노화 방법 - Google Patents

수소의 전기화학적 분리 및 수소의 물로의 전기화학적 반응을 포함하는, 탄화수소의 아미노탄화수소로의 직접 아미노화 방법 Download PDF

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KR101753922B1
KR101753922B1 KR1020127003641A KR20127003641A KR101753922B1 KR 101753922 B1 KR101753922 B1 KR 101753922B1 KR 1020127003641 A KR1020127003641 A KR 1020127003641A KR 20127003641 A KR20127003641 A KR 20127003641A KR 101753922 B1 KR101753922 B1 KR 101753922B1
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hydrogen
hydrocarbons
membrane
amino
hydrocarbon
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KR20120046742A (ko
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페트르 쿠바넥
알렉산더 판첸코
안드레아스 피셔
토마스 하이데만
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바스프 에스이
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/02Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of hydrogen atoms by amino groups
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00Electrolytic production of organic compounds
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00Electrolytic production of organic compounds
    • C25B3/01Products
    • C25B3/09Nitrogen containing compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2256/00Main component in the product gas stream after treatment
    • B01D2256/16Hydrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/10Single element gases other than halogens
    • B01D2257/108Hydrogen
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
KR1020127003641A 2009-07-10 2010-07-07 수소의 전기화학적 분리 및 수소의 물로의 전기화학적 반응을 포함하는, 탄화수소의 아미노탄화수소로의 직접 아미노화 방법 Active KR101753922B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09165224 2009-07-10
EP09165224.8 2009-07-10
PCT/EP2010/059710 WO2011003933A2 (de) 2009-07-10 2010-07-07 Verfahren zur direktaminierung von kohlenwasserstoffen zu aminokohlenwasserstoffen mit elektrochemischer abtrennung von wasserstoff und elektrochemischer umsetzung des wasserstoffs zu wasser

Publications (2)

Publication Number Publication Date
KR20120046742A KR20120046742A (ko) 2012-05-10
KR101753922B1 true KR101753922B1 (ko) 2017-07-04

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KR1020127003641A Active KR101753922B1 (ko) 2009-07-10 2010-07-07 수소의 전기화학적 분리 및 수소의 물로의 전기화학적 반응을 포함하는, 탄화수소의 아미노탄화수소로의 직접 아미노화 방법

Country Status (10)

Country Link
US (1) US8642810B2 (https=)
EP (1) EP2451770B1 (https=)
JP (1) JP5800808B2 (https=)
KR (1) KR101753922B1 (https=)
CN (1) CN102548953B (https=)
BR (1) BR112012000625A2 (https=)
ES (1) ES2533702T3 (https=)
HU (1) HUE024550T2 (https=)
PT (1) PT2451770E (https=)
WO (1) WO2011003933A2 (https=)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PT104812A (pt) * 2009-11-06 2011-05-06 Cuf Qu Micos Ind S A Reactor catal?tico de membrana com bombagem electroqu?mica de hidrog?nio ou de oxig?nio e suas aplica??es
WO2013131864A1 (de) 2012-03-06 2013-09-12 Basf Se Verfahren zur herstellung von aminokohlenwasserstoffen durch direktaminierung von kohlenwasserstoffen
WO2013131723A1 (de) 2012-03-06 2013-09-12 Basf Se Verfahren zur herstellung von aminokohlenwasserstoffen durch direktaminierung von kohlenwasserstoffen
PT106860A (pt) * 2013-03-28 2014-09-29 Cuf Químicos Ind S A Conjunto elétrodos/eletrólito, reator e método para a aminação direta de hidrocarbonetos
US9770688B2 (en) * 2015-10-22 2017-09-26 King Fahd University Of Petroleum And Minerals Si—Y nanocomposite membrane and methods of making and use thereof
JP6691247B1 (ja) * 2019-01-22 2020-04-28 東京瓦斯株式会社 反応装置及び燃料電池発電システム
CN115710185B (zh) * 2021-08-23 2024-05-03 中国石油化工股份有限公司 利用金属碳化物催化剂生产甲胺的方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006286397A (ja) 2005-03-31 2006-10-19 Espec Corp 固体電解質膜構造体とその製造方法、イオン伝導度測定装置
JP2008513336A (ja) 2004-09-14 2008-05-01 本田技研工業株式会社 水素分離方法及び装置
JP2009506090A (ja) 2005-08-30 2009-02-12 ビーエーエスエフ ソシエタス・ヨーロピア 炭化水素の直接アミノ化

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB738515A (en) 1952-04-01 1955-10-12 Rohm & Haas Improvements in or relating to a process of producing amines
US3919155A (en) 1970-12-18 1975-11-11 Du Pont Synthesis of aromatic amines by reaction of aromatic compounds with ammonia
US3929889A (en) 1971-02-16 1975-12-30 Du Pont Synthesis of aromatic amines by reaction of aromatic compounds with ammonia
US4031106A (en) 1973-12-19 1977-06-21 E. I. Du Pont De Nemours And Company Synthesis of aromatic amines by reaction of aromatic compounds with ammonia
US4001260A (en) 1973-12-19 1977-01-04 E. I. Du Pont De Nemours And Company Synthesis of aromatic amines by reaction of aromatic compounds with ammonia
HUP0004613A3 (en) 1997-08-21 2001-05-28 Huntsman Ici Chemicals Llc Sal Process for the production of aromatic amines
US5879828A (en) * 1997-10-10 1999-03-09 Minnesota Mining And Manufacturing Company Membrane electrode assembly
JP3978757B2 (ja) * 1998-08-05 2007-09-19 株式会社ジーエス・ユアサコーポレーション 燃料電池用ガス拡散電極−電解質膜接合体およびその製造方法
AU5014900A (en) 1999-05-13 2000-12-05 Bayer Aktiengesellschaft Amination of aromatic hydrocarbons and heterocyclic analogs thereof
JP3740677B2 (ja) * 2002-10-31 2006-02-01 長一 古屋 ガス拡散電極及びその製造方法
DE112006003579T5 (de) * 2005-12-28 2009-01-29 Hitachi, Ltd. Katalysator mit einer Dehydrierungsfunktion oder Hydrierungsfunktion, Brennstoffzelle unter Verwendung des Katalysators und Wasserstoff-Speicher/Zufuhr-Vorrichtung
EP1989172B1 (de) 2006-02-24 2011-09-21 Basf Se Direktaminierung von kohlenwasserstoffen
KR20080104336A (ko) 2006-02-24 2008-12-02 바스프 에스이 탄화수소의 직접 아미노화
JP2007287357A (ja) * 2006-04-12 2007-11-01 Denso Corp 熱再生型の燃料電池システムならびに燃料電池の燃料循環方法
CN101489978A (zh) 2006-07-21 2009-07-22 巴斯夫欧洲公司 烃的直接胺化方法
US20080199774A1 (en) * 2007-02-20 2008-08-21 Commonwealth Scientific And Industrial Research Organisation Membrane electrode assembly with electrode support
CN101903097A (zh) 2007-12-21 2010-12-01 巴斯夫欧洲公司 制备胺的方法
CN101903096B (zh) 2007-12-21 2013-04-03 巴斯夫欧洲公司 生产胺的方法
WO2009080515A1 (de) 2007-12-21 2009-07-02 Basf Se Verfahren zur herstellung eines amins
CN101903095B (zh) 2007-12-21 2013-07-10 巴斯夫欧洲公司 制备胺的方法
US8293945B2 (en) 2007-12-21 2012-10-23 Basf Se Method for producing an amine
CN101903093A (zh) 2007-12-21 2010-12-01 巴斯夫欧洲公司 制备胺的方法
JP2011506530A (ja) 2007-12-21 2011-03-03 ビーエーエスエフ ソシエタス・ヨーロピア アミンの製造方法
JP5656826B2 (ja) 2008-04-08 2015-01-21 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se メタン及びメタン含有混合物を脱水素芳香族化するための触媒
JP2011526328A (ja) 2008-06-30 2011-10-06 ビーエーエスエフ ソシエタス・ヨーロピア 炭化水素の電気化学的直接アミノ化法
WO2010115765A1 (de) 2009-04-06 2010-10-14 Basf Se Verfahren zur umsetzung von erdgas zu aromaten mit elektrochemischer abtrennung von wasserstoff
ES2529554T3 (es) 2009-04-06 2015-02-23 Basf Se Procedimiento para la transformación de gas natural en compuestos aromáticos con separación electroquímica de hidrógeno con generación de corriente eléctrica e hidrógeno
WO2010115747A1 (de) 2009-04-06 2010-10-14 Basf Se Verfahren zur umsetzung von erdgas zu aromaten mit elektrochemischer abtrennung von wasserstoff und elektrochemischer umsetzung des wasserstoffs zu wasser
EA020793B9 (ru) 2009-04-06 2015-05-29 Басф Се Способ электрохимического отделения водорода из реакционной смеси
WO2011003932A2 (de) 2009-07-10 2011-01-13 Basf Se Verfahren zur direktaminierung von kohlenwasserstoffen zu aminokohlenwasserstoffen mit elektrochemischer abtrennung von wasserstoff
WO2011003934A2 (de) 2009-07-10 2011-01-13 Basf Se Verfahren zur direktaminierung von kohlenwasserstoffen zu aminokohlenwasserstoffen mit elektrochemischer abtrennung von wasserstoff

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008513336A (ja) 2004-09-14 2008-05-01 本田技研工業株式会社 水素分離方法及び装置
JP2006286397A (ja) 2005-03-31 2006-10-19 Espec Corp 固体電解質膜構造体とその製造方法、イオン伝導度測定装置
JP2009506090A (ja) 2005-08-30 2009-02-12 ビーエーエスエフ ソシエタス・ヨーロピア 炭化水素の直接アミノ化

Also Published As

Publication number Publication date
WO2011003933A2 (de) 2011-01-13
WO2011003933A3 (de) 2011-05-19
CN102548953A (zh) 2012-07-04
KR20120046742A (ko) 2012-05-10
HUE024550T2 (en) 2016-02-29
JP5800808B2 (ja) 2015-10-28
ES2533702T3 (es) 2015-04-14
JP2012532984A (ja) 2012-12-20
EP2451770B1 (de) 2015-01-07
CN102548953B (zh) 2014-10-08
EP2451770A2 (de) 2012-05-16
BR112012000625A2 (pt) 2016-02-10
PT2451770E (pt) 2015-03-04
US20120107707A1 (en) 2012-05-03
US8642810B2 (en) 2014-02-04

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